钢铁项目环评报告 - 4空气环境影响评价

山东钢铁集团有限公司日照钢铁精品基地项目变更环境影响报告书4空气环境影响评价PAGE1山东省环科院环境科技有限公司4空气环境影响评价4.1污染源调查4.1.1调查范围本项目排放的主要大气污染物包括二氧化硫、氮氧化物、颗粒物等，大气环境评价范围是以焦炉为中心，边长26km的矩形范围。本次评价将对评价区域内排放SO2、NOx、烟尘的污染源进行调查。根据调查，评价区域内主要污染源排放情况见表4.1-1和图4.1-1。表4.1-1污染源调查表序号单位名称主要大气污染物排放量（t/a）SO2NOX颗粒物1山东石大科技石化有限公司64.17298.55402日照三木冶金矿业有限公司23.512.1428.743日照钢铁控股集团有限公司12589.68418579.797663.9244山东金石沥青股份有限公司13.716.71.0245中粮黄海粮油工业（山东）有限公司131.03896.338.5656日照岚桥港口石化有限公司52.24432.1233.157山东昌华实业发展有限公司3.62.566.28日照岚星化工工业有限公司3.80.882.79山东岚山孚宝仓储有限公司0.0860.81410日照铸福实业有限公司36.8173.632334.8合计4.1.2污染源评价评价标准采用《环境空气质量标准》(GB3095-2012)中二级标准的日均浓度值为环境空气污染源评价标准：SO2：0.15mg/m3，NO2：0.08mg/m3、PM10：0.15mg/m3。评价方法采用等标污染负荷法对评价区内主要污染源和主要污染物进行评价，计算公式为：(1)某污染物的等标污染负荷Pi式中：Pi—第i种污染物的等标污染负荷，m3/a；Qi—第i种污染物的排放量，t/a；Coi—第i种污染物的大气环境质量标准限值，mg/m3；(2)某污染源的等标污染负荷Pn式中：Pn—第n个污染源的等标污染负荷，m3/a；(3)整个区域的等标污染负荷P式中：P—某区域所有污染源等标污染负荷之和，m3/a；(4)某污染源在区域中的污染负荷比Kn式中：Kn—某污染源在区域中的污染负荷之比；(5)某污染物在区域中的污染负荷比Ki式中：Ki—某污染物在区域中的污染负荷之比。评价结果各污染源、各污染物在评价区的等标污染负荷及污染负荷比见表4.1-2。表4.1-2污染物评价结果表序号污染源名称污染物的污染负荷(×109污染源等标污染负荷(×109污染源负荷比(%)名次SO2NOx颗粒物1山东石大科技石化有限公司427.83731.9266.74426.40.55232日照三木冶金矿业有限公司156.7151.8191.6500.10.06263日照钢铁控股集团有限公司83931.2232247.4471092.8787271.498.19414山东金石沥青股份有限公司91.3208.86.8306.90.03875中粮黄海粮油工业（山东）有限公司873.61204.157.12134.80.26656日照岚桥港口石化有限公司348.3401.31554.32303.90.28847山东昌华实业发展有限公司243241.397.30.01288日照岚星化工工业有限公司25.3111854.30.00799山东岚山孚宝仓储有限公司0.610.2010.80.0011010日照铸福实业有限公司245.32170.422324647.70.582污染物污染负荷(×109m3/a)86124.1240168.9475460.6801753.6100污染物负荷比(%)10.7429.9659.30污染物位次321评价范围内等标污染负荷最大的是日照钢铁控股集团有限公司，污染源负荷比为98.194%，是评价区内主要污染源。评价区域内SO2、NOX、烟尘等标污染负荷比分别为10.74%、29.96%和59.30%，颗粒物为主要污染物。4.2环境空气质量现状监测与评价4.2.1环境空气质量现状监测监测布点根据本工程特点及本项目厂址周围环境情况、敏感点，考虑气象条件及敏感点，本次现状监测共布设14个监测点，同时收集岚山区环保分局例行监测点近三年监测数据。其中6#、12#目前已搬迁，现状监测时尚未搬迁。监测点情况见表4.2-1和图4.2-1。表4.2-1环境空气质量现状监测布点一览表序号名称方位距离km意义备注1#高旺庄NW2800主导风向侧风向，敏感点原报告监测点位2#相家结庄W4200主导风向侧风向，敏感点3#黄家峪W8200主导风向侧风向，敏感点4#南夏家村SW7200主导风向侧风向，敏感点5#桥南头村SW6600主导风向下风向，敏感点6#韩家村（已搬迁）S3000主导风向下风向，敏感点7#仁家村SW10000主导风向下风向，敏感点8#车庄村SW8800主导风向下风向，敏感点9#东潘家村S4800主导风向侧风向，敏感点10#岚山头街道S9000主导风向侧风向，敏感点11#东南营村N150主导风向上风向，敏感点本次环评补充点位12#东湖二村（已搬迁）NW500厂址附近敏感点13#泥田沟村W700厂址附近敏感点14#高屯村SSW200主导风向下风向，厂址附近敏感点监测项目和监测方法SO2(小时值、日均值)、NO2(小时值、日均值)、TSP(日均值)、PM10(日均值)、PM2.5(日均值)、CO(小时值)、氟化物(小时值、日均值)、铅(日均值)、汞(日均值)、氨(小时值)、苯并[a]芘(小时值)、氯化氢(小时值)、硫化氢(小时值)、氰化氢(小时值)、酚类(小时值)、苯可溶物(小时值)、非甲烷总烃(小时值)、二噁英共18项。监测时同步进行气压、气温、风向、风速、天气情况等气象要素的观测。监测方法见表4.2-2。表4.2-2环境空气监测分析方法项目名称标准代号标准名称检出限二氧化硫HJ482-2009甲醛吸收吸收副玫瑰苯胺分光光度法小时0.007mg/m3日均0.004mg/m3二氧化氮HJ479-2009盐酸萘乙二胺分光光度法小时0.005mg/m3日均0.003mg/m3PM10、PM2.5HJ618-2011重量法0.010mg/m3TSPGB/T15432-1995重量法0.001mg/m3氟化物HJ480-2009滤膜采样氟离子选择电极法小时:0.9µg/m3日均:0.5µg/m3COGB/T9801-1988非分散红外法0.3mg/m3铅及其化合物HJ657-2013ICP-MS0.001µg/m3汞及其化合物《空气和废气监测分析方法》（第四版）原子荧光分光光度法0.004µg/m3酚类HJ32-19990.01mg/m3苯可溶物HJ690-2014重量法0.02mg/m3苯并[a]芘GB/T15439-1995高效液相色谱法0.0002µg/m3氨HJ533-2009纳氏试剂分光光度法0.02mg/m3氯化氢HJ549-2016离子色谱法0.01mg/m3硫化氢GB/T11742-1989亚甲蓝分光光度法0.002mg/m3氰化氢HJ28-1999异烟酸-吡唑啉酮分光光度法0.001mg/m3非甲烷总烃HJ/T38-1999气相色谱法0.14mg/m监测时间与监测频率（1）二噁英采样时间：2017年3月5日；监测频率：监测一天，采样一次。监测单位：通标标准技术服务（上海）有限公司（2）其它因子监测时间：2017年3月1日—2017年3月7日。SO2、NO2、TSP、PM10、PM2.5连续监测7天，SO2、NO2小时值每天监测4次，时间分别为2:00、8:00、14:00、20:00，每次采样60min；SO2、NO2、PM10、PM2.5、氟化物日均值保证20h以上采样时间；TSP日均值保证24h采样时间。其他特征污染因子连续监测3天,每天监测4次，时间分别为2:00、8:00、14:00、20:00，每次采样60min。1#～6#、9#、11#～13#：SO2、NO2、TSP、PM10、PM2.5、CO、氟化物、铅、汞、氨、苯并[a]芘、氯化氢、硫化氢、氰化氢、酚类、苯可溶物、非甲烷总烃。7#、8#、10#：SO2、NO2、TSP、PM10、PM2.5。14#：二噁英。检测单位：山东省分析测试中心。监测期间气象参数监测期间气象参数见表4.2-3。表4.2-3监测期间气象参数气气象条件时间日期气温(℃)气压(hPa)风速(m/s)风向天气情况03.0102:008.21009.21.9N晴08:006.41009.61.7NW14:005.51009.12.4N20:004.21012.53.6NW03.0202:000.11018.42.5W晴08:001.21018.21.7W14:0010.61014.61.8N20:008.21013.82.9SW03.0302:005.51011.12.3W多云08:006.21011.91.9W14:0011.91008.11.7SW20:006.41008.21.5NE03.0402:005.81009.31.3E晴08:006.21010.40.8N14:0011.71008.41.1NE20:007.21009.20.6N03.0502:006.41010.41.8N晴08:007.71010.62.7N14:009.61011.22.8N20:003.41015.43.1N03.0602:000.11016.21.9SW晴08:001.21016.32.1W14:0010.51011.53.1W20:007.31010.22.6W03.0702:002.61012.33.5N晴08:001.61016.22.2NE14:005.31014.42.9N20:002.51015.31.2NW监测结果SO2现状监测结果见表4.2-4，NO2现状监测结果见表4.2-5，CO现状监测结果见表4.2-6，氟化物现状监测结果见表5.1-6，各监测点监测结果统计情况见表4.1-7。表4.2-4（1）SO2监测结果表监测日期监测时间SO2（mg/m3）1#2#3#4#5#6#03.0102:000.0170.0220.0190.0220.0270.02808:000.0210.0360.0210.0290.0140.03414:000.0290.0270.0150.0160.0200.02420:000.0250.0470.0400.0380.0350.035日均值0.0280.0340.0270.0280.0290.03103.0202:000.0150.0340.0240.0320.0270.02308:000.0480.0510.0320.0650.0440.02814:000.0180.0220.0180.0340.0230.02720:000.0370.0500.0540.0570.0410.099日均值0.0340.0420.0320.0410.0330.04103.0302:000.0170.0320.0360.0350.0240.05108:000.0230.0280.0290.0310.0560.03214:000.0410.0240.0170.0210.0300.02820:000.0600.0670.0660.0590.0760.056日均值0.0370.0380.0380.0330.0450.04303.0402:000.0400.0440.0350.0440.0510.03908:000.0380.0360.0280.0670.0270.08414:000.0280.0240.0120.0250.0130.02320:000.0400.0530.0230.0430.0460.044日均值0.0350.0390.0290.0310.0330.04603.0502:000.0330.0380.0290.0310.0340.03608:000.0450.0420.0470.0280.0380.05614:000.0220.0180.0230.0180.0350.04120:000.0380.0330.0400.0420.0640.032日均值0.0380.0350.0320.0310.0430.03703.0602:000.0290.0230.0400.0140.0120.05408:000.0360.0310.0130.0400.0250.03214:000.0250.0190.0340.0220.0210.01220:000.0410.0460.0510.0760.0460.077日均值0.0340.0300.0310.0390.0300.04503.0702:000.0500.0360.0430.0560.0240.04408:000.0300.0520.0340.0300.0600.03614:000.0150.0170.0320.0270.0230.01420:000.0910.0710.0570.0600.0510.095日均值0.0440.0420.0390.0390.0370.043表4.2-4（2）SO2监测结果表监测日期监测时间SO2（mg/m3）7#8#9#10#11#12#13#03.0102:000.0240.0280.0350.0320.0220.0220.03108:000.0340.0230.0670.0280.0260.0260.02614:000.0100.0280.0310.0340.0170.0240.02520:000.0450.0460.0360.0520.0140.0460.033日均值0.0340.0330.0380.0310.0260.0290.02803.0202:000.0230.0300.0310.0300.0180.0420.02408:000.0280.0420.0140.0390.0220.0710.03114:000.0140.0210.0360.0180.0150.0110.01420:000.0860.0320.0590.0940.0870.0400.043日均值0.0350.0300.0310.0450.0370.0470.02603.0302:000.0590.0220.0330.0470.0370.0330.04008:000.0280.0400.0330.0400.0350.0520.02814:000.0240.0320.0280.0290.0340.0310.03220:000.0430.0950.0440.0800.0660.0400.056日均值0.0390.0470.0370.0490.0420.0370.03703.0402:000.0310.0440.0230.0380.0430.0300.05108:000.0120.0370.0270.0460.0410.0290.05914:000.0330.0220.0350.0200.0660.0380.03420:000.0340.0770.0410.0460.0230.0580.021日均值0.0290.0430.0300.0370.0440.0410.03603.0502:000.0310.0380.0590.0390.0260.0360.02808:000.0250.0580.0380.0580.0360.0400.03414:000.0230.0130.0210.0260.0240.0320.01320:000.0460.0250.0310.0340.0470.0770.037日均值0.0280.0330.0340.0370.0320.0440.02903.0602:000.0370.0470.0250.0230.0350.0400.02208:000.0460.0310.0570.0400.0640.0410.05214:000.0150.0350.0330.0310.0270.0240.02320:000.0830.0670.0380.0400.0490.0400.043日均值0.0420.0420.0350.0290.0390.0370.03303.0702:000.0270.0380.1060.0410.0240.0420.04008:000.0340.0270.0380.0330.0300.0230.02814:000.0110.0340.0250.0190.0200.0160.02720:000.0510.0370.0310.0920.0530.0320.041日均值0.0330.0320.0380.0420.0350.0360.033表4.2-5（1）NO2监测结果表监测日期监测时间NO2（mg/m3）1#2#3#4#5#6#03.0102:000.0340.0390.0260.0290.0270.02708:000.0280.0420.0430.0350.0410.03814:000.0360.0320.0240.0370.0290.02420:000.0320.0440.0380.0480.0490.042日均值0.0330.0370.0300.0320.0340.03103.0202:000.0440.0310.0240.0390.0280.03308:000.0460.0450.0290.0720.0820.03614:000.0630.0290.0240.0430.0320.03720:000.0810.0520.0770.0580.0460.104日均值0.0530.0390.0350.0500.0410.04803.0302:000.0440.0290.0300.0410.0350.03808:000.0550.0360.0320.0440.0610.04214:000.0480.0330.0310.0300.0380.03720:000.0720.0760.0750.0300.0850.064日均值0.0520.0410.0390.0310.0500.04003.0402:000.0360.0360.0370.0280.0530.02408:000.0450.0710.0410.0910.0580.09014:000.0360.0340.0340.0310.0340.02820:000.0490.0730.0750.0410.0490.039日均值0.0400.0480.0420.0420.0400.04203.0502:000.0310.0370.0280.0290.0410.04008:000.0510.0640.0370.0390.0410.07314:000.0280.0320.0310.0280.0400.04520:000.0420.0550.0500.0550.0730.046日均值0.0370.0430.0370.0340.0460.04603.0602:000.0690.0400.0480.0410.0560.06308:000.0310.0470.0420.0440.0330.03414:000.0300.0300.0320.0330.0300.01720:000.0370.0620.0470.0790.0500.086日均值0.0380.0400.0410.0470.0400.05003.0702:000.0550.0410.0550.0320.0430.05208:000.0320.0570.0380.0420.0630.02414:000.0240.0320.0390.0380.0270.01820:000.0980.0790.0670.0660.0600.110日均值0.0480.0490.0450.0410.0420.045表4.2-5（2）NO2监测结果表监测日期监测时间NO2（mg/m3）7#8#9#10#11#12#13#03.0102:000.0270.0350.0370.0290.0350.0310.03208:000.0440.0330.0510.0430.0320.0320.04514:000.0240.0350.0390.0320.0260.0290.02720:000.0530.0410.0350.0530.0480.0450.037日均值0.0360.0350.0420.0360.0330.0340.03603.0202:000.0250.0280.0390.0310.0350.0370.02908:000.0320.0350.0300.0330.0290.0420.03214:000.0200.0320.0320.0250.0240.0490.02620:000.0950.0310.0490.0900.0960.0550.057日均值0.0400.0340.0370.0390.0420.0400.03503.0302:000.0460.0350.0370.0420.0410.0390.04508:000.0390.0440.0340.0350.0580.0610.03114:000.0490.0410.0340.0240.0390.0360.03520:000.0700.1160.1000.0620.0900.0450.035日均值0.0480.0560.0470.0380.0520.0420.03803.0402:000.0260.0720.0520.0420.0530.0370.03808:000.0500.0710.0420.0740.0510.0440.06314:000.0220.0430.0570.0300.0760.0420.03320:000.0260.0880.0390.0430.0300.0760.029日均值0.0360.0570.0450.0420.0510.0510.04003.0502:000.0280.0490.0320.0350.0330.0440.02408:000.0370.0420.0830.0390.0440.0390.03114:000.0340.0340.0350.0290.0350.0340.02920:000.0420.0660.0450.0450.0480.0860.042日均值0.0330.0420.0400.0360.0390.0490.03403.0602:000.0430.0540.0330.0320.0440.0520.04308:000.0540.0380.0420.0440.0730.0650.02814:000.0270.0260.0320.0320.0340.0330.02320:000.0870.0450.0590.0380.0520.0440.059日均值0.0480.0390.0370.0340.0470.0460.03903.0702:000.0460.0430.0640.0420.0640.0340.04408:000.0410.0370.0410.0260.0410.0430.03614:000.0200.0310.0310.0270.0310.0240.03220:000.0830.0370.0460.1010.0600.0670.052日均值0.0430.0380.0440.0470.0510.0440.040表4.2-6（1）TSP监测结果表监测日期监测时间TSP（mg/m3）1#2#3#4#5#6#03.01日均值0.1570.1340.1820.2640.2420.19503.02日均值0.1600.1860.2020.2350.2440.30203.03日均值0.3020.2970.3940.3560.2900.31903.04日均值0.3270.3430.3990.3810.2850.34603.05日均值0.1880.1790.2040.2130.1620.29803.06日均值0.1940.1740.2250.2040.1660.21603.07日均值0.1530.1690.1950.2190.1280.220表4.2-6（2）TSP监测结果表监测日期监测时间TSP（mg/m3）7#8#9#10#11#12#13#03.01日均值0.2320.2240.2290.1660.1570.1350.20203.02日均值0.3550.1680.4540.2300.2680.1750.23503.03日均值0.4060.3730.2640.3000.3060.2550.32803.04日均值0.4770.4150.3480.3130.4270.4270.39503.05日均值0.2770.2300.2400.2250.2170.2160.28303.06日均值0.2090.2090.1950.2030.2600.2150.19603.07日均值0.2160.1850.1320.1670.2330.1860.231表4.2-7（1）PM10监测结果表监测日期监测时间PM10（mg/m3）1#2#3#4#5#6#03.01日均值0.0890.0760.0940.1180.1270.11103.02日均值0.0850.0850.1080.1320.1540.15503.03日均值0.1500.1520.1840.1920.1530.16403.04日均值0.1390.1950.2050.1980.1350.18603.05日均值0.0970.1180.1070.1100.1030.14303.06日均值0.0900.0970.1070.1040.0930.12203.07日均值0.0690.0790.0970.1260.0890.118表4.2-7（2）PM10监测结果表监测日期监测时间PM10（mg/m3）7#8#9#10#11#12#13#03.01日均值0.1380.1080.1000.0880.0820.0690.10403.02日均值0.1800.0860.2580.1010.1360.0970.12503.03日均值0.2150.1910.1380.1720.1660.1440.17003.04日均值0.2460.2370.2100.2160.2220.2140.20703.05日均值0.1490.1220.1180.1020.1170.1040.12403.06日均值0.1150.1170.1000.1010.1350.0920.11303.07日均值0.1230.0830.0780.0830.1370.0840.110表4.2-8（1）PM2.5监测结果表监测日期监测时间PM2.5（mg/m3）1#2#3#4#5#6#03.01日均值0.0570.0500.0570.0730.0840.06403.02日均值0.0580.0590.0660.0780.1090.10303.03日均值0.1010.0980.1110.1160.1030.10503.04日均值0.0840.1200.1180.1220.0920.11803.05日均值0.0660.0740.0640.0670.0720.09203.06日均值0.0600.0580.0580.0700.0610.07803.07日均值0.0400.0500.0480.0860.0560.084表4.2-8（2）PM2.5监测结果表监测日期监测时间PM2.5（mg/m3）7#8#9#10#11#12#13#03.01日均值0.1010.0790.0710.0560.0560.0480.06903.02日均值0.1160.0620.1520.0650.0990.0600.07803.03日均值0.1270.1270.1040.1050.1140.1020.09703.04日均值0.1400.1370.1280.1520.1320.1260.12503.05日均值0.0960.0850.0820.0690.0780.0660.06803.06日均值0.0720.0680.0620.0680.0790.0610.06303.07日均值0.0740.0570.0540.0590.0840.0630.070表4.2-9CO监测结果表监测日期监测时间CO（mg/m3）1#2#3#4#5#6#9#11#12#13#03.0202:001.208:001.914:001.820:000.603.0302:001.01.01.51.308:001.114:001.020:001.403.0402:000.81.01.40.908:001.614:001.420:001.21.01.50.7表4.2-10氨监测结果表监测日期监测时间氨（mg/m3）1#2#3#4#5#6#9#11#12#13#03.0202:000.030.040.040.050.050.050.070.060.070.0508:000.020.050.04未检出0.050.060.080.080.050.0814:000.02未检出0.070.030.040.070.060.050.070.0920:00未检出0.020.060.040.080.150.0103.0302:000.020.040.030.050.060.070.080.050.060.0908:00未检出0.030.030.060.090.080.1514:00未检出0.12未检出0.080.110.090.1820:000.03未检出0.060.060.050.050.100.080.110.0803.0402:000.040.030.050.060.050.070.060.070.070.1008:00未检出0.070.050.070.080.150.1314:000.050.050.030.050.040.080.1420:000.030.030.040.080.030.140.070.120.080.09表4.2-11硫化氢监测结果表监测日期监测时间硫化氢（mg/m3）1#2#3#4#5#6#9#11#12#13#03.0202:00未检出0.002未检出未检出未检出未检出未检出未检出未检出未检出08:00未检出未检出未检出未检出未检出未检出未检出未检出未检出0.00214:00未检出未检出未检出未检出0.0020.0020.0030.0020.002未检出20:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出03.0302:000.0020.002未检出未检出未检出未检出未检出未检出未检出未检出08:00未检出未检出未检出0.0020.002未检出未检出0.002未检出未检出14:00未检出未检出未检出未检出未检出未检出0.002未检出未检出0.00220:00未检出未检出未检出未检出未检出未检出0.002未检出未检出未检出03.0402:00未检出未检出未检出未检出未检出未检出0.002未检出0.0020.00108:00未检出0.002未检出0.002未检出未检出未检出0.002未检出未检出14:000.002未检出未检出0.0020.0020.002未检出未检出未检出0.00220:00未检出未检出未检出未检出未检出未检出0.003未检出未检出0.002表4.2-12氯化氢监测结果表监测日期监测时间氯化氢（mg/m3）1#2#3#4#5#6#9#11#12#13#03.0202:00未检出未检出未检出未检出未检出未检出未检出0.01未检出未检出08:00未检出未检出0.03未检出未检出未检出未检出未检出未检出未检出14:00未检出未检出未检出未检出未检出未检出未检出未检出未检出0.0320:00未检出未检出未检出未检出0.01未检出未检出未检出未检出未检出03.0302:00未检出未检出未检出未检出0.04未检出未检出未检出未检出未检出08:00未检出未检出0.010.02未检出未检出未检出未检出未检出未检出14:00未检出未检出未检出未检出0.04未检出未检出未检出未检出未检出20:000.01未检出未检出未检出未检出未检出未检出未检出未检出未检出03.0402:00未检出未检出未检出未检出未检出未检出0.020.01未检出未检出08:00未检出未检出0.01未检出未检出未检出0.01未检出未检出未检出14:00未检出未检出未检出未检出未检出未检出未检出未检出未检出0.0120:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出表4.2-13酚类监测结果表监测日期监测时间酚类（mg/m3）1#2#3#4#5#6#9#11#12#13#03.0202:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出08:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出14:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出20:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出03.0302:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出08:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出14:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出20:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出03.0402:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出08:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出14:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出20:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出表4.2-14氟化物监测结果表监测日期监测时间氟化物（µg/m3）1#2#3#4#5#6#9#11#12#13#03.0202:001.008:001.714:001.720:001.4日均值1.51.01.92.003.0302:001.41.01.11.008:001.12.01.31.614:001.81.01.31.420:001.41.01.41.4日均值1.303.0402:001.51.01.61.008:002.014:001.420:001.71.01.51.2日均值1.5表4.2-15氰化氢监测结果表监测日期监测时间氰化氢（mg/m3）1#2#3#4#5#6#9#11#12#13#03.0202:000.002未检出未检出未检出0.001未检出0.002未检出未检出未检出08:000.001未检出未检出0.002未检出未检出0.003未检出0.002未检出14:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出20:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出03.0302:00未检出未检出未检出0.001未检出未检出未检出未检出未检出0.00108:000.001未检出未检出未检出未检出未检出0.001未检出0.001未检出14:00未检出未检出未检出未检出0.001未检出未检出未检出未检出未检出20:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出03.0402:00未检出未检出未检出未检出未检出未检出0.001未检出未检出未检出08:000.001未检出未检出未检出未检出未检出未检出未检出未检出未检出14:00未检出未检出未检出未检出未检出未检出未检出未检出0.001未检出20:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出表4.2-16酚类监测结果表监测日期监测时间酚类（mg/m3）1#2#3#4#5#6#9#11#12#13#03.0202:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出08:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出14:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出20:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出03.0302:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出08:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出14:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出20:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出03.0402:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出08:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出14:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出20:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出表4.2-17苯可溶物监测结果表监测日期监测时间苯可溶物（mg/m3）1#2#3#4#5#6#9#11#12#13#03.0202:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出08:00未检出未检出未检出未检出未检出未检出未检出0.02未检出未检出14:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出20:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出03.0302:00未检出未检出未检出未检出未检出未检出未检出未检出未检出0.0208:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出14:00未检出未检出未检出未检出未检出未检出未检出未检出未检出0.0220:00未检出未检出未检出未检出未检出未检出未检出0.02未检出未检出03.0402:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出08:00未检出未检出未检出未检出未检出未检出未检出未检出未检出未检出14:00未检出未检出未检出未检出未检出未检出未检出0.02未检出未检出20:00未检出未检出未检出未检出未检出未检出未检出未检出未检出0.02表4.2-18汞及其化合物监测结果表监测日期监测时间汞及其化合物（µg/m3）1#2#3#4#5#6#9#11#12#13#03.02日均值0.0310.0350.0190.0360.0300.0220.0430.0230.0170.01903.03日均值0.0210.0180.0330.0420.0160.0270.0260.0400.0460.03403.04日均值0.0420.0270.0280.0240.0350.0260.0410.0250.0320.021表4.2-19铅及其化合物监测结果表监测日期监测时间铅及其化合物（µg/m3）1#2#3#4#5#6#9#11#12#13#03.02日均值0.0730.0350.1010.1440.1590.0780.1430.1060.0320.13103.03日均值0.0510.0580.1200.0970.0800.0700.0770.0780.690.099803.04日均值0.0620.0470.0680.0290.0370.1160.0360.0320.0450.032表4.2-20非甲烷总烃监测结果表监测日期监测时间非甲烷总烃（mg/m3）氨1#2#3#4#5#6#9#11#12#13#03.0202:000.870.710.570.670.840.740.840.910.750.8508:000.630.620.530.760.510.740.830.700.921.0814:000.570.510.541.010.850.910.950.890.770.8020:000.550.810.561.000.960.960.880.780.941.1503.0302:000.850.650.600.950.990.800.670.750.901.1108:000.620.640.570.840.800.720.680.840.881.0014:001.000.610.850.960.520.901.070.580.710.9120:000.580.760.540.800.550.781.060.630.690.6603.0402:001.001.150.900.890.510.600.860.850.691.1408:000.560.600.520.690.560.920.820.691.050.6914:000.790.580.700.800.951.160.920.550.790.6820:000.610.680.821.160.560.861.140.710.840.81表4.2-21苯并[a]芘监测结果表监测日期监测时间苯并[a]芘（µg/m3）1#2#3#4#5#6#9#11#12#13#03.02日均值0.00300.00220.00840.00570.00230.00860.00410.01580.00270.005003.03日均值0.00510.00410.00490.00510.00520.003200.00400.00670.00260.004503.04日均值0.00350.00290.00340.00100.00300.00270.00470.00330.00270.0028表4.2-22二噁英监测结果表监测日期仁家村（pg-TEQ/m3）高屯村（pg-TEQ/m3）2080.212030.0312040.10山东钢铁集团有限公司日照钢铁精品基地项目变更环境影响报告书4空气环境影响评价4山东省环境保护科学研究设计院表4.2-23（1）环境空气现状监测结果汇总表项目SO2（mg/m3）NO2（mg/m3）TSP（mg/m3）PM10（mg/m3）PM2.5（mg/m3）CO（mg/m3）氨（mg/m3）硫化氢（mg/m3）氯化氢（mg/m3）小时值日均值日均值日均值日均值日均值日均值小时值小时值小时值小时值1#0.015～0.0910.028～0.0440.024～0.0980.033～0.0530.15～0.330.069～0.150.04～0.1010.6～1.9未检出～0.05未检出～0.002未检出～0.012#0.017～0.0710.03～0.0420.029～0.0790.037～0.0490.13～0.340.0.76～0.1950.05～0.120.8～1.4未检出～0.12未检出～0.002未检出3#0.012～0.0660.027～0.0390.024～0.0770.03～0.0450.18～0.400.094～0.2050.048～0.1180.7～1.7未检出～0.07未检出未检出～0.034#0.014～0.0760.028～0.0410.028～0.0910.031～0.050.20～0.380.104～0.1980.067～0.1220.7～1.7未检出～0.15未检出～0.002未检出～0.025#0.012～0.0760.029～0.0450.027～0.0850.034～0.050.13～0.290.089～0.1540.056～0.1091～3.30.03～0.12未检出～0.002未检出～0.046#0.012～0.0990.031～0.0460.017～0.110.031～0.050.20～0.350.111～0.1860.064～0.1180.6～2.20.05～0.15未检出～0.002未检出7#0.01～0.0860.028～0.0420.02～0.0950.033～0.0480.21～0.480.115～0.2460.072～0.148#0.013～0.0950.03～0.0470.026～0.120.034～0.0570.17～0.420.083～0.2370.057～0.1379#0.014～0.1060.03～0.0380.03～0.100.037～0.0470.13～0.450.078～0.2580.054～0.1520.6～1.90.06～0.13未检出～0.003未检出～0.0210#0.018～0.0940.029～0.0490.024～0.0960.034～0.0470.17～0.310.083～0.2160.056～0.15211#0.014～0.0870.026～0.0440.024～0.0860.033～0.0530.16～0.430.069～0.2140.056～0.1321.1～2.80.05～0.17未检出～0.002未检出～0.0112#0.011～0.0770.029～0.0470.024～0.0860.034～0.0510.14～0.430.069～0.2140.048～0.1260.7～20.05～0.15未检出～0.002未检出13#0.013～0.0590.026～0.0370.023～0.0630.034～0.040.20～0.400.104～0.2070.063～0.1250.6～1.90.05～0.18未检出～0.002未检出～0.03表4.2-23（2）环境空气现状监测结果汇总表项目氟化物（µg/m3）氰化氢（mg/m3）酚类（mg/m3）苯可溶物（mg/m3）汞及其化合物（mg/m3）非甲烷总烃（mg/m3）苯并[a]芘（µg/m3）铅及其化合物（µg/m3）二噁英小时值日均值小时值小时值小时值日均值小时值日均值日均（pg-TEQ/m3）1#1.2～1.91.5～1.6/~0.002//0.021~0.0420.55~10.003~0.00510.051~0.073/2#0.9～1.21～1.2///0.018~0.0350.51~1.150.0022~0.00410.035~0.058/3#1.1～1.81.2～1.4///0.019~0.0330.52~0.90.0034~0.00840.068~0.120/4#1～1.51.2～1.3/~0.002//0.024~0.0420.67~1.60.0010~0.00570.029~0.144/5#1.7～2.41.8～2.2/~0.001//0.016~0.0350.51~0.990.0023~0.00520.037~0.159/6#1.2～2.31.5～1.9/~0.001//0.022~0.0270.6~1.160.0027~0.00860.070~0.116/7#/////////0.14~0.389#1.3～2.61.6～2///0.026~0.0430.67~1.140.0040~0.00470.036~0.143/11#1～1.91.4～1.6///～0.020.023~0.0400.55~0.910.0033~0.01580.032~0.106/12#1.2～2.11.2～1.5/~0.002//0.017~0.0460.69~1.050.0026~0.00270.032~0.69/13#1.2～1.91.3～1.5/~0.001//～0.020.019~0.0340.66~1.150.0028~0.00500.032~0.131/14#/////////0.031~0.21山东钢铁集团有限公司日照钢铁精品基地项目变更环境影响报告书4空气环境影响评价4山东省环科院环境科技有限公司2017年12月，日照焦电关停8座捣固焦炉。关停后，山东钢铁集团日照有限公司委托中持依迪亚（北京）环境检测分析股份有限公司对日照钢铁精品基地项目周边环境进行了苯并[a]芘监测，采样时间为2018年2月10日-2018年2月12日，监测方法和仪器见表4.2-25，监测数据见表4.2-26。表4.2-25监测方法和仪器参数监测方法检出限单位仪器设备苯并[a]芘（日均值）《环境空气苯并[a]芘的测定高效液相色谱法》GB/T15439-19956×10-5μg/m3液相色谱仪表4.2-26监测数据一览表（μg/m3）采样点时间南夏家村东潘家村东南营村泥田沟村200670.0074未检出0.0081200310.00130.00190.0085200200.00410.00070.0080本次评价还收集了岚山区环保分局例行监测点近三年例行监测数据，具体见表4.2-27。该例行监测点位于本项目厂区西南方向约7.5km处。表4.2-27（1）2015年例行监测数据（μg/m3）项目时间SO2NO2PM10PM2.5O31月584313387722月513612780973月4135122621324月3934113601775月393897551776月402584481867月252271491888月242368441889月2425573716810月3638915719011月314175619212月47552489477年均值383510761167注：表中各月份数值为月均值表4.2-27（2）2016年例行监测数据（μg/m3）项目时间SO2NO2PM10PM2.5O31月6256148116672月54459969943月5150122631384月3838134671695月323686431956月292768432027月252064381708月222257251579月2436864718610月2136673911711月3345110669612月39581319982年均值36399860168注：表中各月份数值为月均值表4.2-27（3）2017年例行监测数据（μg/m3）项目时间SO2NO2PM10PM2.5O31月3949124921002月2744113791193月2250100631264月1942116581685月193791471946月122262342117月122052351688月152248281909月1727723418610月2336663413111月2848111559412月37561317966年均值23389253169注：表中各月份数值为月均值4.2.2环境空气质量现状评价评价因子根据项目污染特征和环境空气质量特征，确定评价因子为：SO2、NO2、TSP、PM10、PM2.5、CO、氟化物、铅及其化合物、汞、氨、苯并[a]芘、氯化氢、硫化氢、二噁英。酚类、苯可溶物、氰化氢、非甲烷总烃无环境质量标准值，不再进行评价评价标准SO2、NO2、PM10、TSP、PM2.5、CO执行《环境空气质量标准》（GB3095-2012）二级标准；氟化物、铅及其化合物、汞、H2S、氨、氯化氢执行《工业企业设计卫生标准》（TJ36-79）中“居住区大气中有害物质的最高容许浓度一次值”。评价标准值参见表4.2-28。表4.2-28评价标准值一览表单位：mg/m3评价因子SO2NO2PM10PM2.5TSPCOBaP小时日均小时日均日均日均日均小时日均日均0.5080.150.0750.301042.5×10-6执行标准《环境空气质量标准》（GB3095-2012）二级标准评价因子氟化物铅及其化合物汞H2SNH3氯化氢二噁英0.020.00070.00030.010.20.050.6pg-TEQ/m3执行标准《工业企业设计卫生标准》（TJ36-79）居住区最高容许浓度一次值参照日本环境质量标准评价方法采用单因子指数法进行评价，具体计算公式为：式中：Pi—污染物的单因子指数；Ci—污染因子i的实测浓度值(mg/m3)；Coi—污染因子i的标准值(mg/m3)。评价结果环境空气质量现状评价结果见表4.2-29。表4.2-29环境空气质量现状评价结果一览表点位项目小时平均值日平均值指数范围超标率%指数范围超标率%1#高旺庄SO20.03～0.180——0.19～0.290——NO20.12～0.490——0.41～0.660——TSP——————0.51～1.09282017.3.4PM10——————0.46～10——PM2.5——————0.53～1.35282017.3.3CO0.06～0.190————————氨/～0.250————————硫化氢/～0.20————————氯化氢/～0.20————————汞及其化合物——————0.07～0.140——苯并[a]芘——————1.2～2.041002017.3.3铅及其化合物——————0.07～0.100——氟化物0.06～0.0950————————2#相家结庄SO20.034～0.140——0.2～0.28NO20.15～0.400——0.46～0.61TSP——————0.45～1.14142017.3.4PM10——————0.51～1.3282017.3.4PM2.5——————0.67～1.6142017.3.3CO0.08～0.140————————氨/～0.60————————硫化氢/～0.20————————氯化氢/0————————汞及其化合物——————0.06～0.120——苯并[a]芘——————0.88～1.64672017.3.3铅及其化合物——————0.05～0.080——氟化物0.045～0.060————————3#黄家峪SO20.024～0.130——0.18～0.260——NO20.12～0.390——0.38～0.560——TSP——————0.61～1.33282017.3.4PM10——————0.63～1.37282017.3.4PM2.5——————0.64～1.57282017.3.4CO0.07～0.170————————氨/～0.350————————硫化氢/～0.20————————氯化氢/～0.60————————汞及其化合物——————0.06～0.110——苯并[a]芘——————1.36～3.361002017.3.2铅及其化合物——————0.10～0.170——氟化物0.055～0.090————————4#南夏家村SO20.028～0.150——0.19～0.30——NO20.14～0.460——0.39～0.630——TSP——————0.68～1.27282017.3.4PM10——————0.69～1.32282017.3.4PM2.5——————0.89～1.63572017.3.4CO0.07～0.170————————氨/～0.750————————硫化氢/～0.20————————氯化氢/～0.40————————汞及其化合物——————0.08～0.140——苯并[a]芘——————0.4～2.28572017.3.2铅及其化合物——————0.04～0.210——氟化物0.05～0.0750————0——5#桥南头村SO20.024～0.150——0.19～0.30——NO20.14～0.430——0.43～0.630——TSP——————0.43～0.970——PM10——————0.59～1.03282017.3.4PM2.5——————0.75～1.45572017.3.2CO————————————硫化氢/～0.20————————氨0.15～0.60————————氯化氢/～0.80————————汞及其化合物——————0.05～0.110——苯并[a]芘——————0.92～2.08572017.3.3铅及其化合物——————0.05～0.230——氟化物0.085～0.120————————6#韩家村SO20.024～0.200——0.21～0.310——NO20.085～0.550——0.39～0.630——TSP——————0.65～1.15432017.3.4PM10——————0.74～1.24432017.3.4PM2.5——————0.85～1.57862017.3.4CO0.1～0.330————————氨0.25～0.750————————硫化氢/～0.20————————氯化氢/0————————汞及其化合物——————0.07～0.090——苯并[a]芘——————1.08～3.441002017.3.2铅及其化合物——————0.01～0.170——氟化物0.065～0.130——7#仁家村SO20.02～0.170——0.19～0.280——NO20.1～0.480——0.41～0.60——TSP——————0.70～1.59432017.3.4PM10——————0.77～1.24282017.3.4PM2.5——————0.96～1.87712017.3.4车庄村SO20.026～0.190——0.2～0.310——NO20.13～0.580——0.43～0.710——TSP——————0.56～1.38282017.3.4PM10——————0.55～1.58282017.3.4PM2.5——————0.76～1.83572017.3.4东潘家村SO20.028～0.210——0.2～0.250——NO20.15～0.50——0.46～0.590——TSP0.44～1.51282017.3.2PM100.52～1.72282017.3.2PM2.50.72～2.03572017.3.2CO0.06～0.190——氨0.3～0.650——硫化氢/～0.30——氯化氢/～0.40——氟化物0.065～0.130——苯并[a]芘——————1.6～1.881002017.3.2铅及其化合物——————0.05～0.200——汞及其化合物——————0.08～0.140——岚山头街道SO20.036～0.190——0.19～0.330——NO20.12～0.510——0.43～0.590——TSP——————0.55～1.04142017.3.4PM10——————0.55～1.44282017.3.4PM2.5——————0.75～2.03282017.3.4东南营村SO20.028～0.170——0.17～0.290——NO20.12～0.480——0.41～0.650——TSP——————0.52~1.42282017.3.4PM10——————0.55～1.48282017.3.4PM2.5——————0.75～1.76862017.3.4CO0.11～0.280————————氨0.25～0.850————————硫化氢/～0.20————————氯化氢/～0.20————————汞及其化合物——————0.07～0.130——苯并[a]芘——————1.32～6.321002017.3.2铅及其化合物——————0.05～0.150——氟化物0.05～0.0950————————东湖二村SO20.022～0.150——0.19～0.310——NO20.12～0.430——0.43～0.640——TSP——————0.45~1.42142017.3.4PM10——————0.46～1.43142017.3.4PM2.5——————0.64～1.68282017.3.4CO0.07～0.20————————氨0.25～0.750————————硫化氢/～0.20————————氯化氢/0————————汞及其化合物——————0.06～0.150——苯并[a]芘——————1.04～1.081002017.3.2铅及其化合物——————0.05～0.980——氟化物0.06～0.1050————————13#泥田沟村SO20.026～0.120——0.17～0.250——NO20.12～0.320.43～0.500——TSP——————0.65~1.32282017.3.4PM10——————0.69～1.38142017.3.4PM2.5——————0.84～1.67432017.3.4CO0.06～0.190————————氨0.25～0.90————————硫化氢/～0.20————————氯化氢/～0.60————————汞及其化合物——————0.06～0.110——苯并[a]芘——————1.12～21002017.3.2铅及其化合物——————0.04～0.190——氟化物0.06～0.0950————————注：“/”表示未检出的未进行评价苯并[a]芘补测评价结果见表4.2-30。表4.2-30苯并[a]芘补测数据评价结果采样点时间南夏家村东潘家村东南营村泥田沟村2082.96/3.242040.520.763.402001.640.283.40根据表4.2-29和表4.2-30可知：1、二氧化硫(SO2)监测期间评价区内13个监测点位的小时平均浓度范围为0.01～0.106mg/m3，单因子指数在0.02～0.212之间；日均浓度范围为0.026～0.049mg/m3，单因子指数在0.17～0.33之间。各监测点小时平均浓度和日平均浓度均不超标。2、二氧化氮(NO2)监测期间评价区内13个监测点位的小时平均浓度范围为0.017～0.116mg/m3，单因子指数在0.085～0.58之间；日平均浓度范围为0.03～0.057mg/m3，单因子指数范围为0.38～0.71。各监测点小时平均浓度和日平均浓度均不超标。3、可吸入颗粒物(PM10)监测期间评价区内13个监测点位的日平均浓度范围为0.06～0.258mg/m3，单因子指数范围为0.46～1.72，最大超标倍数是0.72。4、总悬浮颗粒物(TSP)监测期间评价区内13个监测点位的日平均浓度范围为0.128～0.477mg/m3，单因子指数范围为0.43～1.59，最大超标倍数是0.59。5、PM2.5监测期间评价区内13个监测点位的小时平均浓度范围为：0.04~0.152mg/m3，单因子指数范围为0.53～2.03，最大超标倍数是0.01，超标率2.4%。6、CO监测期间评价区内10个监测点位的小时平均浓度范围为：0.6~3.3mg/m3，单因子指数范围为0.06～0.33，无超标现象。7、氨监测期间评价区内10个监测点位的小时平均浓度范围为：未检出~0.18mg/m3，单因子指数范围为/～0.9，无超标现象。8、硫化氢监测期间评价区内10个监测点位的小时平均浓度范围为：未检出~0.003mg/m3，单因子指数范围为/～0.3，无超标现象。9、氯化氢监测期间评价区内10个监测点位的小时平均浓度范围为：未检出~0.04mg/m3，单因子指数范围为/～0.8，无超标现象。10、氟化物监测期间评价区内10个监测点位的小时平均浓度范围为：0.9~2.6mg/m3，单因子指数范围为0.045～0.13，无超标现象。11、氰化氢监测期间评价区内10个监测点位的小时平均浓度范围为：未检出~0.003mg/m3，单因子指数范围为/～0.06，无超标现象。12、非甲烷总烃监测期间评价区内10个监测点位的小时平均浓度范围为：0.51~1.16mg/m3，单因子指数范围为0.026～0.058，无超标现象。13、汞及其化合物监测期间评价区内10个监测点位的小时平均浓度范围为：0.016~0.046mg/m3，单因子指数范围为0.05～0.15，无超标现象。14、苯并[a]芘监测期间评价区内10个监测点位的小时平均浓度范围为：0.001~0.046µg/m3，单因子指数范围为0.4～6.32，最大超标倍数5.32。根据补测结果可知，南夏家村2018年2月11日监测数值满足《环境空气质量标准》（GB3095-2012）二级标准要求；东潘家村2018年2月11日监测数值满足《环境空气质量标准》（GB3095-20