丁羟甲苯BHT MSDS英文

ConformstoRegulation(EC)No.1907/2006(REACH),AnnexII-Europe

SAFETYDATASHEET

VULKANOXBHTFOODGRADE

Identificationofthesubstance/mixtureandofthecompany/undertaking

Productidentifier

Productname :VULKANOXBHTFOODGRADE

REACHSubstanceName:2,6-Di-tert-butyl-p-cresol

REACHRegistrationnumber

Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst

Identifieduses

SectorofUse

Chemical

Process

Product

Cateaorv

Cateaorv

2,6-di-tert-butyI-p-cresol.

SU03

PC28

PROC02

Formulationoffoodand

SU10

PC32

PROC08b

cosmetics(Industrial)

PROC09

2,6-di-tert-butyl-p-cresoL

SU10

PC32

PROC02

Formulationof

SU22

PC29

PROC08b

pharmaceuticals

PROC09

(Professional)

2,6-di-tert-butyl-p-cresoL

SU03

PC21

PROC15

Laboratoryuse(Industrial/

SU22

Suitableuses :Antioxidantagent

Professional)

Article Environmental

Cateaorv Release

Cateaorv

ERC02

ERC02

DetailsofthesupplierofthesafetydatasheetSupplier

Fax:

E-mail:

Emergencytelephonenumber

Hazardsidentification

Classificationofthesubstanceormixture

ClassificationaccordinatoReaulation(EC)No,1272/2008[CLP/GHS1

Classification :AquaticAcute1,H400

AquaticChronic1,H410

ClassificationaccordinatoDirective67/548/EEC[DSD1

Classification

Environmentalhazards

:N;R50/53

:Verytoxictoaquaticorganisms,maycauselong-termadverseeffectsintheaquaticenvironment.

LabelelementsHazardpictograms

Signalword

:Warning

2,6-di-tert.-butyl-p-cresol[128-37-0]

Methodsofdisposal

Hazardouswaste

Packaaina

Methodsofdisposal

Specialprecautions

:Examinepossibilitiesforre-utilisation.Productresiduesanduncleanedemptycontainersshouldbepackaged,sealed,labelled,anddisposedoforrecycledaccordingtorelevantnationalandlocalregulations.Wherelargequantitiesareconcerned,consultthesupplier.Whenuncleanedemptycontainersarepassedon,therecipientmustbewarnedofanypossiblehazardthatmaybecausedbyresidues.FordisposalwithintheEC,theappropriatecodeaccordingtotheEuropeanWasteList(EWL)shouldbeused.ItisamongthetasksofthepollutertoassignthewastetowastecodesspecifictoindustrialsectorsandprocessesaccordingtotheEuropeanWasteList(EWL).

:Theclassificationoftheproductmaymeetthecriteriaforahazardouswaste.

:Thegenerationofwasteshouldbeavoidedorminimisedwhereverpossible.Wastepackagingshouldberecycled.Incinerationorlandfillshouldonlybeconsideredwhenrecyclingisnotfeasible.

:Thismaterialanditscontainermustbedisposedofinasafeway.Careshouldbetakenwhenhandlingemptiedcontainersthathavenotbeencleanedorrinsedout.Emptycontainersorlinersmayretainsomeproductresidues.Avoiddispersalofspiltmaterialandrunoffandcontactwithsoil,waterways,drainsandsewers.

SECTION14:Transportinformation

ADR/RID

ADN/ADNR

IMDG

IATA

14.1UNnumber

UN3077

UN3077

UN3077

UN3077

14.2UNpropershippingname

ENVIRONMENTALLYHAZARDOUSSUBSTANCE,SOLID,N.O.S.(2,6-DI-TERT-BUTYL-P-CRESOL)

ENVIRONMENTALLYHAZARDOUSSUBSTANCE,SOLID,N.O.S.(2,6-DI-TERT-BUTYL-P-CRESOL)

ENVIRONMENTALLYHAZARDOUSSUBSTANCE,SOLID,N.O.S.(2,6-DI-TERT-BUTYL-P-CRESOL)

Environmentallyhazardoussubstance,solid,n.o.s.(2,6-DI-TERT-BUTYL-P-CRESOL)

14.3Transporthazardclass(es)/Marks

◎*

◊上>

0一

14.4Packinggroup

III

III

III

III

14.5Environmentalhazards

Yes.

Yes.

Yes.

Yes.

14.6Specialprecautionsforuser/Additionalinformation

Hazardidentificationnumber90

LimitedauantitvLQ27

Hazardidentificationnumber90

LimitedauantitvLQ27

Emeraencvschedules(EmS)F-A,S-F

Passenaeraircraft956:400kg

Caraoaircraft956:400kg

14.7TransportinbulkaccordingtoAnnexII:Notavailable,ofMARPOL73/78andtheIBCCode

Hazardnotes:

Environmentallyhazardoussubstance.

Keepdry.

Avoidheatabove+50℃.

Keepseparatedfromfoodstuffs.

SECTION15:Regulatoryinformation

15.1Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture

EUReaulation(EC)No,1907/2006(REACH)

AnnexXVII-Restrictions:Notapplicable.

onthemanufacture,placingonthemarketanduseofcertaindangeroussubstances,mixturesandarticles

15.2ChemicalSafetyAssessment

:Notapplicable.

SECTION16:Otherinformation

Abbreviationsandacronyms

ATE=AcuteToxicityEstimate

CLP=Classification,LabellingandPackagingRegulation[Regulation(EC)No.1272/2008]

DNEL=DerivedNoEffectLevel

EUHstatement=CLP-specificHazardstatementPNEC=PredictedNoEffectConcentrationRRN=REACHRegistrationNumber

FulltextofabbreviatedHstatements

FulltextofR-phrasesreferredtoinsections2and3

:H400 Verytoxictoaquaticlife.

H410 Verytoxictoaquaticlifewithlonglastingeffects.

:R50/53-Verytoxictoaquaticorganisms,maycauselong-termadverseeffectsintheaquaticenvironment.

TOC\o"1-5"\h\z

Wordingoftheinstructionsfor:useaccordingtoUse PC28

DescriptorSystem,towhich pc29

referenceismadein PC32

paragraph1: PROC02

PROC08b

PROC09

PROC15

SU03

SU10

SU22

Formulationofpreparations*

Laboratorychemicals

Perfumes,fragrances

Pharmaceuticals

Polymerpreparationsandcompounds

Useinclosed,continuousprocesswithoccasionalcontrolledexposure

Transferofsubstanceorpreparation(charging/discharging)from/tovessels/largecontainersatdedicatedfacilities

Transferofsubstanceorpreparationintosmallcontainers(dedicatedfillingline,includingweighing)Useaslaboratoryreagent

Industrialuses:Usesofsubstancesassuchorinpreparations*atindustrialsites

Formulation[mixing]ofpreparationsand/orre-packaging(excludingalloys)

Professionaluses:Publicdomain(administration,

education,entertainment,services,craftsmen)

Historv

Dateofissue 2011-07-05

Dateofpreviousissue 2011-07-04

Version :3

「Indicatesinformationthathaschangedfrompreviouslyissuedversion.

Noticetoreader

Thedatagivenhereisbasedoncurrentknowledgeandexperience.ThepurposeofthisSafetyDataSheetistodescribetheproductsintermsoftheirsafetyrequirements.Theabovedetailsdonotimplyanyguaranteeconcerningcomposition,propertiesorperformance.

Newdisclamer

Identificationofthesubstanceormixture

Productdefinition

Code

Productname

:Mono-constituentsubstance

:05377617

:VULKANOXBHTFOODGRADE

Section1-Title

Shorttitleoftheexposurescenario

Listofusedescriptors

NameofcontributingenvironmentalscenarioandcorrespondingERC

ListofnamesofcontributingworkerscenariosandcorrespondingPROCs

:2,6-di-tert-butyl-p-cresol.Formulationoffoodandcosmetics.

(Industrial)

:Identifiedusename:2,6-di-tert-butyl-p-cresoLFormulationoffoodandcosmetics(Industrial)

ProcessCategory:PROC02,PROC08b,PROC09

Substancesuppliedtothatuseinformof:Assuch

Sectorofenduse:SU03,SU10

Subsequentserviceliferelevantforthatuse:No.

EnvironmentalReleaseCategory:ERC02

Marketsectorbytypeofchemicalproduct:PC28,PC32

:-ERC02

:-PROC02,PROC08b,PROC09

Section2-Exposurecontrols

Contributingexposurescenariocontrollingenvironmentalexposurefor:"ERC02

ProductCharacteristics

Concentrationofsubstanceinmixtureorarticle

Amountsused

Frequencyanddurationofuse

Environmentalfactorsnotinfluencedbyriskmanagement

OthergivenoperationalconditionsaffectingenvironmentalexposureTechnicalconditionsandmeasuresatprocesslevel(source)topreventrelease

:Solid

Melting/FreezingPoint(℃):69.8

:<100%

:Annualsitetonnage:<16.5t/a

:Continuousrelease(d/a):300

:Localfreshwaterdilutionfactor:10

Ifreceivingsurfacewaterflowis(m3/d):18000

Localmarinewaterdilutionfactor:100

:Notapplicable.

:Fractionoftonnagereleasedintosoil(%):0

Fractionoftonnagereleasedintowastewater(%):0.3

Fractionoftonnagereleasedintoair(%):0.1

Technicalon-siteconditionsandmeasurestoreduceorlimitdischarges,airemissionsandreleasestosoil

Organisationalmeasurestoprevent/limitreleasefromsite

Conditionsandmeasuresrelatedtomunicipalsewagetreatmentplant

ConditionsandmeasuresrelatedtoexternaltreatmentofwastefordisposalConditionsandmeasuresrelatedtoexternalrecoveryofwaste

:Melting/FreezingPoint(℃):69.8

：<100%

:solid

:Dustiness:Medium

:Exposuredurationperyea匚230dExposuredurationperday:8h.

:Respiratoryvolume(m3/d):10(lightactivity)

：Indoorsetting

Useatroomtemperature.

:Nospecialmeasuresrequired.

:Localexhaustventilation.(efficiency%):>90

Organisationalmeasurestoprevent/limitreleases,dispersionandexposure

:Thewastewaterhastobedirectedtoadedicatedsewagetreatmentplantortreatedbyothersuitabletechniques.

Wasteairshouldbescrubbedorfiltered.

Floorshouldbeimperviousandresistanttoliquid.

:Onlyproperlytrainedandauthorisedpersonnelshallhandlethesubstance.

Substance-handlingproceduresshallbewelldocumentedandsupervised.

:Sizeofsewagetreatmentplant(m3/d):2000

Removalrate(%):94

:Nospecialmeasuresrequired.Generalinformationonwastedisposalseesection13.

:Generalinformationonwastedisposalseesection13.

Contributingexposurescenariocontrollingworkerexposurefor:-PROC02,PROC08b5PROC09

ProductCharacteristics

Concentrationofsubstanceinmixtureorarticle

Physicalstate

Dust

Frequencyanddurationofuse

Humanfactorsnotinfluencedbyriskmanagement

Othergivenoperationalconditionsaffectingworkersexposure

Technicalconditionsandmeasuresatprocesslevel(source)topreventrelease

Technicalconditionsandmeasurestocontroldispersionfromsourcetowardstheworker

:Onlyproperlytrainedandauthorisedpersonnelshallhandlethesubstance.

Substance-handlingproceduresshallbewelldocumentedandsupervised.

Conditionsandmeasuresrelatedtopersonalprotection,hygieneandhealthevaluation

Personalprotection

:Wearprotectiveclothingasdescribedinsection8.

-Exposureestimationandreferencetoitssource

Website:

:Notavailable.

Exposureestimationandreferencetoitssource-Environment:-ERC02

Exposureassessment(environment):

Exposureestimation

:UsedEUSESmodel.(Version2.1)ERCmodifiedwithsettingfromEnvironmentAgencyUK:EnvironmentalRiskAssessmentReportonBHT,DraftJanuary2010andEC-TGD(2003)PartII,AppendixI,TableA2.1

:Thepredictedexposureconcentrationsforair,theaquaticandtheterrestrialenvironmentarebelowderivedPNECvalues,resultinginRCRs<1.

Exposureestimationandreferencetoitssource-Workers:-PROC02,PROC08b,PROC09

Exposureassessment( :ECETOCTRA(04/2010)

human):

Exposureestimation

:Thecalculatedindividualandcombined(dermalandinhalation)exposurevaluesarebelowtheDNELsvalues(RCR<1)

-GuidancetoDownstreamUsertoevaluateifheworksinsidetheboundariessetbytheES

Environment :Undertheabovelistedconditionstheprocessisdeemedsafe.

OtherconditionsshouldonlybeconsideredwhenmeasurementsorsuitablecalculationsshowthattheRCRis<1.

Health :Undertheabovelistedconditionstheprocessisdeemedsafe.

OtherconditionsshouldonlybeconsideredwhenmeasurementsorsuitablecalculationsshowthattheRCRis<1.

AdditionalgoodpracticeadvicebeyondtheREACHCSA

Environment :Notapplicable.

Health :Onpossiblecontactwiththeproduct(sampling,sp川age,leakage,

cleaning):

Wearprotectiveclothingasdescribedinsection8.

Wearrespiratoryprotectionasdescribedinsection8.

SeeSection8forinformationonappropriatepersonalprotectiveequipment.

Identificationofthesubstanceormixture

Productdefinition

Code

Productname

:Mono-constituentsubstance

:05377617

:VULKANOXBHTFOODGRADE

Section1-Title

Shorttitleoftheexposurescenario

Listofusedescriptors

NameofcontributingenvironmentalscenarioandcorrespondingERC

ListofnamesofcontributingworkerscenariosandcorrespondingPROCs

:2,6-di-tert-butyl-p-cresoLFormulationofpharmaceuticals

(Professional)

:Identifiedusename:2,6-di-tert-butyl-p-cresoLFormulationofpharmaceuticals(Professional)

ProcessCategory:PROC02,PROC08b,PROC09

Substancesuppliedtothatuseinformof:Assuch

Sectorofenduse:SU10,SU22

Subsequentserviceliferelevantforthatuse:No.

EnvironmentalReleaseCategory:ERC02

Marketsectorbytypeofchemicalproduct:PC32,PC29

:-ERC02

:-PROC02,PROC08b,PROC09

Section2-Exposurecontrols

Contributingexposurescenariocontrollingenvironmentalexposurefor:"ERC02

ProductCharacteristics

Concentrationofsubstanceinmixtureorarticle

Amountsused

Frequencyanddurationofuse

Environmentalfactorsnotinfluencedbyriskmanagement

OthergivenoperationalconditionsaffectingenvironmentalexposureTechnicalconditionsandmeasuresatprocesslevel(source)topreventrelease

:Solid

Melting/FreezingPoint(℃):69.8

:<100%

:Annualsitetonnage:<0.33t/a(widedispersiveuse)

:Continuousrelease(d/a):300

:Localfreshwaterdilutionfactor:10

Ifreceivingsurfacewaterflowis(m3/d):18000

Localmarinewaterdilutionfacto匚100

:Notapplicable.

:Fractionoftonnagereleasedintosoil(%):0

Fractionoftonnagereleasedintowastewater(%):0.3

Fractionoftonnagereleasedintoair(%):0.1

Technicalon-siteconditionsandmeasurestoreduceorlimitdischarges,airemissionsandreleasestosoil

Organisationalmeasurestoprevent/limitreleasefromsite

Conditionsandmeasuresrelatedtomunicipalsewagetreatmentplant

ConditionsandmeasuresrelatedtoexternaltreatmentofwastefordisposalConditionsandmeasuresrelatedtoexternalrecoveryofwaste

:Melting/FreezingPoint(℃):69.8

：<100%

:solid

:Dustiness:Medium

:Exposuredurationperyea匚230dExposuredurationperday:8h.

:Respiratoryvolume(m3/d):10(lightactivity)

：Indoorsetting

Useatroomtemperature.

:Nospecialmeasuresrequired.

:PROC08b,PROC09:

Localexhaustventilation.(efficiency%):>90

Organisationalmeasurestoprevent/limitreleases,dispersionandexposure

:Thewastewaterhastobedirectedtoadedicatedsewagetreatmentplantortreatedbyothersuitabletechniques.

Wasteairshouldbescrubbedorfiltered.

Floorshouldbeimperviousandresistanttoliquid.

:Onlyproperlytrainedandauthorisedpersonnelshallhandlethesubstance.

Substance-handlingproceduresshallbewelldocumentedandsupervised.

:Sizeofsewagetreatmentplant(m3/d):2000

Removalrate(%):94

:Nospecialmeasuresrequired.Generalinformationonwastedisposalseesection13.

:Generalinformationonwastedisposalseesection13.

Contributingexposurescenariocontrollingworkerexposurefor:-PROC02,PROC08b5PROC09

ProductCharacteristics

Concentrationofsubstanceinmixtureorarticle

Physicalstate

Dust

Frequencyanddurationofuse

Humanfactorsnotinfluencedbyriskmanagement

Othergivenoperationalconditionsaffectingworkersexposure

Technicalconditionsandmeasuresatprocesslevel(source)topreventrelease

Technicalconditionsandmeasurestocontroldispersionfromsourcetowardstheworker

:Onlyproperlytrainedandauthorisedpersonnelshallhandlethesubstance.

Substance-handlingproceduresshallbewelldocumentedandsupervised.

Conditionsandmeasuresrelatedtopersonalprotection,hygieneandhealthevaluation

Personalprotection

:Wearprotectiveclothingasdescribedinsection8.

-Exposureestimationandreferencetoitssource

Website:

:Notavailable.

Exposureestimationandreferencetoitssource-Environment:-ERC02

Exposureassessment(environment):

Exposureestimation

:UsedEUSESmodel.(Version2.1)ERCmodifiedwithsettingfromEnvironmentAgencyUK:EnvironmentalRiskAssessmentReportonBHT,DraftJanuary2010andEC-TGD(2003)PartII,AppendixI,TableA2.1

:Thepredictedexposureconcentrationsforair,theaquaticandtheterrestrialenvironmentarebelowderivedPNECvalues,resultinginRCRs<1.

Exposureestimationandreferencetoitssource-Workers:-PROC02,PROC08b,PROC09

Exposureassessment( :ECETOCTRA(04/2010)

human):

Exposureestimation

:Thecalculatedindividualandcombined(dermalandinhalation)exposurevaluesarebelowtheDNELsvalues(RCR<1)

-GuidancetoDownstreamUsertoevaluateifheworksinsidetheboundariessetbytheES

Environment :Undertheabovelistedconditionstheprocessisdeemedsafe.

OtherconditionsshouldonlybeconsideredwhenmeasurementsorsuitablecalculationsshowthattheRCRis<1.

Health :Undertheabovelistedconditionstheprocessisdeemedsafe.

OtherconditionsshouldonlybeconsideredwhenmeasurementsorsuitablecalculationsshowthattheRCRis<1.

AdditionalgoodpracticeadvicebeyondtheREACHCSA

Environment :Notapplicable.

Health :Onpossiblecontactwiththeproduct(sampling,sp川age,leakage,

cleaning):

Wearprotectiveclothingasdescribedinsection8.

Wearrespiratoryprotectionasdescribedinsection8.

SeeSection8forinformationonappropriatepersonalprotectiveequipment.

Identificationofthesubstanceormixture

Productdefinition

Code

Productname

:Mono-constituentsubstance

:05377617

:VULKANOXBHTFOODGRADE

-Title

Shorttitleoftheexposurescenario

Listofusedescriptors

NameofcontributingenvironmentalscenarioandcorrespondingERC

:2,6-di-tert-butyl-p-cresol.Laboratoryuse.(Industrial/Professional)

:Identifiedusename:2,6-di-tert-butyl-p-cresol.Laboratoryuse(

Industrial/Professional)

ProcessCategory:PROC15

Substancesuppliedtothatuseinformof:Assuch

Sectorofenduse:SU03,SU22

Subsequentserviceliferelevantforthatuse:No.

Marketsectorbytypeofchemicalproduct:PC21

:-ERC06a5ERC09a

:-PROC15

ListofnamesofcontributingworkerscenariosandcorrespondingPROCs

Additionalinformation

:ERConlyforcommunicationpurposes.

Noenvironmentalriskassessmentwasperformedduetothelowamoutofsubstanceused(<1kg/d).

-Exposurecontrols

Contributingexposurescenariocontrollingenvironmentalexposurefor:"ERC06a,ERC09a

Amountsused :Noenvironmentalriskassessmentwasperformedduetothelow

amoutofsubstanceused(<1kg/d).

Conditionsandmeasures:Generalinformationonwastedisposalseesection13.

relatedtoexternalrecoveryofwaste

Contributingexposurescenariocontrollingworkerexposurefor:-PROC15

ProductCharacteristics:Melting/FreezingPoint(℃):69.8

Concentrationof ：<100%

substanceinmixtureorarticlePhysicalstate :solid

Dust :Dustiness:Medium

Hazardstatements

PreccationnrystatementsPrevention

Response

Storage

Disposal

2.3Otherhazards

SubstancemeetsthecriteriaforPBTaccordingtoRegulation(EC)No.1907/2006,AnnexXIII

Otherhazardswhichdonotresultinclassification

Remarks

:Verytoxictoaquaticlifewithlonglastingeffects.

:Avoidreleasetotheenvironment.

:Collectspillage.

:Notapplicable.

:Notapplicable.

:Notavailable.

:No.

:Capableofcausingadustexplosion.

Composition/informationoningredients

Productdefinition(REACH):Mono-constituentsubstance

Product/ingredientname

Identifiers

%

Classification

67/548/EEC

Regulation(EC)No.1272/2008[CLP]

2,6-di-tert.-butyl-p-cresol

REACH#:QI-2119555270-46EC:204-881-4CAS:128-37-0

>99.7

N;R50/53

Seesection16forthefulltextoftheR-phrasesdeclaredabove

AquaticAcute1,H400

AquaticChronic1,H410

SeeSection16forthefulltextoftheHstatementsdeclaredabove.

Occupationalexposurelimits,ifavailable,arelistedinSection8.

Firstaidmeasures

Descriptionoffirstaidmeasures

Inhalation :Moveexposedpersontofreshair.Keeppersonwarmandatrest.If

notbreathing,ifbreathingisirregularorifrespiratoryarrestoccurs,provideartificialrespirationoroxygenbytrainedpersonnel.Itmaybedangeroustothepersonprovidingaidtogivemouth-to-mouthresuscitation.Getmedicalattentionifadversehealtheffectspersistoraresevere.Ifunconscious,placeinrecoverypositionandgetmedicalattentionimmediately.Maintainanopenairway.Loosentightclothingsuchasacollar,tie,beltorwaistband.

2,6-di-tert-butyl-p-cresol.Laboratoryuse.

(Industrial/Professional)

Frequencyanddurationofuse

:Exposuredurationperyear:230d

Exposuredurationperday:8h.

Humanfactorsnotinfluencedbyriskmanagement

Othergivenoperationalconditionsaffectingworkersexposure

:Respiratoryvolume(m3/d):10(lightactivity)

：Indoorsetting

Useatroomtemperature.

Technicalconditionsandmeasuresatprocesslevel(source)topreventrelease

:Nospecialmeasuresrequired.

Localexhaustventilation.(efficiency%):>90

Technicalconditionsandmeasurestocontroldispersionfromsourcetowardstheworker

Organisationalmeasurestoprevent/limitreleases,dispersionandexposure

：Onlyproperlytrainedandauthorisedpersonnelshallhandlethesubstance.

Substance-handlingproceduresshallbewelldocumentedandsupervised.

Conditionsandmeasuresrelatedtopersonalprotection,hygieneandhealthevaluationPersonalprotection :Wearprotectiveclothingasdescribedinsection8.

-Exposureestimationandreferencetoitssource

Website: :Notavailable.

Exposureestimationandreferencetoitssource-Environment:-ERC06a,ERC09a

Exposureassessment :Notavailable.

(environment):

Exposureestimation :Notavailable.

Exposureestimationandreferencetoitssource-Workers:-PROC15

Exposureassessment( :""ECETOCTRA (04/2010)

human):

Exposureestimation:Thecalculatedindividualandcombined(dermalandinhalation)exposurevaluesarebelowtheDNELsvalues(RCR<1)

-GuidancetoDownstreamUsertoevaluateifheworksinsidetheboundariessetbytheES

Environment :Notavailable.

Health :Undertheabovelistedconditionstheprocessisdeemedsafe.

OtherconditionsshouldonlybeconsideredwhenmeasurementsorsuitablecalculationsshowthattheRCRis<1.

AdditionalgoodpracticeadvicebeyondtheREACHCSA

Environment

:Notavailable.

VULKANOXBHTFOODGRADE 2,6-dbtert-butyhp-cresoLLaboratoryuse.

(Industrial/Professional)

Health :Wearprotectivegloves/protectiveclothing/eyeprotection/face

protection.Wearrespiratoryprotection.

SeeSection8forinformationonappropriatepersonalprotectiveequipment.

Ingestion

Skincontact

Eyecontact

:Washoutmouthwithwater.Moveexposedpersontofreshair.Keeppersonwarmandatrest.Ifmaterialhasbeenswallowedandtheexposedpersonisconscious,givesmallquantitiesofwatertodrink.Stopiftheexposedpersonfeelssickasvomitingmaybedangerous.Donotinducevomitingunlessdirectedtodosobymedicalpersonnel.Ifvomitingoccurs,theheadshouldbekeptlowsothatvomitdoesnotenterthelungs.Getmedicalattentionifadversehealtheffectspersistoraresevere.Nevergiveanythingbymouthtoanunconsciousperson.Ifunconscious,placeinrecoverypositionandgetmedicalattentionimmediately.Maintainanopenairway.Loosentightclothingsuchasacollar,tie,beltorwaistband.

:Washskinimmediatelywithplentyofwaterandsoap.Subsequentcleansingwithpolyethyleneglycol400,thenagainwithwaterandsoap.Getmedicalattentionifirritationdevelops.Washclothingbeforereuse.Cleanshoesthoroughlybeforereuse.

:Immediatelyflusheyeswithplentyofwater,occasionallyliftingtheupperandlowereyelids.Checkforandremoveanycontactlenses.Continuetorinseforatleast10minutes.Getmedicalattentionifirritationoccurs.

Mostimportantsymptomsandeffects,bothacuteanddelayed

SeeSection11formoredetailedinformationonhealtheffectsandsymptoms.

IndicationofanyimmediatemedicalattentionandspecialtreatmentneededSeeSection11formoredetailedinformationonhealtheffectsandsymptoms.

5.1ExtinguishingmediaSuitableextinguishingmedia

Unsuitableextinguishingmedia

Firefightingmeasures

:Incaseoffire,usewaterspray(fog),foamordrychemical.

:Carbondioxide(CO2).

5.2Specialhazardsarisingfromthesubstanceormixture

Hazardsfromthesubstanceormixture

Hazardouscombustionproducts

5.3AdviceforfirefightersSpecialprecautionsforfirefighters

Specialprotectiveequipmentforfire-fighters

:Nospecificfireorexplosionhazard.

:Decompositionproductsmayincludethefollowingmaterials:carbonoxides

:Promptlyisolatethescenebyremovingallpersonsfromthevicinityoftheincidentifthereisafire.Noactionshallbetakeninvolvinganypersonalriskorwithoutsuitabletraining.Thismaterialisverytoxictoaquaticorganisms.Firewatercontaminatedwiththismaterialmustbecontainedandpreventedfrombeingdischargedtoanywaterway,sewerordrain.

:Fire-fightersshouldwearappropriateprotectiveequipmentandself-containedbreathingapparatus(SCBA)withafullface-pieceoperatedinpositivepressuremode.

Accidentalreleasemeasures

Personalprecautions,protectiveequipmentandemergencyprocedures

Environmentalprecautions

:Noactionshallbetakeninvolvinganypersonalriskorwithoutsuitabletraining.Keepunnecessaryandunprotectedpersonnelfromentering.Donottouchorwalkthroughspiltmaterial.Provideadequateventilation.Putonappropriatepersonalprotectiveequipment(seeSection8).

:Avoiddispersalofspiltmaterialandrunoffandcontactwithsoil,waterways,drainsandsewers.Informtherelevantauthoritiesiftheproducthascausedenvironmentalpollution(sewers,waterways,soilorair).Verytoxictoaquaticorganisms,maycauselong-termadverseeffectsintheaquaticenvironment.

6.3Methodsandmaterialsforcontainmentandcleaningup

Smallspill :Movecontainersfromspillarea.Vacuumorsweepupmaterialand

placeinadesignated,labelledwastecontainer.Disposeofviaalicensedwastedisposalcontractor.

Largespill :Movecontainersfromspillarea.Prevententryintosewers,water

courses,basementsorconfinedareas.Vacuumorsweepupmaterialandplaceinadesignated,labelledwastecontainer.Disposeofviaalicensedwastedisposalcontractor.Note:seesection1foremergencycontactinformationandsection13forwastedisposal.

6.4Referencetoothersections

:SeeSection1foremergencycontactinformation.

SeeSection8forinformationonappropriatepersonalprotectiveequipment.

SeeSection13foradditionalwastetreatmentinformation.

Handlingandstorage

Theinformationinthissectioncontainsgenericadviceandguidance.ThelistofIdentifiedUsesinSection1shouldbeconsultedforanyavailableuse-specificinformationprovidedintheExposureScenario(s).

Precautionsforsafehandling

Conditionsforsafestorage,includinganyincompatibilities

:Putonappropriatepersonalprotectiveequipment(seeSection8).Eating,drinkingandsmokingshouldbeprohibitedinareaswherethismaterialishandled,storedandprocessed.Workers