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2022-2023(T)MOO

-v£100.0tf)

i.«smiOMS.

mW,

BâüÀmStm

C.0W»W

D.moœmniiu

(2)(J$&)»(H2NNH2,

aftl^ifé:0=OSOOkJ•mol"1,N-N154kJ■mol-1,WJN-

A.194kJ■mol-1

B.391kJ■mol-1

C.516kJ■mol-1

D.658kJ■mol-1

(3)(/5Æ-Û&lRjS:

1

®2C(s)+02(g)=2C0(g)AH=—221kJ•mol’

13+1

©WM!.H(aq)+OH-(aq)=H2O(1)AH=—57.3kJ•mol"

1

@H2(g)+|02(g)=H2O(g)AH=—241.8kJ■mol’

-1

@H2O(g)=H2O(1)AH=—44.0kJ•mol

______o

110.5kJ•mol

B.^M^NaOHfê^S&£j£lmol7K,^tti57.3kj^>

C.M^Ô<J®^A241.8kJ■mol-1

-1

D.2H2(g)+02(g)=2H2O(1)AH=-571.6kJ•mol

(4)ÉIm,^^^î.f^p4o6,

$nÆÆ.WMP4o10o

®B^298KB^ÉI^>

-1

P4(s,ÉIW)+5O2(g)=P4010(S)AH1=—2983.2kJ•mol

P(s,M)+?0(g)=7P0(S)AH=-738.5k]•mol’1

4244102

È^)+3O2(g)=P406(s)AH=

—1638RJ•mol-1,ÏE^^Efl^4’ljnA62gâWW50.4LM^(^^ÿt),fëMâH'H£±-^ï

oKÜFrWSJCKJP4O105P4o6ûWiÛ<J:SAbt>JSSiÉë’t’TAfBl'Kl&®A

(5)fflH2o2flH2so4fô?gWTOB&J:

+2+1

(î)Cu(s)+2H(aq)=Cu(aq)+H2(g)AH1=+64.39kJ•mol’

1

@2H2O2(1)=2H2O(1)+O2(g)AH2=-196.46kJ■mol"

1

(3)H2(g)+|02(g)=H20(l)AH3=—285.84kJ•mol’

12+

ÆH2SO4ϧ^4-CuAH2O2^ÉkjSCu>fnH2OÉ<J^{-t^^ïÇA

2N(g)+4H(g)+2O(g)

?r

IÊM

ÀHt

AH?=—2752kj/mol

N2H4(g)+O2(g);

AH,=-534kj/moli

________i__Ï

MSN2(g)+2H2O(g)

2.

Hjbtra&MWtÈME,

(1)(M)^M^S=W,TJiJzWiEmW^

A.^XANaCl,A2C1"-2e"=Cl2î

CiftXMW-»4>H+[n]FeEyg^J

D.^X^NaCl,KJgNfflW,Feffca±£W&ttfeW#.rôG

(2)(OWl!ïiW®)lM.

Zn+Cu2+=Zn2++Cu

cÆ^ièE^,!li-fAftttfiïEfi

+

D.Wf4WféfàZnS04»

(3)ift:fëMlel?iJIRJ®;

ÈtëlMOW,OnW.

W____

+2+

eu+2H=Cu+H2,

oS.Éê:

Wftko7'jl^jhü^J^îÈ,1S

MmW£Wzl<Mâ<JZn&a£,(«“IE”B£“^”)affljîo

ibo^x^,JF^K£-TM^,î^iW^FiÈ^□

a.^w#>-T-tx(«A^B),

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3.ww

JW,ÀtfÆ^Ti^Wfflœn14».

(l)(M)ÿnSXM^%^Na2S047K'M^fi«MJHÆÇMfôaWWM»

ZLW^»»T^WMJS^jEïÆWM,

-=<l^-

IÙBÙI

NaJSOJfr?ftvv;-^

AJ&ÎÜ^ÉHJWÏ.aEyO'b^bffeM

B-tfeMtu■■-Ill«Hl

c.am^isfjÆsafe,b^amÆMfe

D.aÈfôPftiÆMfe,bEfefëMMfe

(2)(j£Æ)iWfê&,£&Fe+2H2O=Fe(OH)2+H2âÙÆ.

MWbEfeMW

c.mjwmmfô,

FHffelS,

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®iÈt¥«i+W±^nê±^ÆT

4.ZKStè±4OiJAWWM^JfcW4t^R&8&*!bjg

ww1-^s^âü^^.o

(l)(WÆTTOê£Wg4',o

A.AÈKMfàfÈ#b

-1

B.2H2(g)+02(g)=8Hz0(l)AH=-483.6kJ•moi

cÆ/KMÆzK^rOJÊ'HW

D.-io°cWM^zKâ^«^S^

(2)(W)WEfeB>J-$^4<JN24nO2꣣RJw.:N2(g)+02(g)=2N0(g)AH=+180.50kJ•

mol"1,âS=+247.3Jmor1K"1,ÆllTWi£+ïEfà

lWo

AÆIOOO°(M,

BÆIOOO°CM.

c.gSÈiÈœ^S®fi®^Wc

D.T^RÉZ^êMffi<T»M^W30K

(3)(^fé^iâ^)T?Ü<ï£lEMM»

A.iWbm«W.«XESUÉiWm

B.NH4HC03(s)=NH3(g)+H2O(g)+CO2(g)AH=+185.57kJ•moMt&ÈOfî.

&êmig'/gfiLSüiraôü|RJfffi[è]

Œ»««MMgg

D.AH<0.AS>OtfOOWWSW

(4)B$11298KÜ-J-wTÿlJUcië:

Na2S04•10H2O(S)Na2S04(s)H2O(g)

AH/kJ■mol-1-4324.08-1384.49-241.83

1-1

Na2SO4•10H2O(S)=Na2S04(s)4-10H2O(g)AS=+1443.8J■mol"•K

(î)±Wm298K0'J-nÈ;i’?gMIT?»

fi'JÎnn^?lï|l|^«

(5)W(CH3OH)M~^MM£BW,

œI:CO(g)+2H2(g)CH3OH(g)AH

ïnn/5250°C300°C350°C

K2.0410.2700.012

È^mg^lJW,AH0(±«“>”,“=”“<”)o

]

©«SJtT,W2molCOfll6nwlH2^À2LÛ^|'flM4,»W0]=

O^molL-1,oC(M^4'iâS)«

(6)-Æ£#T,ÆW^3LMfflW*.

Cu2O/ZnO):CO(g)+2H2(g)#CH3OH(g),

KM(M“i^”“M

/]>”)o

@ÎË500°C,M^ÉlW$Jxfàjâ^v(H2)=«

»WM«io

A.^fôM<d>

D.M«r¥Wn;Q^CngïUinn)të*

@fâWK,£M4«ftWCu2O,ffiïH

Ê^^^ü®co2^swfiJT^iem^cu2o6<j*«,

ASSOISo

▲n^B'/J/mol

[ft^A300“C

n(A)

n(B)7^fttltlîB500X2

0«(B)r(A)

5.

(l)(W)WTi^£îE^Éi<j^»

A.^uini4t^œWWHMHWM>JE^

D.H^W^ÆWâÙHit

(2)(Mjâ)/>fii^>ï-^ioomLo.oimoi/Li^^&gêM,^WÀIt.^TtnOsH&WrfD

®JHH2O

@iOKN03^M

©WÀJLîW'^ikf®

@WNaClï§^

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A-®@@

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D.®@®@®

(3)0£&)^MT,H2(g)+C02(g)^H20(g)+C0(g)AH>0oBftl

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B.VŒ(C02)=

c.^iigiJT^^S±Hl^co2,

1

D.^H2(g)sCO2(g).H2O(g)>CO(g)IU^JtBj^0.1mol-L-,MMMiâfif

nÊf5ÜNO2(g)+CO(g)CO2(g)+N0(g)iEMjÉ$it^KJS4t^T

WWWfW»»

A.it^NO2^COÈÜifcg

BM'bCO^NOfôjfêfë

C.«ÀNeTO«fê*

D.fl-^JxÉZÔÙW

(5)(^Æ^^W)^WL(COS)B]-^>9-ft^Wl^JÏlJ,^CO>fUH2S7fê^n

«iÈSlJTJlJTW:CO(g)+H2S(g)#COS(g)+H2(g)K=O.lcMIÎCOÛ^WiWft^lOmob

¥W/HCOMÔ<J>^8mol,-RiJWîEfà&Ü^»

A,#a-^?W.H2s^Min,

B.jffiÀCOJe,

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D.COÔ«jY^4t^^80%

(6)^Æ£^A®Éfi^#5.0g&À^W500mL0.5mol•L’WlfêfiW'K

fciï.r*wwwmiHJI$MW$nmÉÛM®?ÜM®=

®IttaEli0~ali'J®

(7)Uk±^iso2^<^^^üo

WjWI^+l&£SO2ft<]^&i-:2C0(g)+SO2(g)#2CO2(g)+S(1)(AH<0)o

©iSMlOTW^WiiïC'aMMflm¥W

(W“»”>“£'/h”>£“«”)o

(2)$n0^¥W^so2W^ftÆ7FRM®TBIffi5ââ<]^ft^,Wr=TxT2(iâ«“>”s

,

(3)^2LÛ<J^I^»bjïfï±^lS>É5’aiJ»5min|*lWÛ<)®ftMd<ri.6g,!jJiJo~5min(l<J

¥J$MiÈ$v(CO2)=o

(i)Mi>ik^w,

(2)MW'ê-^^M^-fi<J^IÉÈJ*:Z-ofêfflFeW.OJ.fè$i|fiJ®773K,

H5M3.Ox105Pa,JMWNzWzWTOiJttk^l:3,

______o

(3)A>J^»Ï4«-^fflK2,^^*K^*WNO2®iÉK1.K3OJ?EÀA.

B4>,MÆüW,A.BÈWR;fê|s][B&:2N02(g)N2O4(g)AH<0]«

(ÎWWlW,&ÆiÈglJ¥W.WA.B+^^fKjN2O4â<J»^v(A)v(B)(±A

“>”“<”“=”);WïÈ£K2l(±«“W”)»

£#A.B+WÆX'-j^JfèfîUII^^NO,,JÜfôSÜTW,NO2lWtt.^a(A)

(iA“±^”“M/h”Wc“^”);WJiiSiJ¥W,A41

a

N02W^4tW.B^NO^Wfê(±A^”“^”sK)o

£A.BW^W«>WJü

SlJWlH'h

(4)^Æ^g^A^^À4.6gâ<JNO2,WÜ

¥WH’tN2O4âÙ^Kfi^J________«

1.[^]ABADP4(s,SW)=4P(s,OT)AH=-29.2k]/mol3:11323.45kJCu(s)+

+2+

H2O2(aq)+2H(aq)=Cu(aq)+2H2O(1)△H=-319.68k]/mol

A

feciESÆ;

A;

(2)ÉKnj^ll,AH3=+(2752k]/mol—534kJ/mol)=+2218kJ/mol,i5N-HWt^xkJ/mol,

RIJ154+4x+500=2218,fWt#x=391,KPN-HMÉfê?g391kJ/mol,

B;

-1

(3)A.2C(s)+02(g)=2CO(g)AH=—221kJ■mol,COMMHlM,

110.5kJ/mol,î&AIEfifô;

WMfôfê^NaOHMM^J&lmolzlGSfcfBW^>^T57.3kJ,&

Bfê^;

-1

C-H2(g)+|02(g)=H2O(g)AH=—241.8kJ■mol,

^ÀT241.8kJ-mor1,

1

D.tëfëMféfêh@X2+@X2ilMM2H2(g)+O2(g)=2H2O(l)â-JAH=-241.8kJ•moPx

2+(—44k]•mol-1)x2=—571.6kJ/mol,Dit'fift;

AD;

-1

(4)®MIP4(S,ÛW)+5O2(g)=P4O10(S)AH1=-2983.2k]•mol,£jÈIIP(s,OT)+

-1

|O2(g)=^P4O10(s)AH2=—738.5k)•mol,OJM»;I-Hx2i+WP4(s,ÔW)=4P(s,

-1-1

M)^JAH=-2983.2kJ•mol-(-738.5kJ•mol)x4=-29.2kJ/mol,^^^®^>jP4(s,

A5^)=4P(s,aï^)AH=-29.2kJ/moL

P4(s,SW)=4P(s,OT)AH=-29.2kJ/mol;

@62gâW^50.4LM^(^mWÆ)^W=0.5moL-5°^=2.25,iâ

1IIlOlzz.^L/moi

n(P4Olo)=xmol,n(P406)=ymol.OJÜ-jFyfHHW4x+4y=0.5x4,lOx+6y=2.25x2,

<

WWx=0.375,y=0.125,RlJP/rWïlJflJP4O10-lgP4O6K^^ft<J*±LtA0.375mol:0.125mol=3:

1,Mtôiïfë1^HlMMA2983.2kJ•mol"1x0.375mol+1638kJ•mol"1x0.125mol=

1323.45kJ,

3:1;1323.45kJ;

2++2+

(5)Cu^H2O25ÎJ'V/È^CufllH2Of'l<j{t^7jgxUjCu(s)+H2O2(aq)+2H(aq)=Cu(aq)+

î+2+

2H2O(1),OîMJTAÎÉÎ^:@+@x|+@i't'^S.5ZCu(s)+H2O2(aq)+2H(aq)=Cu(aq)+

11-1

2H2O(l)ÉKlAH=+64.39kJ•mol"+(-196.46kJ•mol")x|+(—285.84kJ•mol)=

+2+

-319.68kJ/mol,M^Sï^Cu(s)+H2O2(aq)+2H(aq)=Cu(aq)+2H2O(1)△H=

—319.68kJ/mol,

+2+

Cu(s)+H2O2(aq)+2H(aq)=Cu(aq)+2H2O(1)△H=-319.68kJ/moL

(2)ÉSnT^n,AH3=+(2752kJ/mol-534k]/mol)=+2218kJ/mol;

(3)A.CO»»*;

CW#»»®!

D.IOWÆW;@X2+@X2i+WHÊî2H2(g)+O2(g)=2H2O(1)ÉKJAH;

-1

(4)®RÊÎIP4(s,Ûgf)+5O2(g)=P4O10(S)AH1=—2983.2kJ■mol,&ÈIIP(s,<EW)+

1

|02(g)=ip4O10(s)AH2=—738.5k]■mol",WMÆWhI-ïïx2W4(s,ÔO=4P(s,

M)6^AH;

{5mo1

@62gÉl5^4n50.4Lftn(^««»)6<)^^ÔJ*^7^-ï=°''77^'/,Li=2-25’

.'rL/Il1C)1

!:

n(P4Olo)=xmol,n(P406)=ymol,^^P>Oj^T4'|'HW4x+4y=0.5x4,lOx+6y=2.25x2,

WWx=0.375,y=0.125;

2++2+

(5)Cu-ÈaH2O2MÉÈJ^Cu4llH2OÛ^t^^^ACu(s)+H2O2(aq)+2H(aq)=Cu(aq)+

+2+

2H2O(1),IWfjm;®+(?)x|+@ifWlxlSCu(s)+H2O2(aq)+2H(aq)=Cu(aq)+

2H2O(l)ÉKlAH

ir^HÊ7jfoiëfflH^jft<j-#â,®«/m.

2.CDFe-2e~=Fe2+Cu2++2e_=CuE&M1I11

ffejfeJx/Sÿjïl,RHLiüÎEtWiÉjS/S^ïÜlRKM#1N®ttP0^ÜBCu0.04

[«OrlM:(l)A.Ï?X^NaCl,KWW-J',&JM5S>jlEfô,

S.&^02+2H2O+4e"=40H",i&Afêi£;

B.^XWL^,K^Mffl»,«ÎÈ,&Bfêi£;

CgXftttK-ÈâNfflim,#^W,^JÎE®,iWHWefcœ,fôCjEïfà;

D.#X/jNaCl,ftM,&7gM,»&^<Fe2+M,B

C;

(2)A.Zn>^®,ZnW41Zn2+,-2e“=Zn2+,AiEïiÆ;

B.i£Ek'Mlft0}Zn-^Cu2+R&£j£Zn2+$nCu,Zn+Cu2+=Zn2++Cu,ttBM

C.lMEyfeTW,teCîEîfô;

+

D.IMEyfeTWZn^W,Cu^M,PWW'JCuS04»,D

D;

Fe^^^Fe2+.

^jFe-2e-=Fe2+,^jEtK,îE®±Cu2+M^^ÉË^Cu,ÆfôS®jUgCu2++2e~=Cu,

2+2+

Fe-2e-=Fe;Cu+2e"=Cu;

+2+

@tt^fi££È^Cu+2H=Cu+H2,

JS,Cu+2H+=Cu2++PH

r+

fô±Cu&l'Hf#È-7-±bkH2,

ffe»;

iuWnMwmmwjznmgiÊ,#*?

ü;^X^W,4F^K^S-T-M^^MJ^FÈ^,&MWWS

N;WIÉPHW;

WS^A^a^Cu,B^OFe,PHlSMï^Cu-2e-=Cu2+,PJlfëMïli^Cu2++2e"=Cu,

iSffc^rbH^ffe^xmol,M64x+64x=5.12,W-fêx=0.04,

B;Cu;0.04»

(l)A.^X^NaCl,K'gMffiim,ÏÏSjWR,

B.^XWïfê,mtÉËWSJWtÈ;

C.#XWL^,^îEfô;

D.^X^NaCl,tëNffiW,^ÎÊ®,

(2)ÉIHrOl,WJ^EiLM+Zn^M,M>jZn-2e~=Zn2+,Cu»,.ïEféJ;

SÉËCU2++2e~=Cu,Zn+Cu2+=Zn2++Cu,ffedFfôfêfàjEtK,

(3)®^fèWM^m,OMOIOO,WWM1OM,FeWWe2+,

Cu2+WEë.^£j£Cu;

cu^tfeftmPH

féirj^<7-^^Cu2+,

(4)®^m»zK4’l^^«tÈ4’WMWt!fe.ÆOïliil’,

(2)^X^m,ôJWFe‘5ffeï©Û<J^tKfflfêW»^Û<]^t!ll;^X^^,nJ«ftlEWfW^WMtik;

ÉJSM^IWWH,M

fôJSFÎZï^^jCu-2e-=Cu2+,|^fôRjStX^/Cu2++2e-=Cu»

E&WtkM.&œffl,»FfctëWW»ffcixœ.

^IRJ>wswrfê/WMzH^w^ûWi,«

++

3.[H^]DCjEM'hMd'2NaCl+2H202NaOH+Cl2T+H2îNa(^Na.

+

H)Cl2H2<H2-2e-+20H--2H20

[OrlW:(1)A,^'MiEfôbMMlW,^Efe»»affij£6Wm

ÎKA^BT^;

B»l'tfl'H'^,ï&BÎH£<:

C»afctsa&TM,MIÈigfë,MPfi

D.aifefôMK-7-M,OMWPfl

ifiMélfe,SkDjEfift,

D;

W+IWOiJW,&Afêi£;

C.m«.MMM+yKîlüt-WMM-T-^Efe,iftCŒffi;

DJWctfftPH®,FBW^Mfc,OWW7MiftDfêîM,

ï&^Tj:C;

(3)$ijffl^Wi£^TfiM^itf,««,IWW

fô&<Zn,Fe>CuMCu2++

2e~=Cu,^û9Jt^lt±T#0,«W-Wl'fW,CUS04ÏOÛW®M'JS

JE;M<h;M<b;

U

(4)©>èl?^n<&7KMÆ^;W5£;lk2NaCI+2H2O=2NaOH+Cl2î+H2î’

;

2NaCI+2H2O2NaOH+Cl2î+H2î

1E;

©aEfetKStoÀWiKik/K,&W<£zK,Î^ÆÈiWM&T,

ÆizFNa+(^Na+,H+)&T®£,

+++

Na(s£Na.H);

(5)®Æ»<’/lk^,WBAS^ÉKjMlEa,i$À»WÎK^^fô,BP^^YÉKI

WPW,FEr^^K^Mn,ax^ÉLMM^,MWmM^ÉÈfl^zk,FTr^a%/ET-b%,

^^79:Cl2:H2;<;

BPMH2-2e-+20H-=

2H2O;

H2-2e-+20H-=2H2O;

MM,

:»ttrtënTœW»»;«

(I)A.<W7K^,PHa^ÉËÈüMnwMi^ts^^finw^-^;

BWMWïW&m:

C.gtfS^MÛ,SMMÈ,MîSKmkMfe;

D.WiS^Mfe,OSSWM«Oâ£.

(2)A.^RÆM^ertM^4»^:^^.MWtiti;

Cjm«,

D.fflwtftimIW*OÆ,«««w?»

M&ftimfimM.IW^7tWiEMJ£££M^

&,CuMWM

WÈSWafcMiQx^^azK,ama<&zK,wwæ.

WiJ^-TÿüM^W.Oÿ».ftftWÎfiii,R&2Cr-

2e-=Cl2î,bEtfôâtoÀWaWt^,i#lÆ!£j£NaOH,ÜJiJ^^ièfôb

>3»,mM6ÜW;

(5)©^i§|50®^3cWÉKJ^ffl^^M^â<]T^JM3:a^^jEfô,mWilÀ£

iEJMS/S;

M^AW^WÏ*H^Û<JH^,MSÂ.

4.[^]CAABDT>361.05K<250°C80%^cojxc^HJ^J^mol•(L•

1

min)’BC“ft<tWJWP$iJMCu2O+CO2Cu+CO2|È]lE&tà^fàS^J,a#Cu2OÔ<JlÿF

se

[Ofn?:(i)A.7KÈiWWl«Jfô^,teA^;

B.WJfîMds

CïEïft;

D.-io°cM^7Kê^éë«^@^,

C;

(2)AH=+180.50kJ/mol,AS=+247.3J/(mol-K),âAH-TAS=Off'f,T=0=

730K,BPMitîT73OK0'J-,AH-TAS<0,ÏÈ£O°CHj£273K,

A>1000°C«il273K,

B.1000°C^1273K,BfêîM;

C>730°C>J1003K,i&Cfêîlh

D.^JÈ^ë^jSfîâ<jftïÈiaj®^^730K,fôDfêilb

A;

(3)A.if±H51,WM»,SUE»;

B.MNH4HC03(s)=NH3(g)+H20(g)+C02(g)â<jAH>0,AS>0,MM»,ife^A

H-TAs<o,&B

jEïft;

âW'O-AH-TAS<

MWMÊg,&cfêilh

D.AH<0,AS>0ÉKJM,O(MWWH-TAS<0,8PÆttMa®Mê£WÎT,

OM

ABD;

Na2SO4•10H2O(S)=Na2S04(s)+10H20(g)AH=

(—1384.49kJ/mol)+10x(-241.83kJ/mol)-(-4324.08kJ/mol)=+521.29kJ/mol,AS=

+1443.8J•mol”1-K-1,AH-TAS=(521.3kJ/mol)-298Kx1443.8x10-3kJ/mol=

91kJ/mol>0,T^H^ZiElnJ^ltiÆ^T,

@AH-TAS=(521.3kJ/mol)-Tx1443.8x10-3k]/mol<0,T>361.05K,

T>361.05K;

iiÊInJ^TORÆS,ÎE

l&AH<0,

<;

@c(CO)=0.2mol/L>0.2mol/Lx2L=0.4mol,

CO(g)+2H2(g)#CH3OH(g)

Safêii(mol)260

^M(mol)1.63.21.6

¥fêîit(mol)0.42.81.6

04?R16

c(CO)=-ÿ-mol/L=0.2mol/L,c(H2)—-^-mol/L=1.4mol/L,c(CH3OH)=-^-mol/L=0.8mol/L,

K=«2.041,JW^®>j250oC,COR<J^W=X100%=80%,

0.2x1.42mol

250°C;80%;

JWtÀK=.-(cSxcW^)’

ÈSW,WiïSS.

rcifSVA_/JScirioyi

An%

@È®MïOhÆ5OO°C0t,ItflaJiOJtBBt,fô^v(CH30H)=J=-3-mol•

"b

(L-min)bÉîÈ$Xtb^T4t^i+fi^Ztt3<i±i,v(H2)=v(CH30H)=2x^-mol•(L•

min)-1=-^mol•(L•min)-1,

^-mol•(L•min)-1;

-Y<In]iEl^S^,fPBWWiQÛÜM^,ÊÈfW

BC;

CO2«WW^»M^CU2O^S^JMS^:-MWfiJ-rW$iJRjScu2o+CO#2Cu+

CO2[n]IERj^|n]^J,^^CUzOÉKj*^^.

~M<tW#iJTW$’JJxJ®Cu2O+CO^2Cu4-CO2|È]iEœ^lRjM,tÈ^Cu2OÈÛ>^F

$'.

G=△H-T•△S<OBt,MnTâ^iï

(2)HjSÊ^â^T^ÆTAH-TASM^/bT^>MAH-TAS<0ft<jMiWë:OHj.

Î^^AH-TAS<0;

gAH-TAS<

D.£&g£iïMO^AH-TAS<0,WJIfoH<(kAS>

MOWftiAH—TAS<0;

@AH-TAS<Oi+W:

(5)©fô1g¥W^«Jg£WFr,

MSilWœ.wo

©rinnfSî;

△n

@ÆO^W^v(CH30H)=pRil!^;t!u(CH3OH),

t±Jv(H2);

Wm^¥WWf£n|nI;Og;

@IOCu20OK0æJ$£/tC02Mu,œ^>90T^Mo

Jx/$JO;WWOJ®hWm@Wr>ft^¥WlWW.W

«m^£tt&5£,

5.[^]CCDDBC^/Î^WJAl^œ,^^2œ»,

z<o.01mol/(Lmin)

c(CO)xc(SO2)

[lOrlW:Æ33LMM4WHfêMWtM?M

M,feA^;

cÆm^&i£-jg&#T,WÆ-ÆëSKHlO,fâcim

D.A^SÈWMSf.&

ik^?9:C;

(2)®i[iH2o,

@inKN03M,

(3)^AJL»M,&ÆWW,^6Wïâ<Ji^'3t

©illAXW,

@M{tW,ffiâfm»,fé^iâWIS,i$(5W;

©WATOWSRM,&OiS&Hüfc,MIMFfe'Jfe,Ml»,

d>,fe(6W-;

©TOWWm),MiW«,WWlMT^,fâ®im

©ëfcffllOmLO.lmol/Lit^,Ü@iEfift;

C;

(3)A.^HÎ(^^^Ô<J^^â<]fi^^,feAiE^;

B.V(CO2)W^£,rOnJÇM^,JjllJnJ^>J^nr^RjSiÈS!lTW^W^^,i&BlE^;

C.ffOféC02,B^I'sJlEjxJSîWM'KîÊlx/SiÊ^'FS:,

3E,ttcHi;

==1HC1

DK~C(H2?XC(CO2)SSïï’^2<g)'°2(g)>H2O(g).CO(g)^â«^A0.1mol-L-,

)==1=K

Q=SXX^’

D;

(4)A.fBAN02M,ifANOâ^MlSl'H],iEMiâW^,

jEMiâWA,(0ii5^h-7S^^W.

B.;^/bco2fi^j^®IWl'0J.ïEJxlSjÈ^A^,.jEJxlSjâWr.h,Md'NOlbJJW,IE

SmWds&BfêiM;

cÆW&W^ÀNe,

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