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2022-2023(T)MOO
-v£100.0tf)
i.«smiOMS.
mW,
BâüÀmStm
C.0W»W
D.moœmniiu
(2)(J$&)»(H2NNH2,
aftl^ifé:0=OSOOkJ•mol"1,N-N154kJ■mol-1,WJN-
A.194kJ■mol-1
B.391kJ■mol-1
C.516kJ■mol-1
D.658kJ■mol-1
(3)(/5Æ-Û&lRjS:
1
®2C(s)+02(g)=2C0(g)AH=—221kJ•mol’
13+1
©WM!.H(aq)+OH-(aq)=H2O(1)AH=—57.3kJ•mol"
1
@H2(g)+|02(g)=H2O(g)AH=—241.8kJ■mol’
-1
@H2O(g)=H2O(1)AH=—44.0kJ•mol
______o
110.5kJ•mol
B.^M^NaOHfê^S&£j£lmol7K,^tti57.3kj^>
C.M^Ô<J®^A241.8kJ■mol-1
-1
D.2H2(g)+02(g)=2H2O(1)AH=-571.6kJ•mol
(4)ÉIm,^^^î.f^p4o6,
$nÆÆ.WMP4o10o
®B^298KB^ÉI^>
-1
P4(s,ÉIW)+5O2(g)=P4010(S)AH1=—2983.2kJ•mol
P(s,M)+?0(g)=7P0(S)AH=-738.5k]•mol’1
4244102
È^)+3O2(g)=P406(s)AH=
—1638RJ•mol-1,ÏE^^Efl^4’ljnA62gâWW50.4LM^(^^ÿt),fëMâH'H£±-^ï
oKÜFrWSJCKJP4O105P4o6ûWiÛ<J:SAbt>JSSiÉë’t’TAfBl'Kl&®A
(5)fflH2o2flH2so4fô?gWTOB&J:
+2+1
(î)Cu(s)+2H(aq)=Cu(aq)+H2(g)AH1=+64.39kJ•mol’
1
@2H2O2(1)=2H2O(1)+O2(g)AH2=-196.46kJ■mol"
1
(3)H2(g)+|02(g)=H20(l)AH3=—285.84kJ•mol’
12+
ÆH2SO4ϧ^4-CuAH2O2^ÉkjSCu>fnH2OÉ<J^{-t^^ïÇA
2N(g)+4H(g)+2O(g)
?r
IÊM
ÀHt
AH?=—2752kj/mol
N2H4(g)+O2(g);
AH,=-534kj/moli
________i__Ï
MSN2(g)+2H2O(g)
2.
Hjbtra&MWtÈME,
(1)(M)^M^S=W,TJiJzWiEmW^
A.^XANaCl,A2C1"-2e"=Cl2î
CiftXMW-»4>H+[n]FeEyg^J
D.^X^NaCl,KJgNfflW,Feffca±£W&ttfeW#.rôG
(2)(OWl!ïiW®)lM.
Zn+Cu2+=Zn2++Cu
cÆ^ièE^,!li-fAftttfiïEfi
+
D.Wf4WféfàZnS04»
(3)ift:fëMlel?iJIRJ®;
ÈtëlMOW,OnW.
W____
+2+
eu+2H=Cu+H2,
oS.Éê:
Wftko7'jl^jhü^J^îÈ,1S
MmW£Wzl<Mâ<JZn&a£,(«“IE”B£“^”)affljîo
ibo^x^,JF^K£-TM^,î^iW^FiÈ^□
a.^w#>-T-tx(«A^B),
JfiM$j5.12g,WJEfeWEtïOMlÏÏEè?>gmol»
3.ww
JW,ÀtfÆ^Ti^Wfflœn14».
(l)(M)ÿnSXM^%^Na2S047K'M^fi«MJHÆÇMfôaWWM»
ZLW^»»T^WMJS^jEïÆWM,
-=<l^-
IÙBÙI
NaJSOJfr?ftvv;-^
AJ&ÎÜ^ÉHJWÏ.aEyO'b^bffeM
B-tfeMtu■■-Ill«Hl
c.am^isfjÆsafe,b^amÆMfe
D.aÈfôPftiÆMfe,bEfefëMMfe
(2)(j£Æ)iWfê&,£&Fe+2H2O=Fe(OH)2+H2âÙÆ.
MWbEfeMW
c.mjwmmfô,
FHffelS,
w
(±ft“fê*”>
“M/h”sS“«”,TfêR).«
©füfelMïO(«“JE”“FC”)®.
&T(WL^)®îî»
(5)--^W<ft¥'/fe^04Efe'»^^ËjrrlZ^itMMl>lk^^30%W±ottW2».
ü«
A(tè^ji!i)BfBMtfeiik)
®mx.yœ,ffi^4>ab(««>”,“<”
Ï£“=”).
©iW^OWlliB^«
®iÈt¥«i+W±^nê±^ÆT
4.ZKStè±4OiJAWWM^JfcW4t^R&8&*!bjg
ww1-^s^âü^^.o
(l)(WÆTTOê£Wg4',o
A.AÈKMfàfÈ#b
-1
B.2H2(g)+02(g)=8Hz0(l)AH=-483.6kJ•moi
cÆ/KMÆzK^rOJÊ'HW
D.-io°cWM^zKâ^«^S^
(2)(W)WEfeB>J-$^4<JN24nO2꣣RJw.:N2(g)+02(g)=2N0(g)AH=+180.50kJ•
mol"1,âS=+247.3Jmor1K"1,ÆllTWi£+ïEfà
lWo
AÆIOOO°(M,
BÆIOOO°CM.
c.gSÈiÈœ^S®fi®^Wc
D.T^RÉZ^êMffi<T»M^W30K
(3)(^fé^iâ^)T?Ü<ï£lEMM»
A.iWbm«W.«XESUÉiWm
B.NH4HC03(s)=NH3(g)+H2O(g)+CO2(g)AH=+185.57kJ•moMt&ÈOfî.
&êmig'/gfiLSüiraôü|RJfffi[è]
Œ»««MMgg
D.AH<0.AS>OtfOOWWSW
(4)B$11298KÜ-J-wTÿlJUcië:
Na2S04•10H2O(S)Na2S04(s)H2O(g)
AH/kJ■mol-1-4324.08-1384.49-241.83
1-1
Na2SO4•10H2O(S)=Na2S04(s)4-10H2O(g)AS=+1443.8J■mol"•K
(î)±Wm298K0'J-nÈ;i’?gMIT?»
fi'JÎnn^?lï|l|^«
(5)W(CH3OH)M~^MM£BW,
œI:CO(g)+2H2(g)CH3OH(g)AH
ïnn/5250°C300°C350°C
K2.0410.2700.012
È^mg^lJW,AH0(±«“>”,“=”“<”)o
]
©«SJtT,W2molCOfll6nwlH2^À2LÛ^|'flM4,»W0]=
O^molL-1,oC(M^4'iâS)«
(6)-Æ£#T,ÆW^3LMfflW*.
Cu2O/ZnO):CO(g)+2H2(g)#CH3OH(g),
KM(M“i^”“M
/]>”)o
@ÎË500°C,M^ÉlW$Jxfàjâ^v(H2)=«
»WM«io
A.^fôM<d>
D.M«r¥Wn;Q^CngïUinn)të*
@fâWK,£M4«ftWCu2O,ffiïH
Ê^^^ü®co2^swfiJT^iem^cu2o6<j*«,
ASSOISo
▲n^B'/J/mol
[ft^A300“C
n(A)
n(B)7^fttltlîB500X2
0«(B)r(A)
5.
(l)(W)WTi^£îE^Éi<j^»
A.^uini4t^œWWHMHWM>JE^
D.H^W^ÆWâÙHit
(2)(Mjâ)/>fii^>ï-^ioomLo.oimoi/Li^^&gêM,^WÀIt.^TtnOsH&WrfD
®JHH2O
@iOKN03^M
©WÀJLîW'^ikf®
@WNaClï§^
®^ffll00mL0.01mol/Lüg£'.
A-®@@
B®®®
c.@®@
D.®@®@®
(3)0£&)^MT,H2(g)+C02(g)^H20(g)+C0(g)AH>0oBftl
-11
H2^C02^JféM^0.1mol■L,¥WW$H2ï£Oj0.04mol•L",T?i]
B.VŒ(C02)=
c.^iigiJT^^S±Hl^co2,
1
D.^H2(g)sCO2(g).H2O(g)>CO(g)IU^JtBj^0.1mol-L-,MMMiâfif
nÊf5ÜNO2(g)+CO(g)CO2(g)+N0(g)iEMjÉ$it^KJS4t^T
WWWfW»»
A.it^NO2^COÈÜifcg
BM'bCO^NOfôjfêfë
C.«ÀNeTO«fê*
D.fl-^JxÉZÔÙW
(5)(^Æ^^W)^WL(COS)B]-^>9-ft^Wl^JÏlJ,^CO>fUH2S7fê^n
«iÈSlJTJlJTW:CO(g)+H2S(g)#COS(g)+H2(g)K=O.lcMIÎCOÛ^WiWft^lOmob
¥W/HCOMÔ<J>^8mol,-RiJWîEfà&Ü^»
A,#a-^?W.H2s^Min,
B.jffiÀCOJe,
C.kJSWH2S^ffiWfi^7mol
D.COÔ«jY^4t^^80%
(6)^Æ£^A®Éfi^#5.0g&À^W500mL0.5mol•L’WlfêfiW'K
fciï.r*wwwmiHJI$MW$nmÉÛM®?ÜM®=
®IttaEli0~ali'J®
(7)Uk±^iso2^<^^^üo
WjWI^+l&£SO2ft<]^&i-:2C0(g)+SO2(g)#2CO2(g)+S(1)(AH<0)o
©iSMlOTW^WiiïC'aMMflm¥W
(W“»”>“£'/h”>£“«”)o
(2)$n0^¥W^so2W^ftÆ7FRM®TBIffi5ââ<]^ft^,Wr=TxT2(iâ«“>”s
,
(3)^2LÛ<J^I^»bjïfï±^lS>É5’aiJ»5min|*lWÛ<)®ftMd<ri.6g,!jJiJo~5min(l<J
¥J$MiÈ$v(CO2)=o
(i)Mi>ik^w,
(2)MW'ê-^^M^-fi<J^IÉÈJ*:Z-ofêfflFeW.OJ.fè$i|fiJ®773K,
H5M3.Ox105Pa,JMWNzWzWTOiJttk^l:3,
______o
(3)A>J^»Ï4«-^fflK2,^^*K^*WNO2®iÉK1.K3OJ?EÀA.
B4>,MÆüW,A.BÈWR;fê|s][B&:2N02(g)N2O4(g)AH<0]«
(ÎWWlW,&ÆiÈglJ¥W.WA.B+^^fKjN2O4â<J»^v(A)v(B)(±A
“>”“<”“=”);WïÈ£K2l(±«“W”)»
£#A.B+WÆX'-j^JfèfîUII^^NO,,JÜfôSÜTW,NO2lWtt.^a(A)
(iA“±^”“M/h”Wc“^”);WJiiSiJ¥W,A41
a
N02W^4tW.B^NO^Wfê(±A^”“^”sK)o
£A.BW^W«>WJü
SlJWlH'h
(4)^Æ^g^A^^À4.6gâ<JNO2,WÜ
¥WH’tN2O4âÙ^Kfi^J________«
1.[^]ABADP4(s,SW)=4P(s,OT)AH=-29.2k]/mol3:11323.45kJCu(s)+
+2+
H2O2(aq)+2H(aq)=Cu(aq)+2H2O(1)△H=-319.68k]/mol
A
feciESÆ;
A;
(2)ÉKnj^ll,AH3=+(2752k]/mol—534kJ/mol)=+2218kJ/mol,i5N-HWt^xkJ/mol,
RIJ154+4x+500=2218,fWt#x=391,KPN-HMÉfê?g391kJ/mol,
B;
-1
(3)A.2C(s)+02(g)=2CO(g)AH=—221kJ■mol,COMMHlM,
110.5kJ/mol,î&AIEfifô;
WMfôfê^NaOHMM^J&lmolzlGSfcfBW^>^T57.3kJ,&
Bfê^;
-1
C-H2(g)+|02(g)=H2O(g)AH=—241.8kJ■mol,
^ÀT241.8kJ-mor1,
1
D.tëfëMféfêh@X2+@X2ilMM2H2(g)+O2(g)=2H2O(l)â-JAH=-241.8kJ•moPx
2+(—44k]•mol-1)x2=—571.6kJ/mol,Dit'fift;
AD;
-1
(4)®MIP4(S,ÛW)+5O2(g)=P4O10(S)AH1=-2983.2k]•mol,£jÈIIP(s,OT)+
-1
|O2(g)=^P4O10(s)AH2=—738.5k)•mol,OJM»;I-Hx2i+WP4(s,ÔW)=4P(s,
-1-1
M)^JAH=-2983.2kJ•mol-(-738.5kJ•mol)x4=-29.2kJ/mol,^^^®^>jP4(s,
A5^)=4P(s,aï^)AH=-29.2kJ/moL
P4(s,SW)=4P(s,OT)AH=-29.2kJ/mol;
@62gâW^50.4LM^(^mWÆ)^W=0.5moL-5°^=2.25,iâ
1IIlOlzz.^L/moi
n(P4Olo)=xmol,n(P406)=ymol.OJÜ-jFyfHHW4x+4y=0.5x4,lOx+6y=2.25x2,
<
WWx=0.375,y=0.125,RlJP/rWïlJflJP4O10-lgP4O6K^^ft<J*±LtA0.375mol:0.125mol=3:
1,Mtôiïfë1^HlMMA2983.2kJ•mol"1x0.375mol+1638kJ•mol"1x0.125mol=
1323.45kJ,
3:1;1323.45kJ;
2++2+
(5)Cu^H2O25ÎJ'V/È^CufllH2Of'l<j{t^7jgxUjCu(s)+H2O2(aq)+2H(aq)=Cu(aq)+
î+2+
2H2O(1),OîMJTAÎÉÎ^:@+@x|+@i't'^S.5ZCu(s)+H2O2(aq)+2H(aq)=Cu(aq)+
11-1
2H2O(l)ÉKlAH=+64.39kJ•mol"+(-196.46kJ•mol")x|+(—285.84kJ•mol)=
+2+
-319.68kJ/mol,M^Sï^Cu(s)+H2O2(aq)+2H(aq)=Cu(aq)+2H2O(1)△H=
—319.68kJ/mol,
+2+
Cu(s)+H2O2(aq)+2H(aq)=Cu(aq)+2H2O(1)△H=-319.68kJ/moL
(2)ÉSnT^n,AH3=+(2752kJ/mol-534k]/mol)=+2218kJ/mol;
(3)A.CO»»*;
CW#»»®!
D.IOWÆW;@X2+@X2i+WHÊî2H2(g)+O2(g)=2H2O(1)ÉKJAH;
-1
(4)®RÊÎIP4(s,Ûgf)+5O2(g)=P4O10(S)AH1=—2983.2kJ■mol,&ÈIIP(s,<EW)+
1
|02(g)=ip4O10(s)AH2=—738.5k]■mol",WMÆWhI-ïïx2W4(s,ÔO=4P(s,
M)6^AH;
{5mo1
@62gÉl5^4n50.4Lftn(^««»)6<)^^ÔJ*^7^-ï=°''77^'/,Li=2-25’
.'rL/Il1C)1
!:
n(P4Olo)=xmol,n(P406)=ymol,^^P>Oj^T4'|'HW4x+4y=0.5x4,lOx+6y=2.25x2,
WWx=0.375,y=0.125;
2++2+
(5)Cu-ÈaH2O2MÉÈJ^Cu4llH2OÛ^t^^^ACu(s)+H2O2(aq)+2H(aq)=Cu(aq)+
+2+
2H2O(1),IWfjm;®+(?)x|+@ifWlxlSCu(s)+H2O2(aq)+2H(aq)=Cu(aq)+
2H2O(l)ÉKlAH
ir^HÊ7jfoiëfflH^jft<j-#â,®«/m.
2.CDFe-2e~=Fe2+Cu2++2e_=CuE&M1I11
ffejfeJx/Sÿjïl,RHLiüÎEtWiÉjS/S^ïÜlRKM#1N®ttP0^ÜBCu0.04
[«OrlM:(l)A.Ï?X^NaCl,KWW-J',&JM5S>jlEfô,
S.&^02+2H2O+4e"=40H",i&Afêi£;
B.^XWL^,K^Mffl»,«ÎÈ,&Bfêi£;
CgXftttK-ÈâNfflim,#^W,^JÎE®,iWHWefcœ,fôCjEïfà;
D.#X/jNaCl,ftM,&7gM,»&^<Fe2+M,B
C;
(2)A.Zn>^®,ZnW41Zn2+,-2e“=Zn2+,AiEïiÆ;
B.i£Ek'Mlft0}Zn-^Cu2+R&£j£Zn2+$nCu,Zn+Cu2+=Zn2++Cu,ttBM
C.lMEyfeTW,teCîEîfô;
+
D.IMEyfeTWZn^W,Cu^M,PWW'JCuS04»,D
D;
Fe^^^Fe2+.
^jFe-2e-=Fe2+,^jEtK,îE®±Cu2+M^^ÉË^Cu,ÆfôS®jUgCu2++2e~=Cu,
2+2+
Fe-2e-=Fe;Cu+2e"=Cu;
+2+
@tt^fi££È^Cu+2H=Cu+H2,
JS,Cu+2H+=Cu2++PH
r+
fô±Cu&l'Hf#È-7-±bkH2,
ffe»;
iuWnMwmmwjznmgiÊ,#*?
ü;^X^W,4F^K^S-T-M^^MJ^FÈ^,&MWWS
N;WIÉPHW;
WS^A^a^Cu,B^OFe,PHlSMï^Cu-2e-=Cu2+,PJlfëMïli^Cu2++2e"=Cu,
iSffc^rbH^ffe^xmol,M64x+64x=5.12,W-fêx=0.04,
B;Cu;0.04»
(l)A.^X^NaCl,K'gMffiim,ÏÏSjWR,
B.^XWïfê,mtÉËWSJWtÈ;
C.#XWL^,^îEfô;
D.^X^NaCl,tëNffiW,^ÎÊ®,
(2)ÉIHrOl,WJ^EiLM+Zn^M,M>jZn-2e~=Zn2+,Cu»,.ïEféJ;
SÉËCU2++2e~=Cu,Zn+Cu2+=Zn2++Cu,ffedFfôfêfàjEtK,
(3)®^fèWM^m,OMOIOO,WWM1OM,FeWWe2+,
Cu2+WEë.^£j£Cu;
cu^tfeftmPH
féirj^<7-^^Cu2+,
(4)®^m»zK4’l^^«tÈ4’WMWt!fe.ÆOïliil’,
(2)^X^m,ôJWFe‘5ffeï©Û<J^tKfflfêW»^Û<]^t!ll;^X^^,nJ«ftlEWfW^WMtik;
ÉJSM^IWWH,M
fôJSFÎZï^^jCu-2e-=Cu2+,|^fôRjStX^/Cu2++2e-=Cu»
E&WtkM.&œffl,»FfctëWW»ffcixœ.
^IRJ>wswrfê/WMzH^w^ûWi,«
++
3.[H^]DCjEM'hMd'2NaCl+2H202NaOH+Cl2T+H2îNa(^Na.
+
H)Cl2H2<H2-2e-+20H--2H20
[OrlW:(1)A,^'MiEfôbMMlW,^Efe»»affij£6Wm
ÎKA^BT^;
B»l'tfl'H'^,ï&BÎH£<:
C»afctsa&TM,MIÈigfë,MPfi
D.aifefôMK-7-M,OMWPfl
ifiMélfe,SkDjEfift,
D;
W+IWOiJW,&Afêi£;
C.m«.MMM+yKîlüt-WMM-T-^Efe,iftCŒffi;
DJWctfftPH®,FBW^Mfc,OWW7MiftDfêîM,
ï&^Tj:C;
(3)$ijffl^Wi£^TfiM^itf,««,IWW
fô&<Zn,Fe>CuMCu2++
2e~=Cu,^û9Jt^lt±T#0,«W-Wl'fW,CUS04ÏOÛW®M'JS
JE;M<h;M<b;
U
(4)©>èl?^n<&7KMÆ^;W5£;lk2NaCI+2H2O=2NaOH+Cl2î+H2î’
;
2NaCI+2H2O2NaOH+Cl2î+H2î
1E;
©aEfetKStoÀWiKik/K,&W<£zK,Î^ÆÈiWM&T,
ÆizFNa+(^Na+,H+)&T®£,
+++
Na(s£Na.H);
(5)®Æ»<’/lk^,WBAS^ÉKjMlEa,i$À»WÎK^^fô,BP^^YÉKI
WPW,FEr^^K^Mn,ax^ÉLMM^,MWmM^ÉÈfl^zk,FTr^a%/ET-b%,
^^79:Cl2:H2;<;
BPMH2-2e-+20H-=
2H2O;
H2-2e-+20H-=2H2O;
MM,
:»ttrtënTœW»»;«
(I)A.<W7K^,PHa^ÉËÈüMnwMi^ts^^finw^-^;
BWMWïW&m:
C.gtfS^MÛ,SMMÈ,MîSKmkMfe;
D.WiS^Mfe,OSSWM«Oâ£.
(2)A.^RÆM^ertM^4»^:^^.MWtiti;
Cjm«,
D.fflwtftimIW*OÆ,«««w?»
M&ftimfimM.IW^7tWiEMJ£££M^
&,CuMWM
WÈSWafcMiQx^^azK,ama<&zK,wwæ.
WiJ^-TÿüM^W.Oÿ».ftftWÎfiii,R&2Cr-
2e-=Cl2î,bEtfôâtoÀWaWt^,i#lÆ!£j£NaOH,ÜJiJ^^ièfôb
>3»,mM6ÜW;
(5)©^i§|50®^3cWÉKJ^ffl^^M^â<]T^JM3:a^^jEfô,mWilÀ£
iEJMS/S;
M^AW^WÏ*H^Û<JH^,MSÂ.
4.[^]CAABDT>361.05K<250°C80%^cojxc^HJ^J^mol•(L•
1
min)’BC“ft<tWJWP$iJMCu2O+CO2Cu+CO2|È]lE&tà^fàS^J,a#Cu2OÔ<JlÿF
se
[Ofn?:(i)A.7KÈiWWl«Jfô^,teA^;
B.WJfîMds
CïEïft;
D.-io°cM^7Kê^éë«^@^,
C;
(2)AH=+180.50kJ/mol,AS=+247.3J/(mol-K),âAH-TAS=Off'f,T=0=
730K,BPMitîT73OK0'J-,AH-TAS<0,ÏÈ£O°CHj£273K,
A>1000°C«il273K,
B.1000°C^1273K,BfêîM;
C>730°C>J1003K,i&Cfêîlh
D.^JÈ^ë^jSfîâ<jftïÈiaj®^^730K,fôDfêilb
A;
(3)A.if±H51,WM»,SUE»;
B.MNH4HC03(s)=NH3(g)+H20(g)+C02(g)â<jAH>0,AS>0,MM»,ife^A
H-TAs<o,&B
jEïft;
âW'O-AH-TAS<
MWMÊg,&cfêilh
D.AH<0,AS>0ÉKJM,O(MWWH-TAS<0,8PÆttMa®Mê£WÎT,
OM
ABD;
Na2SO4•10H2O(S)=Na2S04(s)+10H20(g)AH=
(—1384.49kJ/mol)+10x(-241.83kJ/mol)-(-4324.08kJ/mol)=+521.29kJ/mol,AS=
+1443.8J•mol”1-K-1,AH-TAS=(521.3kJ/mol)-298Kx1443.8x10-3kJ/mol=
91kJ/mol>0,T^H^ZiElnJ^ltiÆ^T,
@AH-TAS=(521.3kJ/mol)-Tx1443.8x10-3k]/mol<0,T>361.05K,
T>361.05K;
iiÊInJ^TORÆS,ÎE
l&AH<0,
<;
@c(CO)=0.2mol/L>0.2mol/Lx2L=0.4mol,
CO(g)+2H2(g)#CH3OH(g)
Safêii(mol)260
^M(mol)1.63.21.6
¥fêîit(mol)0.42.81.6
04?R16
c(CO)=-ÿ-mol/L=0.2mol/L,c(H2)—-^-mol/L=1.4mol/L,c(CH3OH)=-^-mol/L=0.8mol/L,
K=«2.041,JW^®>j250oC,COR<J^W=X100%=80%,
0.2x1.42mol
250°C;80%;
JWtÀK=.-(cSxcW^)’
ÈSW,WiïSS.
rcifSVA_/JScirioyi
An%
@È®MïOhÆ5OO°C0t,ItflaJiOJtBBt,fô^v(CH30H)=J=-3-mol•
"b
(L-min)bÉîÈ$Xtb^T4t^i+fi^Ztt3<i±i,v(H2)=v(CH30H)=2x^-mol•(L•
min)-1=-^mol•(L•min)-1,
^-mol•(L•min)-1;
-Y<In]iEl^S^,fPBWWiQÛÜM^,ÊÈfW
BC;
CO2«WW^»M^CU2O^S^JMS^:-MWfiJ-rW$iJRjScu2o+CO#2Cu+
CO2[n]IERj^|n]^J,^^CUzOÉKj*^^.
~M<tW#iJTW$’JJxJ®Cu2O+CO^2Cu4-CO2|È]iEœ^lRjM,tÈ^Cu2OÈÛ>^F
$'.
G=△H-T•△S<OBt,MnTâ^iï
(2)HjSÊ^â^T^ÆTAH-TASM^/bT^>MAH-TAS<0ft<jMiWë:OHj.
Î^^AH-TAS<0;
gAH-TAS<
D.£&g£iïMO^AH-TAS<0,WJIfoH<(kAS>
MOWftiAH—TAS<0;
@AH-TAS<Oi+W:
(5)©fô1g¥W^«Jg£WFr,
MSilWœ.wo
©rinnfSî;
△n
@ÆO^W^v(CH30H)=pRil!^;t!u(CH3OH),
t±Jv(H2);
Wm^¥WWf£n|nI;Og;
@IOCu20OK0æJ$£/tC02Mu,œ^>90T^Mo
Jx/$JO;WWOJ®hWm@Wr>ft^¥WlWW.W
«m^£tt&5£,
5.[^]CCDDBC^/Î^WJAl^œ,^^2œ»,
z<o.01mol/(Lmin)
c(CO)xc(SO2)
[lOrlW:Æ33LMM4WHfêMWtM?M
M,feA^;
cÆm^&i£-jgT,WÆ-ÆëSKHlO,fâcim
D.A^SÈWMSf.&
ik^?9:C;
(2)®i[iH2o,
@inKN03M,
(3)^AJL»M,&ÆWW,^6Wïâ<Ji^'3t
©illAXW,
@M{tW,ffiâfm»,fé^iâWIS,i$(5W;
©WATOWSRM,&OiS&Hüfc,MIMFfe'Jfe,Ml»,
d>,fe(6W-;
©TOWWm),MiW«,WWlMT^,fâ®im
©ëfcffllOmLO.lmol/Lit^,Ü@iEfift;
C;
(3)A.^HÎ(^^^Ô<J^^â<]fi^^,feAiE^;
B.V(CO2)W^£,rOnJÇM^,JjllJnJ^>J^nr^RjSiÈS!lTW^W^^,i&BlE^;
C.ffOféC02,B^I'sJlEjxJSîWM'KîÊlx/SiÊ^'FS:,
3E,ttcHi;
==1HC1
DK~C(H2?XC(CO2)SSïï’^2<g)'°2(g)>H2O(g).CO(g)^â«^A0.1mol-L-,
)==1=K
Q=SXX^’
D;
(4)A.fBAN02M,ifANOâ^MlSl'H],iEMiâW^,
jEMiâWA,(0ii5^h-7S^^W.
B.;^/bco2fi^j^®IWl'0J.ïEJxlSjÈ^A^,.jEJxlSjâWr.h,Md'NOlbJJW,IE
SmWds&BfêiM;
cÆW&W^ÀNe,
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