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CHEMICALSINTHEWORKPLACEEsraYILMAZEnvironmentalEngineerCHEMICALSINTHEWORKPLACEEsra12ContentGeneralinformationaboutchemicalsRoutesofentryintothebody/healtheffectsCommonchemicalgroupsthatcausehealthrisksFactorsthatdeterminethetypeoftoxiceffectachemicalcanhaveonyou.2ContentGeneralinformationa23CHAPTERI:Generalinformationaboutchemicals3CHAPTERI:34ChemicalsChemicalsareapartofeveryone'slife.Therearefivetosevenmilliondifferentchemicalsknownintheworld.Atleastfourhundredmilliontonnesofchemicalsareproducedworldwideeachyear(includingagriculturalchemicals,foodadditives,fuelsforpowerproduction,chemicalconsumerproducts,etc.)4ChemicalsChemicalsareapart45Typesofchemicalsfoundintheworkplace
Themainphysicalformsofchemicalsaresolids,dusts,liquids,vapoursandgases.5Typesofchemicalsfoundint56Solids
Solidsaretheleastlikelyofthechemicalformstocausechemicalpoisoning.
6SolidsSolidsaretheleas6
Dustsaretinyparticlesofsolids.
Dusts
Dustsaretinyparticle78LiquidsManyhazardoussubstances,suchasacidsandsolvents,areliquidswhentheyareatnormaltemperature.8LiquidsManyhazardoussubs89
Vapours
Avapouristhegasphaseofamaterialwhichisnormallyliquidunderstandardconditions.9VapoursAvapouristhe910
Gases
Somechemicalsubstancesareintheformofagaswhentheyareatanormaltemperature.However,somechemicalsinliquidorsolidformbecomegaseswhentheyareheated.
10GasesSomechemicalsub1011ClassificationAccordingtoBiologicalEffectsAsphyxiantgases
IrritantgasesChlorine,phosgene,nitrogencompoundsSystematicgasesalcohols
andcarbontetrachloride
NarcoticgasesToluene,benzeneSimpleasphyxiants(CO2,methane,ethane,buthane,nitrogengases)Chemicalasphyxiants(CO,hydrogensulphide
)Gases
11AsphyxiantgasesIrritantga1112CHAPTERII:Routesofentryintothebody/healtheffects12CHAPTERII:1213ROUTESofENTRYINTOTHEBODYIngestionInhalation
Contactwithskinoreyes(absorption)13ROUTESofENTRYINTOTHEBOD1314ROUTESofENTRYINTOTHEBODY-1InhalationMorehazardousagentsgetintoyourbodybyinhalation
(bybeingbreathedin)thanbyanyotherroute.
14ROUTESofENTRYINTOTHEBOD1415Howdoyouknowwhetheryouarebeingexposedtorespiratoryhazardsatwork?
smell
sneezing
coughing
arunnynose
Warningsignalsare:15Howdoyouknowwhetheryou1516ROUTESofENTRYINTOTHEBODY-2IngestionHazardousagentscanalsogetintothebodybyingestion.
16ROUTESofENTRYINTOTHEBOD1617ROUTESofENTRYINTOTHEBODY-3AbsorptionSomechemicals(suchasstrongacidsandalkalis)candamageyourskin.Thisconditioniscalleddermatitis.
17ROUTESofENTRYINTOTHEBOD1718Contactdermatitis
Anothercommonoccupationalskindiseaseiscontactdermatitis—atypeofallergicreaction.18Contactdermatitis Anotherc1819Someofthechemicalsthatcausecontactdermatitisare:
formaldehyde;nickelcompounds;epoxyresinsandcatalystsusedintheplasticsindustry;germicidalagentsusedinsoapandothercleanerschromates.
19Someofthechemicalsthatc1920CHAPTERIII:Commonchemicalgroupsthatcausehealthrisks20CHAPTERIII:2021GasesSulphuroxides,
Nitrogenoxides,
Chlorine,AmmoniaSometoxicgasesarecorrosiveandirritatingtotherespiratorysystem.HydrogencyanideSomegasescanpassthroughtheskinCarbonmonoxideSomegasesmayenterthebloodcirculation.21GasesSulphuroxides,Someto2122SolventsMostindustrialsolventsareliquidorganicchemicalsManyofthemevaporaterapidlyatambienttemperaturesTheyareoftenflammableandmayignitebyheatfromsmoking,weldingorstaticelectricity.Exampleofverydangeroussolvents:Benzene,carbontetracloride,carbondisulphide.22SolventsMostindustrialsol2223MetalsMetalscanenterthebodyintheformofdustandfumes(ingrindingorwelding)oreventhroughtheskin.
23MetalsMetalscanentert2324Acidsandbases
Strongacidsandbasesaremostlyusedaswatersolutions.Theyarecorrosivetohumantissue.24Acidsandbases Strongacid2425Pesticides
Pesticidesareusedinindustry,forexample,toimpregnatewood,andinagriculturetocontrolinsects,weed,fungi,andrats.
25PesticidesPesticidesare2526Differentorgansandtissuesthatcanbeaffectedbycertaintoxicindustrialchemicals.
26Differentorgansandtissues2627CHAPTERIV:Factorsthatdeterminethetypeoftoxiceffectachemicalcanhaveonyou.27CHAPTERIV:2728therouteofentrybywhichthechemicalgetsintothebodytheworker'sindividualresponsetothechemical,whichcanvaryagreatdealfrompersontopersonthefrequency,concentration,andlengthofexposurethephysicalformofthechemical(dust,vapour,liquid,etc.)
thechemicalcompositionofthehazardoussubstance
theparticulartissuesandorgansinwhichthechemicalcollectsorlocalizesfactorsthatdeterminethetypeoftoxiceffectachemicalcanhaveonyoufactorsthatdeterminethetypeoftoxiceffect
achemicalcanhaveonyou
28therouteofentrytheworke2829Chemical
Physicalform
Methodof
entry
Organ(s)that
canbe
affected
Classof
effectExamplesof
CadmiummetalandsomeofitscompoundsDusts,vapoursDusts
InhalationIngestionLungs,throat,
kidneysPoisonous,causingdamagetolungs,kidneysonchronicexposure.
Metalindustries,weldingprocesses,heavychemicalsBenzeneVapourInhalation
Absorption
throughskin
Brain,bone,marrow,skin
Poisonous.
Possibly
carcinogenic
Manyindustrialactivities,especiallychemicalindustry,adhesives,
paints,etc.
Nickeland
someofits
compoundsDusts
VapourAbsorption
throughskinInhalationSkinLungs,
nasal
passagesDermatitic
Irritantin
lungs
(nickelcarbonyl).
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