科莱恩农药增效助剂Synergen GL 5

ClariantCropSolutionsProductPortfolioDispersogen®PG3ConfidentialPolymericdispersingagentandadjuvantbasedpolyglycerolesterderivedfromcoconutfattyacidCombinesexcellentdispersionpowerwiththeprovenadjuvanteffectsforthisclassofchemistrySUSTAINABLEDESIGNProductcompositionFriendly,non-hazardousmaterialNPEOfreeBasedonpolyglycerolesterandcoconutfattyacidsRenewableshareca.95%RESPONSIBLEPROCESSProductmanufacturingResourceefficiencyduetohighyield(>85%)toavoidwasteduringmanufacturingCertifiedforsafety&qualityaccordingtoISO9001,ISO14001andOHSAS18001SAFE&EFFICIENTUSEProductformulationandapplicationSafehandlingduetoimprovedhumantoxprofile,i.e.nonirritanttoeyeandskinSolutioninwaterforeasyhandlingLesscomplexformulationduetomultifunctionality,i.e.dispersingagentwithadjuvantcharacteristicsIncreasingefficacyofagrochemicalformulationEfficientusebyreducingwaterconsumptionduringapplicationECOINTEGRATIONProductenvironmentalfateImprovedenvironmentalprofileInherentlybiodegradable(biodegradation42%in28daysaccordingtoOECD301B)>>backtooverviewslideWettinganddispersingagents

New:DispersogenPGDispersogenPGThefirstdispersingagentbasedonClariant’sproprietarypolyglycerolesterchemistryplatformComposition:cross-linkedpolyglycerolester(70%inwater)EPAexemptedunderCFR§180.910DispersogenPGis–likeallotherpolyglycerolesterderivatives–derivedfromnaturalstartingmaterialsExcellenttox-andeco-toxprofile,nohazardouslabelingrequired4ConfidentialWettinganddispersingagents

New:DispersogenPGAdvantages:SCsareenvironmentallyfavorableformulationtypeswithgrowingmarketshareHowever,comparedtoformulations,containingtheactiveingredientindissolvedform,thebioavailabilityisreducedandadjuvantsarenecessaryforcomparableperformanceBecauseofitsuniquestructure,DispersogenPGcombinestwofunctions:dispersingagentandadjuvant–the“DispersingAdjuvant”ItisthereforetheoptimalsolutionforadjuvantsupportedSCformulationsInaddition,DispersogenPGcanbeincludedinSCformulationsathighloadingswithoutnegativeinfluenceonthestability5ConfidentialGlyphosateAdjuvants

The“Ideal”GlyphosateAdjuvantGoodcost-performanceprofileGoodwetting(fastcoverageofleaves,littlelosses)Penetrationenhancement(acceleratesslowpenetrationofGlyphosate)Providesrainfastness(eliminatesrapidwash-off)Safe&environmentallyfriendly(nottoxic,notirritating,noteco-toxic),ideallynohazardouslabelingImprovespropertiesofformulatedproduct(lowviscosity,easydissolutioninwater,heatandcoldtemperaturestability,acceptablefoaming)CompatiblewithvarioussaltsandloadingsNotphytotoxic(Glyphosatetolerantcrops!)Confidential6GlyphosateAdjuvants

HerbicidalPerformanceGlyphosatealoneisbiologicallynotveryefficient,the

additionofanadjuvantboostsherbicidalactivity

dramaticallyThechoiceofadjuvantiscrucialfortheperformance

oftheGlyphosateproductTallowamineethoxylateswithmediumEOrangework

verywell,arecostefficientandhavebeenthefirstchoiceformanyyearsNewformulationtypes(e.g.potassiumsalt)andhigh-loadformulationsrequirealternativeadjuvantsThereisanincreasingpressureonTAEsbecauseoftheirenvironmentalprofileToday,thereisabroadvarietyofGlyphosateadjuvantsavailablewithdiversepropertiesFinally:Themoreadjuvantthehighertheperformance(consideradjuvantloadingintheformulationandactivecontentinadjuvantproduct!)Confidential7Adjuvants

Glyphosateadjuvants

OverviewGlyphosateadjuvantproductsProductDescriptionFormulationMainbenefitEPAGenamin267Formulatedtallowamineethoxlyte

containingsolubilizerIPA360Costperformance§180.920SynergenG2DAqueoussolutionofanamphotericsurfactantIPA360Costefficient-Synergen9903AqueoussolutionofanamphotericsurfactantIPA360Kupto540Costefficient-GenaminoxLAAqueoussolutionofanamineoxidesurfactantIPA360Costefficient-SynergenG480AdjuvantblendinwaterIPA480Highperformance-SynergenGL5PolyglycerolesterinwaterIPAupto480Nolabeling,green§180.910SynergenG-SFattyaminealkoxylateforsolidformulationsNH4(solid)GlyphosateSG-Confidential8Synergen®GL59>>backtooverviewslideConfidentialSUSTAINABLEDESIGNProductcompositionFriendly,non-hazardousmaterialNPEOfreeBasedonpolyglycerolesterandcoconutfattyacidsRenewableshareca.95%RESPONSIBLEPROCESSProductmanufacturingResourceefficiencyduetohighyield(>85%)toavoidwasteduringmanufacturingCertifiedforsafety&qualityaccordingtoISO9001,ISO14001andOHSAS18001Globalproduction(Germany,Spain,Brazil)canhelptoreducetransportECOINTEGRATIONProductenvironmentalfateImprovedenvironmentalprofileLesseffectsontheaquaticlife(LC50>100mg/l)Biodegradable(42%in28daysaccordingtoOECD301B)SAFE&EFFICIENTUSEProductformulationandapplicationSafehandlingduetoimprovedhumantoxprofile,i.e.non-irritanttoeyeandskinSolutioninwaterforeasyhandlingIncreasingefficacyofagrochemicalformulationEfficientusebyreducingwaterconsumptionduringapplicationSuitabletoreplaceTAEinformulationAdjuvantbasedonpolyglycerolesterderivedfromcoconutfattyacidImproveswetting/contactofagrochemicalstoplantsurfacesandenhancesuptakeSafe,environmentallyfriendly,andperformingalternativetotallowamineethoxylatesSynergenGL5–“TheGreenAdjuvant”

Across-linkedcopolymerbasedonglycerolandfattyacids,originatingfromvegetablederivedrenewableresourcesExcellenttoxicologicalandeco-toxicologicalprofile(e.g.nohazardouslabeling,noeyeirritation,noteco-toxic)DualmodeofadjuvantactionImproveswettingofleavesurfaceEnhancespenetrationanduptakeEPAexempted(CFR§180.910),REACHexempted(polymer)AllowsforbroadregistrationsofGlyphosateproducts,e.g.ReductionofdistancerequirementsReductionofpre-harvestintervalsHighapplicationratesofGlyphosateConfidential10SynergenGL5–“TheGreenAdjuvant”PropertiesAqueoussolutionwithlowpourpoint,easytohandle,nosolubilizernecessaryRecommendedforIPA360g/La.e.andhigh-loadformulations(e.g.480g/La.e.)QuickdissolutionofGlyphosateformulation,alsoincoldwaterExcellentcropsafety(notphytotoxic)Confidential11SynergenGL5–“TheGreenAdjuvant”

HerbicidalPerformanceSynergenGL5hasbecomeanestablishedindustrystandardforTAEfreeGlyphosateformulationsComparedtootheralternativeadjuvants,likeAPGsorphosphateesters,itshowsasuperioroverallperformanceGlyphosateadjuvantshavetoperformwellonallweedspecieswhichrepresentathreattothegrower,howeverduetotheverydifferentvarietiesofweeds(shape,surfacestructure,wax-layersetc.),adjuvantshaveacharacteristicperformanceprofileOngrassweeds,theadjuvantperformanceisatleastsimilartoTAE,onsomedifficulttocontrolweedslikeCIRAR(Canadianthistle),SynergenGL5issuperiorOncertaindifficulttopenetratebroadleafweeds,SynergenGL5islessefficientthanTAEConfidential12SynergenGL5–“TheGreenAdjuvant”

HerbicidalPerformanceTheperformanceofSynergenGL5isprovenonvariousimportantgrassesandbroadleafweedsandundertropicalandtemperateclimateconditionsBermudagrass(CYNDA)Barnyardgrass(ECHCG)Commonlambsquarters(CHEAL)Blacknightshade(SOLNI)Largecrabgrass(DIGSA)Wild-oat(AVEFA)Annualryegrass(LOLPE)Canadianthistle(CIRAR)Confidential13SynergenGL5–“TheGreenAdjuvant”

HerbicidalPerformanceSynergenGL5guaranteesthatmoreGlyphosatereachestheplantsurfaceSprayretentionondifficult-to-wetplantsissignificantlyimprovedbySynergenGL5(asshownforwheatandpea)Confidential14Retention[μl/gdrywt]SynergenGL5–“TheGreenAdjuvant”

HerbicidalPerformanceSynergenGL5performsequallygoodasTAE-15EOandbetterthanotherTAEfreeGlyphosateadjuvantsConfidential15TestscarriedoutbyFreshweight[%ofuntreated]14daysaftertreatment

* Applicationratesfrom17to34ga.e./haand0,25%adjuvant(active)SynergenGL5–“TheGreenAdjuvant”

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