二氧化碳捕集与利用技术研究及工程示范

1、BackgroundEngineering DemonstrationBasic ResearchInternational CooperationOn The Way20102020203020402080CCUSYEnergy-related COC emissions and reductions in the Sustainable Development Scenario by sourceCurre nt TrendsGt CO,4D3020Fu el switch, CA.USlOccustsi2oasD9aBrssAaa. Rt9J2050,CCUS%4I/$O11-27I?.

2、G(,aUsnDD:s:JsWsvi1snDD-ozc8f.Trd/5fTF8Y0sd*ocozvnwazwnona:.wz+asnaaB*a+awoszoz.18, COz69:5, CO24S00C(0.1%&/)W1030-1140Cf:JJ=*CuS?JgBrZ,2B4sQ*,r?t8?tJEi:?JSleipner (glad: 20a Snohvit (g$/): 10a Quest8C): 6 Boundary Dam (90:1650 2IfgCO2WtiCo200sCO2200WCO2Starwood.KiewiPgCOJ %/?1Z?sQsaes-hw&/asBcoJ9I?

3、xPa/BN (fenamByt)ldCAPEJC1.412.OBE,; g ja,ogco2020 ,20219 , 3T-;.COxy Low Carbon Ventures OXYJIBna1asesVsa&faHes:sfd6&co.:-toreggaAcomC/C 8.81GJ/tCO2 (-5.25GJ tCO+366 kWhrC+2,x T?tt)In July 2008,i Chinas first COcapturing facility, with capturing capac ity of 3000 Itons/year, was put into operation

4、in CHNG Beijing Cogeneration i,Pow er PIan t. T he fa c ility is inde pe n den tl y de sig ne d and constructed by CHNG. The captured CO2 is utilized as follows.Capture ProcessFeetureScsleEnergy consumption Capture RatioCO2 PUiOthersPost combustionPC power station. CQ 12-15% in flue gas120,000tpa CO

5、C99.997ALargest PCC unit then, have beenoperating 10 years continually.Capture cost 300-400RMB/t CO,&, kT1pllI& CO 2jf (CHN G constructed another COC c apturi ng fac ility i n Shanghai.Ii Shidongkou NO.2 Power Plant, with capac Qty of 120,000t/a, which has been operational by the end of 2009. The pr

6、oject is one of the largest COC capture facility at the time in the world.4 First CO2 capture pilot plant both for natural gas and coal based power station in China, built by CERI in 2012 (1000 tons COC per year)k This plant (named CCM Verification Plant here) is served as a verification plant for N

7、orway CO2 Capture Mongstad (CCM) projectMxccMGtJsza89WsDWs ccffB9tettAVerification plant has been running stably fr 4000 hours with capture efficiency 8596 f8596-9296J in 2013l8&BIIOTB JIC&SA-92s4Very low solvent consumption and NDMA emission saae .o.sks/co2 . aeaonassseChinas fast 1000 tons/year ph

8、ase change capture lest unitj?Ij9sjaBC,aaape&sjS9s/ABco,0tBtni3i aaBI?BiJa. Plt:*:*:sdco*Bfd&st&.sB?2.3GJACO2.In 2020, Chinas first 1,000 tons/year phase-changing” carbon capture iIindustrial device, developed by CHNG, successfully realized continuous and stable Ioperation in Huaneng Changchun Therm

9、al Power Plant. Biphasic carbon capturetechnology belongs to a new generation of transformational carbon capture technology, which effectively solves the problem of high energy consumption causedII IIby the heating of all the carbon dioxide absorption liquid in the traditional method, and can g reat

10、ly reduce the cost of carbon dioxide capture, with huge social and economic benefits. Energy consumption ?2.3GJEOz.4?88s6Ticcc8JsoJde2a t2o1s9First Pre-combustion capture unit in the world started operation in 2010CapureProcessFeaturea&hatScaleEnergy consumptionCOCTransportationCO,AWLbCO,Storageg8%C

11、O2PrecombustionIGCC&CCSs&IGCC based full chain CCS610NPg/ pC2f30MWm)60,000100.000tpaCOC(30MWmh)2.5GJ/t CO2Tanks*40,000t/a EOR+*40,000a/a1 Storage_IA,. Ptyfg”mCO 2tl EWith the support of the Nationa 1863 Program as well as the ,0CO2)i8PQ /+ f*2 Capture R&D ProcessScience and Tech nobogy Support Progr

12、am , after 15 years of hard work, Huaneng have established the flue g as COCcapture theory and c ompl eted set of tec hnolog y system with Chinas independent intelI ectual property rights.i HNKJ06-H022008AA0623O 1 2013DFB601402014BAC18B00 2016YFE01168002016YFE0102fi00 2019Y FE01001 00” ”National/Pro

13、vincial R&D PlatformTA.,3*T State Key Laboratory of Coal-based Clean Energy,n ,o ;,b o f$ A (3)L National Energy Technology R&D Center of Clean andLow carbon Coal-fired Power Generation Technology w ,“e) .)$B a- L China-US Clean Energy Joint Research Center-Clean Coal Technology Center4 j I)L.MM.”)B

14、eijing Key Laboratory of CO2 Capture and treatmentgb (T(b InEAUIB Zf6 LBe ijing Engineering Research Center of Qualify and Clean Efficient Utilization of Poor Fuel)W f4 f1S fA Beijing International Science and Technology Cooperation BaseLab-scale pilot plant was built, tested and run for slurry-base

15、d CO2 capture.DLEMEA$T20 ,CO2IU$t2.6GJ/C2+IfiR D8T 22%-50%.Regeneration energy m 2.6GJ/tCO/; absorbent cost is 204 that of MEA. Solvent loss cost is 22%-50A that of MEA.CO,GO,dchIIICMEAbsorption rate and COC loading are higher than those of MEA solutions.CO,After absorbing CO2, the absorbent can spl

16、it into two li9 uid/liquid phase by itself, and almost atl absorbed COC transfer into the rich phase (more than 95%). Only the rich phase is sent to the regeneration tower for regeneration.show that the desorption of CO2 rich phase can reduee 204-30 I regeneration energy. In September 2020, Huaneng

17、CERI built CA inas first 1000t/year phase-c hanging COC capture industrial p ilot plant in Huaneng Chargc hun Thermal Power Plant, which realized continuous and stable operation for 72 hours and the r egenerated heat consumption2.3GJ/tCO/.Desig ned capture process for biphas ic COC absorbentHu aneng

18、 Changc hun Thermal Power Plant 1 000t/year phase-chang ing COC capture industria I pilot plantcontinuous running historycurve*BKBR8. 6IaBNR12A. tE6JfiPJ6BP, B9B2R%B50KgtT &50%gtC,ayJeh1eja.6aa1ebB66Ba:eBZae66a, x?%?t&a,8144co, c t.CO2 mineralization: Semi-dry CO mineralization process of fly ash in

19、 power plant by circulating fluidized bed.Study u n mld siale lest of gas pha semineralizdfon of fly ashHundred tons Suidized bed sem - dryTrieralNation de :aiboms atiDlJ pilnt pT a1foFW., 6f: 6400 E1DeSign of 50 thousand Tons/year fluid ed bed Beni-diy rriteraIi zatiun dl carbgnization procs; & ( 1

20、5SIB i6): 283.7 1/RCO2 ;iTotal fixed investment: 64 milllon RMB. Carbon sequestration cost (15 yearsdepreciation):283.7 yuan/ton of COC.*co,rra61: co,taaSJ8fa&etfiRfFJRzeCOhydrogenation to methanol: Bimetallic nano-catalyst for CO2 hydrogenation to methanol and its process.CO,B#COclean energyCO2 con

21、taining exhaU9telectricityCO2 captureElectrolysis of water toproduce hydrogenCOCBy-productionMethenol to gasolineMethanol to olefinCOC hydrogenation to!thMethanol to aromaticsH 2Methanol to fine chemicalsCHINA HUANENO”*B1Bf&OaOBBBBQNfiBB2009Qa6x%Ix9L*cERc 9BDsIiIaib%PIn Nov. 2009, President Hu Jinta

22、o and President Barack Obama announced the establishment of the Clean Energy Research Center (CERC).Lawrence LfreiwioreNational LaboratoryDUKEENERGY.usA aiosaasieve xcaonaTocvWO RLD RSOU EC E g I N STtTUT ECOACH(Cooperation Action ithin CCS China EU)Systematic study and design based on 2S0MW and 400

23、MW IGCC:NZEC ( China-EU Cocperation on Near Zero Emissions Coal)Case study program and pre-combustion CO capture of 400MW power plant.ENELCCS demonstration project experience sharing and exchange,1M tons capture pre-feasibility study.CHNG-Duke Energy / AEPSigned Memorandum of Cooperation.Pre-feasibi

24、lity study of 1 million tons-class full-flow CO, c apture and storage projec t:CHhIG-LLNLSigned Memorandum of Cooperation:Partnership in MCS and IGCC.Tec hnical exchange and c ooperation.CERl-SaskPower10Q CO2 capture technology assessment and feasibility study;Engineering stage technical review of BD3 unit large-scale demonstration project.CERI-CSIROCooperatio