化工工艺学第1章 合成氨

1、 20301242pppppKOHCHHCOp OHCOHCOpppppK22202 )/(/ln200RTHdTKdp 883.13108737. 1100814. 2lg3666. 8/57.9864lg27301 TTTTKp298. 21008. 110632. 0lg09361. 0/2183lg27302 TTTTKp220301)2)()()/()3)(xnyxnxnppyxyxKwmp )()3(02yxnyxyxyKwp 图图 1.3OHHOHCHppppkr2224101 42CHpkr 0301/ptKpPm 0402/ptKPpm 0503/ptKpPm 图图 1.6图

2、图 1.7图图 1.8图图 1.9图图 1.10图图 1.11图图 1.12表表 1.2SHOHpppK22/0 图图 1.16OHCOHCOpppppK2220 19.41098 H)1(00COCOCOCOyyyyx *)/1/(1lg0 xxVksp 0/222pHCOOHCOCOKyyyykr 0002222221ppOHCOpHCOqHnCOmOHlCOCOKQppKpppppkpr 表表 1.312120ln1EEEERTTTee 图图 1.19图图 1.20表表 1.4)(2220HpaaaKCOOHKKHa 022222aOHKOHKKHKHCOHKCCCp KxxCpHKCC

3、xxCpOHKKHKCOaOHKOHKKHKCO22222220222)1(4)1(4 图图 1.22 KKppppKpNHNHNHNHf05 . 05 . 15 . 05 . 100223223 00lnffGKRT RTAyATCRTABPRTiiiiiii2055 . 03ln ITBTTTKp 27010856. 1lg4943. 2/8 .2074lg33NHNHPyp 4/ )1(3322iNHHHyyPPyp 4/ )1(322iNHNNyyPPyp 002/325. 0)1(33ppKyyyPiNHNH 0)1()1(2)1(5 . 145 . 125 . 0 rrrrr002

4、5 . 12/)1()1(33pPKrryyypiNHNH 35233101008351. 7105646. 0 . 1371.221096147. 1/1 .358672543.233 .38313TTTPTTH 9 .1490298 H 132223123322HNHNHHNppkpppkr 5 . 125 . 1123322HNHNHHNppkpppkr 221HNppkr 33333333333, 21, 2, 10, 1, 10, 2, 20, 11, 221)1)(1(11NHNHNHNHNHNHNHNHNHNHNHyynyyynyynyynynyna 产产氨氨速速率率)1(4 .2217)1(4 .2217)1)(1(4 .22173333333, 12,21,2, 10NHNHsNHNHsNHNHNHsyyVyyVyyyVG 图图 1.30图图 1.31TpyNH/5 .1099