研讨会PPT-氨基酸表面活性剂毛华丽翻译版

1、氨基酸表面活性剂的市场现状及应用突破Market analysis and application breakthrough of amino acid surfactants广州天赐高新材料股份有限公司Guangzhou Tinci Materials Technology Co. Ltd.毛华丽 Lily Mao 2014.01.11,WWW,个人简介 Introduction,毛华丽 Lily Mao 2009年毕业于浙江工业大学，专业为微生物与生化药学，获得硕士学位。 Graduated from Zhejiang University of Technology with Maste

2、rs degree for Microbiology it is easy to get facial cleanser; low soap content leads to narrow changing temperature range and rough appearance. 1.5%,氨基酸表面活性剂在不同pH条件下的起泡性能 Foamability of amino acid surfactants at different pH,1、月桂酰肌氨酸钠pH在5-9.5区间内均有良好的起泡性能，酸性条件下更佳. Sodium Lauroyl Sarcosinate shows exc

3、ellent foamability at pH 5-9.5, and in acid condition is better. 2、椰油酰甘氨酸钾在pH7时具有良好的起泡效果，pH中性条件下有较好的耐硬水性能. Potassium Cocoyl Glycinate shows excellent foamability when pH7, and shows excellent hard water resistance in neutral condition.,测试方法：SITA 泡沫仪，900rpm，30s，样品浓度：0.3% Test method： SITA Foam Tester

4、，900rpm，30s，sample concentration: 0.3%,氨基酸表面活性剂在不同pH条件下的起泡性能 Foamability of amino acid surfactants at different pH,月桂酰谷氨酸钠在酸性条件下起泡性能优异，当pH7时，其在硬水中形成月桂酰谷氨酸钙反而有较优异的表面活性。 Sodium Lauroyl Glutamate shows excellent foamability in acid condition, when pH7, it shows excellent surface activity for the genera

5、tion of Calcium Lauroyl Glutamate.,月桂酰谷氨酸钠与脂肪酸复配泡沫性能Foamability of Sodium Lauroyl Glutamate combined with fatty acid,泡沫质量评价方法：配制10%的AMIN LGNa溶液，加热至35，取此溶液4ml用双手搓15秒，拍照，观察泡沫的质与量。 Test method: Prepare 10% Sodium Lauroyl Glutamate solution, heat to 35, take 4mL into hand and rub for 15s, photo it and c

6、ompare the quality and quantity of the foam.,AMIN LGNa溶液 AMIN LGNa solution,AMIN LGNa添加1%十四酸 Add 1% myristicacid into AMIN LGNa solution,AMIN LGNa添加1%十二酸 Add 1%lauricacid into AMIN LGNa solution,AMIN LGNa添加1%混合酸十四酸/十二酸=7：3 Add 1% myristic acid and lauricacid at the ratio 7:3 into AMIN LGNa solution,

7、AMIN LGNa的泡沫舒适，细密、柔滑，呈乳脂状。与脂肪酸结合可改变泡沫的状态，添加混合脂肪酸可改变增加泡沫的质与量 The foam of AMIN LGNa is small, fine, smooth and creamy. When combined with fatty acid, the condition of the foam will change: the quality and quantity of the foam will be improved.,氨基酸表面活性剂乳化力性能测定及肤感Emulsifying ability tests and skin feeli

8、ng,滋润感 Emollient,碱性 Alkalinity,酸性 Acidity,清爽感 Refreshing,AMIN,AMIN LG95F,AMIN GCK30,皂基 Soap,AMIN LS30,测试方法：量筒法测试乳化力，30ml0.3%表面活性剂溶液与30ml白油混合震荡乳化，记录分层时间。 Test method: Test with measuring cylinder, mix 30mL 0.3% surfactant solution with 30mL white oil, record the time of phase separating.,氨基酸表面活性剂增稠解决

9、方案Solution of viscosity increasing of amino acid surfactants,结论Conclusion: 1、三种增稠方案在pH=4.5-5.5之间可以达到较好的增稠效果 The thickening ability is the best when pH is among 4.5-5.5 under the 3 condition 2、泡沫性能，pH在5.0以下有更优的起泡性能 The foamability is better when pH is under 5.0,不同氨基酸表面活性剂在不同pH条件下的粘度Viscosity of diffe

10、rent amino acid surfactants under different pH,pH,Viscosity/mPa.S,增稠机理？,氯化钠对含氨基酸表面活性剂体系粘度的影响The influence of NaCl for the viscosity of amino acid surfactants system,结论Conclusion： 氯化钠对三种氨基酸表面活性剂的增稠性能：AMIN GCK30AMIN LS30AMIN LG30 The influence of NaCl for the viscosity of 3 kinds of amino acid surfact

11、ants: AMIN GCK30AMIN LS30AMIN LG30,研究洗发水在适当的固定pH条件下，氯化钠对含氨基酸表面活性剂体系粘度的影响 Test the influence of NaCl for the viscosity of shampoo at specified pH,3、氨基酸表面活性剂在洗发香波中的应用及选择 Application and optimal solution for amino acid surfactants,日本无硫酸盐洗发水例 Sulfate-free shampoo in Japan,配料表： 水，月桂基甜菜碱，甲基椰油酰基牛磺酸钠，椰油酰胺DE

12、A，丁二醇，月桂酰胺丙基羟磺基甜菜碱，椰油酰谷氨酸二钠，吡罗克酮乙醇胺盐，甘草酸二钾，椰油酰胺MEA，椰油酰谷氨酸钠，提取物，聚季铵盐-10 Ingredients: Water, Lauryl betaine, Sodium Methyl Cocoyl Taurate, Cocamide DEA, Butanediol, Cocamidopropyl Hydroxysultaine, Disodium cocoyl glutamate, Piroctone Olamine, Dipotassium Glycyrrhizinate, Cocamide MEA, Sodium Cocoyl Gl

13、utamate, Extract, Polyquaternium-10,市售洗发水泡沫对比 Foamability comparison for marketed shampoo products,含有氨基酸表面活性剂洗发水的粘度对比Viscosity comparison of shampoo with amino acid surfactants,含有氨基酸表面活性剂的洗发水一般都粘度较低 Normally, shampoo with amino acid surfactants appear low viscosity,洗发水的配方突破点Shampoo formula breakthro

14、ugh,天然 Natural 无硫酸盐 Sulfate-free 温和 Mild 低刺激 Low irritation 洗护分开 Cleaning, conditioning separation,宝洁体系洗护二合一 P&G system-2 in 1,新领域 New field： 无硫酸盐 Sulfate-free 洗护二合一 Shampoo, conditioner 2 in 1,含有氨基酸表面活性剂洗发水的单一变数比较实验 Single variable comparison test of shampoo with amino acid surfactants,在本实验配方中，肌氨酸盐

15、比其它在梳理性方面有一定优势 Sarcosinate surfactant shows better combing performance in this test.,Main ingredients: AES 9% or 12%, CAB35 3%, Amino acid surfactants 3% or 0%, PQ-10 0.5%,Sodium Cocoyl Glutamate,Sodium Cocoyl Glycinate,Sodium Lauroyl Sarcosinate,Blank,Untreated(Wet Hair),Before rinse,After rinse,Af

16、ter dry,无硫酸盐洗发水 Sulfate-free shampoo 主要成分 Main ingredients： 卡波姆380 Carbomer 380 椰油酰胺丙基羟基磺基甜菜碱 Cocamidopropyl Hydroxysultaine 月桂酰肌氨酸钠 Sodium Lauroyl Sarcosinate 月桂酰谷氨酸钠 Sodium Lauroyl Glutamate 聚季铵盐-10 Polyquaternium-10 乳化硅油 Silicone emulsion 防腐剂 Preservative 香精 Fragrance,粘度 Viscosity：5,000-10,000 成本

17、 Cost：7-8 RMB/kg,无硫酸盐氨基酸洗发水的开发参考配方框架 Reference formula for sulfate-free amino acid surfactants shampoo,无硫酸盐氨基酸洗发水与市售某产品对比Comparison of sulfate-free amino acid surfactants shampoo with marketed product,无硫酸盐氨基酸洗发水与市售某产品对比Comparison of sulfate-free amino acid surfactants shampoo with marketed product,4

18、、结晶型氨基酸洁面膏介绍 Introduction of crystallized amino acid facial cleanser,结晶型氨基酸洁面膏 Crystallized amino acid facial cleanser,固体（结晶）与液体混合 Mixture of solid(crystal) and liquid,v,结晶 Crystal,表面活性剂饱和溶液 Saturated surfactants solution,室温Room temperature 80-50 45,Mix solid & liquid,Uniform liquid,Crystallize soli

19、d,结晶型洁面膏中主次表活的选择 Choice of primary / secondary surfactants in crystallized amino acid facial cleanser,典型的结晶型洁面膏配方 Typical formula of crystallized amino acid facial cleanser ： 表面活性剂 Surfactants: 15-30% 多元醇 Polyol: 20-40%- 甘油 、山梨醇 、1,3-丁二醇、丙二醇、PEG-6等 Glycinate, sorbitol, butanediol, propyleneglycol, e

20、tc. 水 Water: 30-40% 表面活性剂的选择 Choice of surfactants ： 1、用液体的氨基酸表面活性剂比较难做膏状的洁面产品 Liquid amino acid surfactants are hard to make paste facial cleanser 2、粉末、片状、颗粒状、糊状 Powder, flake, granular, paste 3、溶解性：偏低 Solubility: low,结晶型氨基酸洁面膏应用例Sample of crystallized amino acid facial cleanser,配料表： 水，月桂酰谷氨酸钠，丙二醇，

21、PEG-150硬脂酸酯，半乳糖酵母样菌发酵产物滤液，PCA钠，乙二醇硬脂酸酯，椰油酰胺MEA，丁二醇，提取物等 Ingredients: Water, Sodium Lauroyl Glutamate, Propylene Glycol, PEG-150 Stearate, Galactomyces Ferment Filtrate, Sodium PCA, Glycol Stearate, Cocamide MEA, Butanediol, Extract, etc.,SK-II柔肤洁面乳 SK-II Facial treatment cleanser,上市时间 Time-to-market

22、：2010.12 120.0g 82.71,天赐纯氨基酸洁面膏参考框架Reference formula for Tinci amino acid facial cleanser,纯氨基酸洁面膏 Amino acid facial cleanser 主要成分 Main ingredients： 月桂酰谷氨酸钠 Sodium Lauroyl Glutamate 月桂酰肌氨酸钠 Sodium Lauroyl Sarcosinate 多元醇 Polyol 脂肪酸 Fatty acid 珠光剂 Pearling agent 丙烯酸（酯）类共聚物 Acrylates Copolymer 氯化钠 Sodi

23、um Chloride 防腐剂 Preservative 香精 Fragrance,成本 Cost：22-25 RMB/kg 结膏点 Crystallized temperature：45,纯氨基酸洁面膏参考工艺 Reference manufacture process of amino acid facial cleanser,40水浴浸泡30分钟后，缓慢搅拌 40 water bath for 30min, mix slowly,80-85,通冷凝水降温至55-60 Cool to 55-60 with condensatewater,丙烯酸（酯）类共聚物 Acrylates Copol

24、ymer,结晶温度46-48 Crystallize temperature 46-48,香精、防腐剂 Preservative, fragrance,去离子水/AMIN LG95F/其他表活/多元醇 D.I. water/AMIN LG95F/other surfactants/polyol,持续搅拌至室温，熟化至第二天，挤压灌装 Constantly mix to room temperature, cure to the next day, packing,氨基酸洁面膏对比Comparison of amino acid facial cleansers,v,结晶 Crystal,表面活

25、性剂饱和溶液 Saturated surfactants solution,v,结晶 Crystal,表面活性剂饱和溶液 Saturated surfactants solution,聚合物增稠剂 Polymer thickner,纯氨基酸洁面膏(SKII) SK-II amino acid facial cleanser,天赐氨基酸洁面膏 Tinci amino acid facial cleanser,洁面膏泡沫性能对比Foamability of amino acid facial cleansers,测试方法：SITA泡沫仪，900转/min，10s/次，12次，称取样品2g至400g150ppm