文档磷酸一铵MAP的MSDS

MaterialSafetyDataSheet

RevisionIssued:2/28/11Supercedes:02/28/2011FirstIssued:8/20/2007

SectionI–ProductandCompanyIdentification

ProductName:MAP(MonoammoniumPhosphate)

ERGNo.:N/A

CommonName:MonoammoniumPhosphate

Formula:(NH4)H2PO4

Synonym:MAP

Uses:Agricultural

SectionII–Composition/InformationOnIngredients

ChemicalName：MonoammoniumPhosphate

ChemicalComposition:astotalP2O550%byWeight

TotalNitrogen,asN10%byWeight

Fluorides,asF0.6%byWeight

Moisture,as3.0%byWeight

CASNo.7722-76-1

*Forparticulatesnototherwiseregulated,standardis15mg/m3totaldustand5mg/m3forrespirablefraction.

**Forparticulates(insoluble)nototherwisespecified,adoptedvalueis10mg/m3forinhalablefractionand3mg/m3forrespirable

fraction.

***Productcontainsmonoammoniumphosphateasessentialingredientwithsmallamountsofdiammoniumphosphate,ammonium

sulfate,urea,andaluminum/calcium/iron/magnesiumphosphatecompounds.

SectionIII–HazardIdentification

PotentialAcuteHealthEffects:

EyesandSkin:Contactmaycauseeyeirritationandprolongedcontactwithskinmaycausesomeirritation.

Inhalation:

Highdustconcentrationsofair-bornematerialmaycauseirritationofthenoseandupperrespiratory

tractwithsymptomssuchassorethroatandcoughing.Inhalationofdecompositiongasescan

causeirritationandcorrosiveeffectsontherespiratorysystem.Somelungeffectsmaybedelayed.

Ingestion:Ingestionofsmallquantitiesareunlikelytocausetoxiceffect.Largequantitiesmaygiverisetogastro-intestinaldisorders.

PotentialChronicHealth

Effects:Noadverseeffectsareknown.

CARCINOGENICITYLISTSIARCMonograph:NoNTP:NoOSHA:No

SectionIV–FirstAidMeasures

Eyes:Immediatelyflusheyes(holdingeyelidsapart)withplentyofwaterforatleast15minutes.Getmedicalattentionifirritationdevelopsorpersists.

Skin:Washskinthoroughlywithsoapandwater.

Ingestion:Donotinducevomiting.Drinklargeamountsofwater(ormilkifavailable)todilutestomachcontents.Smallquantitiesareunlikelytocausetoxiceffect.GetmedicalattentionifalargeamountofMAPisingested(smallchildren,morethan50g).

Inhalation:Removefromsourceofexposuretodusts.Obtainmedicalattentioniftheeffectsoccur.Personswhohaveinhaleddecompositiongases(e.g.inafire)shouldobtainimmediatemedicalattention.

SectionV–FireFightingMeasures

FlashPoint:Non-flammableAutoignitionTemperature:NotApplicable

LowerExplosiveLimit:NotApplicableUpperExplosiveLimit:NotApplicable

UnusualFireandExplosion

Hazards:

MAPisanon-flammableinorganicsaltandisnotflammablehoweverwhenstronglyheated,MAPwill

decomposegivingoffammonia.

ExtinguishingMedia:Chemicaltypefoam,CO2(CarbonDioxide),drychemical,waterfog.

SpecialFirefighting

ProceduresandEquipment:

Keeppersonnelremovedfromandupwindoffire.Wearfullfire-fightingturn-outgear(fullBunker

gear)andrespiratoryprotection(SCBA).

SectionVI–AccidentalReleaseMeasures

SmallSpill:

Spillageshouldbesweptupandplacedinchemicalwastecontainertobedisposedatanappropriatewastedisposalfacilityaccordingtocurrentapplicablelawsandregulationsandproductcharacteristicsattimeofdisposal.Adequateventilationisrequired.

LargeSpill:

Containspillandtransferthematerialtoappropriatecontainersforreclamationordisposal.Disposeofmaterialatanappropriatewastedisposalfacilityaccordingtocurrentapplicablelawsandregulationsandproductcharacteristicsattimeofdisposal.Adequateventilationisrequired.

ReleaseNotes:

Ifspillcouldpotentiallyenteranywaterway,includingintermittentdrycreeks,contactthelocalauthorities.IfintheU.S.,contacttheUSCOASTGUARDNATIONALRESPONSECENTERtollfreenumber800-424-8802.Incaseofaccidentorroadspillnotify:CHEMTRECINUSAat800-424-9300;CANUTECinCanadaat613-996-6666CHEMTRECinothercountriesat(Internationalcode)+1-703-527-3887.

Comments:

SeeSectionXIIIfordisposalinformationandSectionXVforregulatoryrequirements.Largeandsmallspillsmayhaveabroaddefinitiondependingontheuser'shandlingsystem.Therefore,thespillcategorymustbedefinedatthepointofreleasebytechnicallyqualifiedpersonnel.

SectionVII–HandlingandStorage

Ventilation:Usewithadequateventilation.

Calculated,fugacitylevelIII:3.98x10-12toair,45.3%towater,54.6%tosoil,0.0755%tosediment.Phosphates,whetherwaterorcitratesoluble,aretranslocatedinthesoilonlyoververyshortperiodsand

arethenimmobilized.

Toxicity:Inorganicphosphateshavethepotentialtoincreasethegrowthoffreshwateralgae,whoseeventualdeathwillreducetheavailableoxygenforaquaticlife.

Biodegradation:

ThePhosphoruscycleiswellunderstood.Phosphatesareconvertedtocalciumoriron/aluminumphosphatesorareincorporatedwiththe

DegradationProducts:organicsoilmatter.

Photodegradation:Nodataavailable

SectionXIII–DisposalConsiderations

ProductDisposal:

Disposeofwasteatanappropriatewastedisposalfacilityaccordingtoapplicablelawsandregulations.

Collectinappropriatecontainers.Disposeofatanappropriatewastedisposalfacilityinaccordancewith

currentapplicablelawsandregulationsandproductcharacteristicsattimeofdisposal.

GeneralComments:None

SectionXIV–TransportationInformation

USDOTTDG-Canada

ProperShippingName:NotregulatedNotregulated

HazardClass:

IdentificationNumber:

PackingGroup(TechnicalName):

Labeling/Placarding:

AuthorizedPackaging:

Notes:

EuropeanTransportation:

SectionXV–RegulatoryInformation

ThisproducthasbeenreviewedaccordingtotheEPAHazardCategoriespromulgatedunderSection311and312oftheSuperfundAmendmentandreauthorizationActof1986(SARAtitleIII)andisconsidered,underapplicabledefinitions,tomeetthefollowingcategories:

Fire:NoPressure

Generating:NoReactivity:NoAcute:YesChronic:No

40CFRPart355-ExtremelyHazardousSubstances:None

40CFRPart370-HazardousChemicalReporting:Applicable

UNITEDSTATES:

SARAHazardCategory:

AllintentionalingredientslistedontheTSCAinventory.

SARATitleIIIInformation:ThisproductcontainsthefollowingsubstancessubjecttothereportingrequirementsofTitleIII(EPCRA)oftheSuperfundamendmentsandReauthorizationActof1986and40CFRPart372:

SARA(1986)Reporting

Chemical:MonoammoniumPhosphate,asP2O552PercentbyWeight

CASNO.7722-76-1

CERCLA

SARA(1986)Reporting:311312313

YesYesNo

CERCLA/Superfund,40CFRParts117,302:

IfthisproductcontainscomponentssubjecttosubstancesdesignatedasCERCLAreportableQuantity(RQ)Substances,itwillbedesignatedintheabovetablewiththeRQvalueinpounds.IfthereisareleaseofRQSubstancetotheenvironment,notificationtotheNationalresponseCenter,WashingtonD.C.(1-800-424-8802)isrequired.

WHMISHazardSymbolandClassification:ThisproductisnotWHMIScontrolled.

CANADA:IngredientDisclosureList:Thisproductdoesnotcontainingredient(s)onthislist.

EnvironmentalProtection:AllintentionalingredientsarelistedontheDSL(DomesticSubstanceList).

EINECS#:(MonoammoniumPhosphate)231-764-5

California:Prop65:Thisisnotachemicalknowntoca