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碳酸盐岩:自生碳酸盐矿物含量超过50%的沉积岩称碳酸盐岩,自生碳酸盐矿物中若一半以上为方解石称石灰岩或简称灰岩,若一半以上为白云石称白云岩或简称云岩。Carbonaterocksarethoseinwhichthematrixandframeworkarecomposedofgreaterthan50%carbonateminerals(thisdefinitionexcludescement).Unlikesilicilasticsediments,wherestructuresandtexturesreflectthephysicalfactorsinthedepositionalenvironment,thestructuresandtexturesofcarbonaterockscommonlyreflectintrabasinal,biologicalfactors.Thesourceforcarbonatesedimentsisalmostexclusivelybiological.Althoughcarbonatesformincolderwaterandmorespecializedsettingssuchas'hot'springsandcaves,mostthickbuildupsrepresenthighorganicaccumulationinshallow,warmseasinareasremovedfromsignificantsiliciclasticinputTheseshallowmarineareaswherecarbonatesedimentsarecreatedbycalcareousorganismsarereferredtoasthe"carbonatefactory"

CARBONATEROCKS

Manyfeaturesofcarbonatesedimentsareanalogoustothoseinterrigenousclasticsediments,butwithsomenotabledifferences:

——Mostcarbonaterocksareintrabasinal:therocksmainlyoriginateinthebasinofsedimentationratherthanbeingtransported.——Manycarbonaterocksare"biogenic"inorigin,dueeithertobiochemically-inducedmineralprecipitationorduetohighconcentrationsofskeletalshellcomponents(biomineralization).Somecarbonaterocks,however,areabiotic(inorganic)inorigin.——Carbonaterocksgenerallylithifyveryrapidly.——Particlesizeincarbonatesdoesnotnecessarilyreflecttheenergyoftheenvironmentofdeposition.Somecoarseparticlescanformorbedepositedinlow-energyenvironments.Modern

Warm

Water

Modern

Cool

Water

Ancient

Counterpart

SedimentarycontributioncoralsNONEarchaeocyathids,corals,bryozoa,stromatoporoids,rudistidbivalves,hydrozoansthelargecomponents,ofteninplaceofreefsandmoundsbivalves,redalgae,echinodermsbivalves,redalgae,echinoderms,brachiopods,barnaclesbivalves,redalgae,brachiopods,cephalopods,trilobitesandotherarthropodsmayoccurwholeorinbrokenpeicestoformsandandgravel-sizedgrainsgastropod,benthicforaminifersgastropod,benthicforaminifersgastropod,tintinids,tentaculitids,salterellids,benthicformainifers,brachiopodssandandgravel-sizedgrainsfromedfromwholeskeletonscodiaceanalgae,spongesredalgae,bryozoanssponges,crinoids,andotherpelmatozoanssand-sizedgrainsfromedfromdisintegrationofthedeadorganismplanktonicforaminifers,coccoliths,pteropodsplanktonicforaminifers,coccoliths,pteropodsplanktonicforaminifers,coccoliths(post-Jurassic)mediumsand-sizedorsmallergrainsthatoccurinbasinaldepositsooids,peloidsNONEooids,peloidsconcentricallylaminatedormicriticsand-sizedparticlesencrustingforaminifers,bryozoans,corallinealgaeencrustingforaminifers,bryozoans,corallinealgae,serpulidwormsencrustingforaminifers,corallinealgae,phylloidalgae,reralcidsbuilduptoformthickdepositsafterencrustingonhardsubstrates,orformlimemudonseafloorcodiaceananddasycladgreenalgaeNONEcodiaceananddasycladgreenalgaedisintegratetoformlimemudcyanobacteriaandothercalcimicrobescyanobacteriaandothercalcimicrobescyanobacteriaandothercalcimicrobes(importantinpre-Ordovician)formstromatolitesandmatsbytrappingandbindingfine-grainedsediments1.石灰岩的一般特征1)形态:——海成石灰岩区域性的稳定层状,也可与净砂岩互层。——湖成石灰岩规模一般不大,以条带状出现。2) 颜色:灰白、灰、灰黑或紫红等色。3) 成分:——方解石//其它成分常在5%以下:粘土矿物、石英粉砂、铁质微粒、海绿石、有机质等。——砂岩过渡的灰岩中可含较多陆源碎屑,——白云石化也可使白云石含量增加。4)沉积构造:——常见泥裂、生痕、生物扰动、结核、缝合线等,特别是虫孔、生物扰动、硅质(燧石)结核和缝合线——水平层理相对常见,——纹层状层理(如交错层理,颗粒性岩石,风暴或浊流石灰岩)——多见块状层理。——叠层构造和鸟眼构造。5)结构:——泥晶结构和各种颗粒结构为主,——生物骨架结构、粘结结构或障积结构。——结晶结构。——叠加的交代结构。6)成岩方式:压实和胶结为主,溶蚀、交代和重结晶等作用常见。MineralogyThemainmineralsincarbonaterocksare:——Calcite:CaCO3(alsocalledlow-magnesiumcalcite)——Mg-calcite:CaCO3,butwithseveralmol%Mg(typically>4mol%)——Aragonite:CaCO3——Dolomite:CaMg(CO3)2Otherlesscommoncarbonatemineralsinclude:Ferroandolomite(Ca(MgFe)(CO3)2(alsocalledankerite);Siderite(FeCO3);Magnesite(MgCO3)Ferroandolomiteandsideritearecommonlyassociatedwithreducing(lowtozerooxygen)environments:sedimentarymagnesiteisfoundinsomesalinelakes.Calciteandaragonitearepolymorphs—theyhavethesamechemicalcomposition(althoughtheirtraceelementsaredifferent),butadifferentcrystalstructure:calciteistrigonal,whereasaragoniteisorthorhombic.Thecommoncarbonatemineralsdifferintheirsolubility.Calciteislesssoluble(i.e.morestable)thanaragoniteinmostfluidsattheearth'ssurface.ThesolubilityofMg-calcite(highmagnesiumcalcite)varieswiththeamountofMgsubstitutionforCainthecalcitecrystallattice,butMg-calciteiscommonlymoresolublethanaragonite.Mg-calcitecommonlyrecrystallizestocalciteduringdiagenesis;aragonite,beingmoresolublethecalcite(especiallyinfreshwater),maydissolvetoproducesecondaryporosityormayaltertocalciteduringdiagenesis.CalciteinskeletalgrainsTheskeletalpartsoforganismsarecommonlycomposedofcalcite,magnesiancalcite,aragoniteoropalinesilica.Thismineralogydeterminesthesusceptibilityoftheskeletalfragmenttodiageneticchangeandsoitscurrentcompositionandfabricinalimestoneordolomite.Calciteskeletalgrains,whichcontainlessthan4mole%magnesiuminthecalcite,includesomeforaminifera(有孔虫),brachiopods(腕足类),bryozoans苔藓虫类,trilobites三叶虫,ostracodes介形虫,calcareousnannoplankton钙质微型浮游生物,andtintinnids纤毛虫.Skeletalgrainsofmagnesiancalcite,thatiswith4-20mole%magnesiuminthecalcite,includethoseproducedbyechinoderms棘皮类动物,mostforaminifera有孔虫类,andredalgae红藻.Aragoniteskeletalgrainsareformedfromcorals珊瑚虫,stromatoporoids层孔藻,mostmolluscs软体动物,greenalgae绿藻,andblue-greenalgae蓝绿藻.Skeletalgrainsofbiogenicopalinesilicaincludespongespicules海绵骨针andradiolarians放射虫.Carbonatesarecomposedlargelyofbothcalciumandmagnesiumcarbonatemineralsaswellascarbondioxide.Aswell,inmostcarbonaterocks,thesilicacompositionisquitelow.Therearethreemainsedimentarycarbonateminerals:aragonite,calcite,anddolomite.Thecompositionofmostcarbonatesliessomewherebetweencalcite(CaCO3)anddolomite(CaMg(CO3)2.Forexample,mostcontainsomemagnesium,butnotasmuchaspuredolomite.Carbonatesedimentmaybeformedbybiologicalprocessesaswellasbyphysicalweatheringanderosion;however,themaincontrolontheformationofthesesedimentsischemistry.

CalciteGroup

(hexagonal)

DolomiteGroup

(hexagonal)

AragoniteGroup

(orthorhombic)

mineralformulamineralformulamineralformulaCalciteCaCO3

DolomiteCaMg(CO3)2

AragoniteCaCO3

MagnesiteMgCO3

AnkeriteCa(Mg,Fe)(CO3)2

WitheriteBaCO3

Siderite,FeCO3

KutnohoriteCaMn(CO3)2

StrontianiteSrCO3

RhodochrositeMnCO3

Thecarbonatemineralssharesomecommoncharacteristics,including:AllshowchangeofreliefwithrotationAllhaveextremebirefringence(delta=0.148to0.242),givinghigh-order,creamyorpastelinterferencecoloursTodistinguish(e.g.)first-orderwhitefromhigh-orderwhite:lookforblue-greytint,showingfirst-orderlookatthinedgesofgrains;entireinterference-coloursequencemaybepresent,makingitpossibletocountcoloursin(orsequenceofpastelsmaybevisible)insertgypsumplate;1?colourschangetoupper1?lower2?high-ordercoloursshowlittlechangeSeveralfactorsinfluencethesolubilityofCaCO3:WhatcanyougetfromaboveFig?FavourableconditionHighpHhighTLowerp(CO2)LowerpressureCarbonatedepositionalsystemsforminginthegeologicpast,andinmodernsettings,fallintothreegeneraltypes:rampmargins,rimmedmarginsisolatedplatforms.gentlysloping(<1°)platform

maybeslightshelfbreaknopronouncedreeftrend,although

discontinuouscarbonatesandshoalsmaybepresentmayhavehighenergybeachandskeletal,ooliticsandshoals.

斜坡的边缘HIGHENERGYLOWERENERGY·pronouncedbreakinslope·presencesofnearlycontinuousrimorbarrieralongplatformedge·thebarrierisawaveresistantstructureconsistingofeitherareeforskeletal,ooliticsandshoals·landwardofrim/barrierisalowenergy"lagoonal"areaofvariablyrestrictedcirculation·lagoonalareacommonlygradeslandwardintotidalflat

· "Bahamatype"-derivedfrommodernanalogywithBahamaplatform· shallowplatform10'sto100'skmwideoffshoreofshallowcontinentalshelves· surrounedbydeepwater(several100'smetrestofewkmdeep)· Mayhaveeithergentlyslopingmarginormoresteeplyslopingmargin.Sedimentarystructuresandearlydiageneticfeaturesofshallowmarinecarbonatedeposits

ThisphotographshowsdetailofripplesonJoulter'sCayooidshoal.Notetheroundedcrestlinesandvariableplanmorphologyoftheripples.Ripplesaresuperimposedonlowdunesorientedroughlyperpendiculartoripplecrestorientation.Ripplespacingapproximately100mm

Large-scalecross-stratificationinUpperPaleozoicgrainstones.Skeletal-peloidalgrainstoneunitintheMississippianLoyalhannaLimestonefromcentralAppalachians.Clifffaceis19.5mhigh.Lower3mandupper6mmostlyflow-parallelviews.Central10mshowsflow-perpendicularandobliqueviewsoflargetroughs.Reactivationsurfaceincross-stratifiedPaleozoicgrainstones.Compositesetoflarge-scalecross-stratadevelopedinquartzsand-bearing,skeletal-peloidalgrainstones,MississippianLoyalhannaLimestone,centralAppalachians.Thefourflow-parallelsetsofcross-stratathatcomprisetheuppertwo-thirdsoftheoutcropincludemanyreactivationsurfaces,someofwhichhavesmall-scaleripplesdirecteduptheforesetslope(arrows).Flow垃par浪alle饶vie陈wof冒wav管e-ri疾pple吹for众mse科t(up思per仙arro霜w)o芽verl披ying逆flo呆wob柔liqu等evi把ewo众fwa消ve-r捐ippl郑ecr燥oss-延stra锦tifi絮cati汤on(l究ower滋arr桃ow).诞Dol阻omit肢emu协ddr堤apes赤bot珠hcr爪oss-万stra碗tal矩sets闯.Mi歉ddle忆Cam稻bria唱nAr辟ctom惯ysF吃orma珠tion丸,Ca秤nadi携anR剥ocky史Mou加ntai环ns,责sout介hwes殖tern幻玉Alb跪erta浪.Wav木yt爽oc苹rin性kle解df麦ine昆la山min美ae匠com朽pos垂ed庆of置cou尖ple假ts疫of凶gra渠ins绘ton腿el颤aye羡rs(尝dar兔k)办and蝴do蛮lom克iti猾cm阳uds捞ton借el汤aye啄rs(授lig燥ht)茧.U或ppe歌rC掌amb丛ria鸭nC铁ono旁coc高hea担gue冤Li偏mes桶ton切eo睬ft垒he谊cen说tra车lA雷ppa墓lac元hia湖ns.Pla清nar碗la怪min悲ae(富gre素ate善rt伍han床5m币mt愈hic仇k)企and处th延in怕bed崖sd屡eve古lop嚼ed心in染dol田omi篮te亏mud臭sto败ne,势Lo德wer换Pr泄ote役roz光oic印Wi怀tte闹noo绢mD全olo莲mit理e,灭Ham柄ers免ley绪Ba咸sin故,W哑est俊ern哗Au厨str指ali酒a.怜Poc段ket复kn戒ife棚,l挂owe暂rl抛eft观ce盆nte设r,虚is准app舰rox煌iat龙ely锐80隆mm庸lon扁g.Cro时ss-双sec际tio稳ns膛of壶mud贺cra猪ck蚂fil皮ls抢fro贺mt串he肚Mid步dle吹Or顶dov各ici语an遥St.或Pa将ul趟Gro庆up搭of唇the爆ce冰ntr手al笑App搂ala茫chi仙ans桶.N震ote俱th黄at循the戏cr突ack栽sc鬼ont傻ain铜se摇ver回al像gen蜂era目tio锡ns潮of僵sed固ime畅nt悄fil欲ls孕wit场ha任mi佩cro真-st所rat菜igr楚aph画yr替ela轻tab费le表to候ove绒rly俭ing薄la工yer抵s.溉The拿se更obs者erv借ati辅ons台de册mon传str料ate毯th丛at毫the升se芳cra须cks班we宾re猴ope靠na宇ta锐se五dim侄ent白-ai堆ro枕rs耕edi柿men抵t-w竖ate翼rs畅urf日ace惩a务num置ber赌of穿ti陶mes残an间dt洲hat赤th炸ese展cr减ack狠sc禾oul对dn警ot游hav团ef仇orm页ed历fro晕mu蓄pwa苏rd豪"in岭jec险tio症n"港of庆sed傍ime竟nt.Conv咬olut些efo乳ldin事gin侨cri界nkle典dla蜡mina建ted搏muds承tone浑sfr呈omt骂heU避pper拥Sil层uria是nTo土nolo真way沸Form棵atio刑n,w挽este关rnM棋aryl描andSmal阻lst窗roma新toli吓tic雹bioh捎erm埋enca刚sed览int础hin母beds解of旱carb倡onat路emu惠dsto欣net温hat曾bend夏aro销und晃the漏bioh携erm佳from犹bot驱hab浆ove信and净belo忽w.A脱ffec慎ted指beds勤thi稻nla渠tera勤lly截abov庆ean咬dbe申low碍the写bioh圣erm誓and蔑show薄inc榜reas吐ing行dips颜and挠thi汤ckne菜sses常dow溜nth仁esi搂des紧oft皂heb歉iohe烟rm.Beds校asr爬eth侵icke疼sta棚long汗the燥fla河nks塔oft厉heb鞠iohe拌rma达ndt影hin再late舰rall消yas旧wel罢l.U尖pper替Cam拒bria封nCo反noco奖chea剥gue牙Lime至ston灿e,w椅este山rnM帽aryl待and.Gyps疗umc狱ast氏int雨hef廉lood滩pla缎inl灶ake貌depo院sits蜂.

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