草甘膦FAO标准

1、 FAO SPECIFICATIONS AND EVALUATIONS FOR PLANT PROTECTION PRODUCTS 联合国粮农组织植保产品规格和评估 GLYPHOSATE N-(phosphonomethyl)glycine 草甘膦 2000/2001 FOOD AND AGRICULTURE ORGANIZATION OF THE UNITED NATIONS 联合国粮食和农业组织 1 TABLE OF CONTENTS 目录 GLYPHOSATE 草甘膦 Page页码 DISCLAIMER声明 2 INTRODUCTIO介绍 3 PART ONE 第一部分 SPECIFIC

2、ATION GLYPHOSATE 草甘膦规格 GLYPHOSATE INFORMATI 5 草甘膦资料 GLYPHOSATE ACID TECHNICAL 6 草甘膦原药 GLYPHOSATE ACID TECHNICAL CONCENTRATES 8 草甘膦酸母药 GLYPHOSATE ISOPROPYLAMINE SALT TECHNICAL CONCENTRATES 10 草甘膦异丙胺盐母药 GLYPHOSATE SOLUBLE CONCENTRATES 12 草甘膦水剂 GLYPHOSATE WATER SOLUBLE GRANULES 14 草甘膦可溶粒剂 PART TWO 第二部分

3、 2000 EVALUATION REPORT GLYPHOSATE 17 2000年版草甘膦评估报告 2001 EVALUATION REPORT GLYPHOSATE 33 2001年版草甘膦评估报告 Page 1 of 33 GLYPHOSATE 2000/2001 2 1 Disclaimer声明 FAO specifications are developed with the basic objective of ensuring that pesticides complying with them are satisfactory for the purpose for whi

4、ch they are intended so that they may serve as an international point of reference. The specifications do not constitute an endorsement or warranty of the use of a particular pesticide for a particular purpose. Neither do they constitute a warranty that pesticides complying with these specifications

5、 are suitable for the control of any given pest, or for use in a particular area. Owing to the complexity of the problems involved, the suitability of pesticides for a particular application must be decided at the national or provincial level. Furthermore, the preparation and use of pesticides compl

6、ying with these specifications are not exempted from any safety regulation or other legal or administrative provision applicable thereto. FAO shall not be liable for any injury, loss, damage or prejudice of any kind that may be suffered as a result of the preparation, transportation, sale or use of

7、pesticides complying with these specifications. Additionally, FAO wishes to alert users of specifications to the fact that improper field mixing and/or application of pesticides can result in either a lowering or complete loss of efficacy. This holds true even where the pesticide complies with the s

8、pecification. Accordingly, FAO can accept no responsibility for the consequences of improper field mixing and/or application. FAO is not responsible for ensuring that any product claimed to comply with FAO specifications actually does so. _ 1 This disclaimer applies to all specifications published b

9、y FAO. Furthermore it does not undertake to insure anyone who utilizes this Manual or the specifications against liability for infringement of any Letters Patent nor assume any such liability. Page2of33 GLYPHOSATE 2000/2001 3 INTRODUCTION 介绍 FAO establishes and publishes specifications* for technica

10、l material and related formulations of plant protection products with the objective that these specifications may be used to provide an international point of reference against which products can be judged either for regulatory purposes or in commercial dealings. Since 1999 the development of FAO sp

11、ecifications follows the New Procedure, described in the 5 edition of the “ Manual on the development and use of FAO specifications for plant protection products” (FAO Plant Production and Protection Page No. 149). This New Procedure follows a formal and transparent evaluation process. It describes

12、the minimum data package, the procedure and evaluation applied by FAO and the Experts of the “FAO Panel of Experts on Pesticide Specifications, Registration Requirements, Application Standards and Prior Informed Consent.” FAO Specifications now only apply to products for which the technical material

13、s have been evaluated. Consequently from the year 2000 onwards the publication of FAO specifications under the New Procedure has changed. Every specification consists now of two parts namely the specifications and the evaluation report(s): Part One: The Specification of the technical material and th

14、e related formulations of the plant protection product in accordance with chapter 4, 5 and 6 of the 5 edition of the “Manual on the development and use of FAO specifications for plant protection products”. Part Two: The Evaluation Report(s) of the plant protection product reflecting the evaluation o

15、f the data package carried out by FAO and the Panel of Experts. The data are to be provided by the manufacturer(s) according to the requirements of Appendix A, annex 1 or 2 of the “Manual on the development and use of FAO specifications for plant protection products” and supported by other informati

16、on sources. The Evaluation Report includes the name(s) of the manufacturer(s) whose technical material has been evaluated. Evaluation reports on specifications developed subsequently to the original set of specifications are added in a chronological order to this report. FAO Specifications under the

17、 New Procedure do not necessarily apply to nominally similar products of other manufacturer(s), nor to those where the active ingredient is produced by other methods of synthesis. FAO has the possibility to extend the scope of the specifications to similar products, but only when the Panel of Expert

18、s has been satisfied that the additional products are equivalent to those which formed the basis of the reference specification. * Footnote: The publications are available on Internet under (/FAOINFO/AGRICULT/AGP/AGPP/Pesticid/) or as hardcopy from the Plant Protection Information Officer. Page 3 of

19、 33 GLYPHOSATE 2000/2001 4 PART ONE SPECIFICATIONS 第一部分 规格 GLYPHOSATE 草甘膦 GLYPHOSATE INFORMATION 5 草甘膦资料 GLYPHOSATE ACID TECHNICAL MATERIAL (2000, 2001) 6 草甘膦酸原药 GLYPHOSATE ACID TECHNICAL CONCENTRATE (2000, 2001) 8 草甘膦酸母药 GLYPHOSATE ISOPROPYLAMINE SALT TECHNICAL CONCENTRATE(2000) 10 草甘膦异丙胺盐母药 GLYPHO

20、SATE SOLUBLE CONCENTRATES (2000) 12 草甘膦水剂 GLYPHOSATE WATER SOLUBLE GRANULES (2000) 14 草甘膦可溶粒剂 Page 4 of 33 GLYPHOSATE 2000/2001 5 FAO SPECIFICATIONS AND EVALUATIONS FOR PLANT PROTECTION PRODUCTS 联合国粮农组织植保产品规格和评估 GLYPHOSATE INFORMATION 草甘膦资料 COMMON NAME : Glyphosate (ISO) 通用名：草甘膦（ISO） Structural form

21、ula结构式 EMPIRICAL FORMULA分子式: C3H8NO5P RMM分子量: 169 CAS REGISTRY NUMBER : 1071-83-6 CAS编码 CIPAC CODE NUMBER: 284 CIPAC代码 CHEMICAL NAMES: N-(phosphonomethyl)glycine (IUPAC and CA) 化学名称：N-膦酸甲基甘氨酸（IUPAC and CA） Page 5 of 33 GLYPHOSATE SPECIFICATIONS 2000/2001 6 GLYPHOSATE ACID TECHNICAL 284/TC (2000/2001

22、) 草甘膦原药 This specification, which is PART ONE of this publication, is based on an evaluation of data submitted by the manufacturers whose names are listed in the evaluation reports (284/2000 + 2001). It should be applicable to relevant products of this manufacturer but it is not an endorsement of th

23、ose products, nor a guarantee that they comply with the specifications. The specification may not be appropriate for the products of other manufacturers. The evaluation reports (284/2000 + 2001) as PART TWO forms an integral part of this publication. .1 DESCRIPTION描述 The material shall consist of gl

24、yphosate (acid), together with related manufacturing impurities. It shall be a white dry powder, free from visible extraneous matter and added modifying agents. 该物质应包含草甘膦（酸），以及相关生产杂质。其为白色干燥粉末，无可见外来杂质和添加剂。 .2 ACTIVE INGREDIENT有效成分 .2.1 Identity tests (284/TC/(M)/2, CIPAC 1C, p.2132), (Note 1) 定性检测(28

25、4/TC/(M)/2, CIPAC 1C, p.2132), (备注 1) The active ingredient shall comply with an identity test and, where the identity remains in doubt, shall comply with at least one additional test. 有效成分应符合定性检测，如果鉴定存在疑问，则至少应采用一种其它附加测试方法。 .2.2 Glyphosate acid (284/TC/(M)/3, CIPAC 1C, p.2132) (AOAC 983.10, 1990) 草甘

26、膦酸(284/TC/(M)/3, CIPAC 1C, p.2132) (AOAC 983.10, 1990) The glyphosate acid content shall be declared (not less than 950 g/kg) and, when determined, the mean measured content shall not be lower than the declared minimum content. 应说明草甘膦酸的含量（不低于950g/kg）,检测时其平均含量应不低于最低含量。 .3 RELEVANT IMPURITIES 相关杂质 .3.

27、1 Formaldehyde (Note 2) 甲醛（备注2） Maximum 1.3 g/kg of the glyphosate acid content found under .2.2. 1.3 g/kg .3.2 N-Nitrosoglyphosate (Note 2) 亚硝基草甘膦（备注2） Maximum 1 mg/kg 1 mg/kg 7 .3.3 Insolubles in 1 M NaOH (MT 71) 氢氧化钠不溶物(MT 71) Maximum: 0.2 g/kg 0.2 g/kg Note 1 An additional identity test is avail

28、able from the Plant Protection officer, Fao Plant Production and Protection Division, or click here to download the document . 备注1：附加鉴定方法可从联合国粮农组织植物种植保护部植保办公室获得，或点击此处下载文件。 Note 2 Method available from the Plant Protection Officer, Plant Production and Protection Division, or download Formaldehyde an

29、d N-Nitrosoglyphosate. . 备注2：该方法可从联合国粮农组织植物种植保护部植保办公室获得，或可下载甲醛和亚硝基草甘膦 8 GLYPHOSATE ACID TECHNICAL CONCENTRATES 284/TK (2000/2001) 草甘膦酸母药 This specification, which is PART ONE of this publication, is based on an evaluation of data submitted by the manufacturers whose names are listed in the evaluatio

30、n reports (284/2000 + 2001). It should be applicable to relevant products of this manufacturer but it is not an endorsement of those products, nor a guarantee that they comply with the specifications. The specification may not be appropriate for the products of other manufacturers. The evaluation re

31、ports (284/2000 + 2001) as PART TWO forms an integral part of this publication. .1 DESCRIPTION描述 The material shall consist of glyphosate (acid) together with related manufacturing impurities. It shall be a white to greyish wet cake, free from visible extraneous matter and added modifying agents. 该物

32、质应包含草甘膦（酸）和相关生产杂质。其应为白色至灰色湿粉，无可见外来杂质和添加剂。 .2 ACTIVE INGREDIENT有效成分 2.1 Identity tests (284/TC/(M)/2, CIPAC 1C, p.2132), (Note 1) 鉴定试验(284/TC/(M)/2, CIPAC 1C, p.2132), (备注1) The active ingredient shall comply with an identity test and, where the identity remains in doubt, shall comply with at least o

33、ne additional test. 该有效成分应进行鉴定试验，如鉴定存在疑问，则应至少采用另外一种附加鉴定方法。 .2.2 Glyphosate acid (284/TC/(M)/3, CIPAC 1C, p.2132) (AOAC 983.10, 1990) 草甘膦酸 The glyphosate acid content shall be declared (not less than 950 g/kg on a dry basis) and, when determined, the mean measured content obtained shall not differ fr

34、om that declared by more than + 20 g/kg. 应声明草甘膦酸含量（不低于950g/kg,干基），检测时平均含量于声明含量偏差应不超过20 g/kg. .3 IMPURITIES 杂质 .3.1 Formaldehyde (Note 2)甲醛（备注2） Maximum 1.3 g/kg of the glyphosate acid content found under .2.2. 1.3 g/kg .3.2 N-Nitrosoglyphosate (Note 2) 亚硝基草甘膦（备注2） Maximum 1 mg/kg 1 mg/kg .3.3 Loss o

35、n drying (MT 17.3, Sample weight: 10 g; temperature: 105 C, time: 3 hours.).The loss on drying shall be declared and, when measured the average loss shall be not more than 200 g/kg. 干燥减量（MT 17.3，样品量：10g;温度：105，时间：3小时） 9 应公布干燥减量，检测时平均干燥减量应不高于200 g/kg. 3.4 Insolubles in 1 M NaOH (MT 71) 氢氧化钠不溶物(MT 71)

36、 Maximum: 0.2 g/kg, dry weight basis 0.2 g/kg，以干基计 Note 1 An additional identity test is available from the Plant Protection officer, Fao Plant Production and Protection Division, or click here to download the document . 备注1：附加鉴定方法可从联合国粮农组织植物种植保护部植保办公室获得，或点击此处下载文件。 Note 2 Method available from the P

37、lant Protection Officer, Plant Production and Protection Division, or download Formaldehyde and N-Nitrosoglyphosate. . 备注2：该方法可从联合国粮农组织植物种植保护部植保办公室获得，或可下载甲醛和亚硝基草甘膦 . 10 GLYPHOSATE ISOPROPYLAMINE SALT TECHNICAL CONCENTRATES 284 /TK (2000) 草甘膦异丙胺盐母药 This specification, which is PART ONE of this public

38、ation, is based on an evaluation of data submitted by the manufacturer whose name is listed in the evaluation report (284/2000). It should be applicable to relevant products of this manufacturer but it is not an endorsement of those products, nor a guarantee that they comply with the specifications.

39、 The specification may not be appropriate for the products of other manufacturers. The evaluation report (284/2000) as PART TWO forms an integral part of this publication. .1 DESCRIPTION描述 The material shall consist of glyphosate (acid), complying with the requirements of FAO specification 284/TC, t

40、ogether with related manufacturing impurities in the form of the isopropylamine salt, and shall be a solution in water, free from visible extraneous matter and added modifying agents except for the diluent. 该物质应包含草甘膦（酸），并符合联合国粮农组织原药规格284/TC；以及在生成异丙胺盐过程产生的相关生产杂质；该物质应为水溶液，无可见外来杂质和除稀释剂以外的添加剂。 .2 ACTIVE

41、 INGREDIENT有效成分 2.1 Identity tests (284/TC/(M)/2, CIPAC 1C, p.2132), (Note 1) 鉴定试验 (284/TC/(M)/2, CIPAC 1C, p.2132), (备注 1) The active ingredient shall comply with an identity test and, where the identity remains in doubt, shall comply with at least one additional test. 有效成分应进行鉴定试验，如鉴定存在疑问，则应至少采用另外一

42、种附加鉴定方法进行鉴定。 .2.2 Glyphosate acid (284/TC/(M)/3, CIPAC 1C, p.2132) (AOAC 983.10, 1990) 草甘膦酸 The glyphosate acid content shall be declared, (g/l or g/kg at 20 2C) and, when determined, the mean measured content shall not differ from that declared by more than the appropriate FAO proposed tolerance as

43、 given below: 应公布草甘膦酸含量，(g/l 或 g/kg 20 2C)，检测时平均含量应不超出联合国粮农组织建议的范围，见下表： Declared content in g/kg or g/l at 202C Tolerance 公布含量 允许范围 以g/kg 或 g/l 表示202C above 250 up to 500 5 % of the declared content 250-500 公布含量的 5 % above 500 25 g/kg or g/l 大于500 25 g/kg 或 g/l 11 .3 IMPURITIES杂质 .3.1 Formaldehyde (

44、Note 2)甲醛（备注2） Maximum 1.3 g/kg of the glyphosate acid content found under .2.2. 1.3 g/kg .3.2 N-Nitrosoglyphosate (Note 2) 亚硝基草甘膦（备注2） Maximum: 1 mg/kg 1mg/kg .3.3 Insolubles in Water (MT 10.2) 水不溶物(MT 10.2) Maximum: 0.1 g/kg, dry weight basis 0.1 g/kg，以干基计 .4 PHYSICAL PROPERTIES 物理性质 .4.1 pH range

45、 (MT 75) (Note 3) PH范围(MT 75) (备注3) pH 4.5 to pH 6.8 4.5-6.8 Note 1 An additional identity test is available from the Plant Protection officer, Fao Plant Production and Protection Division, or click here to download the document . 备注1：附加鉴定方法可从联合国粮农组织植物种植保护部植保办公室获得，或点击此处下载文件。 Note 2 Method available

46、from the Plant Protection Officer, Plant Production and Protection Division, or download Formaldehyde and N-Nitrosoglyphosate. . 备注2：该方法可从联合国粮农组织植物种植保护部植保办公室获得，或可下载甲醛和亚硝基草甘膦 . 12 GLYPHOSATE SOLUBLE CONCENTRATES 284/SL (2000) 草甘膦水剂 This specification, which is PART ONE of this publication, is based o

47、n an evaluation of data submitted by the manufacturer whose name is listed in the evaluation report (284/2000). It should be applicable to relevant products of this manufacturer but it is not an endorsement of those products, nor a guarantee that they comply with the specifications. The specificatio

48、n may not be appropriate for the products of other manufacturers. The evaluation report (284/2000) as PART TWO forms an integral part of this publication. .1 DESCRIPTION描述 The material shall consist of a solution of technical glyphosate, complying with the requirements of FAO specification 284/TC in

49、 the form of a soluble salt, dissolved in water, together with any necessary formulants. 该物质应为一种含有以草甘膦水溶性盐的形式存在的草甘膦溶液，并符合联合国粮农组织原药规格284/TC，其还含有其它必要的助剂成分。 It shall be in the form of a clear or opalescent liquid, free from suspended matter and sediment, to be applied as a true solution of the glyphosa

50、te salt in water. 该物质应为澄清透明液体，无可见悬浮物和沉淀物，使用时在水中形成草甘膦盐的真溶液。 .2 ACTIVE INGREDIENT有效成分 .2 ACTIVE INGREDIENT有效成分 2.1 Identity tests (284/TC/(M)/2, CIPAC 1C, p.2132), (Note 1) 鉴定试验 (284/TC/(M)/2, CIPAC 1C, p.2132), (备注 1) The active ingredient shall comply with an identity test and, where the identity re

51、mains in doubt, shall comply with at least one additional test. 有效成分应进行鉴定试验，如鉴定存在疑问，则应至少采用另外一种附加鉴定方法进行鉴定。 .2.2 Glyphosate (284/TC/(M)/3, CIPAC 1C, p.2132) (AOAC 983.10, 1990) 草甘膦 The glyphosate acid content shall be declared for each specific soluble concentrate (g/kg or g/l at 20 2 C, Note 2) and,

52、when determined, the content measured shall not differ from that declared by more than the following amounts: 应声明草甘膦酸含量，(g/l 或 g/kg 20 2C，备注2)，检测时平均含量应不超出联合国粮农组织建议的范围，详见下表： Declared content in g/kg or g/l Tolerance 声明含量 允许范围 以g/kg 或 g/l 表示 up to 25 15 % of the declared content 0-25 声明含量的 15 % 25 to 100 10 % of the declared content 25-100 声明含量的 10 % 13 6 % of the declared content 100 to 250 6 % 100-250 声明含量的5 % of the declared content 250 to 500 5% 250-500 声明含量的 25 g/kg or g/l above 500 g/l 或 25 g/kg 大于500 in each range t