润滑脂介绍课件

The Lubrizol Corporation 2006, all rights reserved China Sales Training-Grease Bill Ward Shanghai January 23-24, 2008 The Lubrizol Corporation 2007, all rights reserved Agenda LZ grease capability Grease Background and Manufacture What is a grease? Chemistry behind making greases? What are the benefits if each type of grease? What hardware is used in making grease, and how used? Grease market data Grease Testing Lubrizols grease additives AW/EP components Multi-purpose packages Rust Inhibitor Polymers for grease application Water resistant polymer Ca sulfonate Lubrizol 5280GR Developmental ashless package Boron compounds The Lubrizol Corporation 2007, all rights reserved Industrial Additive Technology 工业用油添加剂技术 The broadest industrial testing capability and additive product line: 最全面的测试能力及添加剂产品线： Grease 润滑脂 Hydraulics液压油 Industrial gear工齿 Metalworking金属加工 Turbine oil透平油 Compressor oil压缩机油 Circulating oil循环油 Rust A99; LZ5034A, A6043U Partial packages: LZ5210, LZ5215 Polymers Full line of offers Polymer selling tool The Lubrizol Corporation 2007, all rights reserved Extreme Pressure and Antiwear Component Additives 极压抗磨单剂 Product Chemical Type Treat Rate % Wt Anglamol 33Olefin sulfide0.5-2.0 Lubrizol 732AAntimony Dithiocarbamate2.0-4.0 Lubrizol 1395Primary ZDP0.5-2.0 Lubrizol 677ASecondary ZDP0.5-1.0 Future component development: Ashless Borate The Lubrizol Corporation 2007, all rights reserved Anglamol33 Alkyl polysulfide Used as an EP “backbone” in greases. Improves 4-ball weld 提高四球烧结值 Helps Timken 提高Timken承载值 Commonly used at 1-2%. 加剂量1-2% Produce a protective thin film on surface and provide high load carry capacity 形成表面保护膜从而提供高承载能力 The Lubrizol Corporation 2007, all rights reserved Zinc Dithiophosphates Lubrizol1395 Sulfur/Phosphorus/Zinc Antiwear Agent Primary Alkyl Zinc Dithiophosphate Recommended Treat Rates: 0.5% - 2.0% Lubrizol677A Sulfur/Phosphorus/Zinc Antiwear Agent Secondary Alkyl Zinc Dithiophosphate Recommended Treat Rates: 0.5% - 1.5% Reduces surface wear and impart some oxidation stability to grease 减少表面磨损并提高氧化稳定性 The Lubrizol Corporation 2007, all rights reserved Lubrizol 732A - Antimony Dithiocarbamate Sample12345 Contactor Grease8585858585 Grading Oil12.510.58.510.58.5 Base Additive, Zn/P/S Type2.52.52.52.52.5 LZ 732A24 Competitive A24 Total100100100100100 D217 worked penetration, P60272291292287292 D2265 drop point, C205203231213201 D2266 average scar diameter, mm0.650.670.660.670.67 D2596 weld point, kg315315500250500 load wear index44.851.561.145.663.1 D2509 OK value, lb25451003565 scar width, in0.0380.0710.0960.0590.086 contact pressure, psi1440213139214871238215435 The Lubrizol Corporation 2007, all rights reserved Oxidation Inhibitors and Metal Deactivator Lubrizol 5150CLubrizol 817Lubrizol 5955A Product Chemical Type Treat Rate % Wt Lubrizol 5150C Alkenylamine 0.25-1.0 Lubrizol 817Di-t-butyl-p-cresol0.25-1.0 Lubrizol 5955A Substituted Thiadiazole 0.25-1.0 The Lubrizol Corporation 2007, all rights reserved Multi-Purpose Grease Additive Packages 多功能润滑脂复合剂 ProductChemical TypeTreat Rate% Wt Fully formulated packages （全配方） Lubrizol 5230Sulfur/Phosphorus(ashless)1.0-4.0 Lubrizol 5235Sulfur/Phosphorus/Zn1.0-4.0 Lubrizol 5220 Sulfur/Phosphorus/Zn0.5-4.0 Anglamol 99Sulfur/Phosphorus1.0-4.0 Lubrizol 5034ASulfur/Phosphorus1.0-4.0 Partial Package （半配方） Lubrizol 5210Sulfur/Phosphorus/Zn1.5-3.0 The Lubrizol Corporation 2007, all rights reserved Lubrizol 5230 A complete ashless package containing EP agents, antiwear compounds, rust and copper corrosion inhibitors, and friction modifiers greasetype%Timken Unit Pressure (psi) wearweld ALi2.54519,0000.45250 BLi2.55527,0000.45315 CLi3.03017,0000.42250 DLi2.56016,0000.33400 ELi2.53014,0000.39200 FLi2.54522,0000.45250 GLi3.05021,0000.57250 HLi3.05527,0000.48250 ILiCmpx3.04525,0000.45315 KLiCmpx3.03521,0000.57315 The Lubrizol Corporation 2007, all rights reserved Lubrizol 5235 Lubrizol 5235 is a complete package that provides extreme pressure, antiwear protection while providing rust inhibition, oxidation inhibition and resistance to copper corrosion greasetype%Timken Unit Pressure (psi) wearweld ALi2.52511,0000.45200 BLi2.54022,5000.43200 CLi3.05532,0000.51200 DLi3.04019,0000.45250 ELi3.04521,0000.45250 FLi3.04526,3050.45250 GLi3.05531,0000.48200 The Lubrizol Corporation 2007, all rights reserved Lubrizol 5220 Multipurpose Grease Additive Package NLGI 2 Lithium 12- Hydroxystearate Grease 2.5% Lubrizol 5220 TestMethodResults Timken OK LoadD 250940 lbs. Four-Ball Wear, mmD 22660.39 mm Four-Ball Weld, kgD 2596250 kg LWI32.5 RustD 1743Pass Cu CorrosionD 40481A The Lubrizol Corporation 2007, all rights reserved Lubrizol 5210 greasetype%Timken Unit Pressure (psi) wearweld ALi2.04023,0000.45250 BLi3.03017,0000.48315 CLi2.06036,0000.48250 The Lubrizol Corporation 2007, all rights reserved Lubrizols Rust Inhibitors for Grease Lubrizol 5401 Alkyl Succinic Acid/Ester Improves ASTM D1743 rust results Lubrizol 5402 Calcium Sulfonate Excellent B117 1000 hours salt fog performance Lubrizol 5403 Imidazoline Improves ASTM D1743 rust results Lubrizol 5391 Alkenyl Amide Borate Improves ASTM D1743 rust results Effective in ASTM D5969 and IP220 EMCOR salt water test. Lubrizol 5399 Amine Phosphate Excellent IP220 EMCOR performance testing in both synthetic sea water and 0.5M aqueous NaCl Performs well in both the ASTM D5969 synthetic sea water and ASTM D1743 distilled water rust tests The Lubrizol Corporation 2007, all rights reserved Lubrizol 5401 Alkyl Succinic Acid/Ester Rust Inhibitor Recommended Treat Rates: 0.1% -1.0% wt. Performance in a fully additized Lithium 12-Hydroxystearate Grease D1743 Rust Results Without Lubrizol 5401Fail (moderate) With 0.55 wt% Lubrizol 5401Pass The Lubrizol Corporation 2007, all rights reserved Lubrizol 5402 Calcium Sulfonate Rust Inhibitor Recommended Treat Rates: 0.5% - 5.0% wt Excellent Salt Fog Performance Performance in a Lithium 12-Hydroxystearate Grease B117 Salt Fog Material500 hrs1000 hr Without Lubrizol 5402slight rust2-10% rust + discoloration With 2.25 wt% Lubrizol 5402no rustno rust The Lubrizol Corporation 2007, all rights reserved Lubrizol 5403 Imidazoline Rust Inhibitor Recommended Treat Rates: 0.1% -1.0% wt. Performance in Lithium 12-Hydroxystearate Grease D1743 Rust Without Lubrizol 5403Fail (light) With 0.25 wt% Lubrizol 5403Pass The Lubrizol Corporation 2007, all rights reserved Lubrizol 5391 Alkenyl Amide Borate Rust Inhibitor Recommended Treat Rates: in distilled water testing 0.25 - 1.0 wt% in salt water testing 4.0-5.0 wt% Performance in a Lithium 12-Hydroxystearate Grease D1743 Rust Results Without Lubrizol 5391Fail (light) With 1.0 wt% Lubrizol 5391pass Modified EMCOR (0.02 M NaCl solution) Without Lubrizol 53912 With 3.0 wt% Lubrizol 53910 The Lubrizol Corporation 2007, all rights reserved Lubrizol 5399 Amine Phosphate Rust Inhibitor Li 12-Hydroxystearate Base GreaseD1743 Rust Results Without Lubrizol 5399Fail With 0.5 wt% Lubrizol 5399Pass IP220 EMCOR Result Soap Type Lubrizol 5399 Treat Rate Synthetic Sea Water 0.5 M NaCl Simple Lithium 1.502 2.500 Lithium Complex 2.0000 Calcium Anhydrous 2.522 5.000 Polyurea BaseD5969 Synthetic Sea Water With 2.0 wt% Lubrizol 5399Fail (trace) With 3.0 wt% Lubrizol 5399Pass The Lubrizol Corporation 2006, all rights reserved Polymers for Grease Applications The Lubrizol Corporation 2007, all rights reserved Lubrizols polymer offering Broad product line By type OCP Functionalized OCP PIB SIP SBR MSC Composite By Function Thickeners Water resistant technology Tackifiers Salt fog protection Bright stock alternative The Lubrizol Corporation 2007, all rights reserved Building Base Oil Viscosity with Lubrizol Solid Polymers Equivalent to 51% 150 Bright Stock The Lubrizol Corporation 2007, all rights reserved Lubrizol Olefin Copolymers for Grease Solid/Block, amorphous 固态，无定形 Lubrizol2011 (25 SSI) Lubrizol7065C (35 SSI) Lubrizol7060H (50 SSI) Pelletized OCP, semi-crystalline 半结晶 Lubrizol2019 (10 SSI) Lubrizol Liquid OCP 液态 Lubrizol7077D (13% Lubrizol2011) Lubrizol7075F (9.5% Lubrizol7065C) Lubrizol7070D (9.0% Lubrizol7060H) The Lubrizol Corporation 2007, all rights reserved Grease formulaNoneLZ2019LZ2011LZ7065CLZ7060H Lithium base grease, % by weight70.070.070.070.070.0 Grading oil, % by weight30.028.028.528.929.0 % by weight of polymer0.02.01.51.11.0 Total100.0100.0100.0100.0100.0 Testing: ASTM D217 P0279277269268274 P60272-270267278 P10k283283275273285 P100k296304298301298 ASTM D4693 low temp torque (-40C,Nm)5.267.518.258.557.13 ASTM D1742 oil separation, %, 25C8.61.13.83.63.1 ASTM D942 Bomb oxidation, psi loss76.51.50.535.267.3 LT-37 Mobility (Petro-Lubricant) gm/min. 0F4913352226 20F2246514413496 40F853392500398337 60F16659261178854730 77F25141191159116021448 The Lubrizol Corporation 2007, all rights reserved Lubrizol Styrene Diene Co-polymers Styrene-isoprene copolymers 苯乙烯-异戊二烯共聚 物 Lubrizol7308, crumb, 15 SSI Lubrizol7318, liquid (6% Lubrizol7308) Lubrizol7306, crumb, 60 SSI Styrene-butadiene copolymers 苯乙烯-丁二烯共聚物 Lubrizol7408A, di-block 嵌段 Lubrizol5994A, star 星形 VI boost 提高粘度指数 excellent thickening and shear stable 高增稠能力和 剪切稳定性 Salt fog protection 盐雾防锈保护 The Lubrizol Corporation 2007, all rights reserved Grease formulaNoneLZ7308LZ7306LZ7408ALZ5994A Lithium base grease, % by weight70.070.070.070.070.0 Grading oil, % by weight30.028.729.228.528.6 % by weight of polymer0.01.30.91.51.4 Total100.0100.0100.0100.0100.0 Testing: ASTM D217 P0279285274266268 P60272277274269264 P10k283284283280272 P100k296285302298288 ASTM D4693 low temp torque (-40C,Nm)5.266.666.968.687.59 ASTM D1742 oil separation, %, 25C8.612.24.113.411.4 ASTM D942 Bomb oxidation, psi loss76.553.955.6n/a2.4 LT-37 Mobility (Petro-Lubricant) gm/min. 0F4948624644 20F224217223202152 40F853529517523461 60F16651034110411271240 77F25141999176818341706 The Lubrizol Corporation 2007, all rights reserved Lubrizol Polyisobutylenes Lubrizol5907A High molecular weight tackifier ADDCOADDTAC Mixed polymer tackifier, USDA H-1 approved Lubrizol3130A Synthetic thickener Better low temperature properties than Bright Stock Higher VI boost Cleaner than Bright Stock Possible bearing life improvement The Lubrizol Corporation 2007, all rights reserved Composite Lubrizol7469 OCP-SIP composite Pellet Shear stability 2 SSI Lubrizol7460 OCP-SIP composite Pellet Shear stability 45 SSI The Lubrizol Corporation 2007, all rights reserved Grease formulaNoneLZ7469LZ7460 Lithium base grease, % by weight70.070.070.0 Grading oil, % by weight30.028.729.2 % by weight of polymer0.01.30.9 Total100.0100.0100.0 Testing: ASTM D217 P0279280273 P60272268279 P10k283287274 P100k296299292 ASTM D4693 low temp torque (-40C,Nm)5.269.087.73 ASTM D4049 spray-off, %97.576.772 ASTM D1264 washout, %3.91.511.6 ASTM D6184 oil separation, %, 100C4.61.61.1 ASTM D942 Bomb oxidation, psi loss76.552.650.4 LT-37 Mobility (Petro-Lubricant) gm/min. 0F492631 20F224163151 40F853439429 60F166511891114 77F251417491853 The Lubrizol Corporation 2006, all rights reserved Lubrizols Water-resistant Polymer for Grease Application The Lubrizol Corporation 2007, all rights reserved Lubrizol Water Resistance Polymers Lubrizol2002 Lubrizol2002D 4.5% Lubrizol 2002 in base oil Lubrizol2006E The Lubrizol Corporation 2007, all rights reserved Lubrizol 2002 Multifunctional polymer Recommended at 0.225 - 0.50% wt Incorporates into the soap structure Excellent water resistance Improved thickening efficiency Excellent tack at low treat rates Good low temperature mobility The Lubrizol Corporation 2007, all rights reserved BenefitsBenefits Can reduce process time: LZ 2002 is added with the initial ingredients. Can improve Water Resistance without affecting pumpability: Because LZ 2002 reacts with the soap instead of the oil, the oil phase is unaffected. The Lubrizol Corporation 2007, all rights reserved Lubrizol 2002 Lithium 12 Hydroxystearate Grease The Lubrizol Corporation 2006, all rights reserved Lubrizol 2006E A New Water-resistant Polymer for Grease The Lubrizol Corporation 2007, all rights reserved LZ2006E A new polymer for enhanced water resistance LZ2002 and LZ2002D, premium flagship water resistant polymer technology LZ2006E is a new polymer technology with improved handling properties LZ 2006E has good flow properties for easy handling and use with easy solublization. Water resistance close or comparable to LZ2002/LZ2002D Recommended treat rate: 3% The Lubrizol Corporation 2007, all rights reserved LZ2006E E signifies easy handling and use Lubrizol 2002Lubrizol 2006ELubrizol 2002D Pour point CKV 100 less steam during soap manufacture Making Li complex grease is much easier and more consistent Benefits of Lithium Hydroxide Dispersion The Lubrizol Corporation 2006, all rights reserved Developmental Ashless Package The Lubrizol Corporation 2007, all rights r