55%代森联+5%吡唑醚菌酯WG MSDS（Nufarm Australia公司）

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55%代森联+5%吡唑醚菌酯WGMSDS（NufarmAustralia公司）

CS:1.4.93Page:1MaterialSafetyDataSheet4ofInfosafeNo3NUAQJuly2010ISSUEDbyNUFARMIssueDate:AEROFungicideProductNameClassifiedashazardous1.IDENTIFICATIONOFTHEMATERIALANDSUPPLIERProductNameAEROFungicideProductCode5365ProductTypeGroup11M3FungicideCompanyNameNUFARMAUSTRALIALIMITED.(ABN80004377780)Address103-105PipeRoadLavertonNorthVictoria3026AustraliaEmergencyTel.1800033498(24hrAustralia)Telephone/FaxNumberTel:+6139282-1000Fax:+6139282-1001RecommendedUseForthecontrolofearlyandlate(Irish)blightinpotatoes,earlyblightincapsicum,eggplant,peppersandtomatoes,downymildewinpoppiesandvariousdiseasesinmangoesasspecifiedintheDirectionsforUsetableonthelabel.OtherInformationThisMSDSdescribes,tothebestofourknowledge,thepropertiesoftheconcentratedproduct.Thephysicalpropertiesandsomeoftheassessmentsdonotapplytothepropertiesoftheproductonceithasbeendilutedforapplication.Acutehealtheffectsofthedilutedproductarelikelytobemuchlesssevere.2.HAZARDSIDENTIFICATIONHazardClassificationClassifiedashazardousHAZARDOUSSUBSTANCE.NON-DANGEROUSGOODS.HazardclassificationaccordingtothecriteriaofNOHSC.DangerousgoodsclassificationaccordingtotheAustraliaDangerousGoodsCode.RiskPhrase(s)ClassifiedashazardousR22Harmfulifswallowed.R38Irritatingtoskin.SafetyPhrase(s)S13Keepawayfromfood,drinkandanimalfeedingstuffs.S2Keepoutofreachofchildren.S37Wearsuitablegloves.S46Ifswallowed,seekmedicaladviceimmediatelyandshowthiscontainerorlabel.OtherInformationPoisonsScheduleS53.COMPOSITION/INFORMATIONONINGREDIENTSChemicalCharacterizationSolidCASProportionNameIngredients9006-42-2Metiram550g/kg175013-18-0Pyraclostrobin50g/kgOtheringredients(considerednon-hazardous)Balance4.FIRSTAIDMEASURESInhalationRemoveaffectedpersontofreshairuntilrecovered.Ifsymptomsdeveloporpersist,seekmedicaladvice.IngestionRinsemouthandthendrinkplentyofwater.Donotgiveanythingbymouthtoasemi-consciousorunconsciousperson.Obtainmedicaladvice.SkinWashaffectedareasthoroughlywithsoapandwater.Removecontaminatedclothingandlaunderbeforere-use.Ifirritationpersists,seekmedicaladvice.EyeIfineyes,holdeyelidsopenandwashwithcopiousamountsofwaterforatleast15minutes.Seekmedicaladvice.PrintDate:1/07/2010CS:1.4.93CS:1.4.93Page:2MaterialSafetyDataSheet4ofInfosafeNo3NUAQJuly2010ISSUEDbyNUFARMIssueDate:AEROFungicideProductNameClassifiedashazardousFirstAidFacilitiesIfpoisoningoccurs,contactadoctororthePoisonsInformationCentre(Australia)on131126.AdvicetoDoctorTreatsymptomatically.Avoidgivingalcohol-maycausevomitingandshock.5.FIREFIGHTINGMEASURESSuitableExtinguishingMediaWaterfog,foam,carbondioxideordrychemical.Avoidstrongwaterjets-airbornedustsmayformaflammabledustcloud.HazardsfromCombustionProductsMayemithazardoussmokeandfumesifinvolvedinfiresorexposedtoextremeheat.SpecialProtectiveEquipmentforfirefightersBreathableairapparatusshouldbewornwhenfightingafireinwhichthisproductisinvolved.EmergencyActionincaseofFireIfexposedtofire,keepcontainercoolbysprayingwithwater.OtherInformationSTOPFIREWATERFROMENTERINGDRAINSORWATERBODIES.6.ACCIDENTALRELEASEMEASURESSpillsDisposalRecovertheproductbysweepinguporvacuumingwithoutraisingdust.Collectspilledmaterial,wasteandwashwaterinsealableopen-toptypecontainersfordisposal.On-sitedisposalofconcentrateisnotacceptable.PersonalProtectionForappropriatepersonalprotectiveequipment(PPE),referSection8.7.HANDLINGANDSTORAGEPrecautionsforSafeHandlingDoNOTcontaminatedams,riversorstreams,oranyotherwaterbodieswithpesticideorusedcontainers.Avoidgeneratingdustswhilehandlingtheproductandmixing.ConditionsforSafeStorageStoreintheclosed,originalcontainerinacool,wellventilatedarea.Donotstoreforprolongedperiodsindirectsunlight.OtherInformationAlwaysreadthelabelandanyattachedleafletbeforeuse.8.EXPOSURECONTROLS/PERSONALPROTECTIONNationalExposureStandardsNoexposurestandardshavebeenestablishedforthisproductbyWorksafeAustralia,however,theTWAexposurestandardfordustsnototherwisespecifiedis10mg/m3.EngineeringControlsUseinawellventilatedareaonly.Avoidgeneratingandinhalingdusts.RespiratoryProtectionIfdustsarepresent,wearaclassP1dustmask.PersonalProtectiveEquipmentWhenopeningthecontainer,preparingsprayandusingthepreparedspraywearcottonoverallsbuttonedtotheneckandwristandawashablehat,elbow-lengthPVCglovesandgoggles.Re-entryperiod:Donotentertreatedareauntilsprayhasdried.HygieneMeasuresAfteruseandbeforeeating,drinkingorsmoking,washhands,armsandfacethoroughlywithsoapandwater.Aftereachday’suse,washcontaminatedclothingandsafetyequipment.RequirementsConcerningSpecialTrainingCheckStateorTerritoryregulationsthatrequirepeoplewhousepesticidesintheirjoborbusinesstohavetrainingintheapplicationofthematerials.9.PHYSICALANDCHEMICALPROPERTIESFormSolidAppearanceBrowngranulesOdourAromaticodourSolubilityinWaterDispersesinwater.pHValue4.7(1%suspensioninwater)PrintDate:1/07/2010CS:1.4.93CS:1.4.93Page:3MaterialSafetyDataSheet4ofInfosafeNo3NUAQJuly2010ISSUEDbyNUFARMIssueDate:AEROFungicideProductNameClassifiedashazardousVapourPressure0.01mPa(metiram@20C);2.6x10-5mPa(pyraclostrobin@20C)Octanol/WaterPartitionCoefficientKowLogPis0.3(metiram@pH7);3.99(pyraclostrobin)FlammabilityDustmayformflammabledustcloud.Auto-IgnitionTemperature199C10.STABILITYANDREACTIVITYChemicalStabilityStableundernormalconditions.IncompatibleMaterialsAvoidcontactoftheproductwithstrongacidsandbases.HazardousPolymerizationHazardouspolymerisationisnotpossible.11.TOXICOLOGICALINFORMATIONToxicologyInformationNoharmfuleffectsareexpectediftheprecautionsonthelabelandthisMSDSarefollowed.InhalationMaycauseirritationtotherespiratorytract.Breathinginhighconcentrationsofdustsoraerosolsofthismaterialmaycauseheadache,nausea,dizzinessandweakness.IngestionPossiblesymptomsofexposureinclude:headache,nausea,dizzinessandweakness.Consumptionofalcoholincreasesthetoxiceffects.SkinMayirritatetheskin.EyeMayirritatetheeyes.ChronicEffectsBasedonavailabledata,repeatedexposuresarenotanticipatedtocauseadditionalsignificantadverseeffects.AcuteToxicity-OralLD50(rat)500-2000mg/kgforasimilarformulationAcuteToxicity-DermalLD50(rat)2000mg/kgforasimilarformulationAcuteToxicity-InhalationLC50(rat)(4hr)5.6mg/lforasimilarformulationEyeIrritationMildeyeirritant.SkinIrritationMildskinirritant.OtherInformationTheAustralianAcceptableDailyIntake(ADI)formetiramforahumanis0.02mg/kg/day,setforthepublicfordaily,lifetimeexposure.ThisisbasedontheNOELof5mg/kg/day,theleveldeterminedtoshownoeffectsduringlongtermexposureforthemostsensitiveindicatorsandthemostsensitivespecies.(Ref:Comm.Dept.ofHealthandAgeingOfficeofChemicalSafety,‘ADIList’,December2008).ADIforpyraclostrobinis0.03mg/kg/day,NOEL3mg/kg/day.12.ECOLOGICALINFORMATIONPersistence/DegradabilityNotreadilybiodegradable.KnownHarmfulEffectsontheEnvironmentTheproductisamarinepollutantforseatransport.OtherPrecautionsDonotcontaminatedams,waterwaysorsewerswiththisproductorthecontainerswhichhaveheldthisproduct.Environ.ProtectionSpraydriftcancausedamage,readthelabelformoreinformation.AcuteToxicity-FishToxictofish.LC50(96hr)forrainbowtroutis0.149mg/l.Theabovedataisfortheformulatedproduct.AcuteToxicity-AlgaeEC50(72hr)forPseudokirchneriellasubcapitatais0.25mg/lforasimilarformulation.AcuteToxicity-OtherOrganismsNottoxictobirds.Nottoxictobees.PrintDate:1/07/2010CS:1.4.93CS:1.4.93Page:4MaterialSafetyDataSheet4ofInfosafeNo3NUAQJuly2010ISSUEDbyNUFARMIssueDate:AEROFungicideProductNameClassifiedashazardous13.DISPOSALCONSIDERATIONSProductDisposalOnsitedisposaloftheconcentratedproductisnotacceptable.Ideally,theproductshouldbeusedforitsintendedpurpose.Ifthereisaneedtodisposeoftheproduct,approachlocalauthoritieswhoholdperiodiccollectionsofunwantedchemicals(ChemClear).ContainerDisposalThoroughlywashouttheinnerandaddwashingstothespraytank.Disposeofwashedinnerandcardboardboxinlandfill.Ifnolandfillisavailable,burythecontainersbelow500mminadisposalpitspecificallymarkedandsetupforthispurposeclearofwaterways,desirablevegetationandtreeroots.Emptycontainersandproductshouldnotbeburnt.14.TRANSPORTINFORMATIONStorageandTransportConsiderednondangerousforroadandrailtransport(inpackaging)bytheAustralianCodefortheTransportofDangerousGoodsbyRoadandRail.Ref:ADG7;SPNo.AU01.ForbulkshipmentsasClass9,useUN3077,HazChemcode2Z.UNNumber(SeaTransport)3077IMOClass/PackingGroupClass9;PackingGroupIIIIMOMarinePollutantMarinepollutant.IMOProperShippingNameENVIRONMENTALLYHAZARDOUSSUBSTANCE,SOLID,N.O.S.(ContainsMetiramandPyraclostrobin)15.REGULATORYINFORMATIONPoisonsScheduleS5PackagingLabellingCAUTIONKEEPOUTOFREACHOFCHILDRENREADSAFETYDIRECTIONSBEFOREOPENINGORUSINGHazardCategoryHarmful,IrritantAICS(Australia)AllofthecomponentsinthisproductarelistedontheAustralianInventoryofChemicalSubstances.16.OTHERINFORMATIONDateofpreparation