电化学工作站校准规范实验报告

国家计量技术标准规程制修订试验报告上海市计量测试技术争论院202306月试验报告1、试验目的验证《电化学工作站校准标准》的适用性和可行性。2、试验地点械〔集团〕〔上海〕、上海医疗器械检测所、上海交通大学医学院附属第九人民医院、上海外形记忆合金材料检验中心11家试验单位对瑞士万通公司的PGSTAT128N型、PGSTAT204型、PGSTAT302N型；上海辰华公司的CHI630E型、CHI650E型、CHI660E型；AMETEK公司的VersaSTST3型、PARSTST-40W型、GAMRY公司的Referenee600f型、Solartron公司的SI128715台仪器进展了试验验证。3温度：〔15~30〕C;相对湿度：20%~80%;供电电源：电压〔22022〕V,频率〔501〕Hz4目前瑞士万通和上海辰华的电化学工作站占据一半以上的市场份额。因此，在验证明验中重点考察了以上2家公司的产品，选择了瑞士万通PGSTAT128N、PGSTAT204PGSTAT302N三个系列，上海辰华的CHI630E、CHI650E、CHI660E三个系列进展试验验证，同时兼顾了AMETEK公司的VersaSTST3型、PARSTST-40W型，GAMRY公司的Referenee600f型,Solartron公司的SI1287，累计收集了155、校准用仪器及试剂数字万用表，至少3位半，经计量校准电位相对扩展不确定度切.01%,(k=2);标准电阻，1000KQ,精度至少到达0.01%，经计量校准相对扩展不确定度<1X10-4%，(k=2);分析天平，天平准确度为(T)0.1mg;容量瓶，A级；玻碳电极、银/氯化银电极(Ag/AgCI)、铂丝电极符合试验室要求；铁氰化钾和氯化钾：分析纯；电化学工作站校准溶液：包括0.1moI/L氯化钾，配制方法见校准标准附录B。

0.50mmol/L铁氰化6、试验结果瑞士万通的PGSTAT128N验证明验客户名称客户地址仪器名称生产厂商型号/规格仪器编号温度主要测量设备

常州市康辉医疗器械11号电化学工作站瑞士万通PGSTAT128NAUT8560722C60%20230514日名称名称/型号编号测量范围/准确度证书编号/有效期数字多用表8840A标准电阻BZ34507026U =3X10-5(k=2)rel643132999.78kQUrel=6X10-5(k=2)2023F11-20-0008742023-03-122023F21-20-9150052023-03-10(V)(V)电位测量值(V)平均值(V)示值误差(V)度(k=2)(V)0.10.10020.10020.10020.10020.10020.10020.1002-0.00020.00010.20.20230.20230.20230.20230.20230.20230.2023-0.00030.00010.50.50060.50060.50060.50060.50060.50060.5006-0.00060.00011.01.00031.00031.00031.00031.00031.00031.0003-0.00030.00012.02.00052.00052.00052.00052.00052.00052.0005-0.00050.0001电位(V)电位(V)设测量(A)电化学工作站电流测量值(A)疋(A)示值误差(A)值度(k=2)(A)值0.10.10021.0022X109.9940-7X10-81.0013X10-71.0028X10-71.0016X10-79.9979X10-89.9995 1.0008X10-7X10-7-1.4X10-102.3X10-100.20.2023-7.0 10-11X2.2 10-10X0.50.5006-2.2X10-103.1X10-101.01.0003X10-6X10-6X10-6X10-6X10-6X101.5 10-10X3.8 10-10X-6X10-6X10-62.0009X102.00042.02.0005-6X10-62.0001X10-62.0003X10-62.0001X10-61.9995X10-62.0001X102.0001-8.2 10-10X3.2 10-10X-6X10-62.00342.00352.00222.00352.00382.00192.00102.0027X10-7X10-7X10-7X10-7X10-7X10-7X10-7X10-75.00715.00495.00795.00185.00795.00545.00145.0049X10-7X10-7X10-7X10-7X10-7X10-7X10-7X10-71.00051.00091.00101.00081.00021.00011.00091.0007峰电位重复性瑞士万通的PGSTAT128N验证明验氧化峰复原峰标准电位计算值(V)峰电位重复性(%)客户名称客户地址仪器名称生产厂商型号/规格

0.2630.2630.2630.2630.2630.2630.2010.2010.2000.2010.2010.2010.2320.2320.2320.2320.2320.2320.00上海微创医疗器械(集团)浦东区张江高科技园区张东路1601号电化学工作站瑞士万通PGSTAT128N温度主要测量设备

AUT8424221C50%20230307日名称名称/型号编号测量范围/准确度证书编号/有效期数字多用表8840A标准电阻BZ3C4000044U =3X10-5(k=2)rel643132999.78kQU =6X10-5(k=2)rel2023F11-10-11825270012023-07-102023F21-20-13859150012023-03-07电位测量值(V)电位测量值(V)平均值(V)示值误差度(V)(V)(k=2)(V)0.10.10010.10010.10010.10010.10010.10010.1001-0.00010.00010.20.20230.20230.20230.20230.20230.20230.2023-0.00020.00010.50.50030.50030.50030.50030.50030.50030.5003-0.00030.00011.01.00021.00021.00021.00021.00021.00021.0002-0.00020.00012.02.00032.00032.00042.00042.00032.00032.0003-0.00030.0001电位(V)扩展不电位(V)扩展不设测量(A)电化学工作站电流测量值(A)(A) 示值误差(A)疋确定度(k=2)(A)1.001210“72.00241.0019 9.9731X109.9976X101.0021X101.0018X109.9983X101.0005-7X10-112.5X10-10XX10-7-8-8-7-7-8X10-72.0023 2.00411.99012.00252.0038 1.99932.0004X10-2.1 1010104.8 1010-75.0041X10-71.0004X10-1.5X10-102.8X10-10-610-710-710-7102.5X10-910-9-610-610-62.02.0003-2.2X10-94.8X10-9-6-6-6-6-6-值，值值，值0.10.10010.20.20230.50.50031.01.0002X10-7X10-7X10-7X10-7X10-7X10-7X10-75.00184.99885.00485.00535.00325.00195.0026X10-7X10-7X10-7X10-7X10-7X10-7X10-79.99769.99459.99541.00311.00761.00811.0029XXXXXXX10-62.00071.99581.99621.99251.99482.00522.00661.9985X10-6X10X10X10X10X10X106X10-6氧化峰电位(V)0.263氧化峰电位(V)0.2630.2630.2630.2630.2630.263位(V)标准电位计算值(V)峰电位0.1980.1980.1980.1980.1980.1980.2300.2300.2300.000.2300.2300.2306.36.3瑞士万通的PGSTAT128N验证明验客户名称上海医疗器械检测所客户地址1号仪器名称电化学工作站生产厂商瑞士万通型号/规格PGSTAT128N仪器编号温度相对湿度AUT8534420C40%校准日期20230412日主要测量设备名称名称/型号编号测量范围/准确度证书编号/有效期数字多用表8840A标准电阻BZ34507026U =3X10-5(k=2)rel643132999.78kQUrel=6X10-5(k=2)2023F11-20-10616280012023-03-062023F21-20-9189052023-03-07(V)电位测量值((V)电位测量值(V)平均值(V)示值误差度0.10.20.5(V)(k=2)(V)0.10010.10010.10010.10010.10010.10010.1001-0.00010.00010.20230.20230.20230.20230.20230.20230.2023-0.00020.00010.50010.50010.50010.50010.50010.50010.5001-0.00010.00010.10.10010.20.10.10010.20.20230.50.500110-710-710-72.00242.00162.00132.00192.00152.00112.00252.0017X10-7X10-7X10-7X10-7X10-7X10-7X10-7X10-75.00215.00185.00185.00185.00235.00195.00235.00201.00121.00041.00001.00011.00081.00071.00071.0005X10-7XXX10-7X10-7XX10-7X10-71.00.99980.99980.99980.99980.99980.99980.99980.00020.00012.01.99941.99941.99941.99941.99941.99941.99940.00060.0001电位(V)设测量电位(V)设测量疋值值(A)电化学工作站电流测量值(A)(A)示值误差 度(A) (k=2)(A)-7X10-112.0X10-10-7X10-112.0 10-10X10-710-710-710-710-710-7-1X10-113.0X10-101.00.9998-2.2 10-10X2.5 10-10X2.01.9994X10-6X10-6X10-6X10-6X10-9.5 10-10X2.2 10-10X-6X10-6X10-6X10-7位(V)复原峰电位(V)位(V)复原峰电位(V)标准电位计算值(V)峰电位重复性(%)X10-7XXXXXXX10-71.00009.99769.99769.99459.99899.99919.99939.9978X10-6X10-7X10-7X10-7X10-7X10-7X10-7X10-71.99981.99861.99891.99891.99891.99891.99891.99890.2630.2630.2630.2630.2630.2630.2000.2000.1990.1980.1980.1980.2320.2320.2310.430.2300.2300.2306.46.4瑞士万通的PGSTAT204验证明验客户名称上海市计量测试技术争论院客户地址1500号仪器名称电化学工作站生产厂商瑞士万通型号/规格PGSTAT204仪器编号AUT50884温度主要测量设备

33%20231211日名称名称/型号编号测量范围/准确度证书编号/有效期数字多用表8840A标准电阻BZ34507026U =3X10-5(k=2)rel643132999.78kQU =6X10-5(k=2)rel2023F11-20-10616280012023-03-062023F21-20-9189052023-03-07(V)电位测量值((V)电位测量值(V)平均值(V)示值误差度(V)(k=2)(V)0.10.10060.10060.10060.10060.10060.10060.1006-0.00060.00010.20.20230.20230.20230.20230.20230.20230.2023-0.00080.00010.50.50080.50080.50080.50080.50080.50080.5008-0.00080.00011.01.00091.00091.00091.00091.00091.00091.0009-0.00090.00012.02.00082.00092.00082.00082.00082.00092.0008-0.00080.0001电位(V)设电位(V)设测量电化学工作站电流测量值(A)疋(A)(A)示值误差(A)度(k=2)(A)-9X10-113.5X10-10-7X10-112.8X10-10-5.1X10-10 4.0X10-102X10-1010-91.5X10-910-9值值值值0.10.1006020.2023050.50077101.0009202.00081.00621.00111.00181.00691.00891.00911.00371.0053X10“7X10-7X10-7X10-7X10-7X10-7X10-7X10-72.00842.00672.00312.00892.00912.00892.00962.0077X10“7X10-7X10-7X10-7X10-7X10-7X10-7X10-75.00885.00125.00935.00925.00115.00075.00095.0037X10“7X10-7X10-7X10-7X10-7X10-7X10-7X10-71.00111.00161.00491.00081.00051.00011.00001.0013X10“6X10-6X10-6X10-6X10-6X10-6X10-6X10-62.00132.00872.00592.00122.00072.00022.00012.0028X10“6X10-6X10-6X10-6X10-6X10-6X10-6X10-6氧化峰0.2630.263氧化峰0.2630.2630.2630.2630.2630.263氧化峰

0.263

0.263

0.263

0.263

0.263

0.2630.1980.2000.1980.1990.1980.1990.2300.2320.2300.350.2310.2300.231电位(V)复原峰电位(V)标准电位计算值电位(V)复原峰电位(V)标准电位计算值(V)峰电位客户名称客户地址仪器名称生产厂商型号/规格仪器编号温度主要测量设备

上海外形记忆合金材料/电化学工作站瑞士万通PGSTAT204AUT5073022C35%20231224日名称名称/型号编号测量范围/准确度证书编号/有效期数字多用表289C标准电阻BZ334420235U =0.01%(k=2)rel643132999.78kQUrel=6X10-5(k=2)2023F11-10-1590460002023-09-202023F21-20-13859150012023-03-07(V)(V)电位测量值(V)平均值(V)示值误差度(V)(k=2)(V)0.10.10000.10000.10000.10000.10000.10000.10000.00000.00010.20.20230.20230.20230.20230.20230.20230.2023-0.00010.00010.50.50010.50010.50010.50010.50010.50010.5001-0.00010.00011.01.00021.00021.00021.00021.00021.00021.0002-0.00020.00012.02.01.99971.99971.99971.99971.99971.99971.99970.00030.0002电位(电位(V)设值(A)电化学工作站电流测量值(A)疋(A)(A)(k=2)(A)值0.10.10002X10-112.1X10-100.20.20230.50.50011.01.0002X10-70.50021X10-71.0004X10X10-7X10-7X10-7X10-7X10-7X10-7X10-7-1.1X10-105.1X10-10-64.9905X10-79.9988X10-74.9986X10-79.9915X10-74.9908X10-79.9992X10-75.0021X10-71.0092X10-65.0009X10-71.0008X10-65.0032X10-71.0003X104.9977X10-71.0015-4.4X10-105.0X10-10-6 X10-61.1X10-93.1X10-92.0001X101.99952.0007 1.99981.99962.0003 1.99931.99992.01.9997-6X10-6X10-6X10-6X10-6X10-6X10-6X10-6-2X10-105.9X10-101.00021.00149.99309.99791.00161.00039.99831.0004X10-7X10-7X10-8X10-8X10-7X10-7X10-8X10-72.00142.00902.00201.99932.00121.99891.99112.0003峰电位重复性位(V)复原峰电位(V)标准电位计算值位(V)复原峰电位(V)标准电位计算值(V)峰电位重复性(%)客户名称杭州启明医疗器械客户地址/仪器名称电化学工作站生产厂商瑞士万通型号/规格PGSTAT302N仪器编号温度相对湿度AUT8745923C59%校准日期20230115日0.2640.2630.2630.2630.2630.2630.1980.1980.1980.1980.1980.1980.2310.2300.2300.2300.2300.2300.18主要测量设备名称名称/型号编号测量范围/准确度证书编号/有效期数字多用表8840A4507026U =3X10-5(k=2)rel标准电阻643132BZ3999.78kQUrel=6X10-5(k=2)2023F11-20-10616280012023-03-062023F21-20-9189052023-03-07(V)电位测量值((V)电位测量值(V)平均值示值(V)误差(V)度(k=2)(V)0.10.10000.10000.10000.10000.10000.10000.10000.00000.00010.20.20230.20230.20230.20230.20230.20230.2023-0.00020.00010.50.50040.50040.50040.50040.50040.50040.5004-0.00040.00011.01.00031.00031.00031.00031.00031.00031.0003-0.00030.00012.02.00032.00042.00032.00032.00042.00032.0003-0.00030.0001电位(V)电位(V)设疋测量(A)电化学工作站电流测量值(A)(A)示值误差(A)度(k=2)(A)值值0.1 0.10001.0002X10-71.0013X10-71.0089X10-71.0004X10-71.0005 1.0010X10-7 X10-71.0009X10-71.0022X10-72.0X10-103.4X10-103.7X10-103.2X10-10-7-7-7-7-7-7-70.5 0.50045.0051X10-75.0049X105.0079X105.0018X101.01.0003-71.0004X10-7-75.0049X10-75.0032X10-75.0031X105.0043-7X10-7-8X10-112.6X10-101.0005X10-61.0007X10-61.0004X10-61.0005X10-61.0007X10-61.0008X101.00061X10-102.4X10-10-6-6X10-62.02.00032.8X10-102.00242.01172.00322.00592.00542.00362.00672.00610.20.2023X10X10X10X10X10X10X10X10-72.00072.00102.00072.00042.00062.00052.00092.0007X10-6X10-6X10-6X10-6X10-6X10-6X10-6X10-60氧化峰电位(V)氧化峰电位(V)复原峰电位(V)0.2610.2640.2640.2640.2610.2640.1950.1950.1980.1950.1950.1980.2280.2300.2310.2300.2280.231计算值计算值(V)峰电位重复性(%)0.59瑞士万通的PGSTAT302N验证明验型号/规格仪器编号温度相对湿度校准日期主要测量设备

南京微创医学科技/电化学工作站瑞士万通PGSTAT302NAUT8615521C62%20230104日名称名称/型号编号测量范围/准确度证书编号/有效期数字多用表289C标准电阻BZ334420235U =0.01%rel(k=2)643132999.78kQUrel=6X10-5(k=2)2023F11-10-1590460002023-09-202023F21-20-13859150012023-03-07电位测量值电位测量值(V)(V)平均值(V)示值误差度2.0(V)(k=2)(V)0.10.10000.10000.10000.10000.10000.10000.10000.00000.00010.20.20230.20230.20230.20230.20230.20230.2023-0.00010.00010.50.50010.50020.50010.50010.50010.50010.5001-0.00010.00011.01.00001.00011.00011.00011.00011.00011.0001-0.00010.00012.00012.00012.00002.00002.00002.00002.00000.00000.0002电流示值误差2.00142.00172.00182.00081.99921.99861.99782.0000X10-7X10-7X10-7X10-7X10-7X10-7X10-7X10-75.0021X10-75.0018X10-75.0049X10-74.9988X10-74.9979X10-74.9986X10-75.0005X10-75.0004X10-71.00031.00079.99451.00041.00011.00031.00011.0002电位(V)电位(V)设测量疋值值(A)电化学工作站电流测量值(A)(A)示值误差(A)(k=2)(A)0.10.10001.0002X101.0031 1.0016X10 X109.9982 9.9913-81.0003X101.0001X101.00075X10-102.3X10-10-7-7-7X10X10-8-7-7X10-70.20.2023-1.4X10-102.4X10-100.5 0.5001-1.7X10-102.9X10-101.0 1.0001X10-6X10-6X10-7X10-6X10-6X10-6X10-6X10-6-1X10-104.0X10-102.02.00002.0004X10-62.0001 2.0007X10-6 X10-62.0008X10-62.0001X10-62.0006X10-62.0000 2.0004X10-6 X10-704.9 10-10X氧化峰电位(V)复原峰电位(V)标准电位计算值(V)峰电位重复性(%)0.2660.2640.2660.2640.2640.2660.1950.1950.1950.1950.1950.1950.2300.2300.2300.2300.2300.2300.006.8Solartron6.8Solartron的SI1287验证明验客户名称苏州热工争论院客户地址1788号仪器名称电化学工作站生产厂商Solartron型号/规格SI1287仪器编号温度相对湿度0031977325C67%校准日期20230702日主要测量设备名称名称/型号编号测量范围/准确度证书编号/有效期数字多用表8840A标准电阻BZ3C4000044643132Urel=3X10-5(k=2)999.78kQU =6X10-5(k=2)rel2023F11-10-11825270012023-07-102023F21-20-13859150012023-03-07(V)(V)示值电位测量值(V)平均值(V)误差度0.10.10010.10020.10010.10020.10010.10010.1001(V)-0.0001(k=2)(V)0.00010.20.20230.20230.20230.20230.20230.20230.2023-0.00020.00010.50.49980.49990.49990.49990.49990.49990.49990.00010.00011.00.99950.99950.99950.99950.99950.99950.99950.00050.00012.01.99931.99931.99931.99931.99931.99931.99930.00070.0001电位(V)电位(V)设电化学工作站电流测量值(A)示值误差(A)疋度(k=2)(A)-6X10-112.0X10-10-3X10-112.1X10-103X10-112.0X10-104.8X10-103.3X10-10-5X10-104.5X10-10值0值010.1001020.2023050.4999100.9995201.9993(A)1.00121.00111.00091.00011.00061.00071.0001(A)1.0006X10-7X10-7X10-7X10-7X10-7X10-7X10-7X10-72.00242.00222.00192.00152.00322.00212.00192.0021X10“7X10-7X10-7X10-7X10-7X10-7X10-7X10-75.00015.00005.00095.00085.00015.00025.00025.0004X10-7X10-7X10-7X10-7X10-7X10-7X10-7X10-79.99729.99911.00021.00081.00021.00001.00011.0002X10“7X10-7X10-6X10-6X10-6X10-6X10-6X10-61.99971.99961.99961.99981.99901.99871.99871.9992X10-6X10-6X10-6X10-6X10-6X10-6X10-6X10-6氧化峰电位(V)氧化峰电位(V)复原峰电位(V)标准电位计算值(V)0.2610.2640.2640.2640.2640.2640.1950.1950.1950.1980.1950.1980.2280.2300.2300.2310.2300.231峰电位重复性(％)AMETEK的VersaSTAT3验证明验

0.48客户名称客户地址仪器名称生产厂商型号/规格仪器编号温度主要测量设备

微创心脉医疗科技(上海)/电化学工作站AMETEKVersaSTAT31334573921C50%20230307日名称名称/型号编号测量范围/准确度证书编号/有效期数字多用表8840A标准电阻BZ3C4000044U =3X10-5(k=2)rel643132999.78kQUrel=6X10-5(k=2)2023F11-10-11825270012023-07-102023F21-20-13859150012023-03-07(V)(V)电位测量值(V)平均值(V)示值误差度(V)(k=2)(V)0.10.09990.09990.09990.09990.09990.09990.09990.00010.00010.20.19990.19970.19990.19990.19990.19990.19990.00010.00010.50.49990.49990.49990.49990.49990.49990.49990.00010.00011.00.99970.99970.99970.99970.99970.99970.99970.00030.00012.01.99971.99971.99971.99971.99971.99971.99970.00030.0001电位(电位(V)设电化学工作站电流测量值(A)疋测量(A)(A)示值误差(A)定度(k=2)(A)值值2.0X10-103.0X10-103.7X10-104.3X10-104X10-113.0X10-106X10-106.4X10-1002.8X10-100010.09990201999050.4999100.9997201.99979.99221.00451.00399.98501.00209.99139.98901.0012X10-8X10-7X10-7X10-8X10-7X10-8X10-8X10-71.99941.99912.00832.00892.00411.99911.99902.0031X10-7X10-7X10-7X10-7X10-7X10-7X10-7X10-75.00015.00305.00484.99954.99914.99874.99795.0005X10-7X10-7X10-7X10-7X10-7X10-7X10-7X10-79.99921.00119.99171.00101.00081.00011.00091.0005X10-7X10-6X10-7X10-6X10-6X10-6X10-6X10-62.00012.00041.99992.00032.00012.00021.99982.0001X10-6X10-6X10-6X10-6X10-6X10-6X10-6X10-6氧化峰电位氧化峰电位(V)0.2640.2640.2640.2640.2640.264复原峰电位(V)标准电位计算值(V)峰电位0.1980.1950.1980.1980.1950.1980.2310.2300.2310.220.2310.2300.2316.106.10AMETEKPARSTST4000验证明验客户名称国核电站运行效劳技术客户地址1600号仪器名称电化学工作站生产厂商AMETEK型号/规格PARSTAT4000仪器编号温度相对湿度1332358922C60%校准日期20230607日主要测量设备名称名称/型号编号测量范围/准确度证书编号/有效期数字多用表289C标准电阻BZ334420235U =0.01%(k=2)rel643132999.78kQU =6X10-5(k=2)rel2023F11-10-12361580012023-09-072023F21-20-13859150012023-03-07(V)(V)示值电位测量值(V)平均值(V)误差度0.10.09980.09980.09980.09980.09980.09980.0998(V)0.0002(k=2)(V)0.00010.20.20230.20230.20230.20230.20230.20230.20230.00000.00010.50.50000.50000.50000.50000.50000.50000.50000.00000.00011.01.00001.00001.00001.00001.00001.00001.00000.00000.00012.02.00022.00022.00022.00022.00022.00022.0002-0.00020.0002电位(V)电位(V)扩展不设疋值值(A)电化学工作站电流测量值(A)(A)(A)确定度(k=2)(A)9X10-112.1X10-10“-10-75.001110-71.0002X1010-75.0015-1X10-113.0X10-10XX10-710-75.0010X10-710-75.0006X10-710-75.0009X10-710-75.0011X10-710-75.0015X105.001102.0X10-10-7X10-71.0006-6 X10-61.0003X10-61.0008X10-61.0001X10-61.0000X10-69.9987X101.00031X10-103.6X10-10-7X10-62.02.00022.0006X10-62.0011X10-62.0030X10-62.0005X10-62.0011X10-61.9991X10-61.9997X102.00082X10-1010-9-6X10-60.10.09980.10.09980.20.20230.50.50001.01.00009.98229.99809.99901.00019.98019.98009.99009.9914X108X108X10-8X10-7X10-8X10-8X10-8X10-82.00042.00512.00022.00061.99801.99762.00012.0003XXXXXXXX10-7氧化峰电位(V)氧化峰电位(V)复原峰电位(V)标准电位计算值(V)0.2640.2640.2640.2640.2640.2640.1950.1950.1950.1950.1950.1950.2300.2300.2300.2300.2300.230峰电位峰电位0.00GAMRYReferenee600f验证明验客户名称客户地址仪器名称生产厂商/规格仪器编号温度主要测量设备

国家眼镜产品质量监视检验中心江苏省丹阳市开发区迎春路301号电化学工作站GAMRYReferenee600f01-10627C50%20230614日名称名称/型号编号测量范围/准确度证书编号/有效期数字多用表8840A标准电阻BZ3C4000044U =3X10-5(k=2)rel643132999.78kQUrel=6X10-5(k=2)2023F11-10-11825270012023-07-102023F21-20-13859150062023-03-06(V)(V)电位测量值(V)平均值示值误差(V)度0.10.20.51.02.0(V)(k=2)(V)0.09990.09990.09990.09990.09990.09990.09990.00010.00010.20230.20230.20230.20230.20230.20230.2023-0.00010.00010.50000.50000.50000.50000.50000.50000.50000.00000.00011.00011.00011.00011.00011.00011.00011.0001-0.00010.00012.00032.00032.00032.00032.00032.00032.0003-0.00030.0001电位电位(V)电流电化学工作站电流测量值(A)平均示值扩展不6.11.2电流示值误差电位(V)电流 电化学工作站电流测量值 (A) 平均示值扩展不0.0999X10-8X10-8X10-8X10-8X10-8X10-8X10-8X10-82.00142.00082.00082.00082.00092.00072.00062.00080.2023X10-7X10-7X10-7X10-7X10-7X10-7X10-7X10-7设疋值值设疋值值(A)值(A)误差(A)确定度(k=2)(A)9.99929.99819.9979 9.99779.99739.9986 9.99879.99810.1-1X10-112.0X10-100.2-6X10-112.0X10-100.5 0.50005.0011X105.00115.00115.00135.00145.00115.00135.0012-7X10-7X10-7X10-7X10-7X10-7X10-7X10-71 10-11X2.0 10-10X1.0003X101.00131.0013 1.00131.00131.0013 1.00131.00131.0 1.0001-6X10-6X10-6X10-6X10-6X10-6X10-6X10-61X10-92.0X10-102.02.0007X102.00102.0010 2.00102.00062.0008 2.00112.00092.0003-6X10-6X10-6X10-6X10-6X10-6X10-6X10-62X10-102.5X10-10位(V)复原峰电位(V)标准电位计算值(V)峰电位重复性(%)0.2620.2620.2620.2620.2620.2620.2010.2010.2010.2010.2010.2010.2320.2320.2320.000.2320.2320.232上海辰华的CHI630E验证明验

1500号仪器名称仪器名称电化学工作站生产厂商上海辰华型号/规格CHI630E仪器编号温度相对湿度41280121r50%校准日期20230508日主要测量设备名称/型号编号测量范围/准确度证书编号/有效期数字多用表数字多用表8840A标准电阻BZ3C4000044U =3X10-5(k=2)rei643132999.78kQUrel=6X10-5(k=2)2023F11-10-11825270012023-07-102023F21-20-13859150062023-03-06平均值平均值电位测量值(V)示值误差度(V)(V)(V)(k=2)(V)0.10.09910.09910.09910.09910.09910.09910.09910.00090.00010.20.19920.19920.19920.19920.19920.19920.19920.00080.00010.50.49900.49900.49900.49900.49900.49900.49900.00100.00011.00.99910.99910.99910.99910.99910.99910.99910.00090.00012.01.99901.99901.99901.99901.99901.99901.99900.00100.0001电位(V)电位(V)设电化学工作站电流测量值(A)疋(A)示值误差(A)度(k=2)(A)值9.91220.10.0991X108“1.9924X10“74.9911X10“79.9932X10“71.9994X10“69.9878X10-81.99105.1X10-103.5X10-10X10-74.9871X10-710-102.0X10-107X10-7X10-7X10-7X10-7X10-7X10-710-102.6X10-101.0000X10-62.0002X10-61.0000X10-62.0002X10-61.0000X10-62.0002X10-61.0000X10-62.0002X10-61.0000X10-62.0002X10-61.0000X10-62.0002X10-61.0000X10-62.0002X10-66.8X10-102.0X10-1010-1010-100.20.19920.20.19920.50.49901.00.99912.01.9990(A)9.98799.98819.98119.92319.91309.9635X10-8X10-8X10-8X10-8X10-8X10-81.99101.99101.99001.99001.99001.9905X10-X10-7X10-7X10-7X10-7X10-74.98884.99294.98964.99094.99104.9901位位(V)复原峰电位(V)标准电位计算值(V)峰电位重复性(%)0.2630.2630.2630.2630.2630.2630.2010.2010.2010.2010.2010.2010.2320.2320.2320.2320.2320.2320.006.136.13上海辰华的CHI650E验证明验客户名称上海市计量测试技术争论院客户地址1500号仪器名称电化学工作站生产厂商上海辰华型号/规格CHI650E仪器编号温度B1631221C相对湿度50%校准日期20230508日主要测量设备名称名称/型号编号测量范围/准确度证书编号/有效期数字多用表8840A标准电阻BZ3C4000044U =3X10rel-5(k=2)643132999.78kQUrel=6X10-5(k=2)2023F11-10-11825270012023-07-102023F21-20-13859150062023-03-06(V)(V)电位测量值(V)平均值(V)示值误差度(V)(k=2)(V)0.10.10010.10010.10010.10010.10010.10010.1001-0.00010.00010.20.20230.20230.20230.20230.20230.20230.2023-0.00030.00010.50.50030.50030.50030.50030.50030.50030.5003-0.00030.00011.01.00061.00061.00061.00061.00061.00061.0006-0.00060.00012.02.00092.00092.00092.00092.00092.00092.0009-0.00090.0001电位(V)电位(V)设疋测量(A)电化学工作站电流测量值(A)示值(A)误差(A)度(k=2)(A)值值1.0012X101.0012X10-71.0003X101.0003X101.0003X101.0003X101.0003X101.0003X101.0003-9.0X10-112.0X10-10-7-7-7-7-7-7X10-7-3.0X10-102.0X10-10X10-7X10-7X10-7X10-7X10-7X10-7X10-7X10-710-102.■0010-5X10-102.0X10-10-1X10-92.0X10-10C4000044Urel=3 10-5k=27001标准电阻643132999.78kQ20232110.10010.20.10.10010.20.20230.50.50032.00342.00042.00042.00042.00042.00042.00042.0004X10-7X10-7X10-7X10-7X10-7X10-7X10-7X10-75.00415.00045.00045.00045.00045.00045.00045.00041.01.00061.0008X10-61.0003X10-6P1.0003X10-61.0003X10-61.0003X10-61.0003X10-6P1.0003X10-61.0003X10-62.00132.00032.00032.00032.00032.00032.00032.00032.02.0009X10-6X10-6X10-6X10-6X10-6X10-6X10-6X10-66.13.3峰电位重复性0.2620.2610.2630.2630.2630.2630.2000.2000.1990.1980.1980.1980.2310.2300.2310.220.2300.2300.230位(V)复原峰电位位(V)复原峰电位(V)标准电位计算值(V)峰电位重复性(%)客户名称仪器名称生产厂商国核电站运行效劳技术1600号电化学工作站上海辰华型号/规格CHI660E仪器编号A14034温度22C相对湿度60%校准日期20230607日主要测量设备名称/型号编号 测量范围/准确度证书编号/有效期数字多用表8840AX ( )202311-10-1182522023-07-10BZ3BZ3Urel=6X1Q-5(k=2)2023-03-07(V)(V)电位测量值(V)平均值示值误差(V)度0.10.10020.10020.10020.10020.10020.10020.1002(V)-0.0002(k=2)(V)0.00010.20.19990.19990.19990.19990.19990.19990.19990.00010.00010.50.50010.50010.50010.50010.50010.50010.5001-0.00010.00011.00.99910.99910.99900.99910.99900.99910.99910.00090.00012.01.99961.99961.99961.99961.99961.99961.99960.00040.0001电位(V)电位(V)扩展不设疋值值(A)电化学工作站电流测量值(A)(A)(A)确定度(k=2)(A)1.00221.00151.00231.0029 1.00131.00151.0023 1.002001 0.1002X10-7X10-7X10-7X10-7X10-7X10-7X10-7X10-7-2X10-112.1X10-10020.199905 0.50011.999410-75.002110-79.99322.00162.00182.0