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目概目概 物料衡算原 物料衡算目的和任 工艺流程 乙炔法合成阶 4-1工艺流程 乙烯法合成阶 VAc及乙醛提纯阶 物料衡算 5.1.1反应器 5.1.2反应器 5.1.3闪蒸罐 5.1.4精馏塔 5.1.5精馏塔 5.1.6萃取塔 乙烯合成 5.2.1反应器 5.2.2反应器 5.2.3闪蒸罐 5.2.4闪蒸罐 5.2.5精馏塔 5.2.6精馏塔 5.2.7换热器 5.2.8精馏塔 5.2.9精馏塔 5.2.10闪蒸罐 5.2.11泵 5.2.12精馏塔 VAc及乙醛提纯工 5.3.1精馏塔 5.3.2闪蒸罐 5.3.3精馏塔 5.3.4精馏塔 物料衡算计算1.2.物料衡物料衡算计算1.2.物料衡算原”累积量2-1物料衡算适用范总质量衡算适适类 物料衡算形 无化学反 有化学反组分质量衡算适不适组分衡算元素原子衡算适适组分质量衡算适不适组分衡算元素原子衡算适适元素原子衡算3.物料衡算目的和任元素原子物质的量衡算 适 适组分物质的量衡算 适 不适总物质的量衡算 适 不适4.工艺流程4.14.工艺流程4.14-工艺流程4.2乙烯法合成4-24.3VAc及4.3VAc及乙醛提4-3工艺流55-物料衡算11MassMasscal/gm-EnthalpyMole00000000000000000ETHYL-000000000 55-物料衡算11MassMasscal/gm-EnthalpyMole00000000000000000ETHYL-000000000 Mass Average Mass Molar cal/mol- Molar ETHYL-000000000000005-物料衡算13MassMasscal/gm-EnthalpyMole000000000 1.67E- ETHYL-000000000000005-物料衡算13MassMasscal/gm-EnthalpyMole000000000 1.67E- 1.67E- 1.27E- Mass Average Mass Molar cal/mol- Molar ACETI- EPSIL- METHY- 8.49E-08.49E-7.62E-1.78E-000ETHYL-00000000ETHYL-000000001.59E-04.01E-4.01E-002.58E-02.58E-2.60E-5-物料衡算11111111MassMasscal/gm-EnthalpyMole8.49E-08.49E-7.62E-1.78E-000ETHYL-00000000ETHYL-000000001.59E-04.01E-4.01E-002.58E-02.58E-2.60E-5-物料衡算11111111MassMasscal/gm-EnthalpyMoleAverage Mass Molar cal/mol- Molar ACETI- 1.05E- 1.05E- EPSIL- METHY- 1.17E- 1.72E- 1.72E- 0000000000000000000000ETHYL-00000000ETHYL-00000000000000000000000000005-4物料衡6MassMolar cal/mol- 0000000000000000000000ETHYL-00000000ETHYL-00000000000000000000000000005-4物料衡6MassMolar cal/mol- Molar ACETI- EPSIL- METHY- Mass Masscal/gm-EnthalpyMole000ETHYL-0ETHYL-3.57E-7.31E-7.31E-007.31E-000000000000000000005-5物料衡ACETI- Masscal/gm-EnthalpyMole000ETHYL-0ETHYL-3.57E-7.31E-7.31E-007.31E-000000000000000000005-5物料衡ACETI- EPSIL- METHY- Mass Average Mass 7.74E- 21111126MassMasscal/gm-EnthalpyMole04.32E-2.84E-2.84E-2.77E-2.77E-3.57E-3.57E-ETHYL-ETHYL-04.98E-00000000000021111126MassMasscal/gm-EnthalpyMole04.32E-2.84E-2.84E-2.77E-2.77E-3.57E-3.57E-ETHYL-ETHYL-04.98E-000000000000 EPSIL- METHY- 1.80E- 1.80E- 4.91E- 4.91E- Mass Average Mass Molar cal/mol- Molar 000000005-物料衡算21111MassMasscal/gm-EnthalpyMole01.28E-2.72E-2.72E-2.72E-09.55E-9.55E-9.55E-00007.14E-7.14E-7.14E-05.26E-5.98E-2.13E-2.13E-2.13E-0000ETHYL-000000005-物料衡算21111MassMasscal/gm-EnthalpyMole01.28E-2.72E-2.72E-2.72E-09.55E-9.55E-9.55E-00007.14E-7.14E-7.14E-05.26E-5.98E-2.13E-2.13E-2.13E-0000ETHYL-5.51E-5.51E-5.51E-01.00E-8.98E- 2.06E- 2.06E- 2.06E- 6.32E- 3.54E- 3.54E- 3.54E- 6.73E- 6.73E- 6.73E- Mass Average Mass Molar cal/mol- Molar ACETI- ETHYL-0000009.40E-9.40E-2.96E-2.96E-2.96E-00008.87E-8.87E-8.87E-0000物料衡算5-1112MassMasscal/gm-EnthalpyMole06.50E-1.54E-0000ETHYL-0000009.40E-9.40E-2.96E-2.96E-2.96E-00008.87E-8.87E-8.87E-0000物料衡算5-1112MassMasscal/gm-EnthalpyMole06.50E-1.54E-000002.21E-2.25E- 2.01E- 9.75E- Mass Average Mass Molar cal/mol- Molar ACETI- EPSIL- METHY- 4.19E- 4.19E- 4.19E- 5.28E-5.98E-5.26E-5.26E-0002.02E-ETHYL-8.98E-1.00E-1.00E-ETHYL-0000000005.04E-04.24E-5.02E-2.30E-1.85E-00005-物料衡算3332111MassMasscal/gm-EnthalpyMole5.98E-5.26E-5.26E-0002.02E-ETHYL-8.98E-1.00E-1.00E-ETHYL-0000000005.04E-04.24E-5.02E-2.30E-1.85E-00005-物料衡算3332111MassMasscal/gm-EnthalpyMole1Average Mass Molar cal/mol- Molar ACETI- 1.40E- 1.05E- EPSIL- METHY- 1.13E- 1.02E- 00000000002.21E-1.86E-7.49E-ETHYL-4.66E-4.00E-4.66E-4.00E-2.23E-4.00E-ETHYL-00000000002.30E-2.30E-2.07E-2.07E-5.04E-2.07E-1.09E-2.07E-2.07E-5.85E-5.63E-00000000002.21E-1.86E-7.49E-ETHYL-4.66E-4.00E-4.66E-4.00E-2.23E-4.00E-ETHYL-00000000002.30E-2.30E-2.07E-2.07E-5.04E-2.07E-1.09E-2.07E-2.07E-5.85E-5.63E-ACETI- EPSIL- METHY- 1.21E- 7.32E- 1.13E- 6.26E- 2.45E- 3.40E- 2.01E- 1.07E- 1.12E-Mass 5.1.1换热5-9换热器E0101物料衡CMolarVapor01MassMasscal/gm-MassAverageMass000000000METHY-000EPSIL-000000ACETI-000Volume5.1.2反应5-10反应R0101物5.1.1换热5-9换热器E0101物料衡CMolarVapor01MassMasscal/gm-MassAverageMass000000000METHY-000EPSIL-000000ACETI-000Volume5.1.2反应5-10反应R0101物料衡C Mass ETHYL- ETHYL- Mole Enthalpy Molar 4.17E- 3.85E-Molar cal/mol- Molar MolarVapor11MassMasscal/gm-MassAverageMass000000METHY-00EPSIL-0000ACETI-00Volume5.1.3反应5-11反应R0102物料衡CMolarMolarcal/mol-MassMolarVapor11MassMasscal/gm-MassAverageMass000000METHY-00EPSIL-0000ACETI-00Volume5.1.3反应5-11反应R0102物料衡CMolarMolarcal/mol-MassMass cal/gm- Mass Mass ETHYL- ETHYL- Mole Enthalpy Molar 3.85E- 2.65E-Molar cal/mol- Molar AverageMass00000METHY-00EPSIL-0000ACETI-05.1.4换热5-12换热器E0102物料衡CMolarMolarcal/mol-MassAverageMass00 AverageMass00000METHY-00EPSIL-0000ACETI-05.1.4换热5-12换热器E0102物料衡CMolarMolarcal/mol-MassAverageMass00 Mole Enthalpy Mass cal/gm- Mass ETHYL- ETHYL- Mole Enthalpy 00METHY-00EPSIL-0000ACETI-5.1.5闪蒸5-13闪蒸罐F0101物料CMolarMolarcal/mol-MassAverageMass000000METHY-000EPSIL-000000ACETI- 00METHY-00EPSIL-0000ACETI-5.1.5闪蒸5-13闪蒸罐F0101物料CMolarMolarcal/mol-MassAverageMass000000METHY-000EPSIL-000000ACETI- ETHYL- ETHYL- Mole Enthalpy Mass cal/gm- Mass ETHYL- ETHYL- 5.1.65-14P0101物料衡CMolarMolarcal/mol-MassAverageMass0000METHY-00EPSIL-0000ACETI-5.1.7精馏5-15精馏T0201物料CMolarMolarcal/mol-5.1.65-14P0101物料衡CMolarMolarcal/mol-MassAverageMass0000METHY-00EPSIL-0000ACETI-5.1.7精馏5-15精馏T0201物料CMolarMolarcal/mol-Mass ETHYL- ETHYL- Mole Enthalpy Mass cal/gm- Mass MassAverageMass0001.67E-1.17E-000METHY-000EPSIL-000000ACETI-5.1.8精馏5-16精馏T0202物料CMolarMolarcal/mol-MassAverageMass0000 MassAverageMass0001.67E-1.17E-000METHY-000EPSIL-000000ACETI-5.1.8精馏5-16精馏T0202物料CMolarMolarcal/mol-MassAverageMass0000 Mole Enthalpy Mass cal/gm- Mass 2.58E- 1.59E-ETHYL- ETHYL- 1.78E- 8.49E- Mole Enthalpy Mass cal/gm- 01.72E-0000METHY-0000EPSIL-00000000ACETI-01.05E-5.1.9萃取5-17萃取T0203物料CMolarMolarcal/mol-MassAverageMass0001.67E-1.67E-1.27E-1.17E-00000METHY-000EPSIL-000000 1.59E-01.72E-0000METHY-0000EPSIL-00000000ACETI-01.05E-5.1.9萃取5-17萃取T0203物料CMolarMolarcal/mol-MassAverageMass0001.67E-1.67E-1.27E-1.17E-00000METHY-000EPSIL-000000 1.59E- ETHYL- ETHYL- 1.78E- 8.49E- 8.49E- 7.62E- Mole Enthalpy Mass cal/gm- Mass 4.01E- ETHYL- ETHYL- ACETI-5.2乙烯合成5.2.1混合5-18混合器M0301物料衡CMolarMolarcal/mol-MassAverageMass00000000METHY-000EPSIL-000000ACETI-0005.2.2换热5-19换热器ACETI-5.2乙烯合成5.2.1混合5-18混合器M0301物料衡CMolarMolarcal/mol-MassAverageMass00000000METHY-000EPSIL-000000ACETI-0005.2.2换热5-19换热器E0301物料衡C ETHYL- ETHYL- Mole Enthalpy Mass cal/gm- Mass 2.58E- 2.58E- 2.60E-MolarMolarcal/mol-MassAverageMass0000METHY-00EPSIL-00000000ACETI-00005.2.3换热5-20换热器E0302物料衡CMolarMolarcal/mol-MassAverageMassMolarMolarcal/mol-MassAverageMass0000METHY-00EPSIL-00000000ACETI-00005.2.3换热5-20换热器E0302物料衡CMolarMolarcal/mol-MassAverageMassMole Enthalpy Mass cal/gm- Mass ETHYL- ETHYL- Mole Enthalpy Mass cal/gm- Mass 0000METHY-00EPSIL-0000ACETI-005.2.4混合5-21混合器M0302物料衡CMolarMolarcal/mol-MassAverageMass00000000METHY-000ETHYL- 0000METHY-00EPSIL-0000ACETI-005.2.4混合5-21混合器M0302物料衡CMolarMolarcal/mol-MassAverageMass00000000METHY-000ETHYL- Mole Enthalpy Mass cal/gm- Mass ETHYL- ETHYL- EPSIL-000000ACETI-0005.2.5反应5-反应R0301物料衡CMolarMolarcal/mol-MassAverageMass0000METHY-00EPSIL-0000ACETI-005.2.6反应5-反应R0302物料衡EPSIL-000000ACETI-0005.2.5反应5-反应R0301物料衡CMolarMolarcal/mol-MassAverageMass0000METHY-00EPSIL-0000ACETI-005.2.6反应5-反应R0302物料衡 ETHYL- ETHYL- Mole Enthalpy Mass cal/gm- Mass ETHYL- CMolarMolarcal/mol-MassAverageMass00METHY-0EPSIL-0000ACETI-005.2.7换热5-24换热器E0303物料衡CMolarMolarcal/mol-MassAverageEnthalpyCMolarMolarcal/mol-MassAverageMass00METHY-0EPSIL-0000ACETI-005.2.7换热5-24换热器E0303物料衡CMolarMolarcal/mol-MassAverageEnthalpy Mass cal/gm- Mass ETHYL- ETHYL- Mole Enthalpy Mass cal/gm- Mass MassMETHY-EPSIL-0000ACETI-005.2.8闪蒸5-25闪蒸罐F0401物料CMolarMolarcal/mol-MassAverageMass MassMETHY-EPSIL-0000ACETI-005.2.8闪蒸5-25闪蒸罐F0401物料CMolarMolarcal/mol-MassAverageMass Mole Enthalpy Mass cal/gm- Mass ETHYL- ETHYL- Mole METHY-EPSIL-000000ACETI-0005.2.9闪蒸5-26闪蒸罐F0402物料CMolarMolarcal/mol-Mass7.74E-AverageMassMETHY-EPSIL-000000ACETI-000 METHY-EPSIL-000000ACETI-0005.2.9闪蒸5-26闪蒸罐F0402物料CMolarMolarcal/mol-Mass7.74E-AverageMassMETHY-EPSIL-000000ACETI-000 ETHYL- 7.31E- ETHYL- Mole Enthalpy Mass cal/gm- Mass ETHYL- 3.57E- ETHYL- 5.2.10压缩5-27压缩机C0401物料衡CMolarMolarcal/mol-Mass7.74E-AverageMassMETHY-EPSIL-0000ACETI-005-精馏T0401物料衡CMolar5.2.10压缩5-27压缩机C0401物料衡CMolarMolarcal/mol-Mass7.74E-AverageMassMETHY-EPSIL-0000ACETI-005-精馏T0401物料衡CMolarMolarcal/mol-Mass ETHYL- 7.31E- 7.31E-ETHYL- Mole Enthalpy Mass cal/gm- Mass MassAverageMass0000METHY-0EPSIL-00000000ACETI-00005.2.125-29P0401物料衡CMolarMolarcal/mol-MassAverageMass MassAverageMass0000METHY-0EPSIL-00000000ACETI-00005.2.125-29P0401物料衡CMolarMolarcal/mol-MassAverageMass Mole Enthalpy Mass cal/gm- Mass ETHYL- 7.31E- 7.31E-ETHYL- Mole Enthalpy Mass cal/gm- METHY-EPSIL-0000ACETI-005.2.13精馏5-30精馏塔T0402物料CMolarMolarcal/mol-MassAverageMass4.91E-1.80E-METHY-EPSIL-0000000000 METHY-EPSIL-0000ACETI-005.2.13精馏5-30精馏塔T0402物料CMolarMolarcal/mol-MassAverageMass4.91E-1.80E-METHY-EPSIL-0000000000 ETHYL- 7.31E- 4.98E- ETHYL- 3.57E- 2.77E- 4.32E- Mole Enthalpy Mass cal/gm- Mass ETHYL- ETHYL- ACETI-000005.2.14闪蒸5-31闪蒸罐F0403物料衡CMolarMolarcal/mol-MassAverageMassMETHY-EPSIL-000000ACETI-0005.2.15精馏5-精馏T0403物料衡CMolarACETI-000005.2.14闪蒸5-31闪蒸罐F0403物料衡CMolarMolarcal/mol-MassAverageMassMETHY-EPSIL-000000ACETI-0005.2.15精馏5-精馏T0403物料衡CMolar ETHYL- 4.98E- ETHYL- 2.84E-Mole Enthalpy Mass cal/gm- Mass Molarcal/mol-MassAverageMass6.73E-3.54E-2.06E-METHY-4.19E-EPSIL-00000000ACETI-00005.2.165-33P0406物料衡CMolarMolarcal/mol-MassAverageMass6.73E-6.73E-Molarcal/mol-MassAverageMass6.73E-3.54E-2.06E-METHY-4.19E-EPSIL-00000000ACETI-00005.2.165-33P0406物料衡CMolarMolarcal/mol-MassAverageMass6.73E-6.73E- 2.72E- 2.72E-Mole Enthalpy Mass cal/gm- Mass 8.87E- 9.40E- 9.40E- 2.96E-ETHYL- ETHYL- 5.51E- 2.13E- 7.14E- 9.55E- 2.84E- 1.28E- 2.72E-Mole Enthalpy Mass cal/gm- Mass 3.54E-3.54E-2.06E-2.06E-METHY-4.19E-4.19E-EPSIL-0000ACETI-005.2.17换热5-换热E0407物料衡CMolarMolarcal/mol-MassAverageMass6.73E-6.73E-3.54E-3.54E-2.06E-2.06E-METHY-4.19E-4.19E-EPSIL-03.54E-3.54E-2.06E-2.06E-METHY-4.19E-4.19E-EPSIL-0000ACETI-005.2.17换热5-换热E0407物料衡CMolarMolarcal/mol-MassAverageMass6.73E-6.73E-3.54E-3.54E-2.06E-2.06E-METHY-4.19E-4.19E-EPSIL-00ETHYL- ETHYL- 5.51E- 5.51E- 2.13E- 2.13E- 7.14E- 7.14E- 9.55E- 9.55E- 2.72E- 2.72E-Mole Enthalpy Mass cal/gm- Mass 8.87E- 8.87E- 2.96E- 2.96E-ETHYL- ETHYL- 5.51E- 5.51E- 2.13E- 2.13E- 7.14E- 7.14E- 9.55E- 9.55E-00ACETI-005.2.185-35P0404物料衡CMolarMolarcal/mol-MassAverageMass4.91E-4.91E-1.80E-1.80E-METHY-EPSIL-0000ACETI-005.2.19精馏5-36精馏塔T0501物料衡C00ACETI-005.2.185-35P0404物料衡CMolarMolarcal/mol-MassAverageMass4.91E-4.91E-1.80E-1.80E-METHY-EPSIL-0000ACETI-005.2.19精馏5-36精馏塔T0501物料衡C ETHYL- ETHYL- 3.57E- 3.57E- 2.77E- 2.77E- Mole Enthalpy Mass cal/gm- Mass 8.87E- 8.87E- 2.96E- 2.96E-MolarMolarcal/mol-MassAverageMass4.91E-0001.80E-00006.32E-METHY-05.28E-EPSIL-00000ACETI-00005.2.20精馏5-37精馏塔T0502物料衡CMolarMolarcal/mol-MassAverageMolarMolarcal/mol-MassAverageMass4.91E-0001.80E-00006.32E-METHY-05.28E-EPSIL-00000ACETI-00005.2.20精馏5-37精馏塔T0502物料衡CMolarMolarcal/mol-MassAverageMassMole Enthalpy Mass cal/gm- Mass ETHYL- ETHYL- 1.00E- 8.98E- 3.57E- 5.26E- 5.98E- 2.77E- Mole Enthalpy Mass cal/gm- Mass 0000006.32E-00METHY-5.28E-00EPSIL-000ACETI-0005.2.21换热5-38换热器E0505物料衡CMolarMolarcal/mol-MassAverageMass000000METHY-00ETHYL- 8.98E- 1.00E-0000006.32E-00METHY-5.28E-00EPSIL-000ACETI-0005.2.21换热5-38换热器E0505物料衡CMolarMolarcal/mol-MassAverageMass000000METHY-00ETHYL- 8.98E- 1.00E- 5.98E- 5.26E- Mole Enthalpy Mass cal/gm- Mass ETHYL- ETHYL- 8.98E- 8.98E- 1.00E- 5.98E- 5.98E- 5.26E- EPSIL-00ACETI-005.3VAc5.3.1精馏5-39精馏塔T0601物料衡CMolarMolarcal/mol-Mass477Average4642Mass2.01E-33EPSIL-00ACETI-005.3VAc5.3.1精馏5-39精馏塔T0601物料衡CMolarMolarcal/mol-Mass477Average4642Mass2.01E-3319.75E-702751.13E-481.02E-61.72E- 2.02E- 2.21E- 2.25E- 6.50E- 1.54E- Mole Enthalpy Mass cal/gm- Mass ETHYL- 84310713METHY-0EPSIL-0000000000001.40E-11.05E-7ACETI-1.05E-0005.3.2

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