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DateofDateof:SAFETYDATASectionSection1.Product :快干环氧漆HSPProduct :Product :Product :Coatings:Solvent-RelevantidentifiedusesofthesubstanceormixtureandusesadvisedagainstSupplier'sdetails :中远佐敦船舶涂料(广州)有限公司电话:+862082360908+8620HuakengRoad,Wenchong,Huangpu,Guangzhou510725,ChinaTel:+862082360908Fax:+8620号+86512+86512No.15ChangjiangRoadJiangsuYangtzeRiverInternationalChemicalIndustryPark,ZhangjiagangFreeTradeZone,JiangsuProvince215634Tel:+86512Fax:+86512Emergencytelephonenumber(withhoursof
:EmergencyServicesforChemicalIncidentofChina.Tel:+86532SectionSection2.HazardsClassificationoftheGHSlabel
:FLAMMABLELIQUIDS-Category3ACUTETOXICITY:ORAL-Category5SKINCORROSION/IRRITATION-Category1BSERIOUSEYEDAMAGE/EYEIRRITATION-Category1Percentageofthemixtureconsistingofingredient(s)ofunknownhazardstotheaquaticenvironment:5,9%Hazard :Hazard :FlammableliquidandMaybeharmfulifCausessevereskinburnsandeye :Wearprotectivegloves.Weareyeorfaceprotection.Wearprotectiveclothing.Keepawayfromheat,sparks,openflamesandhotsurfaces.-Nosmoking.Use :IFINHALED:Removevictimtofreshairandkeepatrestinapositioncomfortableforbreathing.ImmediatelycallaPOISONCENTERorphysician.IFSWALLOWED:ImmediatelycallaPOISONCENTERorphysician.DoNOTinducevomiting.IFONSKIN(orhair):Takeoffimmediatelyallcontaminatedclothing.Rinseskinwithwaterorshower.ImmediatelycallaPOISONCENTERorphysician.IFINEYES:ImmediatelycallaPOISONCENTERorSectionSection2.HazardsPage:PenguardHSP :Keep :NotSectionSection3.Composition/informationon :
:NotCAS :NotEC :Product :%CAS10-2.5-2.5-2.5-2.5-1-0-0-Therearenoadditionalingredientspresentwhich,withinthecurrentknowledgeofthesupplierandintheconcentrationsapplicable,areclassifiedashazardoustohealthortheenvironmentandhencerequirereportinginthissection.Occupationalexposurelimits,ifavailable,arelistedinSectionSectionSection4.First-aidDescriptionofnecessaryfirstaidEyeSkin
:Getmedicalattentionimmediately.Callapoisoncenterorphysician.Immediatelyflusheyeswithplentyofwater,occasionallyliftingtheupperandlowereyelids.Checkforandremoveanycontactlenses.Continuetorinseforatleast10minutes.Chemicalburnsmustbetreatedpromptlybyaphysician.:Getmedicalattentionimmediately.Callapoisoncenterorphysician.Removevictimtofreshairandkeepatrestinapositioncomfortableforbreathing.Ifitissuspectedthatfumesarestillpresent,therescuershouldwearanappropriatemaskorself-containedbreathingapparatus.Ifnotbreathing,ifbreathingisirregularorifrespiratoryarrestoccurs,provideartificialrespirationoroxygenbytrainedpersonnel.Itmaybedangeroustothepersonprovidingaidtogivemouth-to-mouthresuscitation.Ifunconscious,placeinrecoverypositionandgetmedicalattentionimmediately.Maintainanopenairway.Loosentightclothingsuchasacollar,tie,beltorwaistband.Incaseofinhalationofdecompositionproductsinafire,symptomsmaybedelayed.Theexposedpersonmayneedtobekeptundermedicalsurveillancefor48hours.:Getmedicalattentionimmediately.Callapoisoncenterorphysician.Flushcontaminatedskinwithplentyofwater.Removecontaminatedclothingandshoes.Washcontaminatedclothingthoroughlywithwaterbeforeremovingit,orweargloves.Continuetorinseforatleast10minutes.Chemicalburnsmustbetreatedpromptlybyaphysician.Washclothingbeforereuse.Cleanshoesthoroughlybeforereuse. :Getmedicalattentionimmediately.Callapoisoncenterorphysician.Washoutmouthwithwater.Removedenturesifany.Removevictimtofreshairandkeepatrestinapositioncomfortableforbreathing.Ifmaterialhasbeenswallowedandtheexposedpersonisconscious,givesmallquantitiesofwatertodrink.Stopiftheexposedpersonfeelssickasvomitingmaybedangerous.Donotinducevomitingunlessdirectedtodosobymedicalpersonnel.Ifvomitingoccurs,theheadshouldbekeptlowsothatvomitdoesnotenterthelungs.Chemicalburnsmustbetreatedpromptlybyaphysician.Nevergiveanythingbymouthtoanunconsciousperson.Ifunconscious,placeinrecoverypositionandgetmedicalattentionimmediately.rtion2.HazardsPage:inian.tightclothingsuchasacollar,tie,PenguardPenguardHSPPage:DateofDateof:Mostimportantsymptoms/effects,acuteanddelayedPotentialacutehealtheffectsEye :Causesseriouseye :Maygiveoffgas,vaporordustthatisveryirritatingorcorrosivetotherespiratorysystem.Exposuretodecompositionproductsmaycauseahealthhazard.Seriouseffectsmaybedelayedfollowingexposure.Skin :Causessevere :Maybeharmfulifswallowed.Maycauseburnstomouth,throatandEyecontact :Adversesymptomsmayincludethefollowing:
:Nospecific:Adversesymptomsmayincludethefollowing:painorirritation:Adversesymptomsmayincludethefollowing:stomachpainsIndicationofimmediatemedicalattentionandspecialtreatmentneeded,ifNotestophysician :Incaseofinhalationofdecompositionproductsinafire,symptomsmaybedelayed.Theexposedpersonmayneedtobekeptundermedicalsurveillancefor48hours.Specific :NospecificProtectionoffirst-aiders :Noactionshallbetakeninvolvinganypersonalriskorwithoutsuitabletraining.Ifitissuspectedthatfumesarestillpresent,therescuershouldwearanappropriatemaskorself-containedbreathingapparatus.Itmaybedangeroustothepersonprovidingaidtogivemouth-to-mouthresuscitation.Washcontaminatedclothingthoroughlywithwaterbeforeremovingit,orweargloves.SectionSection5.Fire-fightingSection4.Section4.First-aidfromthechemicalHazardousthermalforfire-fightersSpecialprotective
:Usedrychemical,CO2,waterspray(fog)or:Donotusewater:Flammableliquidandvapour.Inafireorifheated,apressureincreasewilloccurandthecontainermayburst,withtheriskofasubsequentexplosion.Runofftosewermaycreatefireorexplosionhazard.:Decompositionproductsmayincludethefollowingmaterials:carbondioxidenitrogenoxides:Promptlyisolatethescenebyremovingallpersonsfromthevicinityoftheincidentifthereisafire.Noactionshallbetakeninvolvinganypersonalriskorwithoutsuitabletraining.Movecontainersfromfireareaifthiscanbedonewithoutrisk.Usewaterspraytokeepfire-exposedcontainerscool.:Fire-fightersshouldwearappropriateprotectiveequipmentandself-containedbreathingapparatus(SCBA)withafullface-pieceoperatedinpositivepressurePenguardHSPPenguardHSPPage:DateofDateof:SectionSection6.Accidentalrelease
:NoactionshallbetakeninvolvinganypersonalriskorwithoutsuitableEvacuatesurroundingareas.Keepunnecessaryandunprotectedpersonnelfromentering.Donottouchorwalkthroughspiltmaterial.Shutoffallignitionsources.Noflares,smokingorflamesinhazardarea.Donotbreathevapourormist.Provideadequateventilation.Wearappropriaterespiratorwhenventilationisinadequate.Putonappropriatepersonalprotectiveequipment.Foremergencyresponders:Ifspecialisedclothingisrequiredtodealwiththespillage,takenoteofinformationinSection8onsuitableandunsuitablematerials.Seealsotheinformationin"Fornon-emergencypersonnel".Environmentalprecautions :Avoiddispersalofspiltmaterialandrunoffandcontactwithsoil,waterways,drainsandsewers.Informtherelevantauthoritiesiftheproducthascausedenvironmentalpollution(sewers,waterways,soilorair).MethodsandmaterialsforcontainmentandcleaningSmall Large
Stopleakifwithoutrisk.Movecontainersfromspillarea.Dilutewithwaterandmopupifwater-soluble.Alternatively,orifwater-insoluble,absorbwithaninertdrymaterialandplaceinanappropriatewastedisposalcontainer.Usespark-prooftoolsandexplosion-proofequipment.Disposeofviaalicensedwastedisposalcontractor.Stopleakifwithoutrisk.Movecontainersfromspillarea.Approachthereleasefromupwind.Prevententryintosewers,watercourses,basementsorconfinedareas.Washspillagesintoaneffluenttreatmentplantorproceedasfollows.Containandcollectspillagewithnon-combustible,absorbentmateriale.g.sand,earth,vermiculiteordiatomaceousearthandplaceincontainerfordisposalaccordingtolocalregulations(seesection13).Usespark-prooftoolsandexplosion-proofequipment.Disposeofviaalicensedwastedisposalcontractor.Contaminatedabsorbentmaterialmayposethesamehazardasthespiltproduct.Note:seesection1foremergencycontactinformationandsection13forwasteSectionSection7.Handlingandincludingany
:Putonappropriatepersonalprotectiveequipment(seeSection8).Eating,drinkingandsmokingshouldbeprohibitedinareaswherethismaterialishandled,storedandprocessed.Workersshouldwashhandsandfacebeforeeating,drinkingandsmoking.Removecontaminatedclothingandprotectiveequipmentbeforeenteringeatingareas.Donotgetineyesoronskinorclothing.Donotbreathevapourormist.Donotingest.Useonlywithadequateventilation.Wearappropriaterespiratorwhenventilationisinadequate.Donotenterstorageareasandconfinedspacesunlessadequatelyventilated.Keepintheoriginalcontaineroranapprovedalternativemadefromacompatiblematerial,kepttightlyclosedwhennotinuse.Storeanduseawayfromheat,sparks,openflameoranyotherignitionsource.Useexplosion-proofelectrical(ventilating,lightingandmaterialhandling)equipment.Useonlynon-sparkingtools.Takeprecautionarymeasuresagainstelectrostaticdischarges.Emptycontainersretainproductresidueandcanbehazardous.Donotreusecontainer.:Storeinaccordancewithlocalregulations.Storeinasegregatedandapprovedarea.Storeinoriginalcontainerprotectedfromdirectsunlightinadry,coolandwell-ventilatedarea,awayfromincompatiblematerials(seesection10)andfoodanddrink.Storelockedup.Eliminateallignitionsources.Separatefromoxidizingmaterials.Keepcontainertightlyclosedandsealeduntilreadyforuse.Containersthathavebeenopenedmustbecarefullyresealedandkeptuprighttopreventleakage.Donotstoreinunlabelledcontainers.Useappropriatecontainmenttoavoidenvironmentalcontamination.SectionSection8.Exposurecontrols/personalControlparametersOccupationalexposurelimitsIngredientGBZ-2(China,PC-STEL:100mg/m³15PC-TWA:50mg/m³8GBZ-2(China,PC-TWA:100mg/m³8GBZ-2(China,PC-TWA:100mg/m³8PC-STEL:150mg/m³15PC-STEL:10mg/m³15PC-TWA:4mg/m³8
:Ifthisproductcontainsingredientswithexposurelimits,personal,workplaceatmosphereorbiologicalmonitoringmayberequiredtodeterminetheeffectivenessoftheventilationorothercontrolmeasuresand/orthenecessitytouserespiratoryprotectiveequipment.:Useonlywithadequateventilation.Useprocessenclosures,localexhaustventilationorotherengineeringcontrolstokeepworkerexposuretoairbornecontaminantsbelowanyrecommendedorstatutorylimits.Theengineeringcontrolsalsoneedtokeepgas,vapourordustconcentrationsbelowanylowerexplosivelimits.Useexplosion-proofventilationequipment.:Emissionsfromventilationorworkprocessequipmentshouldbecheckedtoensuretheycomplywiththerequirementsofenvironmentalprotectionlegislation.Insomecases,fumescrubbers,filtersorengineeringmodificationstotheprocessequipmentwillbenecessarytoreduceemissionstoacceptablelevels.Hygienemeasures :Washhands,forearmsandfacethoroughlyafterhandlingchemicalproducts,beforeeating,smokingandusingthelavatoryandattheendoftheworkingperiod.Appropriatetechniquesshouldbeusedtoremovepotentiallycontaminatedclothing.Washcontaminatedclothingbeforereusing.Ensurethateyewashstationsandsafetyshowersareclosetotheworkstationlocation.EyeSkinprotectionHandBody
:Safetyeyewearcomplyingwithanapprovedstandardshouldbeusedwhenariskassessmentindicatesthisisnecessarytoavoidexposuretoliquidsplashes,mists,gasesordusts.:Chemical-resistant,imperviousglovescomplyingwithanapprovedstandardshouldbewornatalltimeswhenhandlingchemicalproductsifariskassessmentindicatesthisisnecessary.:Personalprotectiveequipmentforthebodyshouldbeselectedbasedonthetaskbeingperformedandtherisksinvolvedandshouldbeapprovedbyaspecialistbeforehandlingthisproduct.Otherskinprotection :Appropriatefootwearandanyadditionalskinprotectionmeasuresshouldbeselectedbasedonthetaskbeingperformedandtherisksinvolvedandshouldbeapprovedbyaspecialistbeforehandlingthisproduct.Respiratoryprotection :Useaproperlyfitted,air-purifyingorair-fedrespiratorcomplyingwithanapprovedstandardifariskassessmentindicatesthisisnecessary.Respiratorselectionmustbebasedonknownoranticipatedexposurelevels,thehazardsoftheproductandthesafeworkinglimitsoftheselectedrespirator.PenguardHSPPenguardHSPPage:SectionSection9.PhysicalandchemicalMelting
::Various::Not:Not:NotBoiling :NotFlash :Closedcup:33°CBurning :NotBurningrate
:Not:Not :Not(flammable)limits
:NotVapourdensity
:Not:Not :1
:Insolubleinthefollowingmaterials:coldwaterandhot:Not:Not :Not
:Not:NotSectionSection10.Stabilityand :Nospecifictestdatarelatedtoreactivityavailableforthisproductorits :Theproductis
:Undernormalconditionsofstorageanduse,hazardousreactionswillnotConditionstoavoid :Avoidallpossiblesourcesofignition(sparkorflame).Donotpressurise,cut,weld,braze,solder,drill,grindorexposecontainerstoheatorsourcesofignition.Incompatiblematerials :Reactiveorincompatiblewiththefollowingmaterials:oxidizingmaterials
:Undernormalconditionsofstorageanduse,hazardousdecompositionproductsshouldnotbeproduced.FinedustcloudsmayformexplosivemixtureswithSectionSection11.ToxicologicalInformationontoxicologicaleffectsAcutetoxicity5000800044Dateof :DateofDateof:nguardHSPLD502400034004 Page:LD50LD5079035001200PenguardHSPPenguardHSPSection11.ToxicologicalPage:DateofDateof:NotNotNotNotNotNotSpecifictargetorgantoxicity(singleRouteofTargetNarcoticeffectsSpecifictargetorgantoxicity(repeatedRouteofTargetNotNotroutesofexposure
:NotEye :Causesseriouseye :Maygiveoffgas,vaporordustthatisveryirritatingorcorrosivetotherespiratorysystem.Exposuretodecompositionproductsmaycauseahealthhazard.Seriouseffectsmaybedelayedfollowingexposure.Skin :Causessevere :Maybeharmfulifswallowed.Maycauseburnstomouth,throatandSymptomsrelatedtothephysical,chemicalandtoxicologicalcharacteristicsEyecontact :Adversesymptomsmayincludethefollowing:
:Nospecific:Adversesymptomsmayincludethefollowing:painorirritation:Adversesymptomsmayincludethefollowing:stomachpainsDelayedandimmediateeffectsandalsochroniceffectsfromshortandlongtermexposureShorttermexposure
:Not :NotLongterm
:Not :NotPotentialchronichealthNot
Noknownsignificanteffectsorcriticalhazards.Noknownsignificanteffectsorcriticalhazards.Noknownsignificanteffectsorcriticalhazards.Noknownsignificanteffectsorcriticalhazards. :NoknownsignificanteffectsorcriticalFertility :NoknownsignificanteffectsorcriticalNumericalmeasuresoftoxicityAcutetoxicityestimatesATE2083,310419,313547741,77SectionSection12.EcologicalAcuteEC507,2mg/LAcuteLC504,2mg/LAcuteEC506,84mg/l48489648AcuteLC50467296Notbenzylalcohol--Mobilityin DateofDateof:taiabl.1.Page:PenguardHSPPenguardPenguardHSPPage:DateofDateof:SectionSection11.EcologicalOtheradverse :NoknownsignificanteffectsorcriticalSectionSection13.Disposal :ThegenerationofwasteshouldbeavoidedorminimisedwhereverSignificantquantitiesofwasteproductresiduesshouldnotbedisposedofviathefoulsewerbutprocessedinasuitableeffluenttreatmentplant.Disposeofsurplusandnon-recyclableproductsviaalicensedwastedisposalcontractor.Disposalofthisproduct,solutionsandanyby-productsshouldatalltimescomplywiththerequirementsofenvironmentalprotectionandwastedisposallegislationandanyregionallocalauthorityrequirements.Wastepackagingshouldberecycled.Incinerationorlandfillshouldonlybeconsideredwhenrecyclingisnotfeasible.Thismaterialanditscontainermustbedisposedofinasafeway.Careshouldbetakenwhenhandlingemptiedcontainersthathavenotbeencleanedorrinsedout.Emptycontainersorlinersmayretainsomeproductresidues.Vaporfromproductresiduesmaycreateahighlyflammableorexplosiveatmosphereinsidethecontainer.Donotcut,weldorgrindusedcontainersunlesstheyhavebeenclea
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