n-磺酰基氧杂吖丙啶烯醇不对称羟基化反应

Davis,F.A.;Chen,B.-C.Chem.Rev.1992,92,918-AzusaHashimotoTheOxidationofMetal→-carboneの切断やジカルボニル化HypervalentIodine(PhIO)n,PhI(OAc)2,o-IodosylbenzoicMetal→1,3-dicarbonylの場合はover-oxidationN-TheOxidationofMetal→-carboneの切断やジカルボニル化HypervalentIodine(PhIO)n,PhI(OAc)2,o-IodosylbenzoicMetal→1,3-dicarbonylの場合はover-oxidationN-N-2-arenesulfonylTheOxidationofMetal UsingofN-Substrate-InducedAuxiliary-InducedReagent-InducedSubstrate-Induced Substrate-InducedNarasaka,K;Ukaji,Y.;Watanabe,K.Bull.Chem.Soc.Jpn.1987,60,Substrate-InducedNarasaka,K;Ukaji,Y.;Watanabe,K.Bull.Chem.Soc.Jpn.1987,60,Substrate-InducedMorizawa.Y.;Yasuda,A.;Uchida,K.TetrahedronLett.1986,27,Auxiliary-InducedEnders,D.;Bhushan,V.TetrahedronLett.1988,29,Auxiliary-InducedEnders,D.;Bhushan,V.TetrahedronLett.1988,29,Auxiliary-InducedEnders,D.;Bhushan,V.TetrahedronLett.1988,29,Enders,D.;Bhushan,V.TetrahedronLett.1988,29,Auxiliary-InducedEvans,D.A.;Morrissey,M.M.;Dorow,R.L.J.Am.Chem.Soc.1985,107,Auxiliary-InducedDavis,F.A.;Vishwakarma,L.C.TetrahedronLett.1985,26,Auxiliary-InducedDavis,F.A.;Vishwakarma,L.C.TetrahedronLett.1985,26,Auxiliary-InducedDavis,F.A.;Vishwakarma,L.C.TetrahedronLett.1985,26,Auxiliary-InducedDavis,F.A.;Vishwakarma,L.C.TetrahedronLett.1985,26,Substrate-InducedAuxiliary-Induced不斉補助基の導入，除去の工程がReagent-InducedDavis,F.A.;Shepard,A.C.;Chen,B.-C.;Haque,M.S.J.Am.Chem.Soc.1990,112,TheOxidationofMetal UsingofN- InfluenceofEnolateエノレートのジオメトリーは不斉導入にはあま InfluenceofEnolateSubstitution⇒エノレートの置換様式が立体選択性に強 InfluenceofEnolateSubstitutionInfluenceofEnolateSubstitutionInfluenceofEnolateSubstitution HMPA⇒立体選択性のReagent-InducedDavis,F.A.;Weismiller,M.C.;Murphy,C.K.;Reddy,R.T.;Chen,B.-C.J.Org.Chem.1992,57,Reagent-InducedDavis,F.A.;Weismiller,M.C.;Murphy,C.K.;Reddy,R.T.;Chen,B.-C.J.Org.Chem.1992,57,Reagent-InducedDavis,F.A.;Weismiller,M.C.;Murphy,C.K.;Reddy,R.T.;Chen,B.-C.J.Org.Chem.1992,57, opentransition-statemodel立