浙江大学有机化学(丙)试题库(完成反应2)

1、1CH2=CHCH2CHO+2CH2OHHCl(g)CH2OHKMnO4/OHH2Or.tH+CHO+H2NHNNO2O2N3CHO+CH3MgI4稀OH2CH3CHO5CHO浓碱+HCHOOCH36CH3CH2COCH3+I2/NaOH7CHO2Ag(NH3)2OH8CHONaBH4H2O乙醇9OCH2=CHMgBr+10CH2CCH3+Br2/NaOHOH2OH+H2OH+111CHO浓碱+HCHO（过度）CHO12OHCH2CCH3ZnHgOHCl13CH3CH3CHMgBrCH3CH2CHO2.H3O+14OO+2H2NNHCNH2O15CHOHCN+HOH（用Fischer式表示）O

2、HCH2OH16O+MgBrH2OH+H+17H2O(CH3)3CMgBr+CO2H+18CH3CHCH2CH3+NaOH/I2OH19CH2CHO1.CH3CH2MgBrH2SO42.H3O+202CH2NNH2,OHODMSO,高温21OLiAlH4H2OCH322CHCHOFehlingCH3CHO23()ONOH24()OOO25H2/NiH+Cl2NaOHO光H2O262CH3CHCH2CHO稀OHCH327CH2CHO(C6H5)3P=CHCH(CH3)228CH3NH3NaOH/Br2CH2CHCOOH329CHCHOTollensCH3CHO30O1.CH3CH2ONaCH3C

3、OC2H5312.H+CH2CH2CH2COOHOH32NaOHOO33CH2COOH34CH2CH2COOHCH2CH2COOH35ONH3Br2/NaOHCOOHHOOC36CH2CH2COOC2H51.CH3CH2ONaH3O+CH2CH2COOC2H52.H+437OHOOCOOH+CH3COCCH3H2SO438CH2ClHCNH3O+NaCNH3O+COEtOHCH2Cl39OONaAcCH3COCCH3+CH2OHO40CH3CH3CHCH2COOH+NaHCO341CH3CH3CHCH2COOH+PCl342OOCH3CH2OHO43OCH3稀OHNHCCH3H2ONO244S

4、OCl2OH(CH3)3CCOOH吡啶545COOHSOCl2(CH3)3COH吡啶46ONaOHCH3OCBr+NH47OBr+OHNaOHCH3OC48OO+2NH3O49CH2CH2COOC2H5CH3CH2ONa1.CH3ONaH3O+CH2CH2CH2COOC2H52.CH3I501.LiAlH4KMnO4/H+COOC2H52.H3O+51NH2Br2NaNO232HPOH2SO40CH3526NH2NaNO2H2SO4053NH2NaNO2H2SO4054Fe/HClNO255NO2Fe/HCl56CH3NHCH3+SO2Cl57NH+HNO258OHBr2(H2O)59CH3O

5、OH弱碱性Cu2Cl2HClNaNO2HCl0CH3COCl吡啶N(CH3)2H+CH3AlCl3I2/NaOH+CH3COCl无水+H3O760CH3NaOH/Br2CH3CHCH2CONH261COClCH2+H2NCONH2（酮式）（烯醇式）COCl62N2ClN(CH3)2+CH363CH3CH3CH2CH2CHO+(C6H5)3P=CCH2CH364OO+O65CF3O+CCCF366浓NaOHCHOO678N+KNO3/H2SO4(SO3)68NH（液）3+KNH2H69CH2CH3+HNO3N70Fe/HCl+KNO3/H2SO4(SO3)N71+NaNH72CH2OCO(CH2

6、)16CH3+3NaOH(aq)CHOCO(CH2)14CH3CHOCO(CH2)7CH=CH(CH2)7CH373OHO+CH3(CH2)12CH=CHCHCHCH2O+H3OPO(CH2)2N(CH3)3NHCORO749CH2OCORRCOOCH+O+HOCH2CH2N(CH3)3OHCH2OPOHOH75CH2OHOOHOH+Br2/H2OOHOH76CH2OHOHOOH+HClCH3CH2OHOHOH77CH2OHOOH+Ag(NH)OHOH32OHOH78CH2OHNHNH2OOH+3NO2OHOHOHNO279CHOHOH稀HNO3HOHOHCH2OH1080CHOHOH1.LiAlH4HOH2.HOH2HOCH2OH81CHOHCHOHHO2H2+OHOH3OHOOHOOHOHOH82OHOOHO+Ag