残留溶剂测定法

1、 四氯化碳5.4702.089甲基异丁基酮7.2022.261环己烷5.5832.150乙腈7.3682.328甲基四氢咲喃5.6762.201乙酸异丁酯7.4972.380三氯乙烯6.7602.785氯仿7.9852.577二氧六环6.8232.819仲丁醇8.3902.740异辛烷6.9572.891甲苯8.7462.884正庚烷7.4343.148正丙醇9.2383.083乙酸丙酯7.4783.172二氧六环10.3353.526甲基环己烷&6283.7921,2-二氯乙烷10.8273.724甲基异丁基酮&7383.851乙酸丁酯11.0123.7993-甲基-1-丁醇8.8703.9

2、22甲基丁基酮11.4863.990吡啶9.2834.145甲烷1.602甲苯11.1805.168柱温80C正戊醇11.3825.276异丁醇3.5773.045甲烷1.594正丁醇4.4604.334柱温80C硝基甲烷4.8854.948乙酸异丁酯3.6112.099异丙基苯5.2885.543甲基丁基酮3.8592.345吡啶5.6256.035乙酸丁酯4.2992.7783-甲基-1-丁醇5.9346.486氯苯5.2533.726氯苯6.4397.223甲氧基苯7.4365.890正戊醇7.332&527异丙基苯&1486.589丁酮2.1761.000丁酮2.5021.000甲烷1

3、.491甲烷1.493柱温120C柱温120C甲氧基苯3.8379.890四氢化萘&06729.609四氢化萘7.42724.484丁酮1.6301.000丁酮1.6501.000甲烷1405甲烷1404附表3：常见有机溶剂在程序在升温法测定时相对于丁酮的保留值参考值非极性色谱木主极性色谱柱顺序溶剂名称tR（min）RART顺序溶剂名称tR（min）RART1甲醇1.8460.1271正戊烷1.6910.0332乙醇2.1210.2722正己烷1.8070.0763乙腈2.2010.3143乙醚1.8560.0944丙酮2.3030.3674异辛烷1.9570.1315异丙醇2.4010.41

4、95异丙醚1.9660.1356正戊烷2.5120.4776叔丁基甲基醚2.0530.1677乙醚2.5190.4817正庚烷2.0630.1718甲酸乙酯2.5440.4948环己烷2.2170.2289二甲氧基甲烷2.6110.52991,1-二氯乙烯2.2670.246101,1-二氯乙烯2.6230.53510二甲氧基甲烷2.3030.26011乙酸甲酯2.6650.55811甲基环己烷2.4880.32812二氯甲烷2.6740.56212丙酮2.9880.51313硝基甲烷2.8390.64913甲酸乙酯3.0940.55214正丙醇3.0510.76014乙酸甲酯3.1260.5

5、64151,2-二氯乙烯3.1280.801151,2-二氯乙烯3.5110.70716叔丁基甲基醚3.3020.89216四氢咲喃3.5610.72517丁酮3.5071.00017甲基四氢咲喃3.6530.75918仲丁醇3.7561.13118四氯化碳3.8210.82219正己烷3.9661.241191，1，1-三氯乙烷3.8330.82620异丙醚3.9711.24420乙酸乙酯4.0170.89421乙酸乙酯3.9811.24921乙酸异丙酯4.2070.96422氯仿4.0051.26222甲醇4.2950.99723四氢咲喃4.3871.46223丁酮4.3031.00024

6、异丁醇4.3971.468241，2-二甲氧基乙烷4.8751.212251,2-二氯乙烷4.61241.58125甲基异丙基酮5.0051.260261，1，1-三氯乙烷4.8431.70226二氯甲烷5.0411.27327甲基异丙基酮5.0871.83027异丙醇5.0691.284281,2-二甲氧基乙烷5.0991.83728乙醇5.2751.36029苯5.3801.98429苯5.2751.36030乙酸异丙酯5.3981.99430乙酸丙酯6.4371.79031正丁醇5.4021.99631三氯乙烯7.1082.03932四氯化碳5.5012.04832甲基异丁基酮7.735

7、2.27133环己烷5.6492.12633乙腈7.8922.32934甲基四氢咲喃5.7392.17334乙酸异丁酯&0682.39435三氯乙烯6.8152.73835氯仿&5332.56636异辛烷6.9282.79836仲丁醇&8482.68337二氧六环6.9282.79837甲苯9.1562.79738正庚烷7.5633.13138正丙醇9.4612.91039乙酸丙酯7.5833.14239二氧六环10.1833.17740甲基环己烷&5813.666401,2-二氯乙烷10.4463.27441甲基异丁基酮&8303.79741乙酸丁酯10.5433.310423-甲基-1-丁

8、醇&9683.87042甲基丁基酮10.8013.40643吡啶9.1783.98043异丁醇11.6063.70444甲苯10.2594.54844正丁醇13.0464.23745正戊醇10.4484.64745异丙基苯13.2584.31546乙酸异丁酯10.6384.74746硝基甲烷13.3964.36747甲基丁基酮11.0254.95147吡啶13.9494.57148乙酸丁酯12.1755.555483-甲基-1-丁醇14.5194.78249氯苯13.1666.07649氯苯14.5624.79850甲氧基苯15.2707.18150正戊醇15.5165.15151异丙基苯15.7247.42051甲氧基苯17.4475.86652四氢化萘22.40