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万华化学工业涂料综合解决方IndustrialcoatingWanhuaChemicalGroup SurfaceMaterialJeffZhangOct23,2014 能能 Netprofitbelongingtotheparentcompanyfrom1999to
归属于母公司净利润(Netprofitgrowsannuallybyacompoundrate29.5percentoverthepast13yearsfrom2001to2013.
增长率(百分比右轴
Thenetprofitof2013is28.7timesthatof
0
10,07315,433
BusinessStructureofWanhuaWanhuaWanhuaChemical
PetrochemicalsandAcrylicAcid(AA)ButylAcrylate(BA)EthylAcrylate(EA)…
SpecialtyADIADI(HMDI,HDI,IPDI,SpecialAmines(IPDA,HMDA,MDA,MDBA,SpecialAmines(IPDA,HMDA,MDA,MDBA,(waterbornePUandPAdispersions,表面材料事业 Basic 依托上游聚氨酯和丙烯酸酯原料优势,延伸产业R&D
(Industrial
))
(Textile&Artificial
al))(Interiorpaints
AutoOEM
(Waterbornefootwear(Textilepigmentcoatings
(Hair(Exteriorpaints(Primer
(Wood(Plastic(Floor(Glass(Printing(Electronic
otiveinterior
(Textile
(Fingernail(Skin(Film
PA
反应型树脂
WB
表面材料事业部国内布ChengduplantinJune2017-工厂ZhuhaiplantInJuly仓库Commercialandtechnicalservicecenter
研发中心R&DYantai宁波工厂NingboplantinJuneinJuly2013)CommercialandtechnicalserviceNingboAqueousDispersionPlantof50,000TonsProducts金属涂料产品 -- - -- -- Lightdutyanticorrosionsystem轻防腐体
LightLightdutyanticorrosionpaint,Wantipro®Wantipro®HighperformancelightdutyanticorrosionWantipro®HigherHardness硬ExcellentadhesiononmetalHigherExcellentsalt HigherWantipro®Outstanding Goodsalt Goodstability ,30dSalt , Water
1水/21水/213464786952Black12345Tego67水/8VesmodyTMThicknessofdryfilm,40um,on
pHafterRT40
干膜厚度40umdrying:T=25CRH=55%
Visco,stomer,25°C,RT40dWantipro®Execllentadhesion马口铁
碳钢
铝Testmethod:GB/T9286-1998,RT7days测试方法:GB/T9286-1998,制膜后,室温养护7天。PVC=16%Excellent 5saltwater,7d5%盐水,7d
5%H2SO4,
Water,Testmethod:GB/T9274,RT7daysthicknessofdryfilmis40um,ontinplate.PVC=16%测试方法:GB/T9274将室温放置7d的漆膜(干膜厚40um马口铁)Wantipro® Goodsaltfog 7D
ExcellentorientationofAlWanriproWanripro® Thicknessoffilm干膜厚:80umAluminumphosphate三聚磷酸铝5%Zincphosphate磷酸锌:5%Titaniumdioxide钛白粉物水BYK-AMP-CF-HEUCOPHOS®拜物水BYK-AMP-CF-HEUCOPHOS®拜尔乐滑石粉(1250目Black%1556供应去离子分散剂/毕克化pH调节填膨润土/美洋时炭黑/德固搅拌状态下依次加入,研磨至细度20um以Wantipro® 树脂/万华化二乙二醇丁 成膜助TegoFoamex 消泡剂/迪NALZIN®FA VesmodyTM 增稠剂/万华化VesmodyTM 增稠剂/万华化 指 Smoothsurface,nosaggingGoodstabilitySalt 工艺:浸涂后挂起表干10-20min,然后80-100C施工粘度:17-25s(可根据所需膜厚及现场施工环境调节55 Excellentstability Diluteto20s,50°C3weeks,nosettling,nosegmentationnopigskinnoviscochange开稀至20s,热储ExcellentcompatibilityMixedwithacommercial paint,RT7days,themixisstable,noviscochange,andtheglosskeepsthe光泽/粘度光泽/粘度Wantipro®0612For 用于浸Salt 24h耐盐雾性WantiproWantipro® Thickness膜厚Wantipro®
Postselfcrosslink性硬 Water柔韧 耐SaltwaterGoodbalanceofflexibilityandWantipro®•Bettersaltfog andPerformanceofanticorrosionpaint附着力(碳钢/马口铁 0- 附着力(碳钢/马口铁 P/B=1颜基比=1Thicknessofdryfilm干膜厚度40umDryingconditions干燥条件:7d,T=25CWantipro® Excellentsaltfog 240h
物 供应 1212BYK-颜料分散剂344滑石粉125065Ti-Pure钛白粉6三聚磷酸铝AWP-6758Tego消泡剂121345Tego消泡剂6NALZIN®FA防闪锈助剂/7VesmodyTMU604:水增稠剂/P/B=1颜基比=1Thicknessofdryfilm干膜厚度40um.Dryingconditions干燥条件:7d,T=25C,RH=60%
指 1 Wantipro®0618+Wantipro®Evenbettersalt 优优异的防腐底漆:Wantipro®Excellent优的度面漆:Wantipro®Higher优的度面漆:Wantipro®Higher较高的硬WBindustrybakingpaint水性工业烤WantiproWantipro®OutstandingOutstanding卓越的化学抗ExcellentFlexibility,0.5mm >50/>50kg·cm项目项目结果g 95%,1kg耐醇擦g
≥2000times, H2SO45 NaOH5Saltwater 5%NaCl耐盐水Salt
24h,no12h无变化,24h轻微起泡,可恢复48h,no48h,no to1kg耐MEK≥200slightgloss to1kg耐MEK≥200slightglossloss喷涂,室温干燥30分喷涂,室温干燥30分钟,140C烘烤30分钟,隔天测试性能Spraying,RT30min,140oC30min,testTestmethod:ASTMD5402-2006,load500g100次,漆膜无变2000次,漆膜无100times,nochange2000times,no200次,漆膜有失200times,slightglossMEKAlcohol物%供应123ButylCellosolveTM456CYMEL71防腐助剂 指标1Wantipro®0676+Antkote®2033:wheelhubForwheelhubGoodappearanceandbuildingupproperty Goodflexibility&recoatabilityAntkote®BuildingupAntkote®BuildinguppropertyAppearanceWantipro®FlexibilityRecoatability重涂项目项目 结果Salt
240h,nobubbleand NaOH,0.1mol/L
24h,no,H,H2SO40.1mol/L48hslightglossNo.9348h,no40°C40°C144h,no
2h,noWantipro®0676+Antkote®2033:wheelhubGoodstabilityforaluminum RT30days,apply.Thesameappearanceand国产铝银浆配漆,室温放置一个月,喷涂,漆膜外观及性能无变化Good WBindustrybakingpaint水性工业烤Recipeforaluminumpaint银粉漆参考配 Recipeforwhitepaint白漆参考配物物%供应123445678993水12水/345JNW 物 供应 1分散剂2水/3Ti-Pure钛白粉456CYMEL8748292润湿剂消泡剂Machineryandtransport工程机械及交抗性硬度外观OH羟基丙烯酸(组分 聚异酸酯(组分OH
HH
OH交联反OH羟基反应 异酸酯反应
化学交联–NH-C-与水性体系互溶性Aquolin®self-emulsion与水性体系互溶性Aquolin®self-emulsion能度,100%>100/100andGood优异的机械稳定性OutstandingGoodappearanceandbuildingup优异的外观丰Highgloss>90%,清漆光泽and 优异的耐紫外和耐候Antkote®2KPUsystem双组分聚氨酯卓卓越的化学抗2KPUindustrypaint双组分聚氨酯体系工业Goodappearanceandbuildingupproperty Excellent andweatherability物%供应 物%供应 BYK Ti-PureR- BYK BYK BYK BYK Aquolin®万华 根据实际需求,添加适当粉料。23℃条件下,活2KPUindustrypaint双组分聚氨酯体系工业NCO/OH=1.5,表干30min+80℃/30min,膜厚=40-测试项目 值potlife涂膜干燥条件drytouchGB/T1728实干hard7GB/T1728铅笔硬度pencilHGBglossGB附着力(adhesiveGB/TGB/Timpactkg.cm,GBGB(23℃)耐碱(5%NaOH耐酸(5%H2SO4化NopulverizationGB/T耐UV2KPUindustrypaint双组分聚氨酯体系工业不同产品耐UV测试对321
X-X-7X-76X-50 其中,X-5、X-6、X-7、X-76为市面竞
2KPUindustrypaint双组分聚氨酯体系工业物物%供应12BYK34Ti-PureR-234TegoWet5BYK6BYK75891Aquolin®2Formulationofmotor 各类水性木器漆与溶剂型体系的
0
/ WB WB2K SB2KPU WBProductsforWoodCoatings木器漆产Lacper®Lacper®Highhardness.FastLacper®家andbuildingupLacper®Excellentbuildingup.GoodLacper®Excellentstackability.LowVOCHighhardnessand Lacper®GoodadhesiononMetal/Glass/SBpaint/Plastic.Exellentchemical.木器户Lacper®Flexibility.GoodearlywaterwhiteningDurabilityagainstweather..Lacper®VerylowVOCneeded.Flexibility.GoodwaterDurabilityagainstweather.Good.WBUrosin®Goodadhesionon地Compatiblewithpigment/dye.Re-WBUrosin®Highhardness.DustfreebeforeUVWBUrosin®Forhighglosscoating.GoodchemicalHighhardness..插VeryfineparticleHydrophilicPolyisocyanate亲 PolymerbasedonHDIAquolin®Polyethermodified.GoodchemicalHydrophilicallymodifiedpolyisocyanatebasedonHDIAquolin®Sulfonatemodified.GoodwaterHydrophilicallymodifiedpolyisocyanatebasedonMDIAquolin®TDIfree.Gooddrying.CouldbeusedwithLacper®4316asisolationsealer.WanhuaWB1K万万华水性2KWanhuaWB2K万万华水性UVWanhuaWBUVWanhuaWB1K: Solids,%MFFT, Lacper®
PUD
Outstandingbuildingupproperty,handfeeling,flexibility.ForLacper®Lacper® Excellentstackability,hardness,fastdrying,lowodour.ForLacper®
Aqueousacrylic
Flexibility,Goodearlywater ,Durabilityagainstweather.CouldbeinhighPVCsystem.Forfurniture,DIY,exteriorLacper®Lacper®4316Styrene-acrylatecopolymer Fastdrying,hard,goodsandability.Forfurniture,Lacper®
Acrylicemulsion,self-
,flexible,durabilityagainstweather,goodadhesionondifficultsub.furniture,windowLacper®Lacper®4501Acrylicemulsion,self- LowVOCpossible, .Forfurniture,Lacper®
Acrylicemulsion,self-
Stackability,lowVOCpossible, .ForLeasys®Leasys®5530PUD Fineparticlesize,goodcompatiblitywithcosolvent/dye/pigment.ForWanhuaWBLacper®4221:HighhardnessandLacper®4221:HighhardnessandlowcosolventFastdrying,outstandingCouldbeusedas2KwithAquolin®APEO,NMPandOrganotinTypicalViscosity(25°C),MFFT,PencilImpact,OutstandinghandfeelingandbuildingupGoodadhesiononPU,PVC,Couldbeusedas2KwithAquolin®APEO,NMPandOrganotinTypicalViscosityViscosity(25°C),Non-volatilecontent,MFFT,Pendulumhardness,PencilBImpact,Flexibility,WanhuaWB
6420
Buildingup Early Lacper®Lacper® Lacper®WanhuaWB1K:Lacper®Lacper®4210couldbeusedWithAquolin®268, willbeAdd5%hardenerinLacper®421080%80%Mixby-535355532Gloss20°/60°,--Particlesizein2K,-BFF-Water,555-50%,355-Acetic 30%, ,5%,555-Case:Add5%Aquolin®268/MPA80%inLacper®4210Water atRTisincreasedfrom5daysto7daysonwood-plasticWanhuaWB1K:Lacper®GoodOnonPC/PC+ABS/PVCAquolin®268couldimprovetheadhesiononPVC/PU/plastic-wood.SilaneCouplingAgentZ-6040couldimprovetheadhesiononmelamine. Onpine+PU,Lacper®Aquolin268couldimprovetheearly
OnPVC,whitetopLacper®4210+Aquolin®268(2%to
+Z-6040(4%toWanhuaWB1K:Lacper®Lacper®4210onexcellent
Lacper®4210ontinplateWanhuaWB1K:Lacper®Lacper®4221couldbeusedWithAquolin®268,chemical Andtheglosskeepsthesame.Aging7daysatAcetic Hot Dry50%,30%,Acetic Hot Dry50%,30%,5%,70°C0%268(70%in Withoutmatting 5%268(70%in 5555510%268(70%in 5555550%268(70%in 5555With0.7%CP4- 5%268(70%in 555510%268(70%in 55555*75%Lacper®4221inthe**Thepartoffilmiswhitewhenthediscis***Droptheboilingwateronthefilmandkeepaglassbottlewith250mlboilingwateronit,removethebottleafterWanhuaWB1K:Lacper®Sub:HDF,with2layersofWBUVlacquerbasedfromUrosin®4699,100g/m2foreachlayer.ApplyWBlacquersby150umapplicator.Flashoff3minat25C,then40C40min,cooling3min.StackatRT24hand50C15h,pressure0.12kg/m2.50C 25CLacper®CompetitorCompetitorWanhuaWB1K:Lacper®HardnesscLacper®4221Lacper®4221Lacquer+5%268(70%inLacper®4221Lacquer+10%268(70%in75%Lacper®4221intheApplyonglassby100umspiralapplicator,andagingat25°C,RHWanhuaWB1K:Lacper®ExcellentSolidDipSB2KPUas1stSpray3layers2KWBGoodbuildingupGoodbuildingupGoodhidingGood•Stable,noGoodfilmFastLacper®4055在白色ApplicationofLacper®4055inwhiteRaw% 172Orotan 3BYK 4TegoAirex 5Talc12506Ti-PureR- 7Talc1250Grinding30min,addwaterif8Lacper®429BYK 4LaponiteS048210%water2VesmodyTMU60430%water0.651Freshvisco,2Viscoafter8daysatRT,WanhuaWB1K:Lacper®Lacper®4055在户外漆中的ApplicationofLacper®4055inExteriorwood优异的早期耐水白性Outstandingearlywater清漆,粘度:70-80KU。Clearlacquervisco70-80KU.Brush2layersonpine,includingtheedges.DryingatRTor50°CovernightforeachImmerseinwaterovernight,noWanhuaWB1K:Lacper®Lacper®4055在户外漆中的ApplicationofLacper®4055inExteriorwood户外暴281天(至2014-6-10),烟台,距海1.8km,松木Outdoorexposure281days,Yantai,1.8kmtothecoastonpine哑光白漆
哑光红漆 WanhuaWB1K:Lacper®快Fast打磨ExcellentCouldbeusedwithAquolin®296asisolationsealer
耐水GoodPencilhardnessHB光泽Highgloss,Lacper®4316,P320onmapleveneer
Lacper®4316,P320onrubberwoodWanhuaWB1K:Lacper®清底 RawRaw rRaw r1Lacper®2Highspeed10min,check
50
Lacper®Highspeed10min,check
267267TegoAirexPremix3-7,addingslowlyathighspeed,10min,
3 45367TegoAirexPremix3-7,addingslowlyathighspeed,10min,checkcraters,thenmiddlespeedcraters,thenmiddle8Lacper®9TegoGlide10
30
Neptune5223NRHighspeedLaponiteS48210%Middle
2.5211VesmodyTMU604
0.75
Lacper® TegoGlide VesmodyTMU604 1viscosity23°C,DIN4
Viscosity23°C,DIN4Gloss,
WanhuaWB1K:Lacper®ExcellentflexibilityandhigherGood Lacper®Lacper®AcrylicAcrylicAcrylicMFFT,Breakingelongation, ,Hardness,könig,WanhuaWB1K:Lacper®户外暴晒128天无开裂,烟台,距海1.8kmOutdoorexposure,128days,nocracks,1.8kmtothecoast,on附着力优异,与 剂搭配附着力更好GoodadhesiononUV/plastic-wood/PVC,BetteradhesionwithAquolin®Lacper®4400+Aquolin®296(7%to
Onbirch+UV,mattop,glossLacper®4400+Aquolin®268(5%toWanhuaWB1K:Lacper®CompetitorCompetitorCompetitor543210均衡的性低成膜助剂需求配方宽容度Excellent GoodcomprehensiveLowVOCEasytobeGloss,Alcohol50%Aceticacid30%5NaHCO35%5Coffe4Water5
2layerslacqueronmapleveener,ageing7days.1%TS-100and2%Neptune5223NRintherecipe.WanhuaWB1K:Lacper® 物 供 物 供应,22 6 指 Gloss, 供应 指 1Visco,overnight, 1Lacper®2333465Surfynol1046CP4-17TegoAirex8Vesmody1Lacper®23334BYK56
哑光Mat66TegoAirex7VesmodyTM,8Lacper®9WanhuaWB1K:Lacper®优异的抗粘连GoodSprayonblackwalnutveneer,110g/m2,1layer.Pressure0.33kg/cm2,stack@50°C,4h.136Lacper® Lacper®4500/4210 WanhuaWB1K:Leasys®Leasys®5530非常适合用 Leasys®5530is Veryfineparticlesize,<30nm,goodpermeabilitytoGoodcompatibilitywithWanhuaWB2Ksystem:Hydrophilicallymodifiedpolyisocyanatebasedon
WB2KsolutionofFixedNCO/OH,complexrecipedesignmixingonHighHighlevelofhardenerneeded,highHighpriceSlowSlowdrying,lowproductionFastWanhuaWB2Ksystem:A组份BindersforAMFFT,Lacper®PUDOutstandingstackability,Lacper®Styrene-acrylatecopolymerFastdrying,goodLacper®
Acrylicemulsion,self-
,goodadhesionondifficultLacper®Lacper® Acrylicemulsion,self- LowVOCpossible,B组份 HardenersforB NCO, HydrophilicallyHydrophilicallymodified,polyisocyanatebasedon Excellentwaterdispersion,
Hydrophilicallypolyisocyanatebasedon
Fastdrying,excellentwaterdispersion,economical,TDIfreeWanhuaWB2KALacper® Lacper®ALacper® Lacper®BAquolin®77freshDIN4,Gloss,visco35°C4h,DIN4,Gloss35°C4h,PencilABPencil2K,FFPencil2K,after35°CFFFastImproveImproveImproveSealingVeryeasytomixbyLongpotWanhuaWB2Ksystem:Mapleveneer,spraysealer,80g/m2,drying35°C0.5h,spraytop,80g/m2干燥35°C1h,Drying35°C1h, Drying35°C1h,23°C7day, Lacper® Lacper®43167%Aquolin®WanhuaWB2Ksystem:Hardness&
0Lacper® Lacper®4316+7%Aquolin®100umwetfilmonglass,ageing@23°C可使用时Longpot35°C4h,粘度没有变化;底部没有沉淀。ViscokeepsthesameandnosettlingKeepthesealingpropertytotannin-acid35°C4h,对木塑基材保持一定的附着力。Keeptheadhesiontoplastic-可使用时间取决于具体的指标要求 2K体系35°C4h的沉淀比较。左:Lacper®4316,右:Lacper®Thesettlingof2Ksystemafter35°C4h.Left:Lacper®4316,right:Lacper®WanhuaWB2KSealer:IsolationLacper®4316+Aquolin®WithoutLacper®4316Aquolin®296WithoutLacper®4316Aquolin®296Lacper®4316Aquolin®2964hWithoutLacper®4400Aquolin®296Lacper®4400Aquolin®2964h
基材及工艺:SubstrateandMapleveneer,P240sanding,spraytannin-acidwatersolution,封闭清漆,60-70g/m2,40°C30min,喷一道白面漆Spray2Ksealer,60-70g/m2,drying@40°C30min,spraywhitetop.评估70°Covernight,checkbleeding.结论35°C4h的放置使得2K体系对单宁酸的Thesealingpropertyisdecreasedaafter35°C4h.Lacper®4316asApartisWanhuaWB2KSealer:Isolation柏木Chinese WanhuaWB2KSealer:IsolationLacper®4500+Aquolin®
(DIN4s)随时间(h)的变ViscositychangewithLacper®4500Aquolin®Lacper®4500Aquolin®Without基材及工艺:SubstrateandMapleveneer,P240sanding,spray2.Spray2Ksealer,60-70g/m2,drying@30min,spraywhite评估70°Covernight,checkbleeding.A%Lacper®22B%Aquolin®2687642001234567 WanhuaWB2KAquolin®268在2K中的应用ApplicationofAquolin®268in2Ksystem:TypicalAquolin®Solids,Viscosity63#12r,cPViscosity62#50r,cP25°C80%solidinMPAParticlesizeinwater1, DilutethehardenerbyMPAto80%solid,andthenmixbyinwater.Hardenersolutiontowater,1:10by
Lacper®4210+Aquolin®268WetfilmWanhuaWB2K &在Lacper®4210清漆中加入 剂。Add5%hardenerinLacper®4210Aquolin®268具有更优异的分散性。BetterdispersionforAquolin® and80%80%Mixby-535355532Gloss20°/60°,--Particlesizein2K,-BFF-Water,555-50%,355-Acetic 30%, ,5%,555-Case:Add5%Aquolin®268/MPA80%inLacper®4210lacquer.Water atRTisincreasedfrom5daysto7daysonwood-plasticWanhuaWB2KTop:TheadhesionofWanhua2KtoponUV/PU/PVCisperfect.OnOnPVC,whiteLacper®4210+Aquolin®268(2%toOnpine+PU,clearLacper®4210+Aquolin®268(5%to
Onbirch+UV,mattop,glossLacper®4400+Aquolin®268(5%toWanhuaWBUV:Solids,Urosin®7.0-Multicoatortopforpanelfurniture,kitchenUrosin®7.0-Highgloss,multicoatortopforpanelfurniture,kitchenUrosin®6-Adhesionandstainsealerforfloorandfurniture.Byrollerandmoose橱柜Kitchen 地板WanhuaWBUV:Urosin®无APEONMPAPEO,NMP,Organic-tinGoodmattingagentarrangement,highmatting DustfreebeforeUV Urosin® Gloss60°, ,555550%,5533,555550%,5533 4%, 15555PencilH5555Finenessofthemat/5/3FilmbeforeUVdustdust :keepthemetalcupwithboilingwateronthefilmwithandwithoutwater,15min.WanhuaWBUV:Urosin®Highgloss,mirrorRawRaw%r1234BYK5TegoAirex6Iragcure7VesmodyTM8LaponiteS048210%in,9VesmodyTM12Gloss,PC+ABS,Lacper®4210assealer,Urosin®4695astopGlossPC+ABS,Lacper®4210assealer,Urosin®4695aswhitetopGloss60°/20°94%/87%WanhuaWBUV:底面合一施工工艺:Multicoat基材打磨P240。Woodsanding喷涂第一道,80-90g/m2。Spray1stlayer,80- ,50%能量,≥400mJ/cm2。Flashoff,1min,50°C,15min,2*Hgcuring,50%energy,≥400mJ/cm2.底漆打磨P320。Sanding喷涂第二道,80-90g/m2。Spray2ndlayer,80- ,50%能量,≥400mJ/cm2。Flashoff,1min,50°C,15min,2*Hgcuring,50%energy,≥400mJ/cm2.下线。StackandWanhuaWBUV:Urosin®Urosin®Urosin®4632isanaliphaticurethaneacrylatedispersiondesignedforfloorandfurniturewithoutstandingwoodwetting,highflexibilityandhardness.Ithasgoodcompatibilitywithpigmentsanddyes.Forfloor:adhesionForFurniture:stainFloor
MooseWanhuaWBUV:Urosin®StabilityofCompetitorUros
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