讲义教案202110测样黑胡椒

1、色谱图 F:20150330测样黑胡椒.qgdTIC572,38610.020.030.040.050.060.070.080.0min峰表 TIC 峰面积%峰号1234567891011121314151617181920212223242526272829303132333435363738394041424344454647484950515253545556575859保留时间2.8843.5583.6254.7765.3808.39710.18310.31710.70610.97518.21719.24219.43229.45831.19231.77532.08333.41134.7

2、5034.90036.18338.24138.28940.53341.48741.55841.70742.93343.30844.24444.51144.94846.01749.70051.05352.96753.62553.75054.06654.21254.30854.54257.98358.33359.48860.44160.62562.98364.47564.80567.09167.65073.04274.63275.12575.85076.30076.53978.548I.Time 2.8503.5173.5834.7335.1678.28310.09210.20810.44210.

3、95818.10019.22519.40829.43331.17531.72532.00833.37534.66734.77536.16738.11738.25840.39241.29241.54241.65042.90843.18344.18344.49244.91746.00049.68350.95052.95053.60853.73354.01754.09254.27554.52557.96758.31759.39260.32560.60862.96764.45864.62566.93367.63373.02574.55875.10075.83376.28376.49278.400F.T

4、ime 2.9333.5833.6584.8335.4178.44210.20810.44210.72511.10018.24219.40819.54229.64231.30031.94232.10033.51734.77534.91736.38338.25838.44240.55841.54241.65041.84242.99243.32544.27544.75845.12546.22549.80051.11753.17553.73353.97554.09254.27554.52554.73358.23358.46759.60860.57560.76763.19264.62564.83367

5、.11767.89273.19274.65075.31775.95876.49276.63378.575峰面积17086802415477160731643612362730810396111198370839611856854712744643310358564210196793679536048290324468110924193011556537019594684147586103671041388947927971913138558013529550683791397568691385694727657148267474138886752680271971198683545705863

6、7613210633777711039峰高峰高% 7.683.065.664.691.571.461.530.801.161.611.050.871.341.760.821.020.831.551.341.000.834.054.781.251.831.743.711.751.601.551.061.781.301.111.201.401.071.431.641.121.241.061.151.231.041.381.021.260.980.991.081.021.201.241.241.070.851.171.33积/高度1.712.012.102.638.066.493.669.997.3

7、33.996.1210.484.905.546.007.785.215.054.556.115.615.507.176.718.086.857.652.614.043.767.524.505.275.506.237.193.997.252.585.728.684.999.235.925.638.255.638.455.315.255.139.055.323.535.334.399.555.086.38标记名称2.521.182.282.372.421.821.081.531.641.231.241.751.261.880.951.530.831.501.171.170.894.286.581.

8、612.842.295.450.881.241.121.531.531.311.171.431.940.821.990.811.232.061.012.041.401.132.181.102.050.991.001.061.771.230.841.270.901.571.151.6310004398473726116204019051995104115162097137111311743230010731332108320201744130110795280622916292389227148362280208420161379231516881441156018281397186521311

9、4651610137615021600136017971328164412711295140413251570161516201396111315301731VV VVVVVVV VV V VV V VV2.8843.5652854.7765.3808.39710.31187310.79076518.21719.443229.45831.192321.07873533.41134.9705036.18338.28190.533411.45785078723.3303844.5214144.94846.0179.70051.05352.96753.6702565064.523102858.383

10、359.48860.64245162.98364.4870567.09167.65073.04275.1322576.35006.5398.54881.992峰号 保留时间6081.992I.Time 81.967F.Time 82.175峰面积 峰面积% 92431.36678954 100.00峰高1900130317峰高% 积/高度 标记 名称1.464.86100.00谱库行号#:1保留时间:2.883(扫描数#:47)质量峰:168原始模式:平均 2.875-2.892(46-48)背景模式:峰校准 组 1 -1基峰:93.05(2446)1009377411211056713640

11、147161181202 213233245 2542662943133283392821030507090110130150170190210230250270290310330命中#:1 输入:9602 谱库:NIST05.LIBSI:91式:C10H16 CAS:80-56-8 摩尔质量:136 保留指数:948组分名称:.alpha.-Pinene $ Bicyclo3.1.1hept-2-ene, 2,6,6-trimethyl- $ 2-Pinene $ Pinene $ 2,6,6-Trime10093774112127105536713610305070901101301501

12、70190210230250270290310330命中#:2 输入:9603谱库:NIST05.LIBSI:91式:C10H16 CAS:7785-70-8 摩尔质量:136 保留指数:948组分名称:1R-.alpha.-Pinene $ 1R-.alpha.-Pinene $ Bicyclo3.1.1hept-2-ene, 2,6,6-trimethyl-, (1R)- $ 2,10093771214167105136271030507090110130150170190210230250270290310330命中#:3 输入:9601 谱库:NIST05.LIBSI:90式:C10H

13、16 CAS:7785-26-4 摩尔质量:136 保留指数:948组分名称:1S-.alpha.-Pinene $ 1S-.alpha.-Pinene $ (-)-.alpha.-Pinene $ L-.alpha.-Pinene $ Bicyclo3.1.110093774112127105671361030507090110130150170190210230250270290310330命中#:4 输入:6319 谱库:NIST05s.LIBSI:90式:C10H16 CAS:488-97-1 摩尔质量:136 保留指数:729组分名称:Tricyclo2.2.1.0(2,6)hept

14、ane, 1,3,3-trimethyl- $ Cyclofenchene $1009379391212710513653651030507090110130150170190210230250270290310330命中#:5 输入:6320谱库:NIST05s.LIBSI:90式:C10H16 CAS:80-56-8 摩尔质量:136 保留指数:948组分名称:.alpha.-Pinene $ Bicyclo3.1.1hept-2-ene, 2,6,6-trimethyl- $ 2-Pinene $ Pinene $ 2,6,6-Trime1009377392712153105671361

15、030507090110130150170190210230250270290310330行号#:2保留时间:3.558(扫描数#:128) 质量峰:154原始模式:平均 3.550-3.567(127-129)背景模式:峰校准 组 1 -1基峰:93.10(1031)1009377411366953107121148156176 186203222 235 249279 29034630232020406080100120140160180200220240260280300320340命中#:1 输入:9576 谱库:NIST05.LIBSI:79式:C10H16 CAS:99-84-3

16、摩尔质量:136保留指数:993组分名称:Cyclohexene, 4-methylene-1-(1-methylethyl)- $ p-Mentha-1(7),3-diene $ .beta.-Terpinen $ .beta.100937713641121105436920406080100120140160180200220240260280300320340命中#:2 输入:9568 谱库:NIST05.LIBSI:78式:C10H16 CAS:3387-41-5 摩尔质量:136 保留指数:897组分名称:Bicyclo3.1.0hexane, 4-methylene-1-(1-me

17、thylethyl)- $ 4(10)-Thujene $ Sabinen $ Sabinene $ (10093417727694313612110520命中#:3 SI:78406080100120140160180200220240260280300320340输入:9577 谱库:NIST05.LIB式:C10H16 CAS:28634-89-1 摩尔质量:136 保留指数:873组分名称:Bicyclo3.1.0hex-2-ene, 4-methyl-1-(1-methylethyl)- $ 2-Thujene $ .beta.-Thujene $ 1-Isopropy1009377

18、136416812110720406080100120140160180200220240260280300320340命中#:4 输入:9578 谱库:NIST05.LIBSI:78式:C10H16 CAS:555-10-2 摩尔质量:136 保留指数:964组分名称:.beta.-Phellandrene $ Cyclohexene, 3-methylene-6-(1-methylethyl)- $ p-Mentha-1(7),2-diene $ Ph100937713641276512110720406080100120140160180200220240260280300320340命

19、中#:5 输入:6299谱库:NIST05s.LIBSI:77式:C10H16 CAS:555-10-2 摩尔质量:136 保留指数:964组分名称:.beta.-Phellandrene $ Cyclohexene, 3-methylene-6-(1-methylethyl)- $ p-Mentha-1(7),2-diene $ Ph100937741136276512110520406080100120140160180200220240260280300320340行号#:3保留时间:3.625(扫描数#:136) 质量峰:163原始模式:平均 3.617-3.633(135-137)基

20、峰:93.05(1736)背景模式:峰校准 组 1 -110093416977121 1365310740156169189197222 236254 266290308 3223401030507090110130150170190210230250270290310330命中#:1 输入:9564谱库:NIST05.LIBSI:89式:C10H16 CAS:18172-67-3 摩尔质量:136 保留指数:943组分名称:Bicyclo3.1.1heptane, 6,6-dimethyl-2-methylene-, (1S)- $ 2(10)-Pinene, (1S,5S)-(-)- $

21、(-)-.bet1009341697912127136531071030507090110130150170190210230250270290310330命中#:2 输入:6289谱库:NIST05s.LIBSI:89式:C10H16 CAS:127-91-3 摩尔质量:136 保留指数:943组分名称:.beta.-Pinene $ Bicyclo3.1.1heptane, 6,6-dimethyl-2-methylene- $ 2(10)-Pinene $ Nopinen $ N100934169792753121 136107103050709011013015017019021023

22、0250270290310330命中#:3 输入:6288谱库:NIST05s.LIBSI:87式:C10H16 CAS:127-91-3 摩尔质量:136 保留指数:943组分名称:.beta.-Pinene $ Bicyclo3.1.1heptane, 6,6-dimethyl-2-methylene- $ 2(10)-Pinene $ Nopinen $ N1009341697727531211361071030507090110130150170190210230250270290310330命中#:4 输入:6297谱库:NIST05s.LIBSI:87式:C10H16 CAS:18

23、172-67-3 摩尔质量:136 保留指数:943组分名称:Bicyclo3.1.1heptane, 6,6-dimethyl-2-methylene-, (1S)- $ 2(10)-Pinene, (1S,5S)-(-)- $ (-)-.bet1009341697912127531361071030507090110130150170190210230250270290310330命中#:5 输入:9565谱库:NIST05.LIBSI:86式:C10H16 CAS:127-91-3 摩尔质量:136 保留指数:943组分名称:.beta.-Pinene $ Bicyclo3.1.1hep

24、tane, 6,6-dimethyl-2-methylene- $ 2(10)-Pinene $ Nopinen $ N1009341697727531211361071030507090110130150170190210230250270290310330行号#:4保留时间:4.775(扫描数#:274) 质量峰:171原始模式:平均 4.767-4.783(273-275)背景模式:峰校准 组 1 -1基峰:68.00(1052)100689341791361215310740146209230251275 284335157 170184262301320103050709011013

25、0150170190210230250270290310330命中#:1 输入:9535 谱库:NIST05.LIBSI:88式:C10H16 CAS:5989-27-5 摩尔质量:136 保留指数:1018组分名称:D-Limonene $ Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (R)- $ p-Mentha-1,8-diene, (R)-(+)- $1006893791364112153107271030507090110130150170190210230250270290310330命中#:2 输入:6276 谱库:NIST05s.LI

26、BSI:87式:C10H16 CAS:5989-27-5 摩尔质量:136 保留指数:1018组分名称:D-Limonene $ Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (R)- $ p-Mentha-1,8-diene, (R)-(+)- $1006893417913653121271071030507090110130150170190210230250270290310330命中#:3 输入:6275 谱库:NIST05s.LIBSI:87式:C10H16 CAS:5989-27-5 摩尔质量:136 保留指数:1018组分名称:D-Lim

27、onene $ Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (R)- $ p-Mentha-1,8-diene, (R)-(+)- $1006893417953121 136107381030507090110130150170190210230250270290310330命中#:4 输入:9531 谱库:NIST05.LIBSI:86式:C10H16 CAS:0-00-0 摩尔质量:136 保留指数:934组分名称:Cyclobutane, 1,3-diisopropenyl-, trans1006893395312179271071361030

28、507090110130150170190210230250270290310330命中#:5 输入:9536谱库:NIST05.LIBSI:85式:C10H16 CAS:5989-54-8 摩尔质量:136 保留指数:1018组分名称:Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (S)- $ p-Mentha-1,8-diene, (S)-(-)- $ (-)-Limonene1006893392753791361211071030507090110130150170190210230250270290310330行号#:5保留时间:5.383(扫

29、描数#:347) 质量峰:173原始模式:平均 5.375-5.392(346-348)背景模式:峰校准 组 1 -1基峰:39.95(105)10040594916334325424626883 89102194 202122141176230305285320 3292194220406080100120140160180200220240260280300320340命中#:1 输入:94295谱库:NIST05.LIBSI:30式:C11H9Cl2NS2 CAS:55976-01-7 摩尔质量:289保留指数:2161组分名称:Benzothiazole, 2-(3,3-dichlor

30、o-2-methyl-2-propenyl)thio- $ 2-(3,3-Dichloro-2-methyl-2-propeny100254NS87123S218 Cl Cl1085116628969180782712714920620406080100120140160180200220240260280300320340命中#:2 输入:124226谱库:NIST05.LIBSI:28式:C17H13BrO3 CAS:340977-58-4 摩尔质量:344保留指数:2509组分名称:Benzoic acid, 4-3-(4-bromophenyl)-1-oxo-2-propenyl-,

31、methyl ester $ Methyl 4-(2E)-3-(4-bromop100265O344285102163O178209Br76O2661351835011731532940598920406080100120140160180200220240260280300320340命中#:3 输入:100547 谱库:NIST05.LIBSI:28式:C18H21NO3 CAS:0-00-0 摩尔质量:299保留指数:2645组分名称:2-(7-Ethoxy-6-methoxy-1,2,3,4-tetrahydro-isoquinolin-1-yl)-phenol100NHO 299OH

32、O7727039255915165107 11513615222528423920406080100120140160180200220240260280300320340命中#:4 输入:79374 谱库:NIST05.LIBSI:28式:C14H10Cl2O CAS:92153-01-0 摩尔质量:264 保留指数:2161组分名称:9-Anthracenol, 1,8-dichloro-9,10-dihydro- $ 1,8-Dichloro-9,10-dihydro-9-anthracenol# $100229246ClOHCl19426417621216526619915074876

33、31111231395020406080100120140160180200220240260280300320340命中#:5 输入:147765 谱库:NIST05.LIBSI:28式:C22H19Cl2NO3 CAS:97955-44-7 摩尔质量:415 保留指数:3036组分名称:Cyclopropanecarboxylic acid, 3-(2,2-dichloroethenyl)-2,2-dimethyl-, cyano(3-phenoxyphenyl)methyl100163OO181O91Cl77Cl51N12720841152651091912040608010012014

34、0160180200220240260280300320340行号#:6保留时间:8.400(扫描数#:709) 质量峰:178原始模式:平均 8.392-8.408(708-710)背景模式:峰校准 组 1 -1基峰:39.95(120)10040864113915969839855221225303204260 27028633511214324419016820406080100120140160180200220240260280300320340命中#:1 输入:2812 谱库:NIST05s.LIBSI:40式:C6H12N2 CAS:185-79-5 摩尔质量:112 保留指数:

35、1165组分名称:1,2-Diazaspiro(2.5)octane $ 3,3-Pentamethylenediaziridine $100415483NH2767111NH11220命中#:2 SI:40406080100120140160180200220240260280300320340输入:76926谱库:NIST05.LIB式:C12H21BrO CAS:31236-94-9 摩尔质量:260 保留指数:1868组分名称:2-Bromocyclododecanone $ Cyclododecanone, 2-bromo- $ .alpha.-Bromocyclododecanon

36、e $ 1-Cyclodod1009841551818169O27112260163Br18212620406080100120140160180200220240260280300320340命中#:3 输入:2819 谱库:NIST05s.LIBSI:40式:C6H12N2 CAS:185-79-5 摩尔质量:112保留指数:1165组分名称:1,2-Diazaspiro(2.5)octane $ 3,3-Pentamethylenediaziridine $10083NH111415467NH112282040608010012014016018020022024026028030032

37、0340命中#:4 输入:9396 谱库:NIST05s.LIBSI:40式:C10H18O CAS:16409-43-1 摩尔质量:154 保留指数:1114组分名称:2H-Pyran, tetrahydro-4-methyl-2-(2-methyl-1-propenyl)- $ 2H-Pyran, tetrahydro-4-methyl-2-(2-meth1006913941552783O8514010912115420命中#:5 SI:40406080100120140160180200220240260280300320340输入:16652谱库:NIST05.LIB式:C9H14O2

38、 CAS:40365-61-5 摩尔质量:154 保留指数:1141组分名称:2H-Pyran, 2-(3-butynyloxy)tetrahydro- $ 3-Butynyl tetrahydro-2H-pyran-2-yl ether # $10040558556OO839936115 12615320406080100120140160180200220240260280300320340行号#:7保留时间:10.183(扫描数#:923) 质量峰:181原始模式:平均 10.175-10.192(922-924)背景模式:峰校准 组 1 -1基峰:39.95(160)100405341

39、26029769195170132 14221131332979110231247290156852781030507090110130150170190210230250270290310330命中#:1 输入:77303谱库:NIST05.LIBSI:40式:C17H21Cl CAS:58241-05-7 摩尔质量:260 保留指数:1916组分名称:5,9-Methanobenzocyclooctene, 3-chloro-5,6,9,10-tetrahydro-5,7,8,9-tetramethyl- $ 1,3,4,5-Tetrame1004127245 26011553Cl7791

40、141191631281651051781030507090110130150170190210230250270290310330命中#:2 输入:55745 谱库:NIST05.LIBSI:39式:C14H28N2 CAS:55724-27-1 摩尔质量:224 保留指数:1675组分名称:Pentanal, 2,2-dimethyl-, (2,2-dimethylpentylidene)hydrazone $ (1E)-2,2-Dimethylpentanal (E)-2,2100412770N N139114168691828498140209103050709011013015017

41、0190210230250270290310330命中#:3 输入:120808 谱库:NIST05.LIB SI:38式:C11H17Br2NO CAS:0-00-0摩尔质量:337 保留指数:2083组分名称:Cyclopropanecarboxamide, 2,2-dibromo-1-methyl-N-cyclohexyl-10041555683HNO972301489813121336258Br178Br1601030507090110130150170190210230250270290310330命中#:4 输入:24560谱库:NIST05.LIBSI:37式:C9H14O3 C

42、AS:7500-91-6 摩尔质量:170 保留指数:1292组分名称:1-Methyl-2-oxocyclohexanecarboxylic acid, methyl ester $ Methyl1-methyl-2-oxocyclohexanecarboxy1004155OO6927O12783881701101141421551030507090110130150170190210230250270290310330命中#:5 输入:16652谱库:NIST05.LIBSI:37式:C9H14O2 CAS:40365-61-5摩尔质量:154 保留指数:1141组分名称:2H-Pyran, 2-(3-butynyloxy)tetrahydro- $ 3-Butynyl tetrahydro-2H-pyran-2-yl ether # $10040558556OO839936115 1261531030507090110130150170190210230250270290310330行号#:8保留时间:10.317(扫描数#:939) 质量峰:149原始模式:平均 10.308-10.325(938-940)背景模式:峰校准 组 1 -1基峰:39.95(118)10040443138221117718456911301231662603331412401073032