有机化学(下)完成反应式及答案

1、有机化学II总复习(一完成反应式 ( H+2C2H5CHCOOH ( HOOC CH=CHCHCOOH( COOHHOOC O( COOHCOOHC6H 5COONa +CH2CHCH2Br( ( +CO2Na CH2BrBr+CH3CH2CH2COOH Br2P OH-2( ( ( ( Pb(OAc4, I2CCl4( OOO( +25( COClO2N H NNaOHH2O+( +CH3NH2CH3OO( 25OCH3CH3O25( N OHLiAlH 4H 2O( H 3O +LiAlH 4(1(2OOClCOCl ( 24( 25H +CH 3CH=CHCH 2CH 2COC 2H 5

2、O( H +(CH 212COOCH 3 COOCH 3二 甲 苯 ( COOC 2H 5COCl(CH 3CH 22Cd( CH 3CH 2COCl (CH 32CuLiether( +OO C 2H 5MgBrH +/H 2O乙醚( H +/H 2OCN65 ( NaOC 2H 5CH 2COCH 2CH 3COOC 2H 5 +( COOC 2H 5OCH 3COOC 2H 5C 2H 5ONa+COOC 2H 5COOC 2H 5C 2H 5ONaOH -2H 2O( ( ( +CH 3CH 2NO 2CH 2=CHCOCH 3NaOCH 3( +2H 5COOC 2H 5C 6H 6

3、NaH( +CH 2CN (C 2H 5O2COC 2H 5ONa甲 苯( +CH 3OHCOOC 2H 5ether( ( CH 3CH 2CH 2COOC 2H 5LDA,THF 32 ( C 2H 5ONa NCCH 2COOC 2H 5CH 3COCH=CHPh( ( CH 3COCH 3CHOOH+ClCH 2CO 2C 2H 5NaOC 2H 5 OH /H ( OClCH 2COOC 2H 5KOC(CH 33t BuOH+( +( CHOBrCH 2COOC 2H 5Zn/C 6H 6+1.2.- ( C 2H 5OC(CH 24COC 2H 5O ONaOC2H 5(1(2N

4、aOC 2H 5BrC 2H 5OH - /H O( ( +( H 3O +( N HO对 甲 苯 磺 酸甲 苯ClCH 2CH=CH 2(1(2 ( NH OOKOH(sPhCH 2Br( ( 2OH -( H NH 2PhCCOBr 2 / OH( NH OO Br 2/OH( ( BrZn/OHH +( C 6H 5CONH 2PO ( ( CH 2CClO 33 ( ( (1(2CO 2H SOCl 2CH 2N 2Ag 2O H 2OH 2O( ( (1(2CH 2NHCOCH 3O 2N H 2/PtLiAlH 4( O CH 3CH 2NH 2 + ( 3+ ( OH CH 2N

5、H 2HNO 2( HCl2NaNO 2( 。CH 3COOCHCH 2CH(CH 3233500 C( ( 。500 C CH H D CH 3CH 2CCH 3COO CH 3CH 2CH 2CH N(CH 33OH CH 3( ( N(CH 33OHCH 3CH 3+( ( 。N(CH 322CH 3 3H 2O 2200 C( ( N HCH 332H 2O( +NClN CH 3ClHO 2 ( 32H 5CH 3 ( CO 2CH 3CO 2CH3.CH 3O 2( ( ( 32H5+ CH 2N 2CH 3OCOC CCOOCH 3( + ( +ONCH 2=CHCOOCH3 (

6、 ( HOOC 2H 5 ( CH=CH2CH 2 ( +OCH 3CH 3C C CH 3OOC COOCH 3( ( +SHCHO 2+( COOH SBr 2CH 3CO 2H 25 Co( SH 2SO 425 C。+( NN CH 3IH( (1(2N CH 3CH 3NaNH 2PhCOCl( N24HNO 3( H 3O +( CH 3N C 6H 5LiOCHO( ClClNCH 3ONa CH 3OH, ( ( NCH 3CH 2=CHCN( ( 25NH 2NNaNO 2,HClCuBrCH 2(COOC 2H 52H +O ( OCHONCCH 2COOC 2H 5CH

7、3COONH 4+NCH 3CCH 3O NaNH ( +( HH OH OH CH 2OH 2OHOPhNHNH 23( 3 33CH 333H 3O +( +( HH OH OH CH 2OH 2OHO Ag(NH 32+( ( NaBH 4CH 3COCH 3 HCl有机化学II 总复习(一完成反应式解答H +2C 2H 5CHCOOHOOO OC2H 5C 2H 5 HOOC CH=CHCHCOOHO O OCOOHHOOCOHOOCO COOHCOOH O C 6H 5COONa +CH 2CHCH 2BrC 6H 5COOCH 2CH=CH 2 +CO 2Na CH 2BrBr C

8、H 2OCBrO+CH 3CH 2CH 2COOH Br 2POH -H 2OCH 3CH 2CHCOOHBrCH 3CH 2CHCOOHOHPb(OAc4, I 2 4O O O+25O OOC 2H 5OHOC 2H 5OOOC 2H 5COCl O 2NH NH 2O+NC OO 2N+CH 3NH 2CH 3OOCH 3ONHCH 3OH25OCH 3CH 3O25CH 3CH 3OOH OC 2H 5N OHLiAlH 4H 2ON HH 3O LiAlH 4(1(2OOCH 2OHCH 2OH24ClCOCl CHOCl25+CH 3CH=CHCH 2CH 2COC 2H 5OCH

9、 3CH=CHCH 2CH 2CH 2OHH +(CH 212COOCH 3 COOCH 3二 甲 苯(CH 210OOH COOC 2H 5COCl(CH 3CH 22CdCOOC 2H 5COCH 2CH 3CH 3CH 2COCl(CH 32CuLietherCH 3CH 2COCH 3+OO C 2H 5MgBr+2HOCH 2CH 2CH 2CH 2CC 2H 5OHC 2H 5H +/H 2OCN65CONaOC 2H 5CH 2COCH 2CH 3COOC 2H 5OOCH 3+COOC 2H 5OCH 3COOC 2H 5C 2H 5ONaCOCH 2COOC 2H 5O+CO

10、OC 2H 5COOC 2H 5C 2H 5ONaOH -2H 2OOH 5C 2OOC OO COOC 2H 5 +CH 3CH 2NO 2CH 2=CHCOCH 33CH 3CHCH 2CH 2CCH 3NO 2O+O2H 5COOC 2H 566OCOCOOC 2H 5+CH 2CN (C 2H 5O2COC 2H 5ONa甲 苯CHCOOC 2H 5CN+CH 3OHCOOC 2H 5etherCH 3OCHOCH 3CH 2CH 2COOC 2H 5LDA,THF 32CH 3CH 2CHCOOC 2H 5Li +CH 3CH 2CHCOOC 2H 5CH 2CH 325NCCH 2

11、COOC 2H 5CH 3COCH=CHPhNCCHCOOC 2H 5CHCH 2COCH 3CH 3COCH3CHOOH+ClCH 2CO 2C 2H 5NaOC 2H 5OH /H CH 3OCH 3OCOOC 2H 5CH 3CHO OClCH 2COOC 2H 5KOC(CH 33t BuOH+OCOOC 2H 5+CHOBrCH 2COOC 2H 5Zn/C 6H 6H +1.2.-CH=CHCOOH C 2H 5OC(CH 24COC 2H 5O ONaOC 2H 5(1(2NaOC 2H 525OH -/H O CO 2C 2H 5OCO 2C 2H 5OC 2H 5OC 2H

12、5 +H 3O +N HO对 甲 苯 磺 酸ClCH 2CH=CH 2(1(2NOCH 2CH=CH 2NH OOKOH(sPhCH 2Br2OH -N -K +O ON O OCH 2CH 2NH 2H NH 2PhC CO Br 2 / OHH PhCNH 2NH OO Br 2/OHNH 2COO -BrNO 2Zn/OHH +NHNHBrBrBrBr H 2NNH 2C 6H 5CONH 2P O C 6H 5CN 33CH 2CClO CH 2CH 2NHCOOCH 3 CO 2H2222H 2OCC HN 2O CH 2COOHH 2O(1(2CH 2NHCOCH 3O 2N H

13、2/PtLiAlH 4CH 2NHCOCH 3H 2N CH 2NHCH 2CH 3H 2NOCH 3CH 2NH2+NHCH 2CH 3 3+N CH 3Omannich reactionOH CH 2NH 2HNO 2OHCl2NaNO 2O。CH 3COOCHCH 2CH(CH 32C(CH 33500 CC=CH (CH 33CH CH(CH 32。500 CCH H D CH 3CH 2CCCH 3COOCH OCCH 3O H CH 3CH 2CCC=CCH 3CH CH 3H DCH 3CH 2CH2CH 33OH CH 3CH 3CH 2CH 2CH=CH 2 33OHCH 3

14、CH 3+CH 3CH 3。N(CH 32 2CH 33H O 200 CN(CH 32 2CH 3O -3+CH 2CH 3CH 3N HCH 332H 2ONCH 3CH 3CH 3+OH -N CH 3CH 3CH 3+NClN CH 3ClHO NaOH H 2OClHO N=NCH 3 32H 5CH 3 CH 332H 5CO 2CH 3CO 2CH 3.CH 3O 2( ( HHCO 2CH 3CO 2CH 332H 5+C 3CH 2N 2CH 3OCOCCCOOCH 3+N NCOOCH 3COOCH 3+ONCH 2=CHCOOCH 3NOCH 3OOCHOOC 2H 5H

15、OOC 2H 5OC 2H 5O CH=CH 2CH 2 +OCH 3CH 3C C CH 3OOC COOCH 3 333+SHCHO HCl/ZnCl 2SCH 2Cl+COOH SBr 2CH 3CO 2H25 CCOOHSBrSH 2SO 425 C。SSO 3H+NN CH 3IHN N HCH 3I -+(1N 3CH 3NaNH 2PhCOClNCH 2COphCH 3N 24HNO 3NNO 2NNO 2+H 3O +CH 3NC 6H 5LiOCHONCH=CHONCH 2CHOOLiClClNCH 3ONa CH 3OH,Cl NOCH 3 NCH 3RLiCH 2=CHCNN CH 2Li NCH 2CH 2CH 2CN25NH 2NNaNO 2,HClCuBrCH 2(COOC 2H 52H +OBrNCH 2COOHN OCHONCCH 2COOC 2H 534OCH=CCN COOC 2H 5+NCH 3CC H 3