有机化学一试题及答案答案借鉴

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6、183;··················线·························菏泽学院制药工程系2011级2011-2012学年第二学期制药工程专业有机

7、化学试卷（a）参考答案及评分标准（110分钟）题 号一二三四五总 分得 分阅卷人 得 分阅卷人一、 用系统命名法命名下列化合物或写出下列物质的结构（每小题1分，共10分）1、 2、 3、 （2r,3s）-2-羟基-3-氨基丁酸 （s）-4-甲基-5-己烯-2-醇 2-甲基-1，4-戊内酯4、 5、反十氢化萘的稳定构象式 6、6-甲基-吡啶-3-甲酸 7-甲基二环2.2.1-1-庚烯7、-萘乙酸 8、n,n-二甲基-对甲苯胺 9、偶氮苯磺酸钠 10、-d-吡喃葡萄糖的haworth式得 分阅卷人二、选择题（每题2分，共20分）( d )1、组成萜类化合物的结构单元是a. 丙二烯 b. 甲基 c.

8、 乙烯基单元 d. 异戊二烯单元( a )2、乙醇的1h核磁共振谱有几组峰a. 3 b. 2 c. 1 d. 5( b )3、下列化合物中与氢氧化钠水溶液最易反应的是a. 对氯乙苯 b. 苯甲酰氯 c. 间溴甲苯 d. 对氯甲苯( c )4、在甲基溴的sn2取代反应中，反应活性最强的离子是a. ch3coo- b. ho- c. c2h5o- d. c6h5o-( d )5、肥皂溶于热水中，冷却并用盐酸中和，最后得到的沉淀物可能是a. 氯化钠 b. 苯甲酸钠 c. 苯甲酸 d. 硬脂酸( a )6、碱性最强的化合物是a. 甲胺 b. 丁二酰亚胺 c. 乙酰胺 d. 苯胺( b )7、根据h&#

9、252;ckel规则判定具有芳香性的物质是a. 4h-吡喃 b.吡啶 c. 哌啶 d. 1,4-环己二烯( c )8、属于碱性氨基酸的是a. hoch2ch(nh2)co2h b. ho2cch2ch(nh2)co2h c.h2n(ch2)4ch(nh2)co2h d. ch3ch(nh2)co2h( c )9、下列构象式中最稳定的是 ( d )10、不能用无水氯化钙干燥的是a. 苯 b. 环己烷 c. 石油醚 d. 乙醇得 分阅卷人三、完成反应方程式（每小题3分，共30分）1、2、3、4、5、6、 7、·······

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15、;···········线·························8、 苯9、10、得 分阅卷人四、完成下列转化（每小题6分，共30分）1、由苯为原料合成对羟基乙酰苯胺（扑热息疼）：- ···

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