生物质资源化学利用学术研讨会论文集-封面与.pdf

The Proceedings of International Conference on Chemical and Biological Utilization of Biomass Resources 2010 (ICCUB 2010) Nanjing, China, 22 -26 October Organized by Chinese Society of Forestry Institute of Chemical Industry of Forest Products， CAF Nanjing Forestry University PREFACE With fossil resource being exhausted and environmental problems concerned by people, the research and development on utilization of biomass resource has been paid more attention to by many scholars all over the world. Therefore, International Conference on Chemical and Biological Utilization of Biomass Resources 2010 (ICCUB) will be held from Oct 22 to Oct 26, 2010, in Nanjing, China. It is hosted by Chinese Society of Forestry and undertaken by Institute of Chemical Industry of Forest Products (ICIFP), Chinese Academy of Forestry (CAF) and Nanjing Forestry University (NFU). One of its objectives is to explore R&D progress of the related fields, e.g., bio-energy, bio-materials, bio-chemicals, tree extracts and secretions, etc. The second objective is to explore the ways to exploit green energy and develop cyclic economy. Till the publication of this proceedings, we have received 140 paper abstracts and 125 full-text papers. Among them, 37 papers is on bio-energy development that mainly includes technology of biomass alcohol, treatment of biomass materials, technology of bio-diesel, biomass gasification for power generation, solid briquette fuel and preparation of bio-oil. 62 papers is on bio-materials and bio-chemicals that mainly include activated carbon and new carbon materials, biodegradable polymer and plastics, lingo-cellulosic materials, utilization of lignin and high additional valuable chemicals of bio-resources, etc. 26 papers is about tree extracts and secretions that mainly include rosin and turpentine, terpenes, modern extraction technology, nature fine oil and pigment, plant poly-phenol etc. Meanwhile, the Conference Committee specially invites more than 20 famous international experts and scholars. They are from USA, Japan, Korea, Greece, New Zealand, France, Egypt, Finland, Latvia, etc. The domestic scholars come from Southeast University, Beijing Forestry University, Northeast Forestry University, Guangxi University, Chinese Academy of Forestry, Nanjing Forestry University, etc. They will present their recent R&D progress during the conference. We are hoping that the international communication and cooperation no matter at academic level or industrial lever will be prompted through this event. In order to embody the experts and scholars R&D progress on the chemical and biological utilization of biomass, and prompt the scientific improvement and development on biomass chemical utilization, we compile and publish a proceedings which includes all the abstracts submitted to the conference committee, as well as a CD which consists of the full-text papers commented by the domestic scientific committee. We also wish that they may have some helpful information for your future professional works. Jian-chun Jiang Organizing Committee Chairman October 1, 2010 i ACKNOWLEDGEMENTS The International Conference on Chemical and Biological Utilization of Biomass Resources (ICCUB2010) would not be possible without the kind assistance and support from a number of persons and organizations. I must express my sincerest appreciations to Chinese Society of Forestry, Institute of Chemical Industry of Forest Products (Chinese Academy of Forestry), and Nanjing Forestry University for their full supports, including foreign affairs, monetary and in other forms, to organize the conference. My appreciations also go to all the plenary and Keynote speakers as well as Sessions chairs for their contributions. A number of reviewers who helps tireless with the abstract and manuscript review and revision processes are also gratefully acknowledged. They are Prof. Cheng-zhang Wang, Prof. Fei Wang, Prof. Gui-gan Fang, Prof. Guo-ming Xiao, Prof. Li-xin Huang, Prof. Shi-bing Shang, Prof. Shi-fa Wang, Prof. Song-lin Zuo, and Prof. Zhen-dong Zhao etc. These assistances are indeed heavily responsible for the technical success of ICCUB2010. I also thank all the authors who volunteered their precious time and expertise to make ICCUB2010 technically a major success. In particular, I thank Ms. Yu Wang, Mr. Wen Gu, Ms. Xing-yu Liang and Mr. Zhi-qing Cao for their helps with abstracts and manuscripts collection and formatting as well as the website () updating. My appreciations also go to a number of staffs and graduate students with their helps and hard work to organize this event. Editor, Book of ICCUB 2010 ii iii Conference Committee Chairman: Prof. Hou-min Chang North Carolina State University USA Prof. Zhan-qian Song Academician of China Engineering Academy China Prof. Shi-yuan Yu Nanjing Forestry University China Members: International ( In Frist Name Alphabetical Order) Prof. Akihiko Kondo Kobe University Japan Prof. Alan W Rudie Forest Products Laboratory USA Prof. Antje Spiess RWTH Aachen University Germany Dr. Chuan-bing Tang University of South Carolina USA Prof. Hiroyuki Wariishi Kyushu University Japan Prof. Jean-claude Sigoillot Provence University France Dr. Jie Song University of Michigan-Flint USA Prof. Jin-Suk Lee Korea Institute of Energy Research Korea Prof. Leandors Skaltsounis University of Athens Greece Prof. LiisaViikari University of Helsinki Finland Prof.M.F.Ramadan Hassanien Zagazig University Egypt Prof. Ryuichiro Kondo Kyushu University Japan Prof. Shu-sheng Pang University of Canterbury New Zealand Prof. Takuya Kitaoka Kyushu University Japan Prof. Daisuke Tatsumi. Kyushu University Japan Dr. Wei-hong Yang KTH Royal Institute of Technology Sweden Domestic Prof. Fu-xiang Chu Chinese Academy of Forestry China Prof. Fei Wang Nanjing Forestry University China Prof. Gui-zhen Fang Northeast Forestry University China Prof. Guo-min Xiao Southeast University China Prof. Jian-chun Jiang Institute of Chemical Industry of Forest Products CAF China Prof. Jian-xin Jiang Beijing Forestry University China Prof. Long-long Ma Guangzhou Institute of Energy Conversion CAS China Prof. Run-cang Sun South China University of Technology China Prof. Shao-jun Ding Nanjing Forestry University China Prof. Xi-feng Zhu University of Science and Technology of China China Prof. Xi-qun Jiang Nanjing University China Organizing Committee ICCUB2010 is sponsored by Chinese Society of Forestry and organized by Institute of Chemical Industry of Forest Products Chinese Academy of Forestry and Nanjing Forestry University. Chairman: Mr. Liang-ping Zhao The Secretary-General of Chinese Society of Forestry China Co-Chairman: Mr. Gui Sheng The Deputy Secretary-General of Chinese Society of Forestry China Prof. Jian-chun Jiang Institute of Chemical Industry of Forest Products CAF China Prof. Jian-guo Hong Nanjing Forestry University China Members: ( In Frist Name Alphabetical Order) Prof. Chun-peng Wang Institute of Chemical Industry of Forest Products CAF China Prof. Cheng-zhang Wang Institute of Chemical Industry of Forest Products CAF China Prof. Fei Wang Nanjing Forestry University China Prof. Gui-gan Fang Institute of Chemical Industry of Forest Products CAF China Prof. Jian-bin Zhou Nanjing Forestry University China Prof. Li-xin Huang Institute of Chemical Industry of Forest Products CAF China Prof. Qiang Yong Nanjing Forestry University China Prof. Shi-bin Shang Institute of Chemical Industry of Forest Products CAF China Prof. Shi-fa Wang Nanjing Forestry University China Prof. Tao Zeng Nanjing Forestry University China Prof. Zhen-dong Zhao Institute of Chemical Industry of Forest Products CAF China Prof. Zhong-xiang Lin Nanjing Forestry University China iv CONTENTS Preface Acknowledgements Conference Committee Organizing Committee Session: Biomass Energy Biodiesel Synthesis from Nanometer Magnetic Solid Base Catalyst Peng-mei LV, etc. 1 Process Research on the Production of Renewable Liquid Fuel from Catalytic Cracking of Soybean Oil Jie CHEN, etc. 10 Utilization of Plants Oil and Its Prospects Ke LI, etc. 15 Purification of Polyunsaturated Fatty Acid from Jatropha Curcas L.Seed Oil by Urea Inclusion Compounds Wei LV, etc. 21 Study on Synthesis of Sucrose Esters- High Added Value Products of Bio-diesel Kui WANG, etc. 28 Reaction Mechanism and Impact Factors Analysis of Biodiesel Production by Transesterification Xiang-yu LI, etc. 34 Study on Pentose Production from Bamboo (Sinocalamus affinis) Chippings by Dilute Sulfuric Acid Hydrolysis Yan-fei YIN, etc. 41 Optimization of Poplar Wood Conversion by Sulfuric Acid Hydrolysis Shan-shan LIU, etc. 47 Influences of Benzylated Modification on Liquefaction Wood Catalyzed by Methanesulfonic Acid Jian JIAO, etc. 54 Production of Lactic Acid by Simultaneous Saccharification and Fermentation Using Steam Pretreated Lespedeza Stalks as Inexpensive Raw Materials Xiang QI, etc. 59 Speeding up the Production Standard Formulation of Forestry Biomass Briquetting Densification Fuel Fang ZHAO, etc. 68 Effect of Temperature on the Surface Free Energy and Its Polar Component of Poplar Wood-flour Chao-qun MEI, etc. 73 The Design Specifications of Stoves in Terms of the Forestry Biomass Solid Fuel Ya-zhuo ZHANG, etc. 80 Vacuum Paddle Fast Pyrolysis Reactor Design and Internal Heat Transfer Investigation Xu-sheng DENG, etc. 85 Preparation of Biodiesel Using Carbon Nanotubes Based Solid Acid Catalyst Xue-hai FAN, etc. 92 Kinetics of Transesterification Reaction Catalyzed by Solid Base in Fixed Bed Reactor Yang XIAO, etc. 102 Production of Bio-oil from Vacuum Pyroysis of Chinese Wheat Straw Lian WANG, etc. 110 Preparation of Mesoporous Solid Acid SO42-/ZrO2/MCM-41 and Its Catalytic Activity for Synthesis of Biodiesel Jing-jie ZHOU, etc. 118 Expression of Rhizopus oryzae Lipase for Biodiesel Production Zhi-lin LI, etc. 126 Development of Yeast Cell-surface Display Technology and Its Application in Biofuels Production Ye WANG, etc. 133 A Secreted Expression Vector Construction of -Glucosidase Gene and Its Expression in Picchia pastoris Lin-guo ZHAO, etc. 142 Cloning of a Gene Encoding Exoglucanase CBH II from Aspergillus niger and Its Expression in Picchia pastoris Hao NI, etc. 147 Construction Multiple Gene Copies of -glucosidase in Picchia pastoris and High-level Expression Using FM21 Medium Lin-guo ZHAO, etc. 152 Comprehensive Utilization and Application Technology of Biomass Energy Polygeneration Jian-bin ZHOU 158 Effects of Laccase on the Detoxification of Steam-exploded Corn Stover Prehydrolyzate and Ethanol Fermentation by Picchia stipitis CBS 5776 Jun-jun ZHU, etc. 165 Production of Biodiesel Fuel from Pistacia chinensis bge Seed Oil Using Immobilized Lipase Xun LI, etc. 172 Effect of Green Liquor Pretreatment on the Enzymatic Hydrolysis of Wheat Straw Ting HUANG, etc. 180 Effect of Green Liquor Pretreatment on the Enzymatic Hydrolysis of Cotton Stalks Wang-xia WANG, etc. 187 Effect of Acetic Acid Pretreatment on the Enzymatic Hydrolysis of Rice Straw Wang-xia WANG, etc. 194 Effect of Additive on Green Liquor Pretreatment of Loblolly Pine for Enzymatic Hydrolysis Shu-fang WU, etc. 201 Transesterification of Waste Oils to Biodiesel Using Brnsted Acid Ionic Liquid as Catalyst Shi-wei LIU, etc. 209 Generation and Transition of Liquefied Products from Cellulose in Phenol Hao FENG, etc. 215 High Consistency Enzymatic Hydrolysis of Steam-Exploded Corn Stover Jing YANG, etc. 222 Biomass to Hydrogen-Rich Syngas and Liquid Fuels through Thermochemical Processing Shu-sheng PANG 232 Sustainable Exploitation of Bamboo via Pyrolysis in the Presence of Super High Temperature Steam Efthymios, KANTARELIS etc. 238 Evaluation of Potential of Oil Palm Woods for Bioethanol Production Ryuichiro KONDO 252 Status and Perspectives of Bioenergy R&D in Korea Jin-Suk LEE, etc. 268 Session : Materials and Chemicals from Biomass pinene Isomerization Catalyzed by a Nanometer Aolid Superacid Chun-hua WU, etc. 281 Two-component Waterborne Polyurethane from Terpinene-maleic Ester Type Epoxy Resin Guo-min WU, etc. 287 Renewable Resource-based Composites of Thermoplastic Acorn Kernel and Polycaprolactone: Preparation and Properties Evaluation Shou-hai LI, etc. 295 Synthesis of Maleopimaric Acid Anhydride Polyamides and Their Characteristics of Curing Reaction Gui-fu LIN, etc. 305 Synthesis and Characterization of Acrylpimaric Amides Derivatives with Antibacterial Activities Jian LI, etc. 312 Crosslinking Kinetics of the Formation of Lignin Aminated Polyol Based Polyurethane Foam Shu-ping HUO, etc. 318 Research Progress on Synthesis and Application of p-Menthane-3,8-diol Li-zhi HE, etc. 324 Atomization and Drying Characteristics of Re-dispersible Glue Emulsion Using a Spinning Disk Atomizer Li-xin HUANG, etc. 329 Preparation of (-)-Abietic Acid from Mason Pine Pitch and Its Bioactivity Hong-jun LIU, etc. 336 Preparation and Structure Characterization of -Caryophyllene Alcohol from Mason Pine Pitch and Its Antitussive and Expectorant Effects Hong-Jun LIU, etc. 342 Study on the Properties of Bleached Chemi-mechanical Pulps from Poplar Wood Processing Residues as Furnishes for Offset Paper Yong-jun DENG, etc. 352 Synthesis of Uniform Mesoporous -Al2O3 Using Rosin-based Quaternary Ammonium Salt as a Directing Agent Peng WANG, etc. 357 Optimization of Novolac Resin Modified with Cashew Nut Shell Liquid by Response Surface Methodology Li-hong HU, etc. 362 Effects of Ion Implantation on Cellulase Producing Strain Trichoderma reesei Ning ZHANG, etc. 367 Preparation of Activated Carbon with Developed Mesoporous Structure from Camellia oleifera Shell by Water Vapor Gasification and Phosphoric Acid Modification Kang SUN, etc. 372 Preparation of Bamboo Activated Carbon and Its Application as Loader of Titanium Dioxide Dan-dan CUI, etc. 377 Pilot Experimental Statistics for Preparation of p-Cymene from Industrial Dipentene by Catalytic Dehydrogenation Liang-wu BI, etc. 382 Study on Abietic-type Acids in Rosin under Acidic Treatment Yan GU, etc. 387 The Preparation and Photocatalytic Activity of Zn2+-TiO2 /ACXin-cheng LU, etc. 393 Preparation and Properties of Rosinbased Waterborne Polyurethane Modified by Nano Zinc Oxide Xu XU, etc. 398 Application of Biorefinery in Pulp and Paper Industry and Its Future Development Kui-zhong SHEN, etc. 403 Effect of Morphologies of Polyaniline Doped by Sulfuric Acid on Isomerization and Hydration of -pinene Qing-ming JIA, etc. 410 Studies on Hydrogenation of Rosin by Using Nanoperticles Pd/SBA-15 as Catalysts Lu LI, etc. 415 Nanocellulose: Isolation, Characterization, and Capability of Technical Applications Biao HUANG, etc. 420 Cationic Polymerization of -Pinene with Keggin Silicotungstic Acid Catalyst Zu-guang LIU, etc. 425 Methoxylation of -pinene Catalyzed by Phosphomolybdic Acid Xing-dong YAO, etc. 432 A Novel Porous Carbon Foam Prepared from Liquefied Birch Sawdust Rui WANG, etc. 437 Nanocrystalline Cellulose Prepared from Softwood Sulfate Pulp via Ultrasonic Assisted Acid Hydrolysis Method Wei LI, etc. 442 Preparation of Microwave Absorbing Nickel-based Activated Carbon by Electroless Plating with Palladium Free Activation Bo-yang JIA, etc. 447 Synthesis and Characterization of Biodegradable Superabsorbent Resin Based on Flax Shive Cellulose and Acrylic Acid under Microwave Irradiation Li-juan WANG, etc. 453 Synthesis Monodispersed Nanocarbon Spheres by a Hydrothermal Approach Min LI, etc. 459 Synthesis and Characterization of Dehydroabietic-based Betaine Type Amphoteric Surfactant Yin-feng ZHAO, etc. 464 Synthesis of Carboxymethylcellulose Picric Acid Ester and Its Characterization Xiao-feng DAI, etc. 470 Synthesis of Nano-grade TiO2 Hollow Spheres Using Acid Catalytic Hydrolysis-Hydrothermal Method Qian ZHANG, etc. 475 A Bis-quaternary Ammonium Salt from Rosin and Its Application Zhi-jun CHEN, etc. 480 Preparation and Adsorption of in-situ Immobilized Casuarina Bark to Cr (VI) Shao-ping CHEN, etc. 487 Preparation of Low-AOX PAE Resin and Its Modification with Acrylic Acid Xiu-mei ZHANG, etc. 492 Synthesis and Application of Modified Epoxy Acrylic Resin in Papermaking Peng ZHOU, etc. 497 Chemical Modification of Wood Waste as Oil-absorptive Materials Yuan GAO, etc. 504 Effect of Nanocrystalline Cellulose on the Hydrophilic Property of Polysulfone Membrane Shuai LI, etc. 510 Study on Preparation of Alkali-lignin Polyurethane Film and Its Performance Xiao-li ZHANG, etc. 516 Response of Chemical Changes of the Wood Compositions to Heat-treatment Yao CHEN, etc. 522 XPS Determination of Nitrogen Forms in Larch and Urea-formaldehyde Resin Wood-based Panel Jin-sheng GOU, etc. 529 Research on Preparation of Flame Retardant Epoxy Containing-Phosphorus by Glycerol Di LI, etc. 536 Synthesis of New-type Chiral N-alkyl Nopinanamines Bing LIU, etc. 544 A Study on the Performance of Lignin-Modified Amino-Based Superplasticizers Zhen-yang LUO, etc. 553 Study on Technology of Furfural Preparation from Cornstalk Pentose Solution Ning-ning HE, etc. 566 Synthesis of Acetyl Vanillin Acetals Catalyzed by Solid Superacid Fei LIU, etc. 577 Synthesis and Characterization of Bornylene-sulfurdioxide Polysulfone Resin Zhen-hua WU, etc. 587 Study on Oleoresin-tapping and Essential Oil Components of Chinese Sweetgum A New Resource of Biomass Chemicals Tao ZENG, etc. 595 Catalytic Synthesis of Graphitic Porous Carbons from SucroseJian-xiao YANG, etc. 608 Synthesis and Anti-tumor Activities of a Novel Class of Dehydroabietylamine Derivatives Yong CHEN, etc. 614 Synthesis and Bacteriostatic Activity of Nitrogen-containing Derivatives of 2-hydroxy-3-pinanone Wang-wei AO, etc. 623 Deposition of Silver Nan