62.5g L氟环唑+85g L吡唑醚菌酯SE MSDS（Nufarm Australia公司）

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62.5gL氟环唑+85gL吡唑醚菌酯SEMSDS（NufarmAustralia公司）

CS:1.4.93Page:1MaterialSafetyDataSheet5ofInfosafeNo3NULOJuly2010ISSUEDbyNUFARMIssueDate:OperaFungicideProductNameClassifiedashazardous1.IDENTIFICATIONOFTHEMATERIALANDSUPPLIERProductNameOperaFungicideProductCode5189ProductTypeGroup3and11FungicideCompanyNameNUFARMAUSTRALIALIMITED.(ABN80004377780)Address103-105PipeRoadLavertonNorthVictoria3026AustraliaEmergencyTel.1800033498(24hrAustralia)Telephone/FaxNumberTel:+6139282-1000Fax:+6139282-1001RecommendedUseForthecontrolofabroadrangeoffungaldiseasesinwheat,barleyandoat/oatenhayasspecifiedintheDirectionsforUsetableonthelabel.OtherInformationThisMSDSdescribes,tothebestofourknowledge,thepropertiesoftheconcentratedproduct.Thephysicalpropertiesandsomeoftheassessmentsdonotapplytothepropertiesoftheproductonceithasbeendilutedforapplication.Acutehealtheffectsofthedilutedproductarelikelytobemuchlesssevere.2.HAZARDSIDENTIFICATIONHazardClassificationClassifiedashazardousHAZARDOUSSUBSTANCE.NON-DANGEROUSGOODS.HazardclassificationaccordingtothecriteriaofNOHSC.DangerousgoodsclassificationaccordingtotheAustraliaDangerousGoodsCode.RiskPhrase(s)ClassifiedashazardousR20/22Harmfulbyinhalationandifswallowed.R38Irritatingtoskin.R40Limitedevidenceofacarcinogeniceffect.R43Maycausesensitizationbyskincontact.R62Possibleriskofimpairedfertility.R63Possibleriskofharmtotheunbornchild.SafetyPhrase(s)S13Keepawayfromfood,drinkandanimalfeedingstuffs.S2Keepoutofreachofchildren.S36/37/39Wearsuitableprotectiveclothing,glovesandeye/faceprotection.S46Ifswallowed,seekmedicaladviceimmediatelyandshowthiscontainerorlabel.OtherInformationPoisonsScheduleS53.COMPOSITION/INFORMATIONONINGREDIENTSChemicalCharacterizationLiquidCASProportionNameIngredients175013-18-0Pyraclostrobin85g/L106325-08-0Epoxiconazole62.5g/LWater30-60%64742-94-5Solventnaphtha10-30%64742-94-5LiquidHydrocarbon10-30%-fattyalcoholethoxylate0-10%Otheringredients(non-hazardous)0-5%4.FIRSTAIDMEASURESInhalationRemoveaffectedpersontofreshairuntilrecovered.Ifsymptomsdeveloporpersist,seekmedicaladvice.IngestionRinsemouthandthendrinkplentyofwater.PrintDate:2/07/2010CS:1.4.93CS:1.4.93Page:2MaterialSafetyDataSheet5ofInfosafeNo3NULOJuly2010ISSUEDbyNUFARMIssueDate:OperaFungicideProductNameClassifiedashazardousSkinWashaffectedareasthoroughlywithsoapandwater.Removecontaminatedclothingandlaunderbeforere-use.EyeIfineyes,holdeyelidsopenandwashwithcopiousamountsofwaterforatleast15minutes.Seekmedicaladvice.FirstAidFacilitiesIfpoisoningoccurs,contactadoctororthePoisonsInformationCentre(Australia)on131126.AdvicetoDoctorTreatsymptomatically.Ifvomitingoccurs,solventandsurfactantspresentmaycausepulmonarypneumonitis.5.FIREFIGHTINGMEASURESSuitableExtinguishingMediaIfinvolvedinafire,theproductwillnotburn.Chooseextinguishingmediatosuittheburningmaterial.HazardsfromCombustionProductsIfinvolvedinafire,thedehydratedcomponentsmayemitoxidesofcarbon,oxidesofnitrogen,hydrogenchlorideandhydrogenfluoride.SpecialProtectiveEquipmentforfirefightersBreathableairapparatusshouldbewornwhenfightingafireinwhichthisproductisinvolved.EmergencyActionincaseofFireIfexposedtofire,keepcontainercoolbysprayingwithwater.OtherInformationSTOPFIREWATERFROMENTERINGDRAINSORWATERBODIES.6.ACCIDENTALRELEASEMEASURESSpillsDisposalContainspillandabsorbwithclay,sand,soilorproprietaryabsorbent(suchasvermiculite).Collectspilledmaterialandwasteinsealableopen-toptypecontainersfordisposal.PersonalProtectionForappropriatepersonalprotectiveequipment(PPE),referSection8.EnvironmentalPrecautionsPreventfromenteringdrains,waterwaysorsewers.Useearthenbundsorabsorbentbundingtopreventspreadingofspillage.7.HANDLINGANDSTORAGEPrecautionsforSafeHandlingDoNOTcontaminatedams,riversorstreams,oranyotherwaterbodieswithchemicalorusedcontainers.ConditionsforSafeStorageStoreintheclosed,originalcontainerinadry,coolwellventilatedareaoutofdirectsunlight.OtherInformationAlwaysreadthelabelandanyattachedleafletbeforeuse.8.EXPOSURECONTROLS/PERSONALPROTECTIONNationalExposureStandardsThemanufacturerofthesolventhasrecommendedanoccupationalexposurelimitof100mg/m3;15ppmTWA,astotalhydrocarbon.EngineeringControlsHandleinwellventilatedareas,generallynaturalventilationisadequate.PersonalProtectiveEquipmentWhenopeningthecontainer,preparingthesprayandusingthepreparedspraywearprotectivewaterproofclothing,elbow-lengthPVCgloves,waterresistantfootwearandfull-facepiecerespirator(orgogglesandhalffacepiecerespirator).Re-entryperiod:Donotentertreatedareauntilsprayhasdried.HygieneMeasuresAfteruseandbeforeeating,drinkingorsmoking,washhands,armsandfacethoroughlywithsoapandwater.Aftereachday’suse,washcontaminatedclothingandsafetyequipment.RequirementsConcerningSpecialTrainingCheckStateorTerritoryregulationsthatrequirepeoplewhousepesticidesintheirjoborbusinesstohavetrainingintheapplicationofthematerials.9.PHYSICALANDCHEMICALPROPERTIESFormLiquidAppearanceOffwhiteliquid.PrintDate:2/07/2010CS:1.4.93CS:1.4.93Page:3MaterialSafetyDataSheet5ofInfosafeNo3NULOJuly2010ISSUEDbyNUFARMIssueDate:OperaFungicideProductNameClassifiedashazardousOdourSlightaromaticodour.SolubilityinWaterDispersesinwater.SpecificGravity1.04VapourPressure0.01mPa@20CforepoxiconazoleandpyraclostrobinVolatileComponent50%Octanol/WaterPartitionCoefficientKowLogPis3.99(pH7)forpyraclostrobin;3.44(pH7)forepoxiconazole.FlammabilityNotflammableAuto-IgnitionTemperature475C10.STABILITYANDREACTIVITYChemicalStabilityStableundernormalconditions.HazardousReactionsKeepawayfromstrongoxidisingagents.HazardousPolymerizationHazardouspolymerisationisnotpossible.11.TOXICOLOGICALINFORMATIONToxicologyInformationNoharmfuleffectsareexpectediftheprecautionsonthelabelandthisMSDSarefollowed.InhalationBreathinginhighconcentrationsofvapoursoraerosolsofthismaterialmaycauseheadache,nausea,dizzinessandweakness.IngestionLowtoxicity.However,swallowinglargeamountsofconcentratemaycausenauseaandvomiting.SkinProlongedcontactwiththeconcentratemaycauseirritation.EyeWillirritatetheeyes.ReproductiveToxicityRegardedascausingdevelopmentaltoxicityinhumansbasedonstrongpresumptionfromstudiesonratsandrabbits.Possibleriskofimpairedfertilitybasedonsmallbutsignificanteffectsonreproductionina2ndgenerationstudyofrats.CarcinogenicityWorksafeAustraliahasclassifiedepoxiconazoleintheoccupationalenvironmentasaCarcinogenCategory3substance.Thismeansthatthesubstanceisnotclassifiableastocarcinogenicitytohumans.AcuteToxicity-OralLD50(rat)200-2000mg/kgfortheformulationAcuteToxicity-DermalLD50(rat)4000mg/kgfortheformulationAcuteToxicity-InhalationLC50(rat)(4hr)3.22mg/lfortheformulationEyeIrritationTheproductisaneyeirritant.SkinIrritationMildskinirritant.SkinSensitisationProductisaskinsensitiser.OtherInformationTheAustralianAcceptableDailyIntake(ADI)forpyraclostrobinforahumanis0.03mg/kg/day,setforthepublicfordaily,lifetimeexposure.ThisisbasedontheNOELof3mg/kg/day,theleveldeterminedtoshownoeffectsduringlongtermexposureforthemostsensitiveindicatorsandthemostsensitivespecies.(Ref:Comm.Dept.ofHealthandAgeingOfficeofChemicalSafety,‘ADIList’,December2008).ADIforepoxiconazoleis0.01mg/kg/day,NOEL1mg/kg/day.12.ECOLOGICALINFORMATIONKnownHarmfulEffectsontheEnvironmentTheproductisamarinepollutantforseatransport.OtherPrecautionsDonotcontaminatedams,waterwaysorsewerswiththisproductorthePrintDate:2/07/2010CS:1.4.93CS:1.4.93Page:4MaterialSafetyDataSheet5ofInfosafeNo3NULOJuly2010ISSUEDbyNUFARMIssueDate:OperaFungicideProductNameClassifiedashazardouscontainerswhichhaveheldthisproduct.Environ.ProtectionSpraydriftcancausedamage,readthelabelformoreinformation.AcuteToxicity-FishThefollowingdataisfortheproduct:Toxictofish.LC50(96hr)forrainbowtroutis0.074mg/l.AcuteToxicity-DaphniaEC50(48hr)is0.14mg/l.AcuteToxicity-AlgaeEC50(72hr)forPseudokirchneriellasubcapitata5.05mg/l.AcuteToxicity-OtherOrganismsThefollowingdataisfortheproduct:Birds:Nottoxictobirds.LD50forquailis2000mg/kgBees:Nottoxictobees.LD50100g/bee.13.DISPOSALCONSIDERATIONSProductDisposalOnsitedisposaloftheconcentratedproductisnotacceptable.Ideally,theproductshouldbeusedforitsintendedpurpose.Ifthereisaneedtodisposeoftheproduct,approachlocalauthoritieswhoholdperiodiccollectionsofunwantedchemicals(ChemClear).ContainerDisposalDonotusethiscontainerforanyotherpurpose.Triplerinsecontainers,addrinsatetothespraytank,thenofferthecontainerforrecycling/reconditioning,orpuncturetop,sidesandbottomanddisposeofinlandfillinaccordancewithlocalregulations.drumMUSTERisthenationalprogramforthecollectionandrecyclingofempty,cleaned,nonreturnablecropproductionandon-farmanimalhealthchemicalcontainers.IfthelabelonyourcontainercarriesthedrumMUSTERsymbol,triplerinsethecontainer,ringyourlocalCouncil,andofferthecontainerforcollectionintheprogram.Ifon-sitecontainerdisposalisnecessary,triplerinseemptycontainerwithwater,addrinsatetothespraytank.Puncturetop,sidesandbottom,crushandburyinanapprovedlandfillorburywithatleast500mmofsoilcoverawayfrompastureandcropareas,watersuppliesandhouses.Emptycontainersandproductshouldnotbeburnt.14.TRANSPORTINFORMATIONTransportInformationItisgoodpracticenottotransportagriculturalchemicalproductswithfood,foodrelatedmaterialsandanimalfeedstuffs.StorageandTransportConsiderednondangerousforroadandrailtransport(inpackaging,includingIBCsnotgreaterthan3000Lteach)bytheAustralianCodefortheTransportofDangerousGoodsbyRoadandRail.Ref:ADG7;SPNo.AU01.ForbulkshipmentsasClass9,useUN3082,HazChemcode2Z.UNNumber(SeaTransport)3082IMOClass/PackingGroupClass9IMOMarinePollutantMarinePollutantIMOProperShippingNameENVIRONMENTALLYHAZARDOUSSUBSTANCE,LIQUID,N.O.S.15.REGULATORYINFORMATIONPoisonsScheduleS5PackagingLabellingCAUTIONKEEPOUTOFREACHOFCHILDRENREADSAFETYDIRECTIONSBEFOREOPENINGORUSINGHazardCategoryHarmful,IrritantAICS(Australia)AllofthecomponentsinthisproductarelistedontheAustralianInventoryofChemicalSubstances