离子型稀土矿化学分析方法++第1部分：15个稀土元素含量的测定++硫酸铵溶液提取-电感耦合等离子体质谱法编制说明

《离子型稀土矿石化学分析方法第X部分：镧、铈、镨、钕、钐、铕、钆、铽、镝、钬、铒、铥、镱、镥和钇含量的测定硫酸铵溶液提取-电感耦合等离编制说明 1 1 1 2 3 4 5 5 5第三章试验验证的分析、综述报告、技术经济论证 7 7 8 30 第五章以国际标准为基础的起草情况，以及是否合规引用或者采用国际国外标准，并 第九章实施标准的要求，以及组织措施、技术措施、过渡期和实施日 123456789重稀土矿，是中国特有的离子吸附型稀土矿，多为花岗分馏作用等因素的影响下，离子吸附型稀土矿的稀土配缺少各稀土分量的评价指标，可能会漏掉矿体，影响资国家地质实验测试中心在2017年编制的中心作业指导书123456789探9本标准的主要技术指标包括方法检出限、测定范围（方法定量强度-浓度校准曲线，测定该实验条件下被测物质的浓度范围，通过δ。研究并选定硫酸铵溶液作为淋滤液，但在淋滤液浓度、淋滤固液比、∑REE/(∑REE/(μg/g）200018001600140012001000800600400200固液比0H-1H-2H-10H-53.2.2硫酸铵溶液最佳浓度2.5%、3.5%、4.5%硫酸铵溶液，考察范围内各浓度的淋滤效果， ∑REE/(μg/g∑REE/(μg/g）12000H-1H-5H-110.5%1.5%2.5%3.5%4.5%研究也发现待测样品中所含有的硫酸铵在上机过程中会影响样品的2.5%硫酸铵La8.718.719.179.1510.1010.1110.4110.1210.51Yb10.71LuY0.1111.2711.413.2.3振荡对比与淋滤时间对比∑REE/(μg/g）1400120010008006004002000∑REE/(μg/g）14001200100080060040020001600∑REE/05002000H-2H-4H-84g25002000150010005001500100006g4g5g入2.5%硫酸铵溶液淋滤，考察淋滤的最佳称样量。摇晃均匀后静置∑REE/05002000H-2H-4H-84g25002000150010005001500100006g4g5g8g8g（1）离心对浸提结果的影响WJ053WJ039WJ026WJ023WJ01301002000100200300500WJ013WJ023WJ026WJ039WJ053345171216382165340173214362167WJ026WJ017WJ011WJ002WJ00100100200300400500600700WJ001WJ002WJ011WJ017WJ026WJ038下675442374226203273中670443375220197269上667431374225203271∑REE/(μg/g）200目200目原样S52S51S25S79S780100200300400500600700800S78S79S25S51S52S54200目43764862785274498原样42262363083269524∑REE/(μg/g）硫酸铵结果视为可交换离子态稀土量.硫酸铵浸提稀土总量与五酸消解稀土总量比值为硫酸铵浸提稀土总量(∑REE)提取率。硫酸铵浸提3+含量变化受氧化还原条件等多种因素影响。自然界中的Ce通常呈Sc提取率趋于070%50%40%30%20%10%L20L28L22L14L05L03Ce∑REECe70%50%30%10%-10%L20L28L22L14L05L0340%20%L20L28L22L14L05L03稀土分析测试标准方法的建立以及离子吸附型稀土矿体资源评价具24384372445600905550Y2862504297536338950413545086345243310467011041765304192135427783490520380188037797051195135116843511487113493632343409911251101126718106256810582242074863209539730747053013729137Ba11.232153Eu142Ce11.114141Pr27.212.228.18148Sm11.2428.1813.8233.61150Sm33.612.302.500.313×10-30.514×10-315821.691×10-323.161×10-32.557×10-33.291×10-33.182×10-34.035×10-34.471×10-35.429×10-35.364×10-33.871×10-35.032×10-31.229×10-31.166×10-31.819×10-31.774×10-3则扣除干扰后测定结果的不确定度用公式表示为:S2=SA2+SB2+SC2不确定度；SC—干扰元素测定量的不确定度SA2+SB2+SC2=1.055SA2，测定结果的合成不确定度S=1.027SA，即+SB2+SC2=1.125SA2，合成不确定度S=1.061SA，则表示扣除干扰后+SB2+SC2=1.222SA2，合成不确定度S=1.106SA，+SB2+SC2=1.5SA2，合成不确定度S=1.225SA，则表示扣除干扰后对+SB2+SC2=3SA2，合成不确定度S=1.732SA，则表示扣除干扰后对测1/101/11.231.556.122.573.27300025002000150010005000ySm=0.0644xyEu=0.1258xySm=0.0644xyEu=0.1258xyPr=0.2441xyNd=0.0654xyLa=0.2024xyCe=0.1952x0200040006000800010000元素浓度ng/mL2000150010005000yLu=0.1699xyLu=0.1699xyYb=0.0581xyEr=0.0571xyHo=0.1718xyHo=0.1718xyTm=0.1766xyTb=0.1762xR²=0.9997yDy=0.0488x0200040006000800010000GdTbDyHoErTmYbLuYLa---10.1830.1730.218-101.732.18-9.1323.6-235.9121.7-19531258-YbLu0.0173210.1910.1790.1751017.13171.5181.240117591718571176658100BK-1BK-3BK-10BK-11YLa0.00171YbLu检出限定量限Y0.018La0.00150.015Ce0.0120.00110.011Nd0.0140.012Eu0.0100.00150.0150.00170.0170.0140.00150.015Er0.0120.012Yb0.00110.011Lu0.0103.8.1精密度实验表12离子吸附型稀土矿石样品精密度检测结果0.5514181.74%NdNd3013.9511.31%2.15%0.7411.25%1.77%2.32%0.113Dy0.811Dy7.272.27%1.27%21.10.2311.91%1.74YbYb0.1411.211.25%Y3.1791.57%Y1821.10%2437.3281.81%12.53.25%35.90.6111.3852.81%1.47%Nd1723.18%Nd75911.501.52%25.21.3700.1233.23%3.21%1.73%2.183.22%Dy10.10.3143.11%Dy1.77%1.700.15411.81.73%3.45%1.111.61%Yb3.15Yb0.118Y1.3873.16%Y1.55%3.8.2加标回收实验回收率（%）=加标试样测试样测试值×100%由于本研究中没有有证标准物质可以对实验流程和结果进行监矿产实验室测试质量管理规范》中规定的回收率允许限内（80%~WJ313Y233251113%11835.6Nd73.7//21.27.3122.5Dy55.32.77Yb18.133.9WJ311Y////1543.3421.5110111%Nd117%27.2118%21.523.12.53Dy12.814.52.377.811.19101%Yb1.26WJ312Y7551171937.17Nd178123103%17.8Dy18361.0137Yb139101%101%精密度和加标回收实验结果表明，硫酸铵浸提，电感耦合等离子3.9.1方法精密度协作实验样品的选择和制备1、样品的选择1HS-123BZ-34CJ-1567AYLK8GXYZC2(xi-x)2(xij-xi)2 式中：xi—组内平均值，x—总平均值。分析统计结果见表15。检验结果表明，试验样品符合3、样品的稳定性表15协作实验样品均匀性检验结果CJ-1均匀性检验结果测试参数YLaYbLux1-12232.210.15634.16.173.173.10x1-22230.15432.36.133.16x2-122220.137.221.80.15933.821.93.3021.32212.2521.40.1617.3821.33.2321.13.18x3-121519.12.1835.50.15632.37.18x3-22142.1835.20.15731.437.87.273.16x4-12170.15832.337.93.253.2122035.80.15932.76.317.2721.621.2x5-121621.232.57.3921.73.3721.42192.1835.40.1596.197.1421.221.0x6-121821.033.17.3821.53.3121.13.252222.197.7135.721.20.16132.27.2221.121.03.23x7-12102.140.15431.46.1837.23.143.122262.2537.021.221.73.3221.73.27x8-12162.150.15331.337.87.143.1721719.12.1935.821.10.15832.17.3121.43.2721.43.18x9-12160.15921.33.3221.02132.150.15431.337.13.14x10-12132.120.1546.1137.27.113.183.11x10-221435.50.15731.67.1721.03.2321.03.17x11-12197.7735.50.15631.97.1121.33.213.18x11-22182.167.7535.10.15731.67.1521.03.17x12-122319.12.2221.121.221.5x12-222119.12.1935.80.15932.16.3121.33.3021.33.18MS10.210.2111.90.210.152.122.352.121.331.561.341.731.152.722.722.722.722.722.722.722.722.722.722.722.722.722.722.72BZ-3均匀性检验结果测试参数YLaYbLux1-125113.01771.745.193.16x1-243.723812.23.7118.12.14x2-124112.41703.772.133.1424512.61751.705.15x3-124112.41703.732.1910.13.16x3-243.712.617425.21.715.13x4-145.325212.91781.755.2712.717326.11.773.27x5-112.517025.13.812.1510.11.703.1122411.415723.02.011.560.514x6-124712.617426.11.745.143.2112.517510.11.713.18x7-112.117017.92.1523411.916517.70.551x8-123912.31703.7317.92.110.38112.43.772.171.713.14x9-112.750.11732.211.745.2137.121214721.83.2315.6x10-124712.717325.72.2110.11.703.17x10-224712.617425.310.11.715.230.5713.15x11-124512.517325.31.735.130.5713.190.381x11-224512.717425.22.163.16x12-112.317025.13.7618.12.15x12-225413.019.12.231.783.27MS13.523.2347.10.150.171.161.151.342.722.722.722.722.722.722.722.722.722.722.722.722.722.722.72测试参数YLaYbLux1-1431.6303.15.21237.51.731.19x1-2178425.33.551.741.23x2-1182414.93.345.18837.86.1415.81.721.18419.43.505.3291.761.22x3-1183418.837.81.741.20x3-2410.35.21037.91.741.20x4-11823.375.1891.731.22185417.51.751.22x5-1183413.03.417.771.751.22417.33.5058.137.76.211.731.21x6-118359.11.779.11.23416.35.19137.96.411.741.21x7-1182410.581.4558.157.137.115.81.711.18181415.53.415.13237.916.11.711.21x8-1183416.53.3982.1737.81.741.201773.2355.57.4115.51.15x9-1181413.33.345.1607.7237.315.81.701.185.3341.759.11.23x10-11763.2715.61.17x10-2182415.5301.85.17957.77.7237.86.1716.11.721.18x11-1187421.47.8116.11.731.20x11-2183415.25.2237.7737.96.211.721.18x12-1182411.13.2757.57.7537.36.1215.91.701.16x12-2187416.8301.459.11.751.23MS17.1949.711.5824.191.540.132.722.722.722.722.722.722.722.722.722.722.722.722.722.722.72测试参数YLaYbLux1-137.16771.95.72661.933.43811.82x1-235.71762.197.126.21624.1911.611.110x2-136.315.7396.17211.741.1046.31611.881.114x3-183.1436.1024.5111.971.138x3-224.323.54512.131.128x4-135.1124.1611.761.1165.81161.393.53711.921.125x5-1772.45.7733.5161.13585.14761.45.71424.233.47711.731.101x6-135.41201.65.5796.12624.163.41311.73761.83.5101.128x7-135.7098.5159.7124.5711.711.1280.911811.95.7346.32125.3111.861.136x8-161.226.31211.891.12025.323.53311.951.120x9-125.1111.941.1176.32125.773.55611.961.146x10-1781.712.141.123x10-2813.9761.160.113.55411.761.131x11-1783.1101.55.73561.466.31212.151.122x11-2203.124.533.41711.601.126x12-15.74361.0124.733.5261.118x12-2761.511.991.124MS11.7570.13.19119.72.221.505.14118.12.320.171.171.011.771.281.162.722.722.722.722.722.722.722.722.722.722.722.722.722.722.72测试参数YLaYbLux1-126.21514.5382.2142.5322.277x1-2101.51173.8426.01314.5272.1972.134x2-12.13519.13411.9322.147101.71175.5217.57426.12314.6112.21412.3522.2186.110x3-117.01424.81783.35314.1042.13218.92111.8042.1392.735x3-2175.562.24112.4192.1926.1202.817x4-1178.7618.01126.19814.8172.25920.1536.136101.80177.1414.1772.17719.7522.751x5-1179.8118.1022.3222.36326.13614.62112.3136.120x6-12.1752.33081.41813.5462.31511.627x7-113.37011.2810.51517.38114.2722.1892.4612.170x8-1171.9217.18825.67519.21512.3142.2150.5512.72579.23313.3872.01618.15311.2375.535x9-1101.36175.6317.76726.1102.172101.19173.5517.37925.39514.3722.1932.44111.8055.9132.759x10-12.31911.582x10-2175.3717.47714.1412.14212.1482.1990.551x11-1172.6717.57525.72514.1312.15419.5192.4162.153x11-2164.8116.73013.4812.31011.4862.631x12-1171.5617.53725.57914.1692.45112.1192.163x12-297.1932.33511.6072.725MS17.210.2112.517.770.2135.231.321.381.221.162.722.722.722.722.722.722.722.722.722.722.722.722.722.722.72测试参数YLaYbLux1-11.6121.9011.0211.3260.131x1-25.7121.7831.3870.110x2-111.0221.5857.4370.13111.9742.0718.1711.1151.4320.1110.111x3-12.2161.1660.1130.113x3-25.81711.6301.7832.0111.413x4-15.57311.0501.9107.5110.2311.3340.1335.57211.8587.814x5-112.3351.8382.1021.1441.5500.1560.1180.3160.1196.3182.1831.1560.1510.1160.3100.118x6-113.2250.1540.1200.3120.1175.53211.2731.6331.3230.1340.271x7-15.9211.8191.1101.4130.11012.4371.8382.1131.1670.1140.111x8-111.5891.7472.0111.3830.13911.7721.7592.0157.8121.3670.1100.110x9-11.8312.1151.1560.1120.11411.3971.6371.3440.133x10-112.3671.1021.4500.1430.1100.111x10-212.4412.1061.1301.4740.112x11-111.9981.3410.136x11-211.5117.5311.0121.3190.1290.101x12-112.4231.8572.1241.117x12-28.1731.1201.4520.1430.1130.110MS10.1150.1260.0112.61E-051.411.722.322.722.722.722.722.722.722.722.722.722.722.722.722.722.722.72AYLK均匀性检验结果测试参数YLaYbLux1-113.8541.387x1-213.77910.3372.1751.340x2-113.42210.1802.1231.7320.215x3-113.8551.376x3-21.2550.551x4-113.4562.1284.5712.7120.2311.2390.2180.551x5-14.6122.7759.83113.4414.7372.85110.1461.321x6-12.7471.2250.21113.5179.9130.551x7-112.3412.6611.7130.2180.2512.7161.7140.2211.2230.2180.516x8-12.5749.1700.2171.9101.18313.47310.4111.8912.1900.2711.326x9-19.47113.1712.7541.2790.2199.8172.109x10-113.26810.1382.1611.3530.271x10-213.5284.8132.2331.346x11-110.1113.9361.9571.386x11-213.5824.7752.9171.9122.1611.320x12-113.4582.2360.2711.332x12-29.7194.8162.1581.320MS10.2711.51E-041.351.541.701.731.531.762.121.911.582.722.722.722.722.722.722.722.722.722.722.722.722.722.722.72GXYZC均匀性检验结果测试参数YLaYbLux1-113.4013.5833.21811.9922.1232.1051.1790.215x1-29.25112.7783.5303.15011.8331.1510.213x2-113.79312.6342.1832.1741.21413.7823.37512.7392.2542.2181.255x3-113.2553.15211.8461.160x3-212.58211.4032.0121.105x4-111.3752.0131.10713.1153.5203.20111.7411.1510.571x5-112.4143.4233.13711.7182.1522.1811.23413.62312.2872.1742.2111.2220.314x6-113.3693.6192.1912.1641.1970.22112.7593.4383.11811.5331.138x7-19.13613.2163.5523.18411.7761.1580.2133.44111.5891.116x8-13.10411.7281.1380.2113.5223.19211.9182.1132.1031.1440.210x9-112.8113.5593.19211.9832.1422.1080.2511.1810.21713.4323.5733.2552.1272.2151.2140.310x10-113.5013.27012.4372.1682.1781.212x10-23.52011.7852.1002.1701.1630.215x11-113.151x11-212.52611.4161.1090.271x12-113.1573.5173.22411.7922.1141.1640.214x12-212.83911.5972.0511.131MS10.1195.21E-060.1750.11984.71E-051.581.581.242.112.552.191.912.162.512.722.722.722.722.722.722.722.722.722.722.722.722.722.722.72表16协作实验前后两次测定结果协作实验前测定数据样品编号Y11.91.100.150.110.11GXYZC12.53.1111.72.142.181.220.31AYLK13.310.11.832.151.3117117.515.22.4112.42.34协作实验前测定数据样品编号YCJ-121819.135.932.27.2321.13.19BZ-312.449.117125.12.163.13HS-11824163.4159.17.7537.86.211.731.2036.15.7211.91.12样品编号Y6.1411.21.231.510.130.310.13GXYZCJ12.53.522.171.220.31AYLKJ13.54.162.7110.11.2117315.42.3712.92.516.13CJ-1J2262.130.1735.523.825.2BZ-323912.517125.73.21HS-11794015.517.8137.76.1415.71.779.111.2221059.16.1811.91.21表17协作实验前、后两次测定数据t检验统计统计量观测值相关系数统计结果120-0.261值大于临界t值，则表示两组数据之间的差异显著，反之差异不显著3.8.3方法准确度协作试验数据统计分析3.8.4测试结果的一致性和离群性检查验证样品各元素原始数据一致性和离群性检查结果见表18.1~表18.15，表中标注**为离群值，标注*为岐离值，离群值剔除，岐离值表18.1镧精密度协作试验数据汇总表HS-1BZ-3CJ-1AYLKGXYZC1_1487*22817.71_2491*29121.6222.121.63**17.11_3497*22717.11_4935*22.722121.04**17.92_1461.915.5315.732_2463.117.82_3433.6201.12_4254.117.81*15.743_1226.1171.513.5412.513_2225172.313.4812.3513.753_3170.113.5212.5513.723_4223.813.7212.5213.78411.7176.517.42**13.65423.318.27181.315.64**14.164_3417.2241.1180.115.68**415.6232.6183.215.81**13.27HS-1BZ-3CJ-1AYLKGXYZC5_1529*1036.5*213.816.1313.8314.755_2531*1038*213.916.1413.825_3529.5*213.516.1213.8314.755_4530.5*1035.5*213.816.13255.6193.112.06**16.73196.110.28**12.09**451.819.3218.1310.18**7_1885.121.8617.5115.617_221.8617.5115.617_321.8617.5115.617_421.8617.5115.61817.7251.5174.514.3511.04252.9177.511.312.75254.518.7514.1311.3512.51177.114.312.5413.4813.2210.6*14.5113.63210.7*15.9313.74206.1*15.8185.714.3512.76427.519.3712.1910.51427252.8173.112.312.3712.2311.95831.518.77167.512.3710.1911.911_1431.612.46**13.8511_2425.3237.719.53173.812.9**13.7813.411_3414.913.25**13.4212.7811_4419.7175.512.49**13.79HS-1BZ-3CJ-1AYLKGXYZC1_14.5143.02**15.12.714.041*6.3315.21*1_245.2**15.2823.533.93*5.42*1_343.1**15.223.78*6.3195.379*1_445.3**15.123.83.782*5.181*2_137.3812.419.812.7135.2414.1182_23.72513.32.1292.7532_312.792.1242.7612_43.48120.192.8513_13.5738.81HS-1BZ-3CJ-1AYLKGXYZC3_22.35818.352.3453.8233_33.63339.113.142.3633_417.833.8323.6140.7112.752.973*3.7413.72839.5312.742.17918.124.5134_312.538.1611.812.32418.515_14.1815.7621.185_24.1615.762.7521.154.7753.8155_34.18515.7721.195_44.1815.762.77521.153.8154.31313.8721.453.824*4.3113.8221.523.817*14.1121.793.855*5.734.83*4.32140.1214.12.77721.833.79*7_137.712.34218.532.7537_22.325.2727_311.934.1657_435.1911.962.5195.3194.2354.399**38.512.32517.514.10113.8617.512.5193.58339.192.3114.1313.5473.44112.362.29117.392.5813.5773.771.7594.473*13.531.85114.812.3183.581*3.54539.14*13.3515.332.1913.925*3.855*3.53735.43*13.211.732.2414.231*3.53939.8113.412.31716.413.8113.122.3513.1923.72438.1813.112.1463.1723.5212.7316.132.1663.14611_137.162.211.91511_235.7112.2317.51.9193.58311_33.3436.3112.373.5311_412.562.2517.57HS-1BZ-3CJ-1AYLKGXYZC1_135.11_2102.3*9.314.611HS-1BZ-3CJ-1AYLKGXYZC1_3101*9.513.591_424335.34.7012_151.347.3263.1643.2163.7272_293.737.35129.313.1232_3225.73.1272_4222.553.167.15631.283.4413.733_1205.12.4613_281.4248.157.54725.733_381.1325.143_43.6332.981224.17.7173.5332.8144_3219.727.553.3472.8133.58148.177.77828.333.5255_1107.5*61.632.313.3555_2107.3*27061.732.33.3652.755_361.5532.323.3555_4107.5*61.63.3553.3223.853.1831.874.11222431.934.1213.5744.1222.24.191.36225.132.184.1387_1232.653.4130.13.3454.1697_2233.13.367_3237.351.7830.414.1357_452.353.3283.5374.17827.353.2152.453221.327.323.1382.513.215213.63.1472.5143.159212.527.193.2163.19484.12213.3**22.572.8172.5183.304**195.3**6.21122.783.077**78.81189.3**41.262.5473.039**54.218.17325.52.71953.125.512.5612182.128231.324.5511_126.212.1533.33211_22.1933.21811_32.2773.15HS-1BZ-3CJ-1AYLKGXYZC11_426.122.119HS-1BZ-3CJ-1AYLKGXYZC1_1365*11519.114.1171_2370.1*921*11313.517.91_3370*43.2111213.4118.11_4901*43.512113.72_1336.1179.134.1911.5914.212_233.911.1914.522_3317.612.7511.242_4317.633.3413.3211.1314.343_1177.437.7511.1712.383_2310.111.2512.383_3812.736.8111.2612.273_4791.4174.211.189.31212.45178.214.33*13.1316.1175.113.61*10.1913.364_3816.137.1388.7112.94*13.84312.535.7591.6112.65*14.145_1381*991*106.113.2512.55_2381.1*13.2612.515_3381.6*991.5*13.245_4381.3*13.2512.51111.217.0113.7116.6111313.59811.2191.544.19112.213.7817.6115.713.537_111.2214.527_211.9711.57_3791.8165.112.2511.3714.327_4801.112.0111.66311.937.3212.512.11181.537.2212.2612.11319.2812.738.2312.2311.9316.2179.312.57784.5*162.5**27.1176.148.81311.4275.6152.1**76.111.04149.3**27.181.6713.4*143.2**11.17HS-1BZ-3CJ-1AYLKGXYZC320.1851.4186.110.21315.818310.2110.71318.410.81310.537.767.61711_1303.1771.9177.312.3511_2762.111.9911_337.1910.1811.8311_4174.512.63HS-1BZ-3CJ-1AYLKGXYZC1_173.4117.531.725.622.7*3.13*1_2115.631.326.13.36*1_3119.131.126.121.2*2.53.24**1_473.6118.331.125.921.4*3.26*2.353.1**2_167.1616.732.1282_22719.7315.931.8352_325.752.1042.5412_417.13_161.13103.127.2622.392.1723_262.17103.327.2322.12.1643_322.11.762.2523_422.1715.511.7722.15821.232.3122.0312.35516.122.1591.8552.3544_3101.521.8215.712.1221.85321.241.9165_131.2126.195_231.2226.152.2551.8552.2155_331.226.182.272.215_431.222.252.21121.832.2520.41*3.27412225.513.21378.53118.83.0183.19119.132.8326.1621.38*2.7117_15715.131.9532.4327_224.5721.0115.211.8012.3837_315.142.0152.4147_415.21.75862.122.1516.121.552HS-1BZ-3CJ-1AYLKGXYZC59.5121.95161.5812.02127.4716.171.9131.58521.941.53851.4481.2319.91**14.551.4711.55620.32**92.3122.51**51.3620.32**18.2763.1111.122.561.3361.734111.714.551.3241.77759.1927.1221.9513.91.785111.71.34211_125.41.1422.17911_297.1214.531.1772.12311_321.82141.19511_421.4114.611.151.7322.183HS-1BZ-3CJ-1AYLKGXYZC1_10.23**1_20.211**0.41**1_37.1443.331_40.401**2_10.1542_24.1870.1552.5392_35.4812.6910.3132_44.0170.1542.7240.2713_13.7753_25.1375.7163.730.1570.2313_35.1333.7580.1583_43.7172.1850.2127.3264.3330.1834.354_34.1650.1782.5830.1785_15_24.910.515_37.8150.2715_44.6710.2210.7126.1786.5910.212HS-1BZ-3CJ-1AYLKGXYZC0.2146.1214.7340.217_10.212**2.3917_25.3113.780.182**7_36.1363.770.172**7_46.1170.169**2.4320.1742.5722.5450.2115.8164.3390.1712.5830.212.5415.333.14**0.1215.4713.24**0.1332.437*0.338**3.673**0.1320.237*0.323**3.24**0.1192.675*0.221*0.1740.3710.1770.2115.7780.1752.3290.1750.2186.3330.1732.1990.1790.2175.7146.7412.190.1780.21711_15.2120.1562.21411_25.3473.7130.1542.19711_35.1885.7390.1592.13511_45.3290.1612.2140.251HS-1BZ-3CJ-1AYLKGXYZC1_126.1*2.811_225.2*3.37*1_373.33.35*2.731_4733.23*2.772_165.1335.561.8152.1922_217.535.451.9812.1822_352.1916.7337.1519.752.0112.2392_42.1142.1523_131.871.8231.9153_259.3120.1131.361.8551.9713_365.9120.1731.2918.173_458.3131.631.8352.01657.88**31.652.1532.1163.05**71.221.94_331.582.2552.213HS-1BZ-3CJ-1AYLKGXYZC65.5**30.122.1535_172.7520.121.412.4151.9755_245.121.442.395_372.5521.412.4155_47320.1121.391.97522.2743.2223.78*3.278*21.153.331*81.2854.9121.8242.613.334*2.9212.83322.5543.5724.53*3.271*7_123.7727.2419.112.4732.3267_259.7192.14*23.137_323.2927.2818.722.357_423.2227.232.1762.71435.3917.291.5671.71451.617.561.9181.717.3718.271.9321.5831.6751.53552.7642.0113.7632.331.5781.6571.7151.7614.3518.141.5871.7421.77715.1818.311.70152.7646.1431.6519.571.5631.52861.6133.351.7361.4131.55834.111.7231.39761.932.31.7931.61633.231.7851.43211_161.9318.8134.1411_232.312.1752.10511_358.2133.7719.131.5562.12311_418.3732.792.174HS-1BZ-3CJ-1AYLKGXYZC1_13.703**1_26.112.373.52**1_36.0113.35**0.3411_43.64**2_12_22_35.3837.0212_48.149*1.9230.219HS-1BZ-3CJ-1AYLKGXYZC3_12.5323_22.2380.2183_32.2533_42.2389.1212.4412.8164_32.8617.2777.3155_15_25_32.415_49.8152.395.7342.1545.213.010.3715.7222.1842.192.1820.3717_18.47111.57**0.317_211.05**2.7557_311.23**2.7557_48.43111.2**2.7358.633**1.9172.3310.2127.276**2.360.2127.613**2.4510.210.2127.553**0.2166.3354.531.585.7362.2320.251**6.1614.0120.321**4.355.7792.2810.210.301**1.520.254**2.4320.216.9512.4326.4112.3160.2210.2120.2117.1880.2190.2111_12.2612.53211_26.2162.1456.1340.1520.27**11_36.1722.130.15211_46.3162.196HS-1BZ-3CJ-1AYLKGXYZC1_112.551**1.911.75**HS-1BZ-3CJ-1AYLKGXYZC1_229.112.7350.7**1.799**1_312.752.2**191.9111.94**1_427.712.652.3**1.78**2_124.1741.711.6111.3552_22541.514.211.561.3912_342.0110.121.4152_442.3510.121.3783_122.8110.1243.2213.31.1153_239.5322.8110.1613.373_323.213.181.0183_422.6110.1415.181.3031.49143.3241.371.4014_325.0114.571.2361.361.36141.8225.7243.75151.2325_112.5354.75**1.521.35_212.541.5151.315_312.5354.5**171.51.4751.295_412.5255**1.521.321.3212.6117.562.1112.51*2.126**44.1521.4612.742.1182.111**43.321.3412.7817.62.093**21.5817.822.0712.138**7_137.4513.331.1261.4411.3417_241.1313.171.0167_337.2241.141.0161.3197_437.1741.0113.231.5011.34141.1122.5913.271.1021.11738.2143.191.1341.13723.4113.591.12137.2923.75*38.124.52*9.754**39.3114.251.1471.18421.71*8.128**38.8113.841.1622.77*8.451**41.4814.151.1941.12711.3345.11131.01611.161.0151.01641.0510.6143.5912.2525.4742.9112.1311_137.4512.831.3871.19911_238.1724.191.341.179HS-1BZ-3CJ-1AYLKGXYZC11_337.7939.5311.931.15111_412.351.214HS-1BZ-3CJ-1AYLKGXYZC1_10.35**1_23.770.363**1_35.012.310.13.780.356**1_44.712.370.33**2_12_24.1651.9142.7250.1812_34.122_47.3713_13.7831.8358.182.5583_22.5740.1833_33.7710.1783_43.7151.8214.4122.8157.514.3338.164_31.8522.7555_14.712.2110.133.155_24.712.21510.123.1655_34.7252.19510.143.135_410.133.152.2437.775**5.3582.278.832**3.3530.3712.2797.827**3.3425.3183.9413.397_17.4917_24.41320.317_37.4814.412.0120.2217_40.210.313.9161.9537.327**4.1157.26**4.0111.7970.2126.1611.53*0.214**3.7831.743*7.2390.1910.234**0.283**1.47*7.1972.547HS-1BZ-3CJ-1AYLKGXYZC6.1281.58*2.570.177.3724.3818.7712.5312.5790.1917.191.9552.3797.1392.370.19111_16.2211.7427.0162.2770.11611_22.1340.1170.21511_36.142.1470.1180.21311_47.382.2180.1140.215表18.11铒精密度协作试验数据汇总表HS-1BZ-3CJ-1AYLKGXYZC1_121.512.50.873**1_221.111.80.91**1_321.712.229.2*1_421.312.85.99129.5*0.91**2_118.7123.192_223.152_317.824.017.2382_417.94.8713_117.1111.783_217.2411.865.38323.613_317.2211.935.37723.533_417.2211.835.3917.750.5124_35.0176.81510.145_121.1730.01*5_221.155_321.1712.525_421.1512.5130.01*12.215.44121.7812.347.2817.3345.55119.180.81312.227.3285.57821.750.914**7_115.7522.77_215.757_315.834.71523.277_415.84.713HS-1BZ-3CJ-1AYLKGXYZC17.85.13423.780.5190.5116.915.1246.6510.51415.43.9**21.277.1430.541**9.5194.558**21.910.4130.51815.613.84**21.660.53115.143.962**23.160.591**18.5213.2325.1918.3113.2725.5917.9712.176.1730.51117.7212.915.54123.916.1220.51911_116.3111.825.1911_211.6120.1811_315.7811.7421.9211_411.885.15421.296.110.541表18.12铥精密度协作试验数据汇总表HS-1BZ-3CJ-1AYLKGXYZC1_11.511.10.111_21.454.410.1121_31.4214.4131.121_41.54.512_11.9371.1243.4142_21.1643.4172_31.8351.162_41.1353.2253_11.7761.1663.513_21.1383.4373_31.791.1483.4570.04113_4