主要学术思想和学术成绩

主要学术思想和学术成绩催化剂是催化反应工艺技术的核心。催化反应是一个表/界面过程，但在反应器宏尺度下往往受限于催化剂床层内的流动与传递过程的制约，导致催化剂活性和选择性甚至催化剂稳定性受到负面影响。结构催化剂与反应器技术（StructuredCatalystsandReactors,SCRs）已被广泛证实能显著优化固体催化剂床层的流体力学行为和提高催化剂床层内部的热/质传递性能，因而在多相催化领域的研究受到越来越多的关注，成为当前催化与反应工程交叉领域的热点和国际前沿。然而，目前多数研究主要限于涂层技术的规则2D空隙蜂窝陶瓷和微通道SCR的研究。虽然相关SCR技术已普遍用于汽车尾气催化净化，也在蒽醌加氢、费-托合成、气相丙烯双氧水环氧化等过程中实现了工业应用示范，但是涂层技术成本高、实施难度大、对金属Foam等新型非规则结构基体的技术普适性差。要强调的是，具有三维（3D）非规则空隙结构的Foam/Fiber基体，在消除径向扩散限制、强化涡流混合传质、规模化制备等方面显示出微通道难以企及的优势，但高效的Foam/Fiber基体3D骨架表面催化功能化的研究尚属空白。我们提出了金属Foam/Fiber基体“非涂层”原位催化功能化的“自上而下（Top-Down）”逆向设计策略，原创性地构建了湿式化学刻蚀、原电池反应置换活化、分子筛原位生长、介孔Al2O3同源氧化衍生等的结构催化剂制备新方法和新技术，突破了“涂层技术”通适性差的局限性，将结构催化剂从规则2D空隙蜂窝和微通道结构拓展到了非规则3D空隙金属Foam/Fiber等结构，形成了特色鲜明的反应器（Top，流动与传递）-催化剂（Down，表界面反应）高效耦合一体化设计新方向，实现了反应器（Top）内流动和热/质传递与表界面（Down）催化反应的协同耦合，进而可提高催化剂的利用效率、提升稳态反应速率和选择性、减缓催化剂失活，尤其为众多C1能源化工反应过程存在的传质/传热限制等问题的解决以及为满足环境催化（VOC催化燃烧）和“模块”化工厂等对高通量、低压降等的特殊要求提供了新的技术途径。在煤/生物质基合成天然气（SNG）、甲醇制丙烯（MTP）、DMO加氢合成EG、VOCs/CH4催化燃烧、气相醇选择氧化、甲烷干重整、催化精馏等多个过程的应用中得到有力验证。例如，借助原电池置换反应一步实现了整装式Au(Ag)/Ni(Cu)-fiber催化剂制备，用于强放热气相醇氧化实现了低温高活性与强化传热的统一；揭示了Au/Ni-fiber上Ni2O3-Au+活性位结构以其协同作用关系。研制了纤维结构化Ni/CeAlO3-Al2O3复合催化剂，用于强吸热CH4/CO2重整实现了热力学（高导热消除冷点）和动力学两方面抑制积碳的统一；揭示了CeAlO3的动力学抑制积碳的本质。无需对ZSM-5分子筛进行任何化学修饰和晶粒尺寸控制，仅对其进行微结构化设计合成了整装Metal-fiber@ZSM-5核壳结构催化剂，即大幅提高了ZSM-5分子筛在MTP反应过程中的稳定性和丙烯选择性；本质上，ZSM-5分子筛的结构化设计促进了MTH过程“碳烃池”机理中烯烃循环路径同时明显抑制了芳烃循环路径。借助一步湿法化学刻蚀方法，开发了传热效率高、催化性能好的整装结构化Ni-foam@Ni-MOx(MOx:Al,Ce,Mg等的一元或多元混合氧化物)甲烷化催化剂，实现了优异的甲烷化催化性能与良好导热性的统一，为发展无循环、高通量、快速移热结构化甲烷化合成天然气（SNG）催化反应器工艺提供了核心技术基础；与世界500强的香港中华煤气集团合作，成功实现了整装结构甲烷化催化剂的工业试制，基于该催化剂的无循环一次性通过SNG新工艺技术的工业化应用也在实施中。最近，遵循“逆向设计（Top-Down）”的研发思路，通过一步原电池置换法、可控氧化外延生长法和同源生长等方法，分别设计研制了低温活性高、选择性好、稳定性好和可大通量低压降操作、床层几何构型灵活设计的系列专利催化剂，如：煤层气催化脱氧Ni-Foam@NiPd(alloy,<1%Pd)催化剂、DMO加氢制乙二醇Ni-foam@NiM-alloy催化剂、Ni-foam@NiO-NbOx乙烷氧化脱氢制乙烯催化剂、CO与亚硝酸甲酯反应合成DMO/DMC低Pd（<0.3wt%）Pd/AlOOH/Al-matrix催化剂、Pd@SiO2/Al2O3/Al-matrix(<0.5%Pd)甲烷/VOCs催化燃烧脱除催化剂等。主持国家自然科学基金委‘十五’“能源发展中的若干关键科学问题”重大项目课题1项（20590366）、国家基金委面上项目6项（20573036，20973063，21076083，21273075，21473057，21773069）、科技部“973”项目课题1项（2011CB201403）、科技部“863”“氢能源”专项课题1项（2007AA05Z101）、教育部“高等院校博士点专项基金”（20090076110006）项目1项、上海市科委重大项目子课题1项（05DJ14002）和重点基础研究项目1项（18JC1412100），以及企业（香港中华煤气集团、上海浦景化工、中石化上海工程公司等）委托额合作开发项目多项。发表论文200余篇，申请发明专利40余件（其中PCT专利3件），获得中国发明专利授权30余件、美国专利授权2件。近年来，在Sci.Adv.、iScience、J.

Catal.、AIChE

J.、ACSCatal.、Chem.Commun.、Green

Chem.、ACSAppl.Mater.Interfaces、ChemSusChem、ACSSustainableChem.Eng.、Lab

Chip、J.Mater.Chem.、Int.J.HydrogenEnergy、J.

Power

Sources、Appl.

Catal.

A/B、Catal.

Today

、Nanoscale、Catal.Sci.Technol.等国内外高水平学术刊物公开发表论文100余篇。指导毕业的赵国锋博士、陈伟硕士、高立达硕士和王翔宇硕士分别荣获2016年度、2014年度和2011年度“上海市研究生优秀成果”。技术合作开发与转化进展情况2013年以来，与世界500强的香港中华煤气集团合作，大力开展基于微结构化设计的C1能源与化工关键催化剂技术的研究开发。合成气甲烷化技术可用以消除煤炭在一次性能源利用中的严重污染问题、实现煤炭清洁利用，同时也是生物质能源化利用的可行途径。该反应是一个强放热过程，不仅反应热效应十分强烈而且现有催化剂存在明显传质限制，如何实现催化剂催化性能与强化传质/传热的统一，实现低能耗、低投资无循环的一次性通过反应工艺操作，还面临巨大的挑战。以具有强化热/质传递和优化流体结构功能的孔结构工程化的金属Ni-Foam为基体，合理利用结构金属基体自身的化学活泼性特点，发展了一步湿法化学刻蚀制备自支撑Ni-Al2O3催化剂的新方法，开发了传热效率高、催化性能好的结构化Ni-Al2O3/Ni-foam甲烷化催化剂并成功工业化制备，实现了优异的甲烷化催化性能与良好导热性的统一，为发展无循环、高通量、快速移热结构化甲烷化合成天然气（SNG）催化反应器工艺提供了核心技术。目前，编制完成了首套生物质基合成气无循环甲烷化工艺包，已具备商业化实施条件。另外，遵循“逆向设计（Top-Down）”的催化剂-反应器一体化设计的研发思路，还研发了草酸二酯加氢酯制乙二醇或乙醇酸酯结构化催化剂、甲烷二氧化碳干气重整结构化催化剂以及SS-fiber@ZSM-5核壳结构MTP催化剂和甲烷氧化偶联催化剂。其中，草酸二酯加氢结构化催化剂200mL装量的放大稳定性测试中，已完成连续稳定运行2500小时的稳定性测试，已具有应用转化的良好前景；在与港华煤气前期合作研究的基础上，甲烷干气重整结构催化剂的放大试制和单管中试测试工作也大力推进中。通过技术转让给香港中华煤气集团的CO与亚硝酸甲酯反应合成DMO/DMC低Pd（<0.3wt%）Pd/AlOOH/Al-matrix专利催化剂的中试试验也在顺利开展中。最近，我们以Mn2O3-Na2WO4/SiO2为基础催化剂，基于MnTiO3辅助[Mn3+↔Mn2+]低温循环活化O2驱动低温OCM的科学认识，形成了具有知识产权的低温OCM催化剂。相关成果《TiO2掺杂Mn2O3-Na2WO4/SiO2催化剂上MnTiO3驱动低温甲烷氧化偶联制烯烃》于2017年6月9日发表于国际著名学术出版集团Science旗下2015年新创子刊《ScienceAdvances》（2017,e1603180）。目前已申请3项发明专利（CN

104759291;WO

2015101345;201710146190.1）。在此基础上，正在与中石化上海工程公司合作开展低温OCM热模试验，通过进行创新催化剂的百公斤级试制，实现满足新催化剂反应工艺要求的反应器工程化设计，完成基于创新催化剂和反应工艺条件下的安全工艺流程优化，来达到具备开展全过程中试试验所需的技术基础。发表著作路勇，巩金龙等编著.《结构催化剂与反应器》.

化学工业出版社.

2020.GuofengZhao,YeLiu,and

YongLu*.Fromnano-tomacro-engineeringofnanocompositesandapplicationsinheterogeneouscatalysis.

In:AdvancesinNanostructuredComposites.Vol.2:ApplicationsofNanocoposites.

M.Aliofkhazraei(ed.).

CRCPress,Taylor&FrancisGroup,2017,Chapter5.路勇，赵国锋.

结构催化剂与反应器：新结构、新策略和新进展.

《催化反应工程》，阎子峰，陈诵英等主编.

科学出版社.2017.

第7章.朱吉钦，路勇.规整结构催化剂及反应器.《化工过程强化方法与技术》，刘有智等编著.

化学工业出版社.

2017.

第24章.代表性论文2020JianZhu,WeidongSun,SongWang,GuofengZhao,YeLiu,YongLu*.ANi-foam-structuredMoNi4-MoOxnanocompositecatalystforhydrogenationofdimethyloxalatetoethanol.Chem.Commun.,2020,56,806-809.SongWang,GuofengZhao,YeLiu,andYongLu*.High-PerformancePd@ZnO-CuO/Brass-FiberCatalystforSelectiveHydrogenationofAcetylene:EffectofCalcination-AssistedEndogenousGrowthofZnO-CuOCompositeonBrass-fiber.J.Catal.,2020,382,295-304.GuofengZhao,XiaxiaPan,YeLiu,andYongLu*.Thin-feltPd-MgO-Al2O3/Al-FiberCatalystwithHighResistancetoWater-VaporPoisoningforCatalyticCombustionofMethane.J.Catal.,2020,384,122-135.JianZhu,GuofengZhao*,WeidongSun,SongWang,YeLiu,andYongLu*.Gas-phasehydrogenationofdimethyloxalatetoethanol:SuperiorFeNi3-FeOx/Ni-foamcatalystderivedfromNiFe2O4-NiO/Ni-foam.Appl.Catal.B,2020,118873.JiaDing,ZhiqiangZhang,ChaoMeng,GuofengZhao,*YeLiu,andYongLu*.Fromnano-tomacro-engineeringofZSM-11ontothin-feltstainless-steel-fiber:Steam-assistedcrystallizationsynthesisandmethanol-to-propyleneperformance.Catal.Today,2020,347,10-17.2019JiaDing,YingshuaiJia,PengjingChen,GuofengZhao,*YeLiu,andYongLu*.Thin-felthollow-B-ZSM-5/SS-fibercatalystformethanol-to-propylenereaction:Towardremarkablestabilityimprovementfromdiffusionenhancement.Chem.Eng.J.,2019,361,588-598.Longgang,Tao,GuofengZhao,*PengjingChen,ZhiqiangZhang,YeLiu,YongLu*.High-performanceCo-MnOxcompositeoxidecatalyststructuredontoAl-fiberfeltforhigh-throughputO3decomposition.ChemCatChem,2019,11,1131-1142.PengjingChen,LongangTao,JianZhu,GuofengZhao,*YeLiu,andYongLu*.Morphology-controllablehexagonal-phaseindiumoxideinsitustructuredontoathin-feltAl2O3/Al-fiberforhydrogenationofCO2tomethanol.EnergyTechnol.,2019,7,1800747/1-1800747/10.PengjingChen,GuofengZhao*,XuerongShi*,JianZhu,JiaDing,YongLu*.Nano-intermetallicInNi3C0.5compounddiscoveredasasuperiorcatalystforCO2reutilization.iScience,2019,17,315-324.YingshuaiJia,ChunzhengWang,JiaDing,GuofengZhao,YeLiu,andYongLu*.Carbon-decorated-Pd(Pd@C)nanocatalystsstructuredonAl-fiberthinfeltforcarbonylationofmethylnitritetoDMC.Catal.Commun.,2019,126,1-4.ChunzhengWang,YingshuaiJia,ZhiqiangZhang,GuofengZhao*,YeLiu,andYongLu*.RoleofPdCxspeciesinPd@PdCx/AlOOH/Al-fibercatalystfortheCOoxidativecouplingtodimethyloxalate.Appl.Surf.Sci.,2019,478,840-845.LonggangTao,ZhiqiangZhang,PengjingChen,GuofengZhao*,YeLiu,andYongLu*.Thin-feltAl-fiber-structuredPd-Co-MnOx/Al2O3catalystwithhighmoistureresistanceforhigh-throughputO3decomposition.Appl.Surf.Sci.,2019,481,802-810.ZhiqiangZhang,GuofengZhao*,WeidongSun,YeLiu,andYongLu*.Oxidativedehydrogenationofethane:SuperiorNb2O5-NiO/Ni-foamcatalysttailoredbytuningmorphologyofNiO-precursorsgrownonaNi-foam.iScience,2019,20,90-99.GuofengZhao*,RuijuanChai,ZhiqiangZhang,WeidongSun,YeLiu,andYongLu*.High-performancemonolithicNi-CeAlO3/Al2O3/FeCrAl-fiberCatalystforCatalyticOxy-MethaneReformingtoSyngas.Fuel,2019,258,116102/1-11.SongWang,GuofengZhao,YeLiu,andYongLu*.High-PerformancePd/AlOOH/Al-fiber(ppmPd)forHemi-HydrogenationofAcetylene:PositiveEffectofHydroxyl-EnrichedCatalystSurface.Ind.Eng.Chem.Res.,2019,58,16431-16441.ZhiqiangZhang,GuofengZhao*,WeidongSun,YeLiu,andYongLu*.High-performanceNi-foam-structuredNb2O5-NiOcompositecatalystfortheoxidativedehydrogenationofethanetoethylene:EffectsofNb2O5loadingandcalcinationtemperature.Micropor.Mesopor.Mater.,2019,288,109609/1-9.JiaDing,LizhuoWang,ZhiqiangZhang,ShufangZhao,YongLu*,andJunHuang*Athin-feltmicrofibrous-structuredZSM-11/SS-fibercatalystfordehydrationofglyceroltoacrolein.ACSSustainableChem.Eng.,2019,7,16225-16232.JianZhu,GuofengZhao*,TongZhu,WeidongSun,YongLu*.Top-downevolutionaryengineeringofnanoporousNi3PontoaNi-foam:Asuperiorcatalystforgas-phasehydrogenationofdimethyloxalatetomethylglycolate.ACSAppl.Mater.Interfaces,2019,11,37635-37643.2018赵国锋,张智强,朱坚,柴瑞娟,丁嘉,刘晔,路勇.结构催化剂与反应器：新结构、新策略和新进展.化工进展,2018，38(4):1287-1304.JiaDing,YingshuaiJia,PengjingChen,GuofengZhao,YeLiu,andYongLu*.Microfibrous-structuredhollow-ZSM-5/SS-fibercatalystwithmesoporositydevelopmentdependentlifetimeimprovementforMTPreaction.Micro.Meso.Mater.,261(2018)1-8.ZhiqiangZhang,JiaDing,RuijuanChai,GuofengZhao,YeLiu,andYongLu*.Oxidativedehydrogenationofethanetoethylene:ApromisingCeO2-ZrO2-modifiedNiO-Al2O3/Ni-foamcatalysts.Appl.Catal.A,550(2018)151-159.TaoDeng,YakunLi,GuofengZhao*,YeLiu,andYongLu*.Catalyticdistillationforesterificationofaceticacidwithethanol:developmentofnovelSS-fiber@HZSM-5catalyticpackingsandexperimentaloptimizationviaresponsesurfacemethodology.J.Chem.Technol.Biotechnol.,93(2018)827–841.JiaDing,PengjingChen,GuofengZhao*,YeLiu,andYongLu*High-performancethin-feltSS-fiber@HZSM-5catalystssynthesizedviaseed-assistedvaporphasetransportformethanol-to-propylenereaction:Effectsofcrystalsize,mesoporosityandaluminumuniformity.J.Catal.,360(2018)40-50.LonggangTao,GuofengZhao,*SongyuFan,PengjingChen,ZhiqiangZhang,YeLiu,andYongLu*.Thin-feltmicrofibrous-structuredAu-α-Fe2O3/ns-γ-Al2O3/Al-fibercatalystforhigh-throughputCOoxidation.Appl.Catal.A556(2018)180-190.PengjingChen,ChunzhengWang,LupengHan,GuofengZhao*,YeLiu,andYongLu*.MonolithicNi5Ga3/SiO2/Al2O3/Al-fibercatalystwithenhancedheattransferforCO2hydrogenationtomethanolatambientpressure.Appl.Catal.A562(2018)234-240.PengweiWang,XinZhang,GuofengZhao,*YeLiu,andYongLu*.Oxidativecouplingofmethane:MOx-modified(M:Ti,Mg,Ga,Zr)Mn2O3-Na2WO4/SiO2catalystsandMOx-modificationeffect.Chin.J.Catal.,2018,39,1395–1402.TaoDeng,GuofengZhao,*YeLiu,andYongLu*.Catalyticdistillationforone-stepcyclohexylacetateproductionandcyclohexene-cyclohexaneseparationviaesterificationofcyclohexenewithaceticacidovermicrofibrous-structuredNafion-SiO2/SS-fiberpackings.Chem.Eng.Process.:ProcessIntensification,2018,131,215-226.ZhiqiangZhang,GuofengZhao*,RuijuanChai,JianZhu,YeLiuandYongLu*.Low-temperature,highlyselective,highlystableNb2O5-NiO/Ni-foamcatalystfortheoxidativedehydrogenationofethane.Catal.Sci.Technol.,2018,8,4383-4389.2017PengweiWang,GuofengZhao*,YuWang,andYongLu*.MnTiO3-drivenlow-temperatureoxidativecouplingofmethaneoverTiO2-dopedMn2O3-Na2WO4/SiO2catalyst.Sci.Adv.2017,3:e1603180.GuofengZhao,SongyuFan,YeLiu,andYongLu*.Reaction-InducedSelf-AssemblyofCoO@Cu2ONanocompositesIn-SituontoSiC-FoamforGas-PhaseOxidationofBioethanoltoAcetaldehyde.ChemSusChem,10(2017)1380-1384.ChunzhengWang,PengjingChen,YakunLi,GuofengZhao,YeLiu,andYongLu*.Microfibrous-StructuredPd/AlOOH/Al-FiberforCOCouplingtoDimethylOxalate:EffectofMorphologyofAlOOHEndogenouslyGrownonAl-Fiber.ACSAppl.Mater.Interfaces,9(2017)9795-9804.JiaDing,PengjingChen,ZhiqiangZhang,LupengHan,GuofengZhao,YeLiu,andYongLu*.Microfibrous-structuredSS-fiber@meso-HZSM-5catalystformethanol-to-propylenereaction:Steam-assistedcrystallizationsynthesisandinsightintomesoporocity-dependentstabilityenhancement.ACSSustainableChem.Eng.,

5(2017)

1840-1853.RuijuanChai,SongyuFan,ZhiqiangZhang,PengjingChen,YakunLi,QiaofeiZhang,GuofengZhao,YeLiu,andYongLu*.Free-StandingNiO-MgO-Al2O3NanosheetsDerivedfromLayeredDoubleHydroxidesGrownontoFeCrAl-fiberasStructuredCatalystsforDryReformingofMethane.ACSSustainableChem.Eng.,5(2017)4517-4522.JiaDing,TaoDeng,PengjingChen,GuofengZhao,YeLiu,andYongLu*.Vapor-phasetransportsynthesisofmicrofibrous-structuredSS-fiber@ZSM-5catalystwithdramaticselectivityandstabilityimprovementformethanol-to-propylene.Catal.Sci.Technol.,7(2017)2087-2100.RuijuanChai,YakunLi,QiaofeiZhang,SongyuFan,ZhiqiangZhang,PengjingChen,GuofengZhao,YeLiu,andYongLu*.Foam-structuredNiO-MgO-Al2O3nanocompositesderivedfromNiMgAl-LDHsin-situgrownontoNi-foam:Apromisingcatalystforhigh-throughputcatalyticoxy-methanereforming.ChemCatChem,9(2017)268-272.PengweiWang,GuofengZhao*,YeLiu,andYongLu*.TiO2-dopedMn2O3-Na2WO4/SiO2catalystforoxidativecouplingofmethane:solutioncombustionsynthesisandMnTiO3-dependentlow-temperatureactivityimprovement.Appl.Catal.A,544(2017)77-83.ZhiqiangZhang,LupengHan,RuijuanChai,QiaofeiZhang,YakunLi,GuofengZhao,YeLiu,andYongLu*.MicrostructuredCeO2-NiO-Al2O3/Ni-foamcatalystforoxidativedehydrogenationofethanetoethylene.Catal.Commun.,88(2017)90-93.YanfeiChen,LupengHan,JianZhu,PengjingChen,GuofengZhao*,YeLiu,andYongLu*.Ag-CunanocompositecatalystgalvanicallydepositedontoaNi-foamforgas-phasedimethyloxalatehydrogenationtomethylglycolate.Catal.Commun.,96(2017)58-62.JiaDing,PengjingChen,JianZhu,GuofengZhao,YeLiu,andYongLu*.Synthesis

of

microfibrous-structured

SS-fiber@beta

composite

by

a

seed-assisteddry-gel

conversion

method.Micro.Meso.Mater.,250(2017)1-8.RuijuanChai,ZhiqiangZhang,PengjingChen,GuofengZhao*,YeLiu,andYongLu*.Ni-foam-structuredNiO-MOx-Al2O3(M=CeorMg)nanocompositecatalystforhighthroughputcatalyticpartialoxidationofmethanetosyngas.Micro.Meso.Mater.,253(2017)123-128.RuijuanChai,PengjingChen,ZhiqiangZhang,GuofengZhao,YeLiu,andYongLu*.Thin-feltNiO-Al2O3/FeCrAl-fibercatalystforhigh-throughputcatalyticoxy-methanereformingtosyngas.Catal.Commun.,101(2017)48-50.RuijuanChai,ZhiqiangZhang,PengjingChen,GuofengZhao*,YeLiu,andYongLu*.FromNano-toMacro-engineeringofLDHs-derivedNanosheetCatalystsforHarshReactions.Int.J.HydrogenEnergy,42(2017)27094-27099.RuijuanChai,GuofengZhao*,ZhiqiangZhang,PengjingChen,YeLiu,andYongLu*.HighSintering-/Coke-ResistanceNi@SiO2/Al2O3/FeCrAl-fiberCatalystforDryReformingofMethane:One-Step“MacrotoNano”OrganizationviaCross-LinkingMolecules.Catal.Sci.Technol.,7(2017)5500-5504.2016GuofengZhao,YeLiu,andYongLu*.Foam/fiber-structuredcatalysts:Non-dip-coatingfabricationstrategyandapplicationsinheterogeneouscatalysis.Sci.Bull.,61(2016)745-748.ChunzhengWang,PengjingChen,YakunLi,GuofengZhao,YeLiu,andYongLu*.InsituDRIFTSstudyofCOcouplingtodimethyloxalateoverstructuredAl-fiber@ns-AlOOH@Pdcatalyst.J.Catal.,344(2016)173-183.LupengHan,GuofengZhao*,YanfeiChen,JianZhu,PengjingChen,YeLiu,andYongLu*.Cu-fiber-structuredLa2O3-PdAu(alloy)-Cunanocompositecatalystforgas-phasedimethyloxalatehydrogenationtoethyleneglycol.Catal.Sci.Technol.,6(2016)7024-7028.QiaofeiZhang,GuofengZhao,*ZhiqiangZhang,LupengHan,SongyuFan,RuijuanChai,YeLiu,JunHuang,andYongLu*.Fromnano-tomacro-engineeringofoxide-encapsulated-nanoparticlesforharshreaction:One-steporganizationviacross-linkingmolecules.Chem.Commun.52(2016)11927-11930.QiaofeiZhang,Xin-PingWu,YakunLi,RuijuanChai,GuofengZhao*,ChunzhengWang,Xue-QingGong,*YeLiu,andYongLu*.High-performancePdNinano-alloycatalystin-situstructuredonNi-foamforcoalbedmethanedeoxygenation:ExperimentalandDFTstudies.ACSCatal.6(2016)6236−6245.JiaDing,ZhiqiangZhang,LupengHan,ChunzhengWang,PengjingChen,GuofengZhao*,YeLiu,andYongLu*.Self-supportedSS-fiber@meso-HZSM-5core-shellcatalystviacaramel-assistantsynthesistowardprolongedlifetimeformethanol-to-propylenereaction.RSCAdv.,6(2016)48387-48395.TaoDeng,YakunLi,GuofengZhao*,YeLiuandYongLu*.Catalyticdistillationforethylacetatesynthesisusingmicrofibrous-structuredNafion-SiO2/SS-fibersolidacidpackings.React.Chem.Eng.,1(2016)409-417.ChunzhengWang,LupengHan,GuofengZhao,YeLiu,YongLu*.High-performance,lowPd-loadingmicrofibrous-structuredAl-fiber@ns-AlOOH@PdcatalystforCOcouplingtodimethyloxalate.J.Catal.,337(2016)145-156.QiaofeiZhang,YakunLi,RuijuanChai,GuofengZhao,*YeLiu,andYongLu*.Low-temperatureactive,highlyoscillation-resistantPdNi(alloy)/Ni-foamcatalystwithenhancedheattransferforcoalbedmethanedeoxygenationviacatalyticcombustion.Appl.Catal.B:Environ.,187(2016)148-158.GuofengZhao,SongyuFan,LonggangTao,RuijuanChai,QiaofeiZhang,YeLiu,andYongLu*.Microfibrous-structuredbinary-oxides-nanocompositewithboostedhighly-activeinterfaceforgas-phaseselectiveoxidationofalcohols.ChemCatChem,8(2016)

313-317.LupengHan,LiZhang,GuofengZhao,*QiaofeiZhang,RuijuanChai,YeLiuandYongLu*.Cu-fiber-structuredternaryPd-Au-CuOxcatalyst:Galvanicexchangereactionpreparationandcatalyticperformanceforgas-phasehydrogenationofdimethyloxalatetoethyleneglycol.ChemCatChem,8(2016)1065-1073.YakunLi,QiaofeiZhang,RuijuanChai,GuofengZhao,FahaiCao,YeLiu,andYongLu*.Metal-foam-structuredNi-Al2O3catalysts:Wetchemicaletchingpreparationandsyngasmethanationperformance.Appl.Catal.A,510(2016)216-226.MingWen,JiaDing,ChunzhengWang,YakunLi,GuofengZhao,YeLiu,andYongLu*.High-performanceSS-fiber@HZSM-5core-shellcatalystformethanol-to-propylene:Akineticandmodelingstudy.Micro.Meso.Mater.,221(2016)187-196.LupengHan,ChunzhengWang,GuofengZhao*,YeLiu,YongLu*.Thin-sheetmicrofibrous-structuredFeKMn/meso-Al2O3/Al-fibercatalystsforFischer-Tropschtoolefins.AIChEJ.,62(3)(2016)

742-752.RuijuanChai,YakunLi,QiaofeiZhang,GuofengZhao*,YeLiu,andYongLu*.Free-standingNiO-MgOnanosheetsin-situcontrollablycompositedonNi-foamasmonolithiccatalystforcatalyticoxy-methanereforming.Mater.Lett.,171(2016)248-251.LupengHan,ChunzhengWang,JiaDing,GuofengZhao*,YeLiu,andYongLu*.Microfibrous-structuredAl-fiber@ns-Al2O3core-shellcompositefunctionalizedbyFe-Mn-Kviasurfaceimpregnationcombustion:as-burntcatalystsforsynthesisoflightolefinsfromsyngas.RSCAdv.,6(2016)

9743-9752.2015QiaofeiZhang,Xin-PingWu,GuofengZhao,YakunLi,ChunzhengWang,YeLiu,Xue-QingGong,

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(2015)1.2014QiaofeiZhang,YakunLi,LiZhang,LiChen,YeLiu,YongLu*.Thin-sheetmicrofibrous-structurednanoporous-gold/Al-fibercatalystsforoxidativecouplingofmethanoltomethylformate.J.Catal.317(2014)54-61.XiangyuWang,MingWen,ChunzhengWang,JiaDing,YingSun,YeLiu,YongLu*.Microstructuredfiber@HZSM-5core-shellcatalystswithdramaticselectivityandstabilityimprovementforthemethanol-to-propyleneprocess.Chem.Commun.50(2014)6343-6345.QiaofeiZhang,YakunLi,LiZhang,LiChen,YeLiu,YongLu*.Structurednanoporous-gold/Al-fiber:galvanicdepositionpreparationandreactivityfortheoxidativecouplingofmethanoltomethylformate.GreenChem.16(2014)2992-2996.GuofengZhao,YakunLi,QiaofeiZhang,FahaiChao,YongLu*.Galvanticdepositionofsilveron80um-Cu-fiberforgas-phaseoxidationofalcohols.AIChEJ.60(2014)1045-1053.2013GuofengZhao,HuanyunHu,ZhengJiang,ShuoZhang,YongLu*.NiO-dopedAu/Ti-powder:Acatalystwithdramaticimprovementinactivityforgas-phaseoxidationofalcohols.Appl.Catal.A467(2013)171-177.GuofengZhao,MiaomiaoDeng,YifengJiang,HuanyunHu,JunHuang,YongLu*.MicrostructuredAu/Ni-fibercatalyst:Galvanicreactionpreparationandcatalyticperformanceforlow-temperaturegas-phasealcoholoxidation.J.Catal.301(2013)46-53.GuofengZhao,JunHuang,ZhengJiang,ShuoZhang,LiChen,YongLu*.MicrostructuredAu/Ni-fibercatalystforlow-temperaturegas-phasealcoholoxidation:EvidenceofNi2O3-Au+hybridactivesites.Appl.Catal.B:Environ.140-141(2013)249-257.WeiChen,GuofengZhao,QingsongXue,LiChen,YongLu*.Highcarbon-resistanceNi/CeAlO3-Al2O3catalystforCH4/CO2reforming.Appl.Catal.B:Environ.136-137(2013)260-268.GuofengZhao,HuanyunHu,WeiChen,ZhengJiang,ShuoZhang,JunHuang,YongLu*.Ni2O3-Au+hybridactivesitesonNiOx@Auensemblesforlow-temperaturegas-phaseoxidationofalcohols.Catal.Sci.Technol.3(2013)404-408.XinnanLu,GuofengZhao,YongLu*.PropyleneepoxidationwithO2andH2:ahighperformanceAu/TS-1catalystpreparedviaadeposition–precipitationmethodusingurea.Catal.Sci.Technol.3(2013)2906-2909.2012YuzhuFang,FangtingJiang,HongLiu,XiaomingWu,YongLu*.Standing-freeNi-microfibrous-supportedcarbonnanotubeaerogels(CNAGs)hybridelectrodesin3Dforhigh-performancesupercapacitors.RSCAdv.,2(2012)6562.WeiChen,WenqianSheng,GuofengZhao,FahaiCao,QingsongXue,LiChen,YongLu*.MicrofibrousentrapmentofNi/Al2O3fordryreformingofmethane:Ademonstrationonenhancementofcarbonresistanceandconversion.RSCAdv.2(2012)3651.WeiChen,WenqianSheng,FahaiCao,YongLu*.MicrofibrousentrapmentofNi/Al2O3fordryreformingofmethane:Heat/masstransferenhancementtowardscarbonresistanceandconversionpromotion.IntJHydrogenEnergy37(2012)18021-18030.YuanLi,YuzhuFang,HongLiu,XiaomingWu,YongLu*.Free-standing3Dpolyaniline-CNTs/Ni-fiberhybridelectrodesforhigh-performancesupercapacitors.Nanoscale4(2012)2867-2869.YinTang,G.Chen,YongLu.EfficientaldolcondensationbyusingmodifiedCaOassolid-basecatalysts.Res.Chem.Intermediates38(3-5)(2012)937.2011YinTang,M.Meng,J.\o"Showauthordetails"Zhang,YongLu.EfficientpreparationofbiodieselfromrapeseedoilovermodifiedCaO.Appl.Energy88(8)(2011)2735.GuofengZhao,HuanyunHu,MiaomiaoDeng,YongLu*.MicrostructuredAu/Ni-fibercatalystforlow-temperaturegas-phaseselectiveoxidationofalcohols.ChemCommun,47(2011)9642-9644.GuofengZhao,MinLing,HuanyunHu,MiaomiaoDeng,QingsongXue,YongLu*.AnexcellentAu/meso--Al2O3catalystforaerobicselectiveoxidationofalcohols.GreenChem3(2011)3088-3092.MinLin,GuofengZhao,WeiChen,MiaomiaoWang,QingsongXue,YongLu*.Microfibrous

structured

catalytic

packings

for

miniature

methanol

fuel

processor:

Methanol

steam

reforming

and

CO

preferential

oxidation.IntJHydrogenEnergy36(2011)12833-12842.GuofengZhao,HuanyunHu,MiaomiaoDeng,MinLing,YongLu*.Au/Cu-fibercatalystwithenhancedlow-temperatureactivityandheattransferforgas-phaseoxidationofalcohols.GreenChem13(2011)55-58.GuofengZhao,HuanyunHu,MiaomiaoDeng,MinLing,YongLu*.GalvanicdepositionofAuonpaper-likeCu-fiberforhigh-efficiencylow-temperaturegas-phaseoxidationofalcohols.ChemCatChem3(2011)1629-1636.2010MiaomiaoDeng‚GuofengZhao‚QingsongXue‚LiChen‚andYongLu*.Microfibrous-structuredsilvercatalystforlow-temperaturegas-phaseselectiveoxidationofbenzylalcohol.Appl.Catal.B99(2010)222-228.JipingMao‚MiaomiaoDeng‚LiChen‚YeLiu‚YongLu*.Novelmicrofibrous-strucutredsilvercatalystforhighefficiencygas-phaseoxidationofalcohols.AIChEJ.56(2010)1545-1556.JinZhang,Guofeng\o"Showauthordetails"Zhao,Z.Popović,YongLu,YeLiu.Pd-porphyrinfunctionalizedionicliquid-modifiedmesoporousSBA-15:Anefficientandrecyclablecatalystforsolvent-freeHeckreaction.MaterialsResearchBulletin45(11)(2010)1648.LuLiu,L.\o"Showauthordetails"Wei,YongLu,JunliangZhang.One-pottandemcatalysis:Aconciseroutetofusedbicyclicscaffoldsfromacyclicβ-ketoestersandalkynylaldehydes.Chem.-AEur.J.16(39)(1010)11813.YinTang,Li\o"Showauthordetails"Chen,Miaomiao\o"Showauthordetails"Wang,Jianfeng\o"Showauthordetails"Li,YongLu*.MicrofibrousentrappedZnO-CaO/Al2O3forhighefficiencyhydrogenproductionviamethanolsteamreforming.Particuology8(3)(2010)225.凌敏，赵国锋，曹