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Seven
crystal
systems
and
fourteen
Bravais
latticeCrystalsystemBravaislatticeCrystal
systemBravaislatticeTriclinicSimple
triclinicHexagonalSimple
hexagonala≠b≠c
,α≠β≠γa1=a2=a3≠c,α=β=90º
,
γ=120ºMonoclinica≠b≠c,
α=γ=90ºSimple
monoclinicRhombohedralSimple≠βRhombobedralBottom-centereda=b=c,α=β=γ≠90ºmonoclinicSimple
tetragonalSimple
orthorhombicBody-centeredtetragonalTetragonalOrthorhombicBottom-centeredBottom-centered
orthorhombica≠b≠c,α=
β=
γ=
90°Body-centered
orthorhombica≠b≠c,α=
β=
γ
=
90°Face-centered
orthorhombica≠b≠c,α=
β=
γ
=
90°Simple
hexagonala=b
≠
c,α=β=90°,γ
=120°Simple
rhombobedrala=b=c,α=β=γ
≠
90°Simple
tetragonala=b
≠
c,α=β=γ
=90°Body-centered
tetragonala=b
≠
c,α=β=γ
=90°Simple
cubica=b=c,α=β=γ
=90°Body-centered
cubica=b=c,α=β=γ
=90°Face-centered
cubica=b=c,α=β=γ
=90°2.
Indices
of
directions
and
Indices
of
crystal
planeCrystal
plane
:
one
of
a
set
of
parallel,
equally
spacedplanes
in
a
crystal
structure.Crystal
direction:
the
crystallographic
directions
arefictitious
lines
linking
nodes
(atoms,
ions
or
moleculesof
a
crystal).Indices
of
directions
and
indices
of
crystal
plane(Miller
indices):
a
notation
system
in
crystallographyfor
planes
and
directions
in
crystal
lattice.2.1
Foundation
of
crystallographya)
Indices
of
directions
in
the
cubic
crystal
systemsSteps
of
determining
the
indices
of
directions
[uv
w]
in
cubic
crystal
systems:Building
coordinateSolving
coordinateConverting
into
an
integerListing
square
brackets
[u
v
w],
adding
a
minus
sign
atthe
top
of
the
indices
if
the
coordinate
value
isnegative.The
coordinate
of
each
lattice
pointin
cubic
crystal
systemThe
sketch
map
of
determining
crystaldirection
[u
vw]in
the
cubic
crystal
systemCommon
crystal
directions
[u
v
w]
inthe
cubic
crystal
systemb).
Indices
of
crystal
plane
in
the
cubic
crystalsystemsSteps
of
determining
the
indices
of
crystal
plane(h
k
l)
in
cubic
crystal
systems:Building
coordinateSolving
interceptTaking
reciprocalConverting
into
an
integer
:
h,
k,
lListing
round
brackets
(h
k
l),
adding
a
minus
sign
at
the
top
of
the
indices
if
the
intercept
value
is
negative.The
sketch
map
of
crystal
plane
(h
k
l)
inthe
cubic
crystal
systemTwo
crystal
planes
(h
k
l)
in
the
cubiccrystal
systemh≠k≠
l≠0,then
there
are
24
crystal
planes 3!
×
4
=
24,
for
example:{1
2
3}h≠k
≠0
or
k≠
l≠0
or
h≠
l≠0,
then
there
are
12
crystal
planes3!/2!
=
12,
for
example:
{1
1
2}h=k=l,then
there
are
4
crystal
planes 3!/3!
×
4
=
4,
for
example:{1
1
1}h=0
or
k=0
or
l=0
,then
there
are
12
crystal
planes (3!/2)
×
4
=
12,
foe
example:
{1
2
0}h==k=0
or
h=l=0
or
k=l=0,then
there
are
3
crystal
planes(4)
(3!/2!22)
×
4
=
3,
for
example:{1
0
0}(5)Numbers
the
crystal
planes
in
the
family
ofcrystal
planes
{h
k
l}c).
Indices
of
crystal
direction
and
crystal
plane
inthe
hexagonal
crystal
systemThe
determining
step
is
same
as
that
of
the
cubiccrystal
system,but
we
always
choose
four
coordinatesto
denote
the
indices
of
the
crystal
direction
in
thehexagonal
crystal
system:a1、a2、a3、c,where
a1、a2、a3
locate
the
same
bottom
face
and
the
angle
betweenthem
is
120o
(the
c-axis
orientation
is
normal
to
thebottom
face).Indices
of
crystal
plan
(h
k
i
l),
where
i=-(h+k)Indices
of
crystal
direction
[u
v
t
w],
where
t=-(u+v)Miller
index
in
the
hexagonal
crystal
systemThree
axisa1,a2,cfour
axisa1,a2,a3,c120°120°120°(h
k
i
l
)[u
v
t
w]i=
-(
h+k
)t=
-(
u+v
)The
sketch
map
of
crystal
direction(plane)
in
the
hexagonal
crystal
system[h
k
i
l]
in
the
hexagonal
crystal
systemd).
ZoneZone:
azone
is
defined
as
a
group
of
crystal
facesthat
intersect
in
parallel
edges.Zone
law:
the
relationship
between
[uvw]
and
(hkl)in
the
same
zone
is:hu+kv+lw=0We
can
get
the
[uvw]
or
(h
k
l)according
to
the
zone
law.e).Interplaner
spacingThe
perpendicular
distance
between
successive
parallelplanes
of
atoms
in
a
crystal,
it
is
denoted
with
d,h,k,l.RectangularcoordinatesCubicHexagonalThe
above
formula
is
only
for
simple
unit
cell.
For
a
complex
simple,we
should
consider
the
effect
of
the
additional
planes.Cubi
crystal
system:fcc:
when
h,
k
and
l
are
not
all
odd
or
all
evenFor
example
{100},
{110}bcc
h+k+l=odd, For
example
{100},
{111}Hexagonal
crystal
system
:When
h+2k=3n
(n=0,1,2,3,……),
I=oddFor
example
{0
0
0
1}The
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