联合国关于GHS版本化学品(含危险品)的标签和分类说明

1、GE.06-STSTESecretariatUNITEDNATIONSDistr.GENERALST/SG/AC.10/C.4/2006/8/Add.115 May 2006ENGLISHOriginal: ENGLISH AND FRENCHCOMMITTEE OF EXPERTS ON THE TRANSPORT OFDANGEROUS GOODS AND ON THE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONAND LABELLING OF CHEMICALSSub-Committee of Experts on the GloballyH

2、armonized System of Classification and Labelling of ChemicalsEleventh session, 12-14 July 2006Item 3(c) of the provisional agendaHAZARD COMMUNICATION ISSUESCodification of hazard and precautionary statementsTransmitted by the representative from the European Chemical Industry Council (CEFIC) on beha

3、lf of the precautionary statements correspondence working groupAddendum 1Proposal for the revision of Annex 3 of the GHS.ST/SG/AC.10/C.4/2006/8/Add.1page 2blank pageST/SG/AC.10/C.4/2006/8/Add.1page 3“ANNEX 3CODIFICATION OF HAZARD STATEMENTS, CODIFICATION AND USE OF PRECAUTIONARY STATEMENTS AND EXAMP

4、LES OF PRECAUTIONARY PICTOGRAMSST/SG/AC.10/C.4/2006/8/Add.1page 4blank pageST/SG/AC.10/C.4/2006/8/Add.1page 5ST/SG/AC.10/C.4/2006/8/Add.1page 5Annex 3SECTION 1CODIFICATION OF HAZARD STATEMENTSA3.1.1IntroductionA3.1.1.1Hazard statement means a statement assigned to a hazard class and category that de

5、scribes the nature of the hazards of a hazardous product, including, where appropriate, the degree of hazard.A3.1.1.2This section contains the codes assigned to each of the hazard statements applicable to the hazard categories defined under the GHS.A3.1.1.3The hazard statement codes shall only be us

6、ed for reference purposes and shall neither form part of the hazard statement text that appears on a GHS label, nor replace it. A3.1.2Codification of hazard statementsA3.1.2.1Hazard statements are assigned a unique alphanumerical code which consists of one letter and three numbers, as follows:(a)the

7、 letter “H” (for “hazard statement”);(b)a number designating the type of hazard to which the hazard statement is assigned according to the numbering of the different parts of the GHS, as follows:“2” for physical hazards;“3” for health hazards:“4” for environmental hazards;(c)two numbers correspondin

8、g to the sequential numbering of hazards arising from the intrinsic properties of the substance or mixture, such as explosivity (codes from 200 to 210), flammability (codes from 220 to 230), etc.A3.1.2.2The codes to be used for designating hazard statements are listed, in numerical order, in Table A

9、3.1.1 for physical hazards, Table A3.1.2 for health hazards and Table A3.1.3 for environmental hazards. Each table is divided into 4 columns containing the following information:Column (1)The hazard statement code;Column (2)The hazard statement text;The text in bold is the text that shall appear on

10、the label, except otherwise specified. The text in italics enclosed within brackets provides extra information that can be specified. In such cases, the manufacturer or supplier can choose, or ST/SG/AC.10/C.4/2006/8/Add.1page 6the competent authorities may prescribe the information. For example: “ca

11、uses damages to organs (or state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)”.Column (3)Hazard class, with a reference to the chapter of the GHS where information about

12、the hazard class may be found.Column (4)The hazard category or categories within a hazard class for which the use of a hazard statement is applicable.Table A3.1.1Hazard statement codes for physical hazardsCodePhysical hazard statementsHazard class (GHS chapter)Hazard category(1)(2)(3)(4)H201Unstable

13、 explosiveExplosives (chapter 2.1)Unstable ExplosiveH202Explosive; mass explosion hazardExplosives (chapter 2.1)Division 1.1H203Explosive; severe projection hazardExplosives (chapter 2.1)Division 1.2H204Explosive; fire, blast or projection hazardExplosives (chapter 2.1)Division 1.3H205Fire or projec

14、tion hazardExplosives (chapter 2.1)Division 1.4H206May mass explode in fireExplosives (chapter 2.1)Division 1.5H220Extremely flammable gasFlammable gases (chapter 2.2)1H221Flammable gasFlammable gases (chapter 2.2)2H222Extremely flammable aerosolFlammable aerosols (chapter 2.3)1H223Flammable aerosol

15、Flammable aerosols chapter 2.3)2H224Extremely flammable liquid and vapourFlammable liquids (chapter 2.6)1H225Highly flammable liquid and vapourFlammable liquids (chapter 2.6)2H226Flammable liquid and vapourFlammable liquids (chapter 2.6)3H227Combustible liquidFlammable liquids (chapter 2.6)4H228Flam

16、mable solidFlammable solids (chapter 2.7)1, 2H240Heating may cause an explosionSelf-reactive substances and mixtures (chapter 2.8); and Organic peroxides (chapter 2.15)Type AH241Heating may cause a fire or explosionSelf-reactive substances and mixtures (chapter 2.8); and Organic peroxides (chapter 2

17、.15)Type BST/SG/AC.10/C.4/2006/8/Add.1page 7ST/SG/AC.10/C.4/2006/8/Add.1page 7CodePhysical hazard statementsHazard class (GHS chapter)Hazard category(1)(2)(3)(4)H242Heating may cause a fireSelf-reactive substances and mixtures (chapter 2.8); andOrganic peroxides (chapter 2.15)TypesC, D, E, FH250Catc

18、hes fire spontaneously if exposed to airPyrophoric liquids (chapter 2.9); Pyrophoric Solids (chapter 2.10)1H251Self-heating; may catch fireSelf-heating substances and mixtures (chapter 2.11)1H252Self-heating in large quantities; may catch fireSelf-heating substances and mixtures (chapter 2.11)2H260I

19、n contact with water releases flammable gases which may ignite spontaneouslySubstances and mixtures which, in contact with water, emit flammable gases (chapter 2.12)1H261In contact with water releases flammable gasSubstances and mixtures which, in contact with water, emit flammable gases (chapter 2.

20、12)2, 3H270May cause or intensify fire; oxidizerOxidizing gases (chapter 2.4)1H271May cause fire or explosion; strong oxidizerOxidizing liquids (chapter 2.13); Oxidizing solids (chapter 2.14)1H272May intensify fire; oxidizerOxidizing liquids (chapter 2.13); Oxidizing solids (chapter 2.14)2, 3H280Con

21、tains gas under pressure; may explode if heatedGases under pressure (chapter 2.5)Compressed gasLiquefied gasDissolved gasH281Contains refrigerated gas; may cause cryogenic burns or injuryGases under pressure (chapter 2.5)Refrigerated liquefied gasH290May be corrosive to metalsCorrosive to metals (Ch

22、apter 2.16)1ST/SG/AC.10/C.4/2006/8/Add.1page 8Table A3.1.2Hazard statement codes for health hazardsCode(1)Health hazard statements(2)Hazard class (GHS chapter)(3)Hazard category(4)H301Fatal if swallowedAcute toxicity oral (chapter 3.1)1, 2H302Toxic if swallowedAcute toxicity oral (chapter 3.1)3H303H

23、armful if swallowedAcute toxicity oral (chapter 3.1)4H304May be harmful if swallowedAcute toxicity oral (chapter 3.1)5H305May be fatal if swallowed and enters airwaysAspiration hazard (chapter 3.10)1H306May be harmful if swallowed and enters airwaysAspiration hazard (chapter 3.10)2H310Fatal in conta

24、ct with skinAcute toxicity dermal(chapter 3.1)1, 2H311Toxic in contact with skinAcute toxicity dermal(chapter 3.1)3H312Harmful in contact with skinAcute toxicity dermal(chapter 3.1)4H313May be harmful in contact with skinAcute toxicity dermal(chapter 3.1)5H314Causes severe skin burns and eye damageS

25、kin corrosion/irritation(chapter 3.2)1A, 1B, 1CH315Causes skin irritationSkin corrosion/irritation(chapter 3.2)2H316Causes mild skin irritationSkin corrosion/irritation(chapter 3.2)3H317May cause an allergic skin reactionSensitisation skin (chapter 3.4)1H318Causes serious eye damageSerious eye damag

26、e/eye irritation(chapter 3.3)1H319Causes serious eye irritationSerious eye damage/eye irritation(chapter 3.3)2AH320Causes eye irritationSerious eye damage/eye irritation(chapter 3.3)2BH330Fatal if inhaledAcute toxicity inhalation(chapter 3.1)1, 2H331Toxic if inhaledAcute toxicity inhalation(chapter

27、3.1)3H332Harmful if inhaledAcute toxicity inhalation(chapter 3.1)4H333May be harmful if inhaledAcute toxicity inhalation(chapter 3.1)5ST/SG/AC.10/C.4/2006/8/Add.1page 9ST/SG/AC.10/C.4/2006/8/Add.1page 9Code(1)Health hazard statements(2)Hazard class (GHS chapter)(3)Hazard category(4)H334May cause all

28、ergy or asthma symptoms or breathing difficulties if inhaledSensitisation respiratory(chapter 3.4)1H335May cause respiratory irritationSpecific target organ systemic toxicity single exposure; Respiratory tract irritation (chapter 3.8);3H336May cause drowsiness or dizziness Specific target organ syst

29、emic toxicity single exposure; Narcosis (chapter 3.8)3H350May cause genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)Germ cell mutagenicity(chapter 3.5)1A, 1BH351Suspected of causing genetic defects (state route of exposure if it

30、 is conclusively proven that no other routes of exposure cause the hazard)Germ cell mutagenicity(chapter 3.5)2H352May cause cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)Carcinogenicity (chapter 3.6)1A, 1BH353Suspected of causing cance

31、r (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)Carcinogenicity (chapter 3.6)2H354May damage fertility or the unborn child (state specific effect if known (state route of exposure if it is conclusively proven that no other routes of exposure

32、cause the hazard)Reproductive toxicity (chapter 3.7)1A, 1BH355Suspected of damaging fertility or the unborn child (state specific effect if known)(state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)Reproductive toxicity (chapter 3.7)2H356May cause

33、harm to breast-fed childrenReproductive toxicity effects on or via lactation (chapter 3.7)Additional categoryH360Causes damage to organs (or state all organs affected, if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)Specific target or

34、gan systemic toxicity single exposure (chapter 3.8)1ST/SG/AC.10/C.4/2006/8/Add.1page 10Code(1)Health hazard statements(2)Hazard class (GHS chapter)(3)Hazard category(4)H361May cause damage to organs (or state all organs affected, if known)(state route of exposure if it is conclusively proven that no

35、 other routes of exposure cause the hazard)Specific target organ systemic toxicity single exposure(chapter 3.8)2H362Causes damage to organs (or state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of ex

36、posure cause the hazard)Specific target organ systemic toxicity repeated exposure(chapter 3.9)1H363May cause damage to organs (or state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause t

37、he hazard)Specific target organ systemic toxicity repeated exposure(chapter 3.9)2ST/SG/AC.10/C.4/2006/8/Add.1page 11ST/SG/AC.10/C.4/2006/8/Add.1page 11Table A3.1.3Hazard statement codes for environmental hazardsCode(1)Environmental hazard statements(2)Hazard class (GHS chapter)(3)Hazard category(4)H

38、401Very toxic to aquatic lifeHazardous to the aquatic environment acute toxicity(chapter 4.1)1H402Toxic to aquatic lifeHazardous to the aquatic environment acute toxicity(chapter 4.1)2H403Harmful to aquatic lifeHazardous to the aquatic environment acute toxicity(chapter 4.1)3H410Very toxic to aquati

39、c life with long lasting effectsHazardous to the aquatic environment chronic toxicity(chapter 4.1)1H411Toxic to aquatic life with long lasting effectsHazardous to the aquatic environment chronic toxicity(chapter 4.1)2H412Harmful to aquatic life with long lasting effectsHazardous to the aquatic envir

40、onment chronic toxicity(chapter 4.1)3H413May cause long lasting harmful effects to aquatic lifeHazardous to the aquatic environment chronic toxicity(chapter 4.1)4ST/SG/AC.10/C.4/2006/8/Add.1page 12blank pageST/SG/AC.10/C.4/2006/8/Add.1page 13ST/SG/AC.10/C.4/2006/8/Add.1page 13Annex 3SECTION 2CODIFIC

41、ATION OF PRECAUTIONARY STATEMENTSA3.2.1IntroductionA3.2.1.1A Precautionary statement is a phrase (and/or pictogram) which describes recommended measures that should be taken to minimize or prevent adverse effects resulting from exposures to a hazardous product, or improper storage or handling of a h

42、azardous product (see 1.4.10.5.2 (c).A3.2.1.2For the purposes of the GHS, there are five types of precautionary statements: general, prevention, response (in case of accidental spillage or exposure, emergency response and first-aid), storage and disposal. For guidance on the use of GHS precautionary

43、 statements, including advice on the selection of the appropriate statements for each GHS hazard class and category, see section 3 to this annex.A3.2.1.3This section contains the codes assigned to each of the precautionary statement types described in the GHS.A3.2.2Codification of precautionary stat

44、ementsA3.2.2.1Precautionary statements are assigned a unique alphanumerical code which consists of one letter and three numbers as follows:(a)a letter “P” (for “precautionary statement”)(b)one number designating the type of precautionary statement as follows:“1” for general precautionary statements;

45、“2” for prevention precautionary statements;“3” for response precautionary statements;“4” for storage precautionary statements;“5” for disposal precautionary statements;(c)two numbers (corresponding to the sequential numbering of precautionary statements)A3.2.2.2The precautionary statement codes sha

46、ll only be used for reference purposes and shall neither form part of the precautionary statement text that appears on a GHS label, nor replace it.A3.2.2.3The codes to be used for designating precautionary statements are listed, in numerical order, in Table A3.2.1 for general precautionary statement

47、s, Table A3.2.2 for prevention precautionary statements, Table A3.2.3 for response precautionary statements, Table A3.2.4 for storage precautionary statements and Table A3.2.5 for disposal precautionary statements.ST/SG/AC.10/C.4/2006/8/Add.1page 14A3.2.3Structure of the precautionary statement tabl

48、esA3.2.3.1Each table is divided into 5 columns containing the following information:Column (1)The precautionary statement code;Column (2)The precautionary statement text;Column (3)The hazard class and the route of exposure, where relevant, for which the use of a precautionary statement is recommende

49、d together with a reference to the chapter of the GHS where information about the hazard class may be found.Column (4)The hazard category or categories within a hazard class for which the use of a precautionary statement is applicable.Column (5)Where applicable, conditions relating to the use of a p

50、recautionary statement;A3.2.3.2The tables show the core part of the precautionary statements in bold print in column (2). This is the text, except as otherwise specified, that should appear on the label. Derogations from the recommended labelling statements are at the discretion of competent authori

51、ties.A3.2.3.3When a backslash or diagonal mark / appears in a precautionary statement text in column (2), it indicates that a choice has to be made between the phrases they separate. For example in P280 “Wear protective gloves/protective clothing/eye protection/face protection. In such cases, the ma

52、nufacturer or supplier can choose, or the competent authorities may prescribe the most appropriate phrase(s).A3.2.3.4When three full stops appears in a precautionary statement text in column (2), they indicate that all applicable conditions are not listed. For example in P241 “Use explosion-proof el

53、ectrical/ventilating/lighting/./equipment”, the use of “.” indicates that other equipment may need to be specified. Further details of the information to be provided may be found in column (5). In such cases the manufacturer or supplier can choose, or the competent authorities may prescribe the othe

54、r conditions to be specified.A3.2.3.5In cases where additional information is required or information has to be specified, this is indicated by a relevant entry in column (5) in plain text.A3.2.3.6When text in italics is used in column (5), this indicates specific conditions applying to the use or a

55、llocation of the precautionary statement. This may be conditions attaching to either the general use of a precautionary statement or its use for a particular hazard class and/or hazard category. For example, for P241 “Use explosion-proof electrical/ventilating/lighting/./equipment”, only applies for

56、 flammable solids “if dust clouds can occur”.A3.2.3.7To facilitate translation into the languages of users, precautionary statements have been broken down into individual sentences in the tables in this section. In a number of instances the text that appears on a GHS label requires that these be add

57、ed back together. This is indicated in this annex by codes conjoined with a plus sign “+”. For example P305 + P351 + P338 indicates that the text to appear on the label is “IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

58、”. These additive precautionary statements can also be found at the end of each of the precautionary statement tables in this section. Translation of only the ST/SG/AC.10/C.4/2006/8/Add.1page 15ST/SG/AC.10/C.4/2006/8/Add.1page 15single precautionary statements is required, as this will enable the co

59、mpilation of the additive precautionary statements.ST/SG/AC.10/C.4/2006/8/Add.1page 16Table A3.2.1Codification of general precautionary statementsCodeGeneral precautionary statementsHazard classHazard categoryConditions for use(1)(2)(3)(4)(5)P101 If medical advice is needed, have product container o

60、r label at hand.Consumer productsP102 Keep out of reach of children.Consumer productsP103 Read label before use.Consumer productsTable A3.2.2Codification of prevention precautionary statementsCodePrevention precautionary statementsHazard classHazard categoryConditions for use(1)(2)(3)(4)(5)Explosive