含氮有机化合物3

1、rnh2+rsnhroo（碱碱）et3n+hclrscloorsoroo（碱碱）et3n+hcl+rohrnh2r2nhr3nphso2nhrphso2nr2naohnaoh不不溶溶不不溶溶phso2nr naphso2nhr溶溶解解不不溶溶h+phso2nr2不不溶溶h+phso2nr2不不溶溶未未变变化化未未变变化化phso2cl +r3nh+r3nh溶溶解解phso2cl1o 胺胺2o 胺胺3o 胺胺不不溶溶（不不反反应应）rnh2rohh2o+hno2n2r2nhr2n nohno2r3nr3nhhno2no2sncl2 / hclr2nhohr3n油状物油状物溶于水溶于水nhrnr2

2、nh2nano2 / hclhno2hno2油油状状物物0 5ocx重重氮氮盐盐（05oc稳稳定定）n2nnornr2onnr2onhxhxno 对对苯苯环环的的亲亲电电取取代代溶溶解解于于酸酸 -萘萘酚酚honnph红红色色染染料料ccho+ccnr2hor ohrhnr2rccnrccnroccnrccnr2rccnr2rccorccorrx1.2. h2o / h+ccorrcocl1.2.cccororo1.2.rocoh2o / h+h2o / h+rrr ccnr2ronhh+n(1)br(2) h3o+o(1) ch3cocl(2) h3o+och3oh3co2conh+(1)(

3、2) h3o+ch3h3cbroh3co2coch3ch3oh3co2cnhr3nrx+rr3nxrr3nxnaohrr3nnaxoh+hr3nxr3n+h2o+季季铵铵碱碱季季铵铵盐盐普普通通铵铵盐盐naohnax+亲亲 水水 部部 分分亲亲 油油 部部 分分n(ch3)3 clphch2cl(n-bu)4n brn(ch3)3c16h33r4n ohr4n xag2o或或 agoh+agxnch2h3cch3ch3crch2chr+h h2oohnh3cch3ch3h+ 主主要要naoc2h5ch2chh3cchch2x hhch2chh3cchch2hch2chh3cchch2n(ch3

4、)3 ohch2chh3cchch2ch2chh3cchch298%2%+ hhhh nch2h2cch3ch3ch2hch3cohch2ch2+ hhnh2cch3ch3h2ch3c 主主要要产产物物 ch2n(ch3)3 ohch2ch2+99%1%ch2chch3chch2n(ch3)3 ich2chch3chch296%naoc2h5,hoc2h5hhhhhhh ch2ch3n(ch3)3 ohch3n(ch3)3ich3nh2ch3cnh2och2ch3cnh2och3nh2br2 / naoh3 ch3ich3n(ch3)3iagohch3n(ch3)3 oh nch3nch3hhnch3hnch3ch3ch3iag2onch3ch3ch3ohnch2ch3ch3彻彻底底甲甲基基化化彻彻底底甲甲基基化化ag2o ch3i2 ch3i nch3hag2onch3ch3ch3ch32 ch3i彻彻底底甲甲基基化化 phch2ch2nch2ch3ch3ch3ohchch2ph93%ch2ch2+0.4% ch3n(ch3)3oh ch3+n(ch3)3150occhch2r+hon(ch3)2rchch2n(ch3)2h or3nh2o2r3nochhon(ch3)2ch2r ho n(ch3)2+chhon(ch3)2chr chch2rn(ch3)2hdh3c