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1、Metalworking Additives 金属加工添加剂金属加工添加剂 Agenda 议程 Introduction 概况介绍 Metalworking Capabilities and Support 金属加工系列产品线和技术支持 Product Offering and Formulation Advices 产品介绍和配方举例 Questions 问题 Lubrizol Lockhart -Locksol -Lockguard Becher Chemie -Becrosan -Contram -Skosanor Alox -Aqualox -Alox Gateway -Addco -

2、Synester -Addconate Lubrizol Metalworking Brand Names Sulfurized EP Additives, Traditional Soluble Oil Emulsifier 硫系极压剂及乳化剂产品硫系极压剂及乳化剂产品 Waterbased Additives, Emulsifier Expertise, Speciality Polymeric Esters 水基添加剂、乳化剂和聚合酯水基添加剂、乳化剂和聚合酯 Water based Additives, Corrosion Inhibitor Expertise,水基防锈及防腐水基防锈

3、及防腐 蚀剂蚀剂Biocides杀菌剂杀菌剂 Rust Preventives, Water based Corrosion Inhibitors 防锈剂防锈剂 Rust Preventives, Natural Sulfonate supply, Thixotropic Gelled Sulfonate 防锈剂、磺酸盐防锈剂、磺酸盐 Global Support 全球技术支持 Technical laboratories 技术实验室 Wickliffe, OH USA Brecksville, OH USA Hazelwood, England Spartanburg, SC USA Met

4、alworking Research low aluminum staining tendency 能够增强配方的润滑性,对铝基本无腐蚀。 LUBRIZOL 5636: Benefits Summary特点总结 Ability to produce low foam emulsion products that solve problems at end user operations LZ5636可配制低泡沫乳液,从而解决终端用户使用过程中出现的诸多问题。 Reduce reliance on defoamer treatments that provide temporary soluti

5、ons 减少了对消泡剂的依赖性,消泡剂所能提供的只是短期和暂时的效果。 Product performance differentiation vs competitors using traditional emulsion approaches 相比传统乳化技术,它可使产品性能差异化,满足各种不同需求 New chemistry for the industryalternative to sulfonates that offer less performance and uncertain supply future LZ5636是行业中新颖的化学品, 可做为磺酸钠的替代品使用。磺酸钠

6、与之 相比性能较差,并且在将来供应很可能极不稳定。 Economically viable approach for a wide range of finished fluid emulsion types & product performance levels 对广泛的乳化液类型和不同性能和档次 的产品,它都是一个经济可行的解决方案。 Lubrizol 5477 SOE Package for Paraffinic Oil Lubrizol 5477-用于石蜡基油的全新可溶油复合剂 Used in variety of paraffinic base stock with 3% Cont

7、ram ST-1 可以和可以和3%Contram ST-1并用于并用于 广泛的石蜡基油广泛的石蜡基油 Contains copper corrosion inhibitor 含有铜合金缓 蚀剂 Provides good hard water stability, high pH value, Cu protection, good bloom and rust protection 优异的硬水稳定性,较高的pH值,铜合金保护,自乳化性能和防锈保护 Used to make conventional and EP type soluble oils 可以调配通用和极压型乳化液 Adjustme

8、nts with fatty acid, triethanolamine or other coupling agents may be required to obtain emulsion stability desired 可以使用脂肪酸、TEA或其他偶合剂来调整乳液安定性 SOLUBLE BASE 133U112C in ESSO150SN Base 133U112Cwt%15.0 ESSO 150SNwt%82.0 Contram ST-1wt%3.0 1.Concentrate stability IP311 a) High Temp 50/14daysOK b) Low Temp

9、 0/14daysOK 2.pH value 5% in DI H2O9.74 5% in Shanghai tap water (180ppm)9.46 3. Emulsion stability IP263 5% in 200ppm 50 Cream/Oil0.3/0.0 5% in 400ppm 50 Cream/Oil0.3/0.1 4. Rust Protection IP287, 5% 100ppmrust area1% 200ppmrust area1% 5. Cu Corrosion 5% in tap water, ASTM D130 100/3hrs Class1b 5.F

10、oam Test IP312, 5% in 180ppm start120ml 1min0 (3sec) 6. Bloom 自乳化性能自乳化性能 Inversion1 Formulate at 15% in ESSO150SN ( or GaoQiao, DaLian) Addition of Contram ST-1 Excellent hard water stability SOLUBLE BASE 133U112C in ESSO150SN Base 133U112Cwt%15.0 ESSO 150SNwt%82.0 Contram ST-1wt%3.0 1.Concentrate s

11、tability IP311 a) High Temp 50/14daysOK b) Low Temp 0/14daysOK 2.pH value 5% in DI H2O9.74 5% in Shanghai tap water (180ppm)9.46 3. Emulsion stability IP263 5% in 200ppm 50 Cream/Oil0.3/0.0 5% in 400ppm 50 Cream/Oil0.3/0.1 4. Rust Protection IP287, 5% 100ppmrust area316316316 D1743 (Rust, distilled

12、water)passpassfail, tr D1264 (Wash out, %)3.3%1.61.3 D4049 (Spray off, %)24.4%8.114.2 Grease Performance of Lubrizol 86GR Based Grease LZ86GR磺酸钙润滑脂性能 提高润滑脂高温流变性的添加剂 Lubrizol 5370C 提高润滑脂滴点 LZ 5370C 硼酸脂类型,2.7% wt 的硼 提高锂基脂(12HSA)的滴点 帮助复合锂基脂稳定滴点 帮助提高极压和抗磨性 加剂量 1 - 3% 与LZ 1395复配可获得更高的滴点 与其他竞争产品相比,与其他竞争产品

13、相比, 不通过欺瞒不通过欺瞒D2265滴点滴点 检测仪来获得需要的滴点。实际上是改善润滑检测仪来获得需要的滴点。实际上是改善润滑 脂的高温流变性能来提高滴点。脂的高温流变性能来提高滴点。 Testing ASTM D 2265: 滴点测试仪 GR6 40/GR-SP 37 1-27-98 Thermometer Test Tube Test Cup Test Grease Applied to the Wall of Cup Thermometer Does Not Touch Grease Aluminum Block Oven Testing ASTM D 2265: 润滑脂滴点测试 He

14、ating Unit with Observation Ports “仪器欺瞒”是指将油完全从润滑脂中分离出去,形成 一个长的油滴,悬挂在油杯上而不滴落-这样形成一个 润滑脂具有很好高温滴点的假象。 Lithium 12-Hydroxystearate Greases ASTM D2265 Dropping Point Test Results MoDTP = Molybdenum di(2-ethylhexyl) phosphorodithioate, an additive typically recommended at 0.75%/wt to improve the dropping

15、point of grease. 123456 Base Grease10098.5979794.599.25 LZ 5370C1.53.01.51.5 LZ 13951.5 LZ 52354.0 MoDTP0.75 Drop Point (C)207263283316316205 In simple lithium greases, MoDTP has NO effect Lithium Complex Greases (Azelaic Acid/12-HSA) ASTM D2265 Dropping Point Test Results 123456 Base Grease10098.59

16、79794.599.25 LZ 5370C1.53.01.51.5 LZ 13951.5 LZ 52354.0 MoDTP0.75 Drop Point (C)316315313315316305 MoDTP = Molybdenum di(2-ethylhexyl) phosphorodithioate, an additive typically recommended at 0.75%/wt to improve the dropping point of grease. In a good Li complex, MoDTP has reduced the drop pt. Failed Lithium Complex Greases (Azelaic Acid/12-HSA) ASTM D2265 Dropping Point Test Results 123456 Base Grease10098.5979794.599.25 LZ 5370C1.53.01.51.5 LZ 13951.5 LZ 52354.0 MoDTP0.75 Drop Point (C)223282298316316283 MoDTP

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