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PART1MaterialsUnit1EngineeringMaterialsUnit2MechanicalPropertiesofMetalsUnit3SteelsUnit4CastIronUNIT5StainlessSteelsUnit1EngineeringMaterialsNewwordsandexpressionsUnit1EngineeringMaterialsAllproductsthatcomeoutofindustryconsistofatleastoneandoftenmanytypesofmaterials.Themostobviousexampleistheautomobile.Acarcontainsawidevarietyofmaterials,rangingfromglasstosteeltorubber,plusnumerousothermetalsandplastics.Thenumberofmaterialswhichareavailabletotheengineerinindustryisalmostinfinite.Thevariouscompositionsofsteelalonerunintothethousands.Ithasbeensaidthattherearemorethan10,000varietiesofglass,andthenumbersofplasticsareequallygreat.Itaddition,severalhundrednewvarietiesofmaterialsappearonthemarketeachmonth.Thismeansthatindividualengineersandtechnicianscannothopetobefamiliarwithallthepropertiesofalltypesofmaterialsintheirnumerousforms.Allhecandoistrytolearnsomeprinciplestoguidehimintheselectionandprocessingofmaterials.Thepropertiesofamaterialoriginatefromtheinternalstructureofthatmaterial.ThisisanalogoustosayingthattheoperationofaTVsetdependsonthecomponentsandcircuitswithinthatset.Theinternalstructuresofmaterialsinvolveatoms,andthewayatomsareassociatedwiththeirneighborsintocrystals,molecules,andmicrostructures.Itisconvenienttodividematerialsintothreemaintypes:(1)metals(2)plasticsorpolymersand(3)ceramics.Characteristically,metalsareopaque,ductile,andgoodconductorsofheatandelectricity.Plastics(orpolymers),whichusuallycontainlightelementsandhaverelativelylowdensity,aregenerallyinsulators,andareflexibleandformableatrelativelylowtemperatures.Ceramics,whichcontaincompoundsofbothmetallicandnonmetallicelements,areusuallyrelativelyresistanttoseveremechanical,thermal,andchemicalconditions.Metalsaredividedintoferrousandnon-ferrousmetals.Theformercontainironandthelatterdonotcontainiron.Certainelementscanimprovethepropertiesofsteelandarethereforeaddedtoit.Forexample,chromiummaybeincludedtoresistcorrosionandtungstentoincreasehardness.Aluminum,copper,andthealloys,bronzeandbrass,arecommonnon-ferrousmetals.Plasticsandceramicsarenon-metals;however,plasticsmaybemachinedlikemetals.Plasticsareclassifiedintotwotypes:thermoplasticsandthermosets.Thermoplasticscanbeshapedandreshapedbyheatandpressurebutthermosetscannotbereshapedbecausetheyundergochemicalchangesastheyharden.Ceramicsareoftenemployedbyengineerswhenmaterialswhichcanwithstandhightemperaturesareneeded.Unit2MechanicalPropertiesofMetalsNewwordsandexpressionsMechanicalpropertiesarethecharacteristicresponsesofamaterialtoappliedforces.Thesepropertiesfallintofivebroadcategories:strength,hardness,elasticity,ductility,andtoughness.Strengthistheabilityofametaltoresistappliedforces.Strengthpropertiesarecommonlyreferredtoastensilestrength,bendingstrength,compressivestrength,torsionalstrength,shearstrengthandfatiguestrength.Tensilestrengthisthatpropertywhichresistsforcesactingtopullthemetalapart.Itisoneofthemostimportantfactorsintheevaluationofametal.Compressivestrengthistheabilityofamaterialtoresistbeingcrushed.Compressionistheoppositeoftensionwithrespecttothedirectionoftheappliedload.Mostmetalshavehightensilestrengthandhighcompressivestrength.However,brittlematerialssuchascastironhavehighcompressivestrengthbutonlyamoderatetensilestrength.Unit2MechanicalPropertiesofMetalsBendingstrengthisthatqualitywhichresistsforces

from

causingamembertobendordeflectinthedirectioninwhichtheloadisapplied.Actuallyabendingstressisacombinationoftensileandcompressivestresses.Torsionalstrengthistheabilityofametaltowithstandforcesthatcauseamembertotwist.Shearstrengthreferstohow

well

amembercanwithstandtwoequalforcesactinginoppositedirections.Fatiguestrengthisthepropertyofamaterialtoresistvariouskindsofrapidlyalternatingstresses.Forexample,apistonrodoranaxleundergoescompletereversalofstresses

from

tensiontocompression.Bendingapieceofwirebackandforthuntilitbreaksisanotherexampleoffatiguestrength.Hardnessisthatpropertyin

steel

whichresistsindentationorpenetration.Hardnessisusuallyexpressedintermsoftheareaofanindentationmadebyaspecial

ball

undera

standard

load,orthedepthofaspecialindenterunderaspecificload.Elasticityistheabilitytospringbacktooriginalshape.Autobumpersandallspringsshouldhavethisquality.Ductilityistheabilitytoundergopermanentchangesofshapewithoutrupturing.Modern,deep-formedautobodiesandfenders,andotherstampedandformedproductsmusthavethisproperty.Toughnessistheabilitytoabsorbmechanicallyappliedenergy.Strengthandductilitydetermineamaterial’stoughness.Toughnessisneededinrailroadcars,automobileaxles,hammers,rails,andsimilarproducts.Unit3SteelsNewwordsandexpressionsWithoutalloyironsandsteels,thestateoftechnologywouldbesetbackconsiderably.Manyvarietiesofalloyshavebeendevelopedtomeetspecificneedsofanadvancingcivilization.However,theavailabilityofmanyvarietieshasoftenresultedinpoorselectionandexcesscostforanunnecessaryandexpensivealloymaterial.Itistheresponsibilityofthedesignandmanufacturingengineertobeknowledgeableinthisareaandtomakethebestselectionfromtheavailablealternatives.Unit3SteelsSteeltheoreticallyisanalloyofironandcarbon.Whenproducedcommercially,however,certainotherelements-notablymanganese,phosphorus,sulfurandsiliconarepresentinsmallquantities.Whenthesefourforeignelementsarepresentintheirnormalpercentages,theproductisreferredtoasplain-carbonsteel.Itsstrengthisprimarilyafunctionofitscarboncontent.Unfortunely,theductilitydecreasesasthecarboncontentisincreased,anditshardenabillityisquitelow.Inaddition,thepropertiesofordinarycarbonsteelsareimpairedbybothhighandlowtemperatures,andtheyaresubjecttocorrosioninmostenvironments.Plain-CarbonSteelPlain-carbonsteelsaregenerallyclassedintothreesubgroups,basedoncarboncontent.Low-carbonsteelshavelessthan0.30percentcarbon,possessgoodformabilityandweldability,butnotenoughhardenabilitytobehardentoanysignificantdepth.Theirstructuresusuallyareferriteandpearlite,andthematerialgenerallyisusedasitcomesfromthehot-formingorcold-formingprocess.Medium-carbonsteelshavebetween0.30and0.80percentcarbon,andtheycanbequenchedtoformmartensiteorbainiteifsectionsizeissmallandaseverewaterorbrinequenchisused.Thebestbalanceofpropertiesisattainedatthesecarbonlevels,thehighfatigueandtoughnessofthelow-carbonmaterialbeingingoodcompromisewiththestrengthandhardnessthatcomeswithhighercarboncontent[4].Thesesteelsfindnumerousapplications.High-carbonsteelshavemorethan0.80percentcarbon;toughnessandformabilityarequitelow,buthardnessandwearresistancearehigh.Severequenchescanformmartensite,buthardenabilityisstillpoor.Quenchcrackingisoftenaproblemwhenthematerialispushedtoitslimit.Plaincarbonsteelsarethelowest-coststeelmaterialandshouldbeconsideredformanyapplications.Often,however,theirlimitationsbecomerestrictive.Whenimprovedmaterialisrequired,steelscanbeupgradedbytheadditionofonemorealloyingelements.Thedifferentiationbetween“plaincarbon”and“alloy”steelisoftensomewhatarbitrary.Bothcontaincarbon,manganese,andusuallysilicon.Copperandboronalsoarepossibleadditionstobothclasses.Steelscontainingmorethan1.65percentmanganese,0.60percentsilicon,or0.60percentcopperaredesignatedasalloysteels.Also,steelisconsideredtobeanalloysteelifadefiniteamountorminimumofotheralloyingelementisspecifiedorrequired.Themostcommonalloyelementsarechromium,nickel,molybdenum,vanadium,tungsten,cobalt,boron,andcopper,aswellasmanganese,silicon,phosphorus,andsulfurinamountsgreaterthannormallyarepresent.AlloySteelsUnit4CastIronNewwordsandexpressionsCastiron,essentiallyanalloyofiron,carbon,andsilicon,iscomposedofironandfrom2to6.67percentcarbon,plusmanganese,sulfur,andphosphorus.Commerecialcastironcontainsnomorethan4percentcarbon.Castironisoftenalloyedwithelementssuchasnickel,chromium,molybdenum,vanadium,copper,andtitanium.Alloyingelementstoughenandstrengthencastirons.Unit4CastIronGraycastironisarelativelybrittlematerial,mainlybecauseofitslongthingraphiteflakesthatareveryweak.Graycastironisametalthatwillwithstandlargecompressiveloadsbutsmalltensileloads.GrayCastIronWhitecastironisveryhard,brittle,andvirtuallynonmachinable.Insomecasesitisusedwherethereisaneedforresistancetoabrasion.Whitecastironisoftenfoundincombinationwithothercastiron,suchasgraycastiron,toimprovethehardnessandwearresistantproperties.Therearebasicallytwowaysofobtainingwhitecastiron.Onewayisbyloweringtheiron`ssiliconcontent;thesecondisbyrapidcooling,whichinthiscaseyieldswhatiscalledchilledcastiron.Whencooledatarapidrate,theexcesscarbonformsironcarbideandnotgraphite,thusmakingwhitecastirons.WhiteCastIronMalleablecastironisnotedforitsstrength,toughness,ductility,andmachinability.Intheprocessofmakingmalleablecastiron,itisfirstnecessarytobeginwithwhitecastiro.Thewhitecastironisthenheattreatedasfollows.1.Heattoabout1700℉(927℃);2.Holdatthistemperatureforabout15hours.Thisbreaksdowntheironcarbidetoausteniteandgraphite;3.Slowcooltoabout1300℉(704℃);4.Holdatthistemperatureforapproximately15hours;5.Aircooltoroomtemperature.Theaboveprocessbreaksdowntheironcarbideintoadditionalausteniteandgraphite.Uponcoolingthegraphitewillformintoclustersorballs.Theaustenitewilltakeonanyoneofthetransformationproducts,dependingonthecoolingrate.MalleableCastIronNodularcastironisknownbyseveralnames:nodulariron,ductileiron,andspheroidalgraphiteiron.Itgetsthenamesfromtheball-likeformofthegraphiteinthemetalandtheveryductilepropertyitexhibits.Nodularcastironcombinesmanyoftheadvantageofcastironandsteel.Itsadvantagesincludegoodcastability,toughness,machinability,goodwearresistance,weldability,lowmeltingpoint,andhardenability.Theformationofthegraphiteintoaballformisaccomplishedbyaddingcertainelementssuchasmagnesiumandceriumtothemeltjustpriortocasting.Thevigorousmixingreactioncausedbyaddingtheseelementsresultsinahomogeneousspheroidalorball-likestructureofthegraphiteinthecastiron.Theironmatrixorbackgroundmaterialcanbeheattreatedtoformanyoneofthemicrostructuresassociatedwithsteelssuchasferrite,pearlite,ormartensite.NodularCastIronUNIT5StainlessSteelsNewwordsandexpressionsStainlesssteelsdonotrustintheatmosphereasmostothersteelsdo.Theterm“stainless”impliesaresistancetostaining,rusting,andbitingintheair,moistandpollutedasitis,andgenerallydefinesachromiumcontentinexcessof11%butlessthan30%.Andthefactthatthestuffis“steel”meansthatthebaseisiron.Stainlesssteelshaveroom-temperatureyieldstrengthsthatrangefrom205MPa(30ksi)tomorethan1725MPa(250ksi).Operatingtemperaturesaround750℃(1400ºF)arecommon,andinsomeapplicationstemperaturesashighas1090℃(2000ºF)arereached.Attheotherextremeoftemperaturesomestainlesssteelsmaintaintheirtoughnessdowntotemperaturesapproachingabsolutezero.UNIT5StainlessSteelsWithspecificrestrictionsincertaintypes,thestainlesssteelscanbeshapedandfabricatedinconventionalways.Theycanbeproducedandusedintheas-castcondition;shapescanbeproducedbypowder-metallurgytechniques;castingotscanberolledorforged(andthisaccountsforthegreatesttonnagebyfar).Therooledproductcanbedrawn,bent,extruded,orspun.Stainlesssteelcanbefurthershapedbymachining,anditcanbejoinedbysoldering,brazing,andwelding.Itcanbeusedasanintegralcladdingonplaincarbonorlowalloysteels.Thegenericterm“stainlesssteel”coversscoresofstandardcompositionsaswellasvariationsbearingcompanytradenamesandspecialalloysmadeforparticularapplications.Stainlesssteelsvaryintheircompositionfromafairlysimplealloyof,essentially,ironwith11%chromium,tocomplexalloysthatinclude30%chromium,substantialquantitiesofnickelandhalfadozenothereffectiveelements.Atthehigh-chromium,high-nickelendoftherangetheymergeintoothergroupsofheat-resistingalloys,andonehastobearbitraryaboutacutoffpoint.Ifthealloycontentissohighthattheironcontentisabouthalf,however,thealloyfallsoutsidethestainlessfamily.Evenwiththeseimposedrestrictionsoncomposition,therangeisgreat,andnaturally,thepropertiesthataffectfabricationandusevaryenormously.Itisobviouslynotenoughtospecifysimplya“stainlesssteel”.Thevariousspecifyingbodiescategorizestainlesssteelsaccordingtochemicalcompositionandotherproperties.Forexample,theAmericanIronandSteelInstitute(AISI)listsmorethan40approvedwroughtstainlesssteelcompositions;theAmericanSocietyforTestingandMaterials(ASTM)callsforspecificationsthatmayconformtoAISIcompositionsbutadditionallyrequirecertainmechanicalpropertiesanddimensionaltolerances;theAlloyCastingInstitute(ACI)specifiescompositionsforcaststainlesssteelswithinthecategoriesofcorrosion-andheat-resistingalloys;theSocietyofAutomotiveEngineers(SAE)hasadoptedAISIandACIcompositionalspecifications.MilitaryspecificationMIL-HDBK-5listsdesignvalues.Inaddition,manufacturers’specificationsareusedforspecialpurposesorforproprietaryalloys.Federalandmilitaryspecificationsandmanufacturers’specificationsarelaiddownforspecialpurposesandsometimesacquireageneralacceptance.However,allthestainlesssteels,whateverspecificationstheyconformto,canbeconvenientlyclassifiedintosixmajorclassesthatrepresentthreedistincttypesofalloyconstitution,orstructure.Theseclassesareferritic,martensitic,austenitic,manganese-substitutedaustenitic,duplexaustenitic-ferritic,andprecipitation-hardening.FerriticStainlesssteelissonamedbecausethecrystalstructureofthesteelisthesameasthatofironatroomtemp

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