化工设计竞赛附录3-物料衡算表

2019“东华科技-恒逸石化杯”第十三届全国大学生化工设计竞赛中国石化中科炼化

年产10万吨醋酸乙烯酯和4.5万吨的碳酸乙烯酯项目物料衡算表丹东路1号团队队伍成员：崔荣凯、赵越、崔梓铭、王金林、陈子璇指导老师：封瑞江、王吉林、龙文宇、鞠佳、梁飞雪目录TOC\o"1-5"\h\z\o"CurrentDocument"第一章概述 1\o"CurrentDocument"第二章物料衡算原理 2\o"CurrentDocument"第三章物料衡算任务 4\o"CurrentDocument"第四章物料衡算表 5\o"CurrentDocument"醋酸乙烯合成工段 5\o"CurrentDocument"气体分离车间 12\o"CurrentDocument"醋酸乙烯精制车间 25\o"CurrentDocument"碳酸乙烯合成精制工段 41第一章概述本项目以总厂在广东省湛江市中国石化中科炼化化工业园区的中国石化中科炼化责任有限公司的醋酸为主要工业原料进行生产醋酸乙烯烯酯。以醋酸为原料经醋酸乙烯酯合成工段、气体分离工段、醋酸乙烯精制工段、碳酸乙烯合成精制工段。设计过程中利用AspenPlus对全流程进行模拟，并在此基础上完成物料衡算、能量衡算，Aspenplus全模拟流程如图1-1所示。原料氧气醋酸蒸发器品酸乙烯合成反应器图1-1第二章物料衡算原理系统累计的质量=输入系统的质量一输出系统的质量+反应生成的质量一反应消耗的质量假设系统无泄漏，有：dF/dt=FIN-FouT+GR-CR当系统无化学反应发生时，有：dF/dt=FIN-FouT在稳定状态下，有：dF/dt=FIN-FOUT=0，FIN=FOUT注：FIN一进入系统的物料流率；fout一流出系统的物料流率；GR—反应产生物料速率；CR—反应消耗物料速率。第三章物料衡算任务通过对系统整体以及部分主要单元的详细物料衡算，得到主、副产品的产量，原料的消耗量，“三废”的排放量以及最后产品的质量指标等关键经济技术指标，对所选工艺路线、设计流程进行定量评述，为后阶段的设计提供依据。

第四章物料衡算表醋酸乙烯合成工段换热器E0101UnitsS0110S0111FromV0101E0101ToE0101R0101TemperatureC115.7568307155.5Pressurebar11MoleFractionsMassFlowskg/hr87279.2417687279.24176MassFractionsVolumeFlowcum/hr82889.452691360.09206MolarVaporFraction11MolarLiquidFraction00MoleFlowskmol/hr2563.4593952563.459395O2kmol/hr161.686741161.686741N2kmol/hr1.0084817951.008481795H2Okmol/hr97.7795293297.77952932CH3COOHkmol/hr222.33194222.33194C2H4kmol/hr1542.4895921542.489592VACkmol/hr0.166288640.16628864CO2kmol/hr537.9968222537.9968222EOkmol/hr00ECkmol/hr00EGkmol/hr00MoleFractionsMassFlowskg/hr87279.2417687279.24176MassFractionsVolumeFlowcum/hr82889.452691360.09206

E0102UnitsS0110S0111FromV0101E0101ToE0101R0101TemperatureC115.7568155.5Pressurebar11MoleFractionsMassFlowskg/hr87279.2487279.24MassFractionsVolumeFlowcum/hr82889.4591360.09MolarVaporFraction11MolarLiquidFraction00MoleFlowskmol/hr2563.4592563.459O2kmol/hr161.6867161.6867N2kmol/hr1.0084821.008482H2Okmol/hr97.7795397.77953CH3COOHkmol/hr222.3319222.3319C2H4kmol/hr1542.491542.49VACkmol/hr0.1662890.166289CO2kmol/hr537.9968537.9968EOkmol/hr00ECkmol/hr00EGkmol/hr00MoleFractionsMassFlowskg/hr87279.2487279.24MassFractionsVolumeFlowcum/hr82889.4591360.09

E0103UnitsS0110S0111FromV0101E0101ToE0101R0101TemperatureC115.7568155.5Pressurebar11MoleFractionsMassFlowskg/hr87279.2487279.24MassFractionsVolumeFlowcum/hr82889.4591360.09MolarVaporFraction11MolarLiquidFraction00MoleFlowskmol/hr2563.4592563.459O2kmol/hr161.6867161.6867N2kmol/hr1.0084821.008482H2Okmol/hr97.7795397.77953CH3COOHkmol/hr222.3319222.3319C2H4kmol/hr1542.491542.49VACkmol/hr0.1662890.166289CO2kmol/hr537.9968537.9968EOkmol/hr00ECkmol/hr00EGkmol/hr00MoleFractionsMassFlowskg/hr87279.2487279.24MassFractionsVolumeFlowcum/hr82889.4591360.09

混合器V0101UnitsS0102S0109S0110FromT0101V0101ToV0101V0101E0101TemperatureC25119.289115.7568Pressurebar18.9451MoleFractionsMassFlowskg/hr5191.96682087.27687279.24MassFractionsVolumeFlowcum/hr4020.5488759.110982889.45MolarVaporFraction111MolarLiquidFraction000MoleFlowskmol/hr162.18972401.26972563.459O2kmol/hr161.68670161.6867N2kmol/hr0.0026351.00584681.008482H2Okmol/hr0.15027997.6292597.77953CH3COOHkmol/hr0222.33194222.3319C2H4kmol/hr01542.48961542.49VACkmol/hr00.16628860.166289CO2kmol/hr0.35537.64682537.9968EOkmol/hr000ECkmol/hr000EGkmol/hr000MoleFractionsMassFlowskg/hr5191.96682087.27687279.24MassFractionsVolumeFlowcum/hr4020.5488759.110982889.45

压缩机C0101UnitsS0102S0109S0110FromT0101V0101ToV0101V0101E0101TemperatureC25119.289115.7568Pressurebar18.9451MoleFractionsMassFlowskg/hr5191.96682087.2887279.24MassFractionsVolumeFlowcum/hr4020.5488759.11182889.45MolarVaporFraction111MolarLiquidFraction000MoleFlowskmol/hr162.18972401.272563.459O2kmol/hr161.68670161.6867N2kmol/hr0.0026351.0058471.008482H2Okmol/hr0.15027997.6292597.77953CH3COOHkmol/hr0222.3319222.3319C2H4kmol/hr01542.491542.49VACkmol/hr00.1662890.166289CO2kmol/hr0.35537.6468537.9968EOkmol/hr000ECkmol/hr000EGkmol/hr000MoleFractionsMassFlowskg/hr5191.96682087.2887279.24MassFractionsVolumeFlowcum/hr4020.5488759.11182889.45

反应器R0101UnitsS0102S0109S0110FromT0101V0101ToV0101V0101E0101TemperatureC25119.289115.7568Pressurebar18.9451MoleFractionsMassFlowskg/hr5191.96682087.2887279.24MassFractionsVolumeFlowcum/hr4020.5488759.11182889.45MolarVaporFraction111MolarLiquidFraction000MoleFlowskmol/hr162.18972401.272563.459O2kmol/hr161.68670161.6867N2kmol/hr0.0026351.0058471.008482H2Okmol/hr0.15027997.6292597.77953CH3COOHkmol/hr0222.3319222.3319C2H4kmol/hr01542.491542.49VACkmol/hr00.1662890.166289CO2kmol/hr0.35537.6468537.9968EOkmol/hr000ECkmol/hr000EGkmol/hr000MoleFractionsMassFlowskg/hr5191.96682087.2887279.24MassFractionsVolumeFlowcum/hr4020.5488759.11182889.45

T0101UnitsS0102S0109S0110FromT0101V0101ToV0101V0101E0101TemperatureC25119.289115.7568Pressurebar18.9451MoleFractionsMassFlowskg/hr5191.96682087.2887279.24MassFractionsVolumeFlowcum/hr4020.5488759.11182889.45MolarVaporFraction111MolarLiquidFraction000MoleFlowskmol/hr162.18972401.272563.459O2kmol/hr161.68670161.6867N2kmol/hr0.0026351.0058471.008482H2Okmol/hr0.15027997.6292597.77953CH3COOHkmol/hr0222.3319222.3319C2H4kmol/hr01542.491542.49VACkmol/hr00.1662890.166289CO2kmol/hr0.35537.6468537.9968EOkmol/hr000ECkmol/hr000EGkmol/hr000MoleFractionsMassFlowskg/hr5191.96682087.2887279.24MassFractionsVolumeFlowcum/hr4020.5488759.11182889.45气体分离车间换热器E201UnitsS0112S0201FromR0101E0202ToE0202T0201TemperatureC155.5118Pressurebar88MolarVaporFraction11MassFlowskg/hr87280.4887280.48MassFractionsVolumeFlowcum/hr11110.6410138.63MolarLiquidFraction00EnthalpyFlowGcal/hr-71.5622-72.7616MoleFlowskmol/hr2494.0142494.014O2kmol/hr00N2kmol/hr1.0084821.008482H2Okmol/hr298,242298,242CH3COOHkmol/hr83.3635983.36359C2H4kmol/hr1372.7741372.774VACkmol/hr139.1346139.1346CO2kmol/hr599.491599.491EOkmol/hr00ECkmol/hr00EGkmol/hr00

E0202UnitsS0112S0201FromR0101E0202ToE0202T0201TemperatureC155.5118Pressurebar88MolarVaporFraction11MassFlowskg/hr87280.4887280.48MassFractionsVolumeFlowcum/hr11110.6410138.63MolarLiquidFraction00EnthalpyFlowGcal/hr-71.5622-72.7616MoleFlowskmol/hr2494.0142494.014O2kmol/hr00N2kmol/hr1.0084821.008482H2Okmol/hr298,242298,242CH3COOHkmol/hr83.3635983.36359C2H4kmol/hr1372.7741372.774VACkmol/hr139.1346139.1346CO2kmol/hr599.491599.491EOkmol/hr00ECkmol/hr00EGkmol/hr00E0203UnitsS0112S0201FromR0101E0202ToE0202T0201TemperatureC155.5118Pressurebar88MolarVaporFraction11MassFlowskg/hr87280.4887280.48MassFractionsVolumeFlowcum/hr11110.6410138.63MolarLiquidFraction00EnthalpyFlowGcal/hr-71.5622-72.7616MoleFlowskmol/hr2494.0142494.014O2kmol/hr00N2kmol/hr1.0084821.008482H2Okmol/hr298,242298,242CH3COOHkmol/hr83.3635983.36359C2H4kmol/hr1372.7741372.774VACkmol/hr139.1346139.1346CO2kmol/hr599.491599.491EOkmol/hr00ECkmol/hr00EGkmol/hr00

E0204UnitsS0112S0201FromR0101E0202ToE0202T0201TemperatureC155.5118Pressurebar88MolarVaporFraction11MassFlowskg/hr87280.4887280.48MassFractionsVolumeFlowcum/hr11110.6410138.63MolarLiquidFraction00EnthalpyFlowGcal/hr-71.5622-72.7616MoleFlowskmol/hr2494.0142494.014O2kmol/hr00N2kmol/hr1.0084821.008482H2Okmol/hr298,242298,242CH3COOHkmol/hr83.3635983.36359C2H4kmol/hr1372.7741372.774VACkmol/hr139.1346139.1346CO2kmol/hr599.491599.491EOkmol/hr00ECkmol/hr00EGkmol/hr00

混合器V0202UnitsS0210S0306S0211FromV0303V0202ToV0202V0202E0204TemperatureC30186.6343159.7596Pressurebar8.58.58.5MolarVaporFraction000MassFlowskg/hr489.04611964.2092453.248MassFractionsVolumeFlowcum/hr0.4877512.4802622.943034MolarLiquidFraction111EnthalpyFlowGcal/hr-1.088-4.18278-5.27077MoleFlowskmol/hr12.0863547.9136560O2kmol/hr000N2kmol/hr01.83E-481.83E-48H2Okmol/hr5.63238721.7218827.35442CH3COOHkmol/hr6.45396526.1917732.64558C2H4kmol/hr02.88E-312.88E-31VACkmol/hr04.11E-134.11E-13CO2kmol/hr02.29E-342.29E-34EOkmol/hr000ECkmol/hr000EGkmol/hr000

P0201UnitsS0210S0306S0211FromV0303V0202ToV0202V0202E0204TemperatureC30186.6343159.7596Pressurebar8.58.58.5MolarVaporFraction000MassFlowskg/hr489.04611964.2092453.248MassFractionsVolumeFlowcum/hr0.4877512.4802622.943034MolarLiquidFraction111EnthalpyFlowGcal/hr-1.088-4.18278-5.27077MoleFlowskmol/hr12.0863547.9136560O2kmol/hr000N2kmol/hr01.83E-481.83E-48H2Okmol/hr5.63238721.7218827.35442CH3COOHkmol/hr6.45396526.1917732.64558C2H4kmol/hr02.88E-312.88E-31VACkmol/hr04.11E-134.11E-13CO2kmol/hr02.29E-342.29E-34EOkmol/hr000ECkmol/hr000EGkmol/hr000

P0202UnitsS0204S0205FromT0201P0202ToP0202T0202TemperatureC104.2798104.3666Pressurebar7.8199MolarVaporFraction00MassFlowskg/hr95190.3895190.38MassFractionsVolumeFlowcum/hr107.8605107.8752MolarLiquidFraction11EnthalpyFlowGcal/hr-193.909-193.904MoleFlowskmol/hr2303.5842303.584O2kmol/hr00N2kmol/hr0.0049330.004933H2Okmol/hr1074.1581074.158CH3COOHkmol/hr1016.6421016.642C2H4kmol/hr47.9031247.90312VACkmol/hr147.0279147.0279CO2kmol/hr17.8475617.84756EOkmol/hr00ECkmol/hr00EGkmol/hr00P0203UnitsS0204S0205FromT0201P0202ToP0202T0202TemperatureC104.2798104.3666Pressurebar7.8199MolarVaporFraction00MassFlowskg/hr95190.3895190.38MassFractionsVolumeFlowcum/hr107.8605107.8752MolarLiquidFraction11EnthalpyFlowGcal/hr-193.909-193.904MoleFlowskmol/hr2303.5842303.584O2kmol/hr00N2kmol/hr0.0049330.004933H2Okmol/hr1074.1581074.158CH3COOHkmol/hr1016.6421016.642C2H4kmol/hr47.9031247.90312VACkmol/hr147.0279147.0279CO2kmol/hr17.8475617.84756EOkmol/hr00ECkmol/hr00EGkmol/hr00

P0204UnitsS0204S0205FromT0201P0202ToP0202T0202TemperatureC104.2798104.3666Pressurebar7.8199MolarVaporFraction00MassFlowskg/hr95190.3895190.38MassFractionsVolumeFlowcum/hr107.8605107.8752MolarLiquidFraction11EnthalpyFlowGcal/hr-193.909-193.904MoleFlowskmol/hr2303.5842303.584O2kmol/hr00N2kmol/hr0.0049330.004933H2Okmol/hr1074.1581074.158CH3COOHkmol/hr1016.6421016.642C2H4kmol/hr47.9031247.90312VACkmol/hr147.0279147.0279CO2kmol/hr17.8475617.84756EOkmol/hr00ECkmol/hr00EGkmol/hr00T0201UnitsS0201S0203S0206S0204S0207FromE0202P0201T0202T0201T0201ToT0201T0201T0201P0202E0203TemperatureC11833.0631570.12503104.279835.55438Pressurebar89.37.8247.8197.8MolarVaporFraction10101MassFlowskg/hr87280.4870338.632895.86395190.3865324.6MassFractionsVolumeFlowcum/hr10138.6370.30489284.0586107.86056528.885MolarLiquidFraction01010EnthalpyFlowGcal/hr-72.7616-155.245-1.88049-193.909-39.7647MoleFlowskmol/hr2494.0141715.80177.868592303.5841984.1O2kmol/hr00000N2kmol/hr1.0084826.57E-470.0049330.0049331.008482H2Okmol/hr298,242777.8724.1278941074.1586.083599CH3COOHkmol/hr83.36359937.92922.11E-211016.6424.650862C2H4kmol/hr1372.7741.03E-2947.8313947.903121372.702VACkmol/hr139.13461.47E-118.066972147.02790.173739CO2kmol/hr599.4918.21E-3317.837417.84756599.4808EOkmol/hr00000ECkmol/hr00000EGkmol/hr00000

T0202UnitsS0205S0206S0208FromP0202T0202T0202ToT0202T0201V0201TemperatureC104.366670.12503166.6321Pressurebar97.8248MolarVaporFraction010MassFlowskg/hr95190.382895.86392294.54MassFractionsVolumeFlowcum/hr107.8752284.0586114.2433MolarLiquidFraction101EnthalpyFlowGcal/hr-193.904-1.88049-188.697MoleFlowskmol/hr2303.58477.868592225.715O2kmol/hr000N2kmol/hr0.0049330.0049331.03E-08H2Okmol/hr1074.1584.1278941070.031CH3COOHkmol/hr1016.6422.11E-211016.642C2H4kmol/hr47.9031247.831390.071046VACkmol/hr147.02798.066972138.9617CO2kmol/hr17.8475617.83740.009609EOkmol/hr000ECkmol/hr000EGkmol/hr000T0203UnitsS0209S0213S0215S0216S0217FromE0203P0203P0204T0203T0203ToT0203T0203T0203V0201V0203TemperatureC11835,1424220.6602482.043473.76144Pressurebar7.89.397.87.792MolarVaporFraction10001MassFlowskg/hr65324.62453.2481801.5283083.8766495.5MassFractionsVolumeFlowcum/hr8272.5532.4588371.8048973.3860577634.279MolarLiquidFraction01110EnthalpyFlowGcal/hr-37.9835-5.42019-6.8339-6.8454-43.3922MoleFlowskmol/hr1984.16010081.708612062.391O2kmol/hr00000N2kmol/hr1.0084821.83E-4800.000211.008272H2Okmol/hr6.08359927,3544210041,2000492.23797CH3COOHkmol/hr4.65086232.64558037.183960.112481C2H4kmol/hr1372.7022.88E-3102.3797121370.323VACkmol/hr0.1737394.11E-1300.0072740.166466CO2kmol/hr599.48082.29E-3400.93741598.5434EOkmol/hr00000ECkmol/hr00000EGkmol/hr00000

膜分离M0201UnitsS0219S0220S0221FromXV0201MR0201MR0201ToMR0201C0201V0401TemperatureC73.7614573.7614573.76145Pressurebar555MolarVaporFraction111MassFlowskg/hr8266.8385581.4642685.373MassFractionsVolumeFlowcum/hr1479.0881126.809352.2794MolarLiquidFraction000EnthalpyFlowGcal/hr-5.39460.314467-5.70907MoleFlowskmol/hr256.4001195.332461.06767O2kmol/hr000N2kmol/hr0.125350.1229250.002425H2Okmol/hr11.4671911.383950.083237CH3COOHkmol/hr0.0139840.0139840C2H4kmol/hr170.3609170.36090VACkmol/hr0.0206950.0206950CO2kmol/hr74.4119713.4299660.982EOkmol/hr000ECkmol/hr000EGkmol/hr000

醋酸乙烯精制车间换热器E0301UnitsS0219S0220S0221FromXV0201MR0201MR0201ToMR0201C0201V0401TemperatureC73.7614573.7614573.76145Pressurebar555MolarVaporFraction111MassFlowskg/hr8266.8385581.4642685.373MassFractionsVolumeFlowcum/hr1479.0881126.809352.2794MolarLiquidFraction000EnthalpyFlowGcal/hr-5.39460.314467-5.70907MoleFlowskmol/hr256.4001195.332461.06767O2kmol/hr000N2kmol/hr0.125350.1229250.002425H2Okmol/hr11.4671911.383950.083237CH3COOHkmol/hr0.0139840.0139840C2H4kmol/hr170.3609170.36090VACkmol/hr0.0206950.0206950CO2kmol/hr74.4119713.4299660.982EOkmol/hr000ECkmol/hr000EGkmol/hr000

E0303UnitsS0313S0314FromE0304E0303ToE0303VX0302TemperatureC159.0053132.008Pressurebar65.6MolarVaporFraction0.0322020MassFlowskg/hr5262.4745262.543MassFractionsVolumeFlowcum/hr61.707385.965023MolarLiquidFraction0.9677981EnthalpyFlowGcal/hr-18.9392-19.1914MoleFlowskmol/hr288.9588288.9626O2kmol/hr00N2kmol/hr00H2Okmol/hr287.6076287.6114CH3COOHkmol/hr1.3512021.351202C2H4kmol/hr00VACkmol/hr5.89E-125.89E-12CO2kmol/hr00EOkmol/hr00ECkmol/hr00EGkmol/hr00E0306UnitsS0325S0335S0326S0336FromE0401T0304E0306E0306ToE0306E0306E0307V0305TemperatureC134.0716121.5374131.2249121.666Pressurebar64.12564.125MolarVaporFraction0.51424700.4730440.22023MassFlowskg/hr21558.7715294.3821558.7715294.38MassFractionsVolumeFlowcum/hr1772.71419.427461620.373326.6875MolarLiquidFraction0.48575310.5269560.77977EnthalpyFlowGcal/hr-39.5905-14.1107-39.8553-13.8459MoleFlowskmol/hr608.7156177.7557608.7156177.7557O2kmol/hr0000N2kmol/hr0.0002132.75E-460.0002132.75E-46H2Okmol/hr450.21830.127651450.21830.127651CH3COOHkmol/hr0.0002799.18E-060.0002799.18E-06C2H4kmol/hr2.6597872.43E-242.6597872.43E-24VACkmol/hr154.8209177.6281154.8209177.6281CO2kmol/hr1.016141.59E-261.016141.59E-26EOkmol/hr0000ECkmol/hr0000EGkmol/hr0000

E0307UnitsS0331S0332FromT0304E0308ToE0308V0308TemperatureC105.126925.96673Pressurebar44MolarVaporFraction10MassFlowskg/hr9821.9519821.966MassFractionsVolumeFlowcum/hr1232.97210.9068MolarLiquidFraction01EnthalpyFlowGcal/hr-9.86153-11.341MoleFlowskmol/hr156.8109156.8111O2kmol/hr00N2kmol/hr0.0010360.001036H2Okmol/hr40.848640.84861CH3COOHkmol/hr2.79E-092.79E-09C2H4kmol/hr12.074912.0749VACkmol/hr99,2204199.22058CO2kmol/hr4.6659674.665968EOkmol/hr00ECkmol/hr00EGkmol/hr00E0308UnitsS0331S0332FromT0304E0308ToE0308V0308TemperatureC105.126925.96673Pressurebar44MolarVaporFraction10MassFlowskg/hr9821.9519821.966MassFractionsVolumeFlowcum/hr1232.97210.9068MolarLiquidFraction01EnthalpyFlowGcal/hr-9.86153-11.341MoleFlowskmol/hr156.8109156.8111O2kmol/hr00N2kmol/hr0.0010360.001036H2Okmol/hr40.848640.84861CH3COOHkmol/hr2.79E-092.79E-09C2H4kmol/hr12.074912.0749VACkmol/hr99,2204199.22058CO2kmol/hr4.6659674.665968EOkmol/hr00ECkmol/hr00EGkmol/hr00

E0309UnitsS0342S0343FromV0307E0309ToE0309TemperatureC106.342440Pressurebar1.299811.29981MolarVaporFraction0.074620MassFlowskg/hr5587.0875587.087MassFractionsVolumeFlowcum/hr562.36465.715799MolarLiquidFraction0.925381EnthalpyFlowGcal/hr-20.3041-20.9027MoleFlowskmol/hr307.3408307.3408O2kmol/hr00N2kmol/hr2.92E-062.92E-06H2Okmol/hr305.8429305.8429CH3COOHkmol/hr0.7961870.796187C2H4kmol/hr0.4107240.410724VACkmol/hr0.1211830.121183CO2kmol/hr0.1698270.169827EOkmol/hr00ECkmol/hr00EGkmol/hr00

P0301UnitsS0302S0303FromE0301P0301ToP0301T0301TemperatureC8080.08739Pressurebar7.89MolarVaporFraction00MassFlowskg/hr95378.4195378.41MassFractionsVolumeFlowcum/hr102.4819102.4944MolarLiquidFraction11EnthalpyFlowGcal/hr-199.96-199.956MoleFlowskmol/hr2307.4242307.424O2kmol/hr00N2kmol/hr0.000210.00021H2Okmol/hr1111.2311111.231CH3COOHkmol/hr1053.8261053.826C2H4kmol/hr2.4507582.450758VACkmol/hr138.969138.969CO2kmol/hr0.9470190.947019EOkmol/hr00ECkmol/hr00EGkmol/hr00P0302UnitsS0302S0303FromE0301P0301ToP0301T0301TemperatureC8080.08739Pressurebar7.89MolarVaporFraction00MassFlowskg/hr95378.4195378.41MassFractionsVolumeFlowcum/hr102.4819102.4944MolarLiquidFraction11EnthalpyFlowGcal/hr-199.96-199.956MoleFlowskmol/hr2307.4242307.424O2kmol/hr00N2kmol/hr0.000210.00021H2Okmol/hr1111.2311111.231CH3COOHkmol/hr1053.8261053.826C2H4kmol/hr2.4507582.450758VACkmol/hr138.969138.969CO2kmol/hr0.9470190.947019EOkmol/hr00ECkmol/hr00EGkmol/hr00

P0303UnitsS0302S0303FromE0301P0301ToP0301T0301TemperatureC8080.08739Pressurebar7.89MolarVaporFraction00MassFlowskg/hr95378.4195378.41MassFractionsVolumeFlowcum/hr102.4819102.4944MolarLiquidFraction11EnthalpyFlowGcal/hr-199.96-199.956MoleFlowskmol/hr2307.4242307.424O2kmol/hr00N2kmol/hr0.000210.00021H2Okmol/hr1111.2311111.231CH3COOHkmol/hr1053.8261053.826C2H4kmol/hr2.4507582.450758VACkmol/hr138.969138.969CO2kmol/hr0.9470190.947019EOkmol/hr00ECkmol/hr00EGkmol/hr00混合器V0301UnitsS0315S0316S0317FromVX0302V0301V0301ToV0301T0302V0307TemperatureC132.008132.008132.008Pressurebar2.862.862.86MolarVaporFraction000MassFlowskg/hr5262.5434012.6891249.854MassFractionsVolumeFlowcum/hr5.9650234.548331.416692MolarLiquidFraction111EnthalpyFlowGcal/hr-19.1914-14.6335-4.55797MoleFlowskmol/hr288.9626220.33468.62859O2kmol/hr000N2kmol/hr000H2Okmol/hr287.6114219.303768.30768CH3COOHkmol/hr1.3512021.0302910.32091C2H4kmol/hr000VACkmol/hr5.89E-124.49E-121.40E-12CO2kmol/hr000EOkmol/hr000ECkmol/hr000EGkmol/hr000

V0302UnitsS0319S0320S0321FromE0304V0302V0302ToV0302T0302P0302TemperatureC155.1202155.12155.12Pressurebar2.9952.9952.995MolarVaporFraction0.82823710MassFlowskg/hr30735.5725294.145441.204MassFractionsVolumeFlowcum/hr5429.2195423.036.17576MolarLiquidFraction0.17176301EnthalpyFlowGcal/hr-53.7386-43.8895-9.84884MoleFlowskmol/hr550.7319456.135594.59645O2kmol/hr000N2kmol/hr000H2Okmol/hr55.6003849.907165.698643CH3COOHkmol/hr495.1315406.228388.89781C2H4kmol/hr000VACkmol/hr4.16E-2600CO2kmol/hr000EOkmol/hr000ECkmol/hr000EGkmol/hr000

V0303UnitsS0305S0306S0307S0308FromT0301V0303V0303V0303ToV0303V0202E0201E0302TemperatureC186.6343186.6343186.6343186.6343Pressurebar8.58.58.58.5MolarVaporFraction0000MassFlowskg/hr78994.291964.20970338.636691.214MassFractionsVolumeFlowcum/hr99.748342.48026288.81868.449187MolarLiquidFraction1111EnthalpyFlowGcal/hr-168.218-4.18278-149.786-14.2489MoleFlowskmol/hr1926.93647.913651715.801163.2212O2kmol/hr0000N2kmol/hr7.38E-471.83E-486.57E-476.25E-48H2Okmol/hr873.585421.72188777.87273.99708CH3COOHkmol/hr1053.35126.19177937.929289.2241C2H4kmol/hr1.16E-292.88E-311.03E-299.82E-31VACkmol/hr1.65E-114.11E-131.47E-111.40E-12CO2kmol/hr9.22E-332.29E-348.21E-337.81E-34EOkmol/hr0000ECkmol/hr0000EGkmol/hr0000T0301UnitsS0303S0304S0305FromP0301T0301T0301ToT0301T0303V0303TemperatureC80.08739113.2362186.6343Pressurebar96.58.5MolarVaporFraction000MassFlowskg/hr95378.4116384.1378994.29MassFractionsVolumeFlowcum/hr102.494419.9262399.74834MolarLiquidFraction111EnthalpyFlowGcal/hr-199.956-26.8692-168.218MoleFlowskmol/hr2307.424380.48771926.936O2kmol/hr000N2kmol/hr0.000210.000217.38E-47H2Okmol/hr1111.231237.6454873.5854CH3COOHkmol/hr1053.8260.4752861053.351C2H4kmol/hr2.4507582.4507581.16E-29VACkmol/hr138.969138.9691.65E-11CO2kmol/hr0.9470190.9470199.22E-33EOkmol/hr000ECkmol/hr000EGkmol/hr000

T0302UnitsS0310S0316S0320S0311S0318FromE0302V0301V0302T0302T0302ToT0302T0302T0302C0301E0304TemperatureC143132.008155.12132.1091153.75Pressurebar8.52.862.9952.862.995MolarVaporFraction00110MassFlowskg/hr6691.2144012.68925294.145262.47430735.57MassFractionsVolumeFlowcum/hr7.7954774.548335423.033404.31634.98773MolarLiquidFraction11001EnthalpyFlowGcal/hr-14.4165-14.6335-43.8895-16.4992-56.4403MoleFlowskmol/hr163.2212220.334456.1355288.9588550.7319O2kmol/hr00000N2kmol/hr6.25E-480000H2Okmol/hr73.99708219.303749.90716287.607655.60038CH3COOHkmol/hr89,22411.030291406.22831.351202495.1315C2H4kmol/hr9.82E-310000VACkmol/hr1.40E-124.49E-1205.89E-124.16E-26CO2kmol/hr7.81E-340000EOkmol/hr00000ECkmol/hr00000EGkmol/hr00000T0303UnitsS0304S0328S0324S0330FromT0301V0304T0303T0303ToT0303T0303E0401V0307TemperatureC113.2362102.8203147.6111159.0309Pressurebar6.5666.011MolarVaporFraction0010MassFlowskg/hr16384.138916.01621558.773741.374MassFractionsVolumeFlowcum/hr19.926239.926533549.1644.391375MolarLiquidFraction1101EnthalpyFlowGcal/hr-26.8692-29.2048-36.742-13.5785MoleFlowskmol/hr380.4877434.7967608.7156206.5688O2kmol/hr0000N2kmol/hr0.000212.52E-060.0002131.90E-34H2Okmol/hr237.6454418.6663450.2183206.0935CH3COOHkmol/hr0.4752860.0002710.0002790.475277C2H4kmol/hr2.4507580.2090292.6597871.17E-21VACkmol/hr138.96915.85196154.82091.49E-20CO2kmol/hr0.9470190.0691211.016141.68E-23EOkmol/hr0000ECkmol/hr0000EGkmol/hr0000

T0304UnitsS0329S0334S0337S0331S0335FromV0304P0303V0305T0304T0304ToT0304T0304T0304E0308E0306TemperatureC102.820329.36842121.666105.1269121.5374Pressurebar654.12544.125MolarVaporFraction10110MassFlowskg/hr12642.759109.4763364.1299821.95115294.38MassFractionsVolumeFlowcum/hr906.100310.22552311.52891232.97219.42746MolarLiquidFraction01001EnthalpyFlowGcal/hr-12.0297-9.09972-2.84285-9.86153-14.1107MoleFlowskmol/hr173.9189121.500939.14716156.8109177.7557O2kmol/hr00000N2kmol/hr0.000210.00082600.0010362.75E-46H2Okmol/hr31.551949.3351880.08912540.84860.127651CH3COOHkmol/hr8.52E-062.22E-096.60E-072.79E-099.18E-06C2H4kmol/hr2.4507589.624139012.07492.43E-24VACkmol/hr138.96998.8218139.0580499.22041177.6281CO2kmol/hr0.9470193.71894804.6659671.59E-26EOkmol/hr00000ECkmol/hr00000EGkmol/hr00000

碳酸乙烯合成精制工段P0401UnitsS0329S0334S0337S0331S0335FromV0304P0303V0305T0304T0304ToT0304T0304T0304E0308E0306TemperatureC102.820329.36842121.666105.1269121.5374Pressurebar654.12544.125MolarVaporFraction10110MolarLiquidFraction01001MolarSolidFraction00000EnthalpyFlowGcal/hr-12.0297-9.09972-2.84285-9.86153-14.1107MoleFlowskmol/hr173.9189121.500939.14716156.8109177.7557O2kmol/hr00000N2kmol/hr0.000210.00082600.0010362.75E-46H2Okmol/hr31.551949.3351880.08912540.84860.127651CH3COOHkmol/hr8.52E-062.22E-096.60E-072.79E-099.18E-06C2H4kmol/hr2.4507589.624139012.07492.43E-24VACkmol/hr138.96998.8218139.0580499.22041177.6281CO2kmol/hr0.9470193.71894804.6659671.59E-26EOkmol/hr00000ECkmol/hr00000EGkmol/hr00000MoleFractionsMassFlowskg/hr12642.759109.4763364.1299821.95115294.38MassFractionsVolumeFlowcum/hr906.100310.22552311.52891232.97219.42746

反应器R0401Units123FromS0404R0401-1R0402-2ToR0401-1R0402-2S0405TemperatureC127.3607130130Pressurebar2.52.52.5MolarVaporFraction10.8264770.826303MolarLiquidFraction00.1735230.173697MolarSolidFraction000EnthalpyFlowGcal/hr-9.86683-11.5456-11.5482MoleFlowskmol/hr434.0573373.0077372.9403O2kmol/hr000N2kmol/hr0.002680.002680.00268H2Okmol/hr0.0936330.0936330.000936CH3COOHkmol/hr000C2H4kmol/hr000VACkmol/hr000CO2kmol/hr61.049574.68E-090.025281EOkmol/hr372.9114311.8618311.7944ECkmol/hr061.0495761.02428EGkmol/hr000.092697MoleFractionsMassFlowskg/hr19116.4719116.4719116.47MassFractionsVolumeFlowcum/hr5781.6054137.7294136.118

混合器V0401UnitsS0221S0401S0402S0403Fr