MSDS-2822032757F 芦荟葡萄 40mgml物质安全资料表

SAFETYDATASHEET

[INACCORDANCEWITHTHECRITERIAOFREGULATIONNO1907/2006(REACH)AND2015/830]

Section1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1Productidentifiers

AloeVeraGrape40mg/mLnicotineE-liquid

1.2RelevantidentifiedusesofthesubstanceormixtureandusesadvisedagainstIdentifieduses:liquidfillingforelectroniccigarettes

Usesadvisedagainst:notdetermined

1.3DetailsofthesupplierofthesafetydatasheetCompany:XXXCo.,Ltd

Address:XXX,GuangmingDistrict,Shenzhen,

Guangdong,518107,China

Telephone:+860755-3662XXXX

E-mailaddress:XXXX

1.4EmergencytelephonenumberTelephone:

110(Emergencynumber),

120(Ambulance),

119(Fire)

Section2:Hazardsidentification

2.1Classificationofthesubstanceormixture:

ClassificationaccordingtoRegulation1272/2008/EC

AcuteTox.3(H301)(ContainsNicotine)

2.2Labelelements

Hazardpictogramsandsignalwords

DANGER

Hazardphrases

H301:Toxicifswallowed

H312:Harmfulincontactwithskin

H315:Causesskinirritation

H318:Causesseriouseyedamage

H332:Harmfulifinhaled.

Safetyphrases

P101:Ifmedicaladviceisneeded,haveproductcontainerorlabelathand.

P102:Keepoutofreachofchildren.

P264:Washcontactingpartsthoroughlyafterhandling.

P301+P310:IFSWALLOWED:ImmediatelycallaPOISONCENTERordoctor/physician.

P302+P352:IFONSKIN:Washwithplentyofsoapandwater.

P305+P351+P338:IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,ifpresentandeasytodo.Continuerinsing.

P310:ImmediatelycallaPOISONCENTERordoctor/physician.

P501:Disposeofcontents/containertodesignatedplaceinaccordancewithlocal/regional/national/internationalregulations.

Namesofcomponentsonthelabel

Contains:Benzoicacid

2.3Otherhazards:

Productdoesnotcontainingredients,whichmeetcriteriaforPBTorvPvBinaccordancewithAnnexXIIIofREACHRegulation.

Section3:Composition/informationoningredients

3.1Substance:Notapplicable.Pleasereferto3.2formoreinformation.

3.2Mixtures:

IngredientName

CASNo.

%ByWeight

(%Active)

Glycerin

56-81-5

39.74

PropyleneGlycol

57-55-6

35.34

Ethanol

64-17-5

4.47

Pyridine,3-(1-methyl-2-pyrrolidinyl)-,(S)-

54-11-5

3.60

Benzoicacid

65-85-0

3.60

water

7732-18-5

3.34

Cyclohexanecarboxamide,N-ethyl-5-methyl-2-(1-

39711-79-0

2.62

methylethyl)-

Ethylmaltol

4940-11-8

1.92

2-Isopropyl-N,2,3-Trimethylbutyramide

51115-67-4

1.90

Butanoicacid,ethylester

105-54-4

0.92

Propanoicacid,ethylester

105-37-3

0.66

3-Hexen-1-ol,(Z)-

928-96-1

0.39

Butanoicacid,2-methyl-,ethylester

7452-79-1

0.33

Methylanthranilate

134-20-3

0.22

Propanoicacid

79-09-4

0.19

Butanoicacid

107-92-6

0.13

d1-Menthol

89-78-1

0.12

D-Limonene

5989-27-5

0.08

Linalool

78-70-6

0.08

Benzenemethanol,α-methyl-,acetate

93-92-5

0.08

Benzoicacid,2-(methylamino)-,methylester

85-91-6

0.06

Octanoicacid,ethylester

106-32-1

0.04

Aceticacid

64-19-7

0.04

PhenylethylAlcohol

60-12-8

0.04

Propanoicacid,2-methyl-,ethylester

97-62-1

0.03

β-Pinene

127-91-3

0.01

Butanoicacid,3-methylbutylester

106-27-4

0.01

Heptanoicacid,ethylester

106-30-9

0.01

trans-Roseoxide

876-18-6

0.01

1-Hexanol

111-27-3

0.01

2-Buten-1-one,1-(2,6,6-trimethyl-1-cyclohexen-1-

35044-68-9

0.01

yl)-

SubstancesforwhichthereareUnionworkplaceexposurelimitsarelistedinSECTION8.

ForfulltextofH-statements:seeSECTION16.

Section4:Firstaidmeasures

4.1Descriptionoffirstaidmeasures

Skincontact:takeoffcontaminatedclothing.Washthecontaminatedskinwithwaterandsoap.Immediatelyconsultadoctor.

Eyecontact:removecontactlenses.Washthecontaminatedeyewithplentyofwaterforatleast15minutes.Avoidpowerfulwaterstream.Consultadoctorifdisturbingsymptomsoccur.

Ingestion:donotinducevomiting.Rinsemouthwithwater.Nevergiveanythingtodrinktoanunconsciousperson.

Consultadoctor.Showthecontainerorlabel.

Inhalation:Removetofreshair.Keepwarmandcalm.Consultadoctor,ifdisturbingsymptomsappear.

4.2Mostimportantsymptomsandeffects,bothacuteanddelayed:

Nonereasonablyforeseeable

4.3Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded:

Physicianmakesadecisionregardingfurthermedicaltreatmentafterthoroughlyexaminationoftheinjured.

Symptomatictreatment.

Section5:Firefightingmeasures

5.1Extinguishingmedia

Suitableextinguishingmedia:Foam,dryextinguishingagents,waterspray.

Unsuitableextinguishingmedia:Waterjet-riskofthepropagationoftheflame.

5.2Specialhazardsarisingfromthesubstanceormixture:

Duringthefire,theproductmayproducetoxicfumesofcarbonmonoxideanddioxide,nitricoxidesandotherunidentifiedproductsofthermaldecomposition.Donotinhalecombustionproducts.

5.3Adviceforfirefighters:

Personalprotectiontypicalincaseoffire.Donotstayinthefirezonewithoutself-containedbreathingapparatusandprotectiveclothingresistanttochemicals.

Section6:Accidentalreleasemeasures6.1Personalprecautions,protectiveequipmentandemergencyprocedures

Limittheaccessfortheoutsidersintothebreakdownarea,untilsuitablecleaningoperationsarecompleted.Incaseoflargespills,isolatetheexposedarea.Avoidcontactwithskinandeyes.Usepersonalprotectivemeasures.

6.2Environmentalprecautions:

Incaseofreleaseoflargeamountsoftheproduct,itisnecessarytotakeappropriatestepstopreventitfromspreadingintotheenvironment.Materialmaybehazardousifreleasedinlargequantitiestotheenvironment.Notifyrelevantemergencyservices.

6.3Methodsandmaterialforcontainmentandcleaningup

Damagedcontainerputinemergencycontainer.Absorbleakagewithincombustibleliquid-bindingmaterial(e.g.sand,earth,universalbinders,silica,vermiculite)andcollectmechanicallyintoproperlylabeledcontainersfordisposal.Cleanthecontaminatedplace.

6.4Referencetoothersections:Section13andsection8.

Section7:Handlingandstorage

7.1Precautionsforsafehandling:

Handleinaccordancewithgoodoccupationalhygieneandsafetypractices.Avoidskinandeyescontamination.Beforebreakandafterworkwashhandscarefully.Usepersonalprotectivemeasures.Ensureadequateventilation.Donotlettheproducttogetintomouth.

7.2Conditionsforsafestorage,includinganyincompatibilities:

Keeponlyinoriginal,tightlyclosedcontainersinacoolandwell-ventilatedarea.Keepawayfromfood,beveragesorfeedforanimals.Avoiddirectexposuretosunlight.Keepawayfromstrongacidsandoxidizingagents.Afteropening,sealthecontainerandstoreinanuprightpositiontopreventleakage.

7.3Specificenduse(s):

Liquidfillingfore-liquid.

Section8:Exposurecontrols/personalprotection

8.1Controlparameters

Substance

Country

OELvalue

Workevaluatingexistinglimits,

Germany,Denmark,France,

0.5mg/m3(8h)

Norway,Belgium,Spain,Ireland

Nicotine

Finland,UnitedKingdom

0.5mg/m3(8h)

1.5mg/m3(15min)

Austria,Switzerland

0.5mg/m3(8h)

2mg/m3(15min)

Sweden

0.1mg/m3(8h)

10mg/m3Inhalation,localeffectsLong-term

REACHRegulations

exposure

168mg/m3Inhalation,systemiceffectsLong-term

1,2-Propyleneglycol

exposure

UnitedKingdom

474mg/m3(8h)

Norway

79mg/m3(8h)

Ireland

470mg/m3(8h)-Vaporandparticulates

10mg/m3(8h)-Particulates

AmericanConferenceof

79mg/m3(8h)

GovernmentalIndustrialHygienists

REACHRegulations

56mg/m3Inhalation,localeffectsLong-term

exposure

Glycerol

Finland

20mg/m3(8h)

France,UnitedKingdom,

Switzerland,Belgium,Spain,

10mg/m3(8h)

Ireland

6.3mg/m3Inhalation,localeffectsLong-term

Benzoicacid

REACHRegulations

exposure

10.4mg/m3Inhalation,systemiceffectsLong-term

exposure

LegalBasis:CommissionDirective2006/15/EC,2000/39/EC,2009/161/EC.

Recommendedcontrolprocedures

ProceduresConcerningthecontroloverthedangerouscomponentsconcentrationsintheairandcontrolovertheairqualityintheworkplaceinAccordancewiththeEuropeanStandards.

8.2Exposurecontrols:

Usetheproductinaccordancewithgoodoccupationalhygieneandsafetypractices.Ensureexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsofvaporsbelowtheirrespectivethresholdlimitvalue.Ensureeyestationsandsafetyshowers.

Handandbodyprotection:

Incaseofshorttermcontactuseprotectiveglovesmadeofnitrilerubber(minimalthickness:0.2mm;breakthrough

time>30minutes).Incaseoflongtermcontactuseprotectiveglovesmadeofbutylrubber(minimalthickness:0.3mm,breakthroughtime>480minutes).

Thematerialthattheglovesaremadeofmustbeimpenetrableandresistanttotheproduct’seffects.Theselectionofmaterialmustbeperformedwithconsiderationofbreakthroughtime,penetrationspeedanddegradation.

Eyeprotection:

Weartightlyfittingsafetyglassesifthereisariskofeyecontamination.

Respiratoryprotection:

Incaseofnormaluse,inaccordancewiththeintendeduse,itisnotnecessary.

AppliedpersonalprotectiveequipmentmustcomplywiththerequirementsoftheDirective89/686/EC.Theemployerisobligedtoprovideprotectiveequipmentrelevanttoperformedactivitiesandinaccordancewithallqualityrequirements,includingitsmaintenanceandcleaning.

8.3Environmentalexposurecontrols:

Donotallowtoenterlargeamountsofproducttoreachgroundwater,sewage,wastewaterorsoil.

Section9.Physicalandchemicalproperties

9.1Informationonbasicphysicalandchemicalproperties

Appearance:Yellowoilyliquidatroomtemperature

Odour:Notavailable

Odourthreshold:Notavailable

pH:Notavailable

Meltingpoint/freezingrange:Notavailable

Initialboilingpointandboilingrange:Notavailable

Flashpoint:Notavailable

Evaporationrate:Notavailable

Flammability(solid,gaseous):Thisproductisliquid,notavailable.

Upper/lowerflammabilityorexplosivelimits:Notavailable

Vapourpressure:Notavailable

Vapourdensity:Notavailable

Relativedensity(water=1g/mL):Notavailable

Solubility(ies):Notavailable

Partitioncoefficient:n-octanol/water:Notavailable

Auto-ignitiontemperature:Productisnotself-igniting.

Decompositiontemperature:Notavailable

Viscosity:Notavailable

Explosiveproperties:Productdoesnotpresentanexplosionhazard.

Oxidisingproperties:Productdoesnotpresentoxidizingproperties.

9.2Otherinformation:Notavailable

Section10:Stabilityandreactivity

10.1Reactivity:Productisfeeblyreactive.Productdoesnotundergoadangerouspolymerization.Seealso10.4-10.5

10.2Chemicalstability:Theproductisstableundernormalstorageandusingcondition.

10.3Possibilityofhazardousreactions:Dangerousreactionsarenotknown.

10.4Conditionstoavoid:Avoiddirectexposuretosunlight.

10.5Incompatiblematerials:Strongoxidizingagents,acids.

10.6Hazardousdecompositionproducts:Notavailable

Section11:Toxicologicalinformation

11.1Informationontoxicologicaleffects

Toxicityofcomponents

LD/LC50valuesrelevantforclassification:

CAS:54-11-5Nicotine

Oral

LD50

5mg/kgbw

Dermal

LD50

70mg/kgbw

Inhalation

LC50

0.19mg/L(dusts/mists)

Toxicityofthemixture

Theacutetoxicityestimate(ATEmix)fortheclassificationofasubstanceinamixturewasdeterminedusingtheappropriatevaluefromECHAwebsite.

Acutetoxicity

ATEmix(oral)=138.9mg/kgbw(AcuteTox.3(H301))

ATEmix(dermal)=1944.4mg/kgbw(Notclassified)

ATEmix(inhalation)=5.3mg/L(Notclassified)

Skincorrosion/irritation:

Basedonavailabledata,thisproductcancauseskinirritation.

Seriouseyedamage/irritation:

Basedonavailabledata,thisproductcancauseskinsensitization.

Respiratoryorskinsensitization:

Basedonavailabledata,theclassificationcriteriaarenotmet.

Germcellmutagenicity:

Basedonavailabledata,theclassificationcriteriaarenotmet.

Carcinogenicity:

Basedonavailabledata,theclassificationcriteriaarenotmet.

Reproductivetoxicity:

Basedonavailabledata,theclassificationcriteriaarenotmet.

0atmm3/mol

Henry'sLawconstant

71%degradationafter28days

81%biodegradation

HighconcentrationsofPropyleneglycolreleasedintoasoilenvironmentcanbeexpectedtobiodegrade.DT50=1.3year

Readilybiodegradable

>=89%over21-35days

-1.75(pH=7.4,25℃)

0.09

-1.75(pH=7.4,25℃)

Koc

SummaryofevaluationoftheCMRproperties:

Basedonavailabledata,theclassificationcriteriaarenotmet.

STOT-singleexposure:

Basedonavailabledata,theclassificationcriteriaarenotmet.

STOT-repeatedexposure:

Basedonavailabledata,theclassificationcriteriaarenotmet.

Aspirationhazard:

Basedonavailabledata,theclassificationcriteriaarenotmet.

Section12:Ecologicalinformation

12.1Toxicity:

Parametersofenvironmentaltoxicity:

CAS:54-11-5Nicotine

Classification:

AquaticChronic2(H411)

Fish(Onchorhynchusmykiss)

LC50-96h

=4mg/L

Fish(freshwater)

3-29ppm

Daphnia(Daphniamagna)

EC50-48h

=0.24mg/L

Alga(Desmodesmussubspicatus)

EC50-72h

=37mg/L

AccordingtoRegulation(EC)No1272/2008,thisproductdoesnotmeetthecriteriaofclassificationofenvironmentaltoxicity.

12.2Persistenceanddegradability:

Dataforthemixturearenotavailable.

Nicotine

OECDGuideline301B

1,2-Propyleneglycol

OECDGuideline301FBiodegradationinsoil

Phototransformationinwater

Glycerol

Biodegradationinwater

Benzoicacid

OECDGuideline311(equivalentorsimilarto)

12.3Bioaccumulativepotential:

Dataforthemixturearenotavailable.

Nicotine

LogPow

1,2-Propyleneglycol

BCF

Glycerol

LogPow

12.4Mobilityinsoil:

Dataforthemixturearenotavailable.

1,2-propyleneglycolKoc

Henry'sLawconstant

Glycerol

Henry'sLawConstant(H):

12.5ResultsofPBTandvPvBassessment:

Productdoesnotcontainingredients,whichmeetcriteriaforPBTorvPvB.

12.6Otheradverseeffects:

Themixtureisnotclassifiedashazardoustotheozonelayer.

Section13:Disposalconsiderations

13.1Wastetreatmentmethods

Disposalmethodfortheproduct:disposalinaccordancewiththelocallegislation.Donotemptyintodrains.Wastecodeshouldbegivenintheplaceofwasteformation.Theclassificationofthiswastemeetscriteriafordangerouswaste.Disposalmethodsforusedpacking:reuse/recycling/liquidationofemptycontainersdisposeinaccordancewiththelocallegislation.Theclassificationofthiswastemeetscriteriafordangerouswaste.LegalBasis:Directive2008/98/EC,94/62/EC.

Section14:Transportinformation

14.1.UNnumber:

ADR:UN3144

IMDG:UN3144

ICAO:UN3144

14.2.UNpropershippingname:

ADR:NICOTINEPREPARATION,LIQUID,N.O.S.(AloeVeraGrape40mg/mLnicotineE-liquid)

IMDG:NICOTINEPREPARATION,LIQUID,N.O.S.(AloeVeraGrape40mg/mLnicotineE-liquid)

ICAO:NICOTINEPREPARATION,LIQUID,N.O.S.(AloeVeraGrape40mg/mLnicotineE-liquid)

14.3.Transporthazardclass(es):

ADR:Class6.1:Toxicsubstances

IMDGclass:Class6.1:Toxicsubstances

ICAOclass:Class6.1:Toxicsubstances

Transportpictogramsonthelabel:

14.4.Packinggroup:

ADR:Ⅲ

IMDG:Ⅲ

ICAO:Ⅲ

14.5.Environmentalhazards:

Notavailable

14.6.Specialprecautionsforuser:

Movecarefullytopreventleakageduringcarriage.Keepnecessaryprotectivearticlesathandincaseofaccident.

Useemergencyescapemaskwheninneed.

14.7.TransportinbulkaccordingtoAnnexIIofMARPOLandtheIBCCode":

Notavailable

Section15:Regulatoryinformation

15.1Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture

Regulation(EC)No1907/2006oftheEuropeanParliamentandoftheCouncilof18December2006concerningtheRegistration,Evaluation,AuthorizationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.

Regulation(EC)No1272/2008oftheEuropeanParliamentandoftheCouncilof16December2008onclassification,labelingandpackagingofsubstancesandmixtures,amendingandrepealingDirectives67/548/EECand1999/45/EC,andamendingRegulation(EC)No1907/2006(TextwithEEArelevance).

CommissionRegulation(EU)No2015/830of28May2015amendingRegulation(EC)No1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation,AuthorizationandRestrictionofChemicals(REACH)(TextwithEEArelevance)

Directive2008/98/ECoftheEuropeanParliamentandoftheCouncilof19November2008onwasteandrepealingcertainDirectives.

EuropeanParliamentandCouncilDirective94/62/ECof20December1994onpackagingandpackagingwaste.EconomiccommissionforEuropeCommitteeonInlandTransportECE/TRANS/257(Vol.Ⅰ)ofapplicableas

from1January2017EuropeanAgreementconcerningtheInternationalCarriageofDangerous(ADR)

ConventionconcerningInternationalCarriagebyRail(COTIF):AppendixC–RegulationsconcerningtheInternationalCarriageofDangerousGoodsbyRail(RID)witheffectfrom1January2017.

TechnicalInstructionsfortheSafeTransportofDangerousGoodsbyAir:OrderNumber:Doc9284,2017-2018

Edition.

15.2Chemicalsafetyassessment:

AChemicalSafetyAssessmentisnotrequiredformixturesinaccordancewithREACHRegulation.

Section16:Otherinformation

FulltextifindicatedHphrasesmentionedinsection2,3:

H300:Fatalifswallowed

H301:Toxicifswallowed

H302:Harmfulifswallowed

H310:Fatalincontactwithskin

H330:Fatalifinhaled

H411:Toxictoaquaticlifewithlonglastingeffects

Clarificationsofaberrationsandacronyms

AcuteTox.2,4:Acutetoxicity,Category2,4

AquaticChronic2:Hazardoustotheaquaticenvironment,long-termhazardCategory2

EyeDam.1:Seriouseyedamage,Category1

SkinIrrit.2:Skinirritation,Category2

PBT:Persistent,Bioac