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Chapter1IntroductionLearningObjectives21.1HistoricalPerspective21.2MaterialsScienceandEngineering21.3WhyStudyMaterialsScienceandEngineering?41.4ClassificationofMaterials51.5AdvancedMaterials61.6ModernMaterials’Needs6

Chapter1IntroductionLearning汉语翻译成英文材料科学材料工程金属材料非金属材料陶瓷材料高分子材料复合材料生物材料半导体材料先进材料汉语翻译成英文材料科学WordsandphrasesDeep-seated:close/intimate紧密的Virtually:practically/infact/nearly/asgoodas/ineffect/inessence实际上地Everysegmentofoureverydaylives:日常生活的每个方面Segment:section/division/part/piece部分、片Manipulate:control/employ控制、使用WordsandphrasesDeep-seated:Designate:define/denote/label/name标记、命名Accessto):approach途径Pottery:pots/dishesorotheritemsmadefromclayandfiredinakiln(oven)陶器Alter:change改变Utilization:application/use应用、用途Empower:control驾驭、控制Designate:define/denote/labelWordsandphrasesCharacteristic:peculiarity,feature/trait/attribute/property特质Evolve:produce生产Complex:sophisticated复杂的Contemporary:Someonewholivedorwasinaparticularplaceatthesametimeassomeoneelse.Modern/belongingtothepresenttime同时代的Nebulous:vague.Anideathatisnebulousisnotatallclearorexact.模棱两可的WordsandphrasesCharacteristiRelatedto:beconcernedwith相关的Encompass:tocompletelycoverorsurroundsth.覆盖或环绕Realm:territroy/monarchy/zone/domain/region/kingdom/area/branch区域Agglomerate:melt团聚、成块-volcanicrockconsistingoflargefragmentsfusedtogetherRelatedto:beconcernedwithVocabularyContemporary当代Stimulus激励,刺激Opaque不透明Translucent半透明Transparent透明Deep-seated根深蒂固的,深层的Existence存在,实在,生活,存在物,实在物Sophisticated复杂的Forerunner先驱(者),传令官,预兆Intimately密切地VocabularyContemporary当代Elaboration解释,阐述Stepwise楼梯式的,逐步的Recreation消遣,娱乐segment段,节,片断Deteriorative恶化,变质,Elaboration解释,阐述Evoke引起,唤起Interdisciplinary交叉学科Metallurgy冶金Nebulous模糊的,云雾状的Agglomerate团聚,大块Dielectriccurrent介电常数Thermalconductivity热传导Evoke引起,唤起Heatcapacity热容Refraction折射,衍射Ductility延展性Overriding最重要的Prohibitive抑制Judicious明智的criterion准则Heatcapacity热容1.1Historicalperspective(观察,透视)

Materialsareprobablymoredeep-seated(根深蒂固的,深层的)inourculturethanmostofusrealize.Transportation,housing,clothing,communication,recreation(娱乐),andfoodproduction—virtually(事实上)everysegment(方面)ofoureverydaylivesisinfluencedtoonedegreeoranother(不同程度地)

bymaterials.1.1Historicalperspective(观察Historically,thedevelopmentandadvancementofsocietieshavebeenintimately(密切地)tiedtothemembers’abilitytoproduceandmanipulate

(使用)materialstofilltheirneeds.Infact,earlycivilizationshavebeendesignated(命名)bytheleveloftheirmaterialsdevelopment(i.e.,StoneAge,BronzeAge,IronAge).Historically,thedevelopmentStoneageironageSteelageAdvancedmaterialsagebronzeageStoneageironageSteelageAdvaTheearliesthumanshadaccesstoonlyaverylimitednumberofmaterials,thosethatoccurnaturally:stone,wood,clay(粘土),skins,andsoon.Withtimetheydiscoveredtechniquesforproducingmaterialsthathadpropertiessuperiortothoseofthenaturalones;thesenewmaterialsincludedpottery(陶器)andvariousmetals.TheearliesthumanshadaccesFurthermore,itwasdiscoveredthatthepropertiesofamaterialcouldbealtered

(改变)byheattreatmentsandbytheadditionofothersubstances.Atthispoint,materialsutilization(利用)wastotallyaselectionprocess,thatis,decidingfromagiven,ratherlimitedsetofmaterialstheonethatwasbestsuitedforanapplicationbyvirtueof

(凭借)itscharacteristics(特性).Furthermore,itwasdiscoveredItwasnotuntilrelativelyrecenttimesthatscientistcametounderstandtherelationshipbetweenstructuralelementsofmaterialsandtheirproperties.Thisknowledge,acquiredinthepast60yearsorso,hasempowered

(使能够)themtofashion(shape),toalargedegree(非常),thecharacteristicsofmaterials.ItwasnotuntilrelativelyreThus,tensofthousandsofdifferentmaterialshaveevolved

(出现)withratherspecializedcharacteristicsthatmeettheneedsofourmodernandcomplexsociety.Theseincludemetals,plastics,glasses,andfibers.Thus,tensofthousandsofdifTheuglybowlandthebeautifulcuparedifferentinappearance,butdoyouknowthebowlistheancestorofthecupiftracebackto7000yearsago?porcelainceramicsTheuglybowlandthebeautifuThedevelopmentofmanytechnologiesthatmakeourexistencesocomfortablehasbeenintimatelyassociatedwiththeaccessibility(途径)ofsuitablematerials.Anadvancementintheunderstandingofamaterialtypeisoftentheforerunner(先驱)

tothestepwise(逐步的)progressionofatechnology.ThedevelopmentofmanytechnForexample,automobileswouldnothavebeenpossiblewithouttheavailability

(利用)ofinexpensivesteelorsomeothercomparablesubstitute.Inourcontemporary(同时代的)era,sophisticated

(复杂的)electronicdevicesrelyoncomponentsthataremadefromwhatarecalledsemi-conducting(半导体的)materials.Forexample,automobileswouldMaterialsscientistsandengineersseek

(try,investigate寻求)tounderstandandcontrolthebasicstructureofmaterialsinordertomaketheproductsstronger,lighter,brighter,safer,fasterandbettersuited(adapt,fit)to(适合)humanneeds.Everypartinyourcarandeverypieceofyourcomputerarecarefullyselectedtooptimize(优化)performanceandcosteffectiveness.3.TaskforMaterialsscientistsandengineersMaterialsscientistsandengin4.MaterialsScienceandEngineering(MSE)discipline

Thedisciplineofmaterialsscience

involvesinvestigatingtherelationshipsthatexistbetweenthestructuresandpropertiesofmaterials.Incontrast,materialsengineering

is,onthebasisofthesestructure–propertycorrelations,designingorengineeringthestructureofamaterialtoproduceapredetermined(预定的)setofproperties.Throughoutthistextwedrawattentiontotherelationshipsbetweenmaterialpropertiesandstructuralelements.4.MaterialsScienceandEngine‘‘Structure’’isatthispointanebulous(模糊的)termthatdeservessomeexplanation.Inbrief,thestructureofamaterialusuallyrelatestothearrangementofitsinternalcomponents.Subatomicstructureinvolveselectronswithintheindividualatomsandinteractionswiththeirnuclei(原子核).Onanatomiclevel,structureencompasses(包含)theorganizationofatomsormoleculesrelativetooneanother.‘‘Structure’’isatthispointThenextlargerstructuralrealm(区域),whichcontainslargegroupsofatomsthatarenormallyagglomerated(团聚)together,istermed‘‘microscopic,’’meaningthatwhichissubjecttodirectobservationusingsometypeofmicroscope.Finally,structuralelementsthatmaybeviewedwiththenakedeyearetermed‘‘macroscopic.’’ThenextlargerstructuralreaThenotionof‘‘property’’deserveselaboration.Whileinserviceuse,allmaterialsareexposedtoexternalstimuli(刺激)

thatevoke(唤起)

sometypeofresponse.Forexample,aspecimensubjectedtoforceswillexperiencedeformation;orapolishedmetalsurfacewillreflectlight.Propertyisamaterialtrait(特性)intermsofthekindandmagnitudeofresponsetoaspecificimposed(施加的)stimulus(刺激).Generally,definitionsofpropertiesaremadeindependentof

(与无关)materialshapeandsize.Thenotionof‘‘property’’desVirtuallyallimportantpropertiesofsolidmaterialsmaybegroupedintosixdifferentcategories:mechanical,electrical,thermal,magnetic,optical,anddeteriorative.Foreachthereisacharacteristictypeofstimuluscapableof

provoking(evoke)differentresponses.Mechanicalpropertiesrelatedeformationtoanappliedloadorforce;examplesincludeelasticmodulus(弹性模量)andstrength.VirtuallyallimportantproperForelectricalproperties,suchaselectricalconductivity

(电导率)anddielectricconstant(介电场数),thestimulusisanelectricfield(电场).Thethermal(热的)behaviorofsolidscanberepresentedintermsofheatcapacity(热容)andthermalconductivity(热导率).Forelectricalproperties,suMagnetic(磁性的)propertiesdemonstratetheresponseofamaterialtotheapplicationofamagneticfield

(磁场).Foroptical(光学的)properties,thestimulusiselectromagnetic(电磁的)orlightradiation(光辐射);indexofrefraction(折射)andreflectivity

(反射)arerepresentativeopticalproperties.Finally,deteriorative(腐败的)characteristicsindicatethechemicalreactivity(化学反应)ofmaterials.Thechaptersthatfollowdiscusspropertiesthatfallwithineachofthesesixclassifications.Magnetic(磁性的)propertiesdemon

Inadditiontostructureandproperties,twootherimportantcomponentsareinvolvedinthescienceandengineeringofmaterials,viz(namely,thatis).‘‘processing’’(加工)and‘‘performance(性能).’’

Withregardtotherelationshipsofthesefourcomponents,thestructureofamaterialwilldependonhowitisprocessed.Furthermore,amaterial’sperformancewillbeafunctionofitsproperties.Thus,theinterrelationshipbetweenprocessing,structure,properties,andperformanceislinear,asdepictedintheschematicillustrationshowninFigure1.1.

InadditiontostructThroughoutthistextwedrawattentiontotherelationshipsamongthesefourcomponentsintermsofthedesign,production,andutilizationofmaterials.MaterialsScienceandEngineering(MSE)isthediscipline(学科)devotedto(专心于)helpinghumanbeingsusematerialsmoreeffectively(有力的)andefficiently(有效的).Thestoryofmaterialsisanancientonethatbeganwithhumanitylearningtoshape(成形)

rockandworkmetal.Fromtheprehistoricbeginning,thestoryofhumanadvancesinmaterialscontinuestounfold(展开).ThroughoutthistextwedrawaForexample,thedevelopmentofsteelspermittedthebuildingofskyscrapersandsuspensionbridges;advancesinsiliconbasedtechnologyprovidedthefoundationforelectronicsandcomputers,Newbiomaterialshaveresultedinmedicalbreakthroughsthatsaveandimprovelives.MaterialsscientistsandengineersfocusonthemanipulationofatomicscalestructuretochangematerialspropertiesForexample,thedevelopmentoThisfocushaspushedourdisciplinetotheforefront(最前沿)ofdevelopingandapplyingnewtoolstoobserveandmanipulatematteratthesmallestscales.Theseadvancescontinuetoplayanimportantpartintheemergenceoffieldssuchasnanotechnologyatthebeginningofthe21stcentury.Thisfocushaspushedourdisc5ThefutureofhumanitydependsonourwiseuseofmaterialsMostofthetechnologicalinnovationsthatweassociatewithcontemporary(现代)lifehaveinvolvedsomemajoradvanceinmaterialsprocessingorapplication.5ThefutureofhumanitydepenAutomobiles,satellites,televisions,computersandDVDplayersallwouldnotbepossiblewithoutadvancesinpolymers,ceramics,metalsandsemiconductors.Newadvancesarebeingpioneeredinourlaboratories.Automobiles,satellites,televThedirectthreatofglobalwarminganddwindling(缩小)fossilfuelresourceshavemadetheefficientuseofenergyapriority(优先).MSEfacultyandstudentsworkactivelytomakelight-weightenginecomponentsoutofaluminumandmagnesiuminordertoboost(促进,增强)fuelefficiency.Theyalsopioneerimprovedhigh-temperaturematerialsthatareimportantforefficientjetenginesandelectricitygeneration.ThedirectthreatofglobalwaTorestorehearingtodeafpeopleandsighttoblindpeopleprostheticdevicesmustmakecontactbetweenthebrainandamicrophoneorcamera.MSEfacultyandstudentsworktofindwaystoInterface(界面)silicontechnologytoneuraltissue(神经组织).Thisrequiresthedevelopmentofcoatingsthatarebiocompatible(生物相容的)andelectricallyconducting.TorestorehearingtodeafpeoMoore'slawstatesthatthenumberoftransistors(晶体管)onthelatestcomputerchipdoublesapproximatelyevery18months.Thistranslatesintomorememoryandfaster,cheapercomputers.Butthereisalimittothedensityoftransistorsthatcanbeplacedonacomputerchipusingcurrenttechnology.Moore'slawstatesthatthenuMSE

facultyandstudentsdevelopmethodstospontaneously(自发)generatestructuresafewtenstohundredsofatomsacrosstoformthebasisforquantum(量子)computers.Thesenextgenerationcomputerswillexploitthephysicsofquantumconfinement(量子陷阱)thatdominateatthattinyscale.MSEfacultyandstudentsMakingcomponentsoutofnewmaterialsofteninvolvesanextensivecycleofdesign,creation,testingandredesign.Thisprocessiscostlyandtimeconsuming.MSEfacultyandstudentsdevelopcomputersimulationtechniquestopredictmaterialbehaviorsuchasresistancetofailure,stability,andhightemperatureformability.Thesecomputingadvancesspeedthewaytowardtheintroductionofnewmaterialsinasafeandcost-effectivemanner.MakingcomponentsoutofnBuildingonasolidfoundationandbridgingmanyfieldsBuildingonasolidfoundationCourseworkintheMSEdepartmentemphasizestherelationshipbetweenhowamaterialisprocessed,itsstructureandtheresultingpropertiesandisbuiltonafirmgroundinginphysicsandchemistry.Hands-onlearningandaccesstosophisticatedinstrumentationallowstudentstogainvaluableexperienceincharacterizingmaterialsstructureandproperties.(youcanbeapoliceusingSEMorTEM)CourseworkintheBecausematerialsenablenewproductsandtechnologies,itisnearlyimpossibletofindanengineeringdisciplinethatdoesnotinterfaceinsomewaywithMaterialsScienceandEngineering.Thisisespeciallytrueformechanical,aerospace,electrical,chemicalandbiomedicalengineeringwheredualmajorsareoftenpursued.

Becausematerialsenablenewp1.2Materialsscienceandengineering1.Termsofdefinition

MaterialsScience:investigatingtherelationshipsthatexistbetweenthestructuresandpropertiesofmaterials.MaterialsEngineering:onthebasisofstructure–propertycorrelations,designingorengineeringthestructureofamaterialtoproduceapredeterminedsetofproperties.1.2MaterialsscienceandengStructure:

Anebulous(模糊)term;Inbrief,thearrangementofitsinternalcomponentsSubatomicstructure---involveselectronswithintheindividualatomsandinteractionswiththeirnucleiAtatomiclevel---structureencompassestheorganizationofatomsormoleculesrelativetooneanother.microscopic(显微)—alargegroupofatomsagglomeratedtogether.Macroscopic(宏观)–wherethestructureelementsmightbeviewedbynakedeye.Structure:microscopic(显微)—aproperty:

1.amaterialtrait(特性)intermsofthekindandmagnitudeofresponsetoaspecificimposedstimulus。Examples:AloadedsteelbarwillbedeformedAheatedplasticplatewillbesoftenedApolishedmetalsurfacewillreflectlightproperty:1.Mechanical2.electrical

3.thermal

4.Magnetic

5.optical 6.deteriorative(变质,化学)aelasticmodulusb.indexofrefractionc.strengthd.reflectivitye.thermalconductivityf.heatcapacityg.electricalconductivityh.plasticityI.electromagneticj.lightradiationchemicalreactivityDielectricconstantVirtuallyallimportantpropertiesofsolidmaterialsmaybegroupedintosixdifferentproperty:1.MechanicalaelasticmodulInadditiontostructureandproperties,processingandperformanceareanothertwoimportantcomponentsforMSE.Fourcomponentsthatareinvolvedinthedesign,productionandutilizationofmaterialsprocessing→structure→properties→performanceInadditiontostructureandpThreethinaluminumdiskspecimensplacedoverprintedmatter,fromlefttorighttheyaretransparent,translucentandopaque,why?Becausetheyareprocesseddifferently,thenhavedifferentstructure;differentstructureleadstodifferentpropertiesandiftheyareputintouse,theperformancemustbedifferenttoo.Threethinaluminumdiskspeci1.3WhystudyMaterialsscienceandengineering?Manyanappliedscientistorengineerwillatonetimeoranother,whethermechanical,

civil(土木),chemical,orelectrical,beexposedtoadesignprobleminvolvingmaterials.Examplesmightincludeatransmissiongear(传动齿轮),thesuperstructureforabuilding,anoilrefinery(炼油厂)component,oranintegratedcircuitchip(集成电路板).Ofcourse,materialsscientistsandengineersaresuchspecialistwhoaretotallyinvolvedintheinvestigationanddesignofmaterials.Forthemtrytoselectionpropermaterialstofulfillspecificpurposeisnoteasy.1.3WhystudyMaterialssciencThreecriteriathatareimportantinthematerialsselectionpurpose:1.

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