固定污染源废气挥发性有机物的测定真空瓶气袋采样气相

表1-3实验室1方法检出限、测定下限测试数据表序号化合物名称加标量(μmol/mol)测定值(μmol/mol)平均值(μmol/mol)标准偏差Si(μmol/mol)检出限(μmol/mol)检出限(mg/m3)测定下限(mg/m3)第一次第二次第三次第四次第五次第六次第七次1氯乙烯0.1000.1060.08730.08930.09190.09250.10280.1030.09600.00740.0230.070.2821，3-丁二烯0.1000.1140.1030.1130.1020.1020.11380.1230.1100.00810.0250.060.243环氧乙烷0.1000.1160.09750.1180.1280.1220.12190.1110.1160.00980.0310.060.244溴甲烷0.1000.09270.08890.09100.09550.09420.11640.1050.09760.00970.0310.10.405环氧丙烷0.1000.09090.07430.07900.08700.09480.08930.09240.08680.00750.0230.060.246丙酮0.1000.1080.1110.09970.1100.1060.09550.09690.1040.00640.0200.050.207溴乙烷0.1000.1010.09820.09790.1030.1020.12260.1030.1040.00840.0260.10.408异丙醇0.1000.07500.08030.09230.09080.08090.07830.07570.08190.00690.0220.060.249乙腈0.1000.07130.08490.08030.08770.08170.08960.07950.08210.00610.0190.040.1610二氯甲烷0.1000.09910.09760.09860.1030.1020.11970.1050.1040.00760.0240.090.3611丙烯腈0.1000.1040.09350.1020.1050.09940.09160.07910.09650.00930.0290.070.2812甲基叔丁基醚0.1000.09080.08910.07880.07630.07360.07980.08350.08170.00640.0200.080.3213正己烷0.1000.09100.09220.1050.1060.1060.10700.1070.1020.00710.0220.090.3614乙酸乙烯酯0.1000.08760.06600.06770.07430.06890.07460.07080.07280.00730.0230.090.36152-丁酮0.1000.1010.1130.1130.1030.1040.10240.1240.1090.00830.0260.080.3216乙酸乙酯0.1000.07010.06220.06220.07260.07380.06680.07870.06950.00620.0190.080.3217四氢呋喃0.1000.06210.06730.06520.06630.07070.07870.07240.06900.00550.0170.060.2418氯仿0.1000.09000.09160.09190.09780.09690.10530.1160.09850.00930.0290.20.8019环己烷0.1000.07560.06840.06820.07110.06880.08620.08730.07510.00840.0260.100.4020四氯化碳0.1000.08540.08860.09070.09630.09500.10390.1140.09630.00980.0310.20.8021苯0.1000.1100.08970.09050.09390.09410.09040.09060.09410.00710.0220.080.32221,2-二氯乙烷0.1000.08660.09160.09350.09830.09880.10500.1060.09720.00720.0230.100.4023三氯乙烯0.1000.08650.09030.09090.09900.09770.10740.1080.09710.00840.0270.20.80241,2-二氯丙烷0.1000.09310.09700.09690.1030.1020.11260.1130.1030.00780.0240.10.4025环氧氯丙烷0.1000.08540.09350.1060.1040.09950.09630.1030.09830.00730.0230.10.40264-甲基-2-戊酮0.1000.08050.07790.06610.07870.07700.08520.08520.07870.00650.0200.090.3627甲苯0.1000.1040.1070.08700.09130.09240.08820.08920.09410.00790.0250.10.4028乙酸异丁酯0.1000.07760.07870.06570.07110.07680.06130.07920.07290.00710.0220.10.40291-戊醇0.1000.09220.1020.08360.08730.07860.08460.07760.08660.00850.0270.10.4030四氯乙烯0.1000.08350.08960.09170.09900.09870.11010.1100.09760.01010.0320.20.8031乙酸正丁酯0.1000.06800.07910.06190.06980.07460.07680.06530.07080.00630.0200.10.4032氯苯0.1000.1090.08910.09030.09650.09760.08830.08840.09420.00770.0240.10.4033乙苯0.1000.08110.09150.08160.08750.08750.07940.09910.08680.00690.0220.10.4034对，间二甲苯0.1000.1730.1630.1630.1850.1740.16290.1930.1730.01170.0370.31.2035邻二甲苯0.1000.09400.07340.07420.08080.08110.07200.07120.07810.00810.0250.10.4036苯乙烯0.1000.09590.07570.07800.08500.08510.07880.07760.08230.00700.0220.10.4037异丙苯0.1000.09460.09450.09620.1030.1030.09510.09390.09720.00420.0130.070.2838环己酮0.1000.1150.09100.1050.1100.1170.11910.09850.1080.01040.0330.10.40391,3,5-三甲苯0.1000.09270.09300.09470.1070.1060.09360.09290.09710.00640.0200.10.40401,2,4-三甲苯0.1000.08820.09020.09120.1030.1050.09080.08890.09390.00700.0220.10.40411,2,3-三甲苯0.1000.08940.09000.09180.1050.1070.09060.08900.09470.00770.0240.10.40421,2-二氯苯0.1000.08360.08410.08520.1010.1030.09200.09140.09160.00810.0250.20.80表1-4实验室2方法检出限、测定下限测试数据表序号化合物名称加标量(μmol/mol)测定值(μmol/mol)平均值(μmol/mol)标准偏差Si(μmol/mol)检出限(μmol/mol)检出限(mg/m3)测定下限(mg/m3)第一次第二次第三次第四次第五次第六次第七次1氯乙烯0.1000.1030.1030.1010.0960.0920.0930.1130.1000.0070.030.10.421，3-丁二烯0.1000.1310.1360.1320.1370.1220.1220.1380.1310.0070.030.10.43环氧乙烷0.1000.1030.1200.1160.1160.1280.1220.1220.1180.0080.030.10.44溴甲烷0.1000.1090.1110.1120.0930.0960.0940.1160.1040.0100.030.20.85环氧丙烷0.1000.0930.0880.0960.0910.0870.0750.0790.0870.0070.030.10.46丙酮0.1000.0910.0950.0940.1080.1100.1060.0960.1000.0080.030.10.47溴乙烷0.1000.1140.1240.1150.1010.1030.1020.1230.1120.0100.030.20.88异丙醇0.1000.0640.0650.0590.0650.0610.0710.0780.0660.0070.020.10.49乙腈0.1000.0710.0820.0800.0610.0780.0820.0700.0750.0080.030.10.410二氯甲烷0.1000.1090.1180.1090.0990.1030.1020.1200.1090.0080.030.20.811丙烯腈0.1000.0840.0860.0810.1040.1050.0990.0920.0930.0100.040.10.412甲基叔丁基醚0.1000.0820.0810.0850.0810.0760.0640.0700.0770.0080.030.20.813正己烷0.1000.1670.1690.1630.1650.1590.1470.1700.1630.0080.030.20.814乙酸乙烯酯0.1000.0580.0650.0760.0780.0740.0690.0750.0700.0070.030.20.8152-丁酮0.1000.1240.1260.1290.1340.1340.1350.1140.1280.0070.030.10.416乙酸乙酯0.1000.0590.0620.0600.0700.0730.0740.0570.0650.0070.030.20.817四氢呋喃0.2500.2240.1900.1870.1950.2240.2130.2180.2070.0160.060.20.818氯仿0.1000.1170.1070.1170.0900.0980.0970.1050.1040.0100.040.31.219环己烷0.1000.0860.0850.0860.0760.0710.0690.0860.0800.0080.030.20.820四氯化碳0.1000.1050.1040.1150.0850.0960.0950.1040.1010.0090.030.31.221苯0.1000.0900.0910.0910.0900.0940.0940.1100.0940.0070.030.20.8221,2-二氯乙烷0.1000.1080.1070.1170.0870.0980.0990.1050.1030.0100.030.20.823三氯乙烯0.1000.1090.1180.1090.0860.0990.0980.1070.1040.0100.040.31.2241,2-二氯丙烷0.1000.1120.1130.1120.0930.1030.1020.1130.1070.0080.030.20.825环氧氯丙烷0.1000.0930.0940.0950.0950.1040.1000.0760.0940.0090.030.20.8264-甲基-2-戊酮0.1000.0620.0590.0730.0600.0790.0670.0550.0650.0080.030.20.827甲苯0.1000.0900.0890.0880.0840.0910.0920.1080.0920.0080.030.20.828乙酸异丁酯0.1000.0590.0560.0510.0580.0710.0670.0610.0600.0070.030.20.8291-戊醇0.1000.0680.0600.0680.0820.0870.0790.0850.0750.0100.040.20.830四氯乙烯0.1000.1110.1110.1110.0840.0990.0990.1100.1030.0100.040.31.231乙酸正丁酯0.1000.0540.0480.0530.0580.0700.0550.0570.0560.0070.030.20.832氯苯0.1000.0890.0890.0890.0890.0960.0980.1080.0940.0070.030.20.833乙苯0.1000.0800.0790.0790.0810.0880.0870.0990.0850.0070.030.20.834对+间二甲苯0.2000.1300.1290.1270.1310.1480.1440.1290.1340.0080.030.31.235邻二甲苯0.1000.0720.0710.0700.0740.0810.0810.0920.0770.0080.030.20.836苯乙烯0.1000.0770.0760.0770.0760.0850.0850.0990.0820.0080.030.20.837异丙苯0.1000.0940.0930.0930.0950.1030.1130.0950.0980.0080.030.20.838环己酮0.2500.2680.2410.2900.2290.2410.2300.2420.2490.0220.070.41.2391,3,5-三甲苯0.1000.0920.0900.0920.0930.1070.1060.0940.0960.0070.030.20.8401,2,4-三甲苯0.1000.0890.0890.0880.0880.1030.1050.0910.0930.0070.030.20.8411,2,3-三甲苯0.1000.0890.0890.0890.0890.1050.1070.0910.0940.0080.030.20.8421,2-二氯苯0.1000.0900.0890.0890.0840.1010.1030.0920.0930.0070.030.20.8表1-5实验室3方法检出限、测定下限测试数据表序号化合物名称加标量(μmol/mol)测定值(μmol/mol)平均值(μmol/mol)标准偏差Si(μmol/mol)检出限(μmol/mol)检出限(mg/m3)测定下限(mg/m3)第一次第二次第三次第四次第五次第六次第七次1氯乙烯0.1000.0860.0930.0880.0880.0870.1090.1010.0930.0090.0270.10.421，3-丁二烯0.1000.1310.1280.1190.1250.1210.1400.1320.1280.0070.0220.10.43环氧乙烷0.1000.1080.1230.1130.1320.1090.1220.1150.1180.0090.0280.10.44溴甲烷0.1000.0910.0900.0900.0960.0960.1000.1190.0980.0100.0310.10.45环氧丙烷0.1000.0760.0730.0750.0830.0800.0920.0870.0810.0070.0220.10.46丙酮0.1000.0950.0990.1010.1120.1100.1000.0950.1020.0070.0210.10.47溴乙烷0.1000.0970.0990.0970.1020.1020.1150.1240.1050.0100.0320.20.88异丙醇0.1000.0710.0610.0790.0660.0660.0670.0580.0670.0070.0210.10.49乙腈0.1000.0670.0750.0850.0930.0700.0720.0820.0780.0100.0300.10.410二氯甲烷0.1000.0990.0980.0980.1050.1040.1020.1260.1040.0100.0310.10.411丙烯腈0.1000.0940.1050.1040.1040.1040.0860.0790.0970.0110.0330.10.412甲基叔丁基醚0.1000.0710.0700.0690.0730.0760.0850.0850.0760.0070.0210.10.413正己烷0.1000.1540.1540.1530.1570.1540.1690.1700.1590.0070.0240.10.414乙酸乙烯酯0.1000.0680.0650.0630.0730.0680.0540.0580.0640.0060.0200.10.4152-丁酮0.1000.1170.1160.1270.1330.1340.1250.1240.1250.0070.0220.10.416乙酸乙酯0.1000.0630.0630.0610.0710.0740.0550.0580.0640.0070.0210.10.417四氢呋喃0.2500.1850.1750.2020.1750.1520.1580.2010.1790.0190.0610.20.818氯仿0.1000.0920.0930.0920.0990.0970.1080.1080.0980.0070.0220.10.419环己烷0.1000.0680.0690.0680.0700.0700.0840.0870.0740.0080.0260.10.420四氯化碳0.1000.0910.0900.0900.0970.0960.1060.1060.0970.0070.0220.20.821苯0.1000.0910.0890.0890.0940.0960.0770.0810.0880.0070.0220.10.4221,2-二氯乙烷0.1000.0920.0930.0920.0990.1010.1090.1180.1010.0100.0310.10.423三氯乙烯0.1000.0930.0920.0920.0990.0980.1200.1000.0990.0100.0310.20.8241,2-二氯丙烷0.1000.0970.0980.0970.1040.1060.1220.1130.1050.0100.0300.20.825环氧氯丙烷0.1000.1080.0940.0950.1060.1070.0950.0950.1000.0070.0210.10.4264-甲基-2-戊酮0.1000.0710.0780.0660.0670.0730.0680.0520.0680.0080.0260.10.427甲苯0.1000.0870.0860.0860.0930.0940.0980.1080.0930.0080.0250.10.428乙酸异丁酯0.1000.0550.0510.0480.0610.0780.0510.0580.0570.0100.0320.20.8291-戊醇0.1000.0920.0710.0870.0710.0700.0750.0660.0760.0100.0300.10.430四氯乙烯0.1000.0930.0930.0920.1000.1000.1100.1120.1000.0080.0260.20.831乙酸正丁酯0.1000.0560.0490.0540.0620.0760.0590.0590.0590.0090.0270.10.432氯苯0.1000.0900.0900.0910.0970.0980.0890.1090.0950.0070.0230.10.433乙苯0.1000.0820.0820.0830.0870.0880.0790.1000.0860.0070.0220.10.434对+间二甲苯0.2000.1340.1330.1340.1440.1460.1300.1280.1360.0070.0210.20.835邻二甲苯0.1000.0740.0740.0740.0810.0820.0730.0920.0790.0070.0220.10.436苯乙烯0.1000.0770.0780.0770.0850.0880.0800.0970.0830.0070.0230.10.437异丙苯0.1000.0950.0960.0950.1030.1050.0950.0850.0960.0070.0210.10.438环己酮0.2500.2450.2320.2590.2550.2150.2420.2360.2400.0150.0470.20.8391,3,5-三甲苯0.1000.0940.0950.0940.1060.1090.0940.0920.0980.0070.0220.10.4401,2,4-三甲苯0.1000.0900.0910.0910.1050.1070.0900.0890.0950.0080.0240.10.4411,2,3-三甲苯0.1000.0900.0910.0900.1070.1100.0910.0900.0960.0090.0280.10.4421,2-二氯苯0.1000.0840.0850.0850.1030.1080.0920.0900.0930.0100.0300.20.8表1-6实验室4方法检出限、测定下限测试数据表序号化合物名称加标量(μmol/mol)测定值(μmol/mol)平均值(μmol/mol)标准偏差Si(μmol/mol)检出限(μmol/mol)检出限(mg/m3)测定下限(mg/m3)第一次第二次第三次第四次第五次第六次第七次1氯乙烯0.100.097080.099060.097840.098750.086640.098380.090870.0960.00480.01520.040.1721，3-丁二烯0.100.103760.104670.089630.106430.104380.107070.092670.1010.00700.02210.050.213环氧乙烷0.100.106650.098820.110560.106450.115710.116370.103490.1080.00640.02010.040.164溴甲烷0.100.101480.096150.086740.102160.09370.102650.106480.0980.00670.02110.090.365环氧丙烷0.100.09790.083870.127280.105480.110990.079840.096970.1000.01620.05090.130.536丙酮0.100.108180.08710.09290.102910.1090.09720.110580.1010.00900.02820.070.297溴乙烷0.100.100620.096520.106290.095720.096240.100080.098290.0990.00370.01160.030.128异丙醇0.100.094840.086840.082220.106930.109210.099360.095460.0960.00980.03090.150.609乙腈0.100.104020.091610.098790.092480.102330.097310.103950.0990.00520.01620.030.1210二氯甲烷0.100.102730.117470.090430.107270.091520.104980.095220.1010.00970.03050.120.4611丙烯腈0.100.106460.098560.089830.084130.094320.1040.097850.0960.00780.02450.060.2312甲基叔丁基醚0.100.094850.106810.098250.100940.093310.092950.10090.0980.00500.01580.060.2513正己烷0.100.093050.098830.106460.095060.109060.097710.086850.0980.00770.02410.090.3714乙酸乙烯酯0.100.081670.095650.081520.093250.104750.09230.09970.0930.00870.02720.100.42152-丁酮0.100.103190.092620.107370.095740.109780.082960.108030.1000.00990.03110.100.4016乙酸乙酯0.100.099770.093830.104160.10020.09430.095880.096770.0980.00370.01170.050.1817四氢呋喃0.100.113330.096470.091810.0840.073740.104830.107490.0960.01390.04380.140.5618氯仿0.100.086120.084960.087160.081100.096370.096590.091530.0890.00590.01850.100.4019环己烷0.100.105960.106010.091280.108910.093060.097450.100050.1000.00680.02150.080.3220四氯化碳0.100.079030.098670.08750.103350.095880.099530.080350.0920.00970.03060.210.8421苯0.100.093320.104380.095740.097520.101770.111880.117060.1030.00870.02740.100.38221,2-二氯乙烷0.100.088380.09290.10060.098380.106970.092770.090810.0960.00650.02040.090.3623三氯乙烯0.100.088260.081010.086370.091490.097350.090360.086680.0890.00510.01590.090.37241,2-二氯丙烷0.100.078080.108610.088220.095170.09170.09960.104770.0950.01040.03260.160.6625环氧氯丙烷0.100.096310.079370.095390.091110.091010.085130.082880.0890.00640.02020.110.42264-甲基-2-戊酮0.100.08320.106110.098720.091380.098820.093330.108270.0970.00870.02730.120.4927甲苯0.100.100220.120290.106780.109370.103630.09670.101790.1060.00770.02430.130.5028乙酸异丁酯0.100.102140.090980.092590.104690.091480.107870.106690.0990.00750.02370.100.39291-戊醇0.100.104230.072180.09830.074040.113780.096130.096770.0940.01530.04800.190.7530四氯乙烯0.100.094290.093120.089470.101320.097380.099930.09090.0950.00450.01410.100.4231乙酸正丁酯0.100.109750.097420.108970.091970.105470.10930.100170.1030.00690.02170.110.4532氯苯0.100.069130.105410.09410.105880.109190.090640.091230.0950.01370.04320.220.8733乙苯0.100.095710.107620.093020.100190.103470.087730.096590.0980.00660.02090.100.4034对+间二甲苯0.100.193920.206640.195020.191190.196180.19890.193030.1960.00510.01610.080.3035邻二甲苯0.100.093790.104920.091660.106560.109130.090780.106570.1000.00800.02520.120.4836苯乙烯0.100.081580.098010.095830.09940.107270.09320.086240.0950.00850.02690.120.5037异丙苯0.100.082130.108790.088390.101880.107070.099650.0980.0980.00970.03040.160.6538环己酮0.100.101150.095410.106930.096620.095240.089490.11810.1000.00950.02990.130.52391,3,5-三甲苯0.100.100790.103150.098150.096460.101050.10110.099380.1000.00220.00690.040.15401,2,4-三甲苯0.100.105430.099020.101410.100810.105250.102570.111570.1040.00420.01310.070.28411,2,3-三甲苯0.100.107810.106760.10470.101030.107740.098070.104150.1040.00360.01150.060.25421,2-二氯苯0.100.111340.104410.102840.098270.106070.096010.103390.1030.00500.01580.100.42表1-7实验室5方法检出限、测定下限测试数据表序号化合物名称加标量(μmol/mol)测定值(μmol/mol)平均值(μmol/mol)标准偏差Si(μmol/mol)检出限(μmol/mol)检出限(mg/m3)测定下限(mg/m3)第一次第二次第三次第四次第五次第六次第七次1氯乙烯0.1000.103300.103390.101360.095620.091920.092500.112800.1000.0070.030.10.421，3-丁二烯0.1000.131220.135990.132180.137320.121610.121720.137940.1310.0070.030.10.43环氧乙烷0.1000.102740.120340.115840.116490.127650.121500.121870.1180.0080.030.10.44溴甲烷0.1000.109030.110780.112450.092680.095520.094160.116420.1040.0100.030.20.85环氧丙烷0.1000.092500.087840.095520.090940.086960.074750.079350.0870.0070.030.10.46丙酮0.1000.090560.094660.093790.107680.110280.106130.095530.1000.0080.030.10.47溴乙烷0.1000.114320.124040.114680.101440.103450.102040.122550.1120.0100.030.20.88异丙醇0.1000.063780.065450.059250.064960.060780.070910.078300.0660.0070.020.10.49乙腈0.1000.070800.081790.079570.061270.077670.081680.069610.0750.0080.030.10.410二氯甲烷0.1000.109470.118320.108540.099060.102950.101660.119700.1090.0080.030.20.811丙烯腈0.1000.083760.086060.081320.104200.105260.099410.091610.0930.0100.040.10.412甲基叔丁基醚0.1000.082440.080800.084560.080790.076290.063570.069800.0770.0080.030.20.813正己烷0.1000.166970.168680.162940.164670.158820.147480.169940.1630.0080.030.20.814乙酸乙烯酯0.1000.057510.064710.075770.077580.074320.068910.074620.0700.0070.030.20.8152-丁酮0.1000.124460.125630.129270.133810.134200.135260.114280.1280.0070.030.10.416乙酸乙酯0.1000.058860.062320.059730.070070.072570.073840.056750.0650.0070.030.20.817四氢呋喃0.2500.224250.189590.186620.194590.223520.212710.218260.2070.0160.060.20.818氯仿0.1000.117360.106890.116520.090040.097780.096940.105310.1040.0100.040.31.219环己烷0.1000.085770.084680.086160.075550.071110.068800.086170.0800.0080.030.20.820四氯化碳0.1000.105340.104350.115110.085420.096270.094980.103880.1010.0090.030.31.221苯0.1000.089510.090680.090570.089800.093930.094110.110370.0940.0070.030.20.8221,2-二氯乙烷0.1000.107540.106910.117300.086600.098280.098830.105020.1030.0100.030.20.823三氯乙烯0.1000.108770.117700.109270.086490.099000.097730.107430.1040.0100.040.31.2241,2-二氯丙烷0.1000.112200.112610.112160.093080.102820.102310.112580.1070.0080.030.20.825环氧氯丙烷0.1000.093480.094020.095390.095430.104390.099530.076350.0940.0090.030.20.8264-甲基-2-戊酮0.1000.061510.058940.073220.060470.078670.066990.055220.0650.0080.030.20.827甲苯0.1000.089520.089030.088410.083690.091350.092400.108150.0920.0080.030.20.828乙酸异丁酯0.1000.058630.056330.050610.057560.071110.066820.061300.0600.0070.030.20.8291-戊醇0.1000.068030.059730.067830.082230.087330.078630.084620.0750.0100.040.20.830四氯乙烯0.1000.110640.111020.111170.083520.099040.098720.110140.1030.0100.040.31.231乙酸正丁酯0.1000.054400.048430.053090.057950.069790.054600.056800.0560.0070.030.20.832氯苯0.1000.088940.088780.088770.089400.096460.097620.108330.0940.0070.030.20.833乙苯0.1000.080000.078820.079170.081110.087550.087470.099410.0850.0070.030.20.834对+间二甲苯0.2000.129560.128830.127330.131490.147880.143870.128600.1340.0080.030.31.235邻二甲苯0.1000.072120.071450.070440.074020.080810.081060.092050.0770.0080.030.20.836苯乙烯0.1000.077350.076080.077130.075910.085010.085080.098770.0820.0080.030.20.837异丙苯0.1000.093780.093230.092610.094590.103230.113220.095110.0980.0080.030.20.838环己酮0.2500.267520.241330.290450.229360.241220.230400.242310.2490.0220.070.41.2391,3,5-三甲苯0.1000.091780.090470.092440.092670.106750.106110.093620.0960.0070.030.20.8401,2,4-三甲苯0.1000.089450.088650.087960.088190.103280.104790.090760.0930.0070.030.20.8411,2,3-三甲苯0.1000.089370.089350.088820.089430.105350.106530.090630.0940.0080.030.20.8421,2-二氯苯0.1000.090130.089180.089470.083600.101440.103220.092000.0930.0070.030.20.8表1-8实验室6方法检出限、测定下限测试数据表序号化合物名称加标量(μmol/mol)测定值(μmol/mol)平均值(μmol/mol)标准偏差Si(μmol/mol)检出限(μmol/mol)检出限(mg/m3)测定下限(mg/m3)第一次第二次第三次第四次第五次第六次第七次1氯乙烯0.100.0860.0800.0720.0720.0730.0830.0790.0780.0060.0180.060.2421，3-丁二烯0.100.0770.0730.0690.0710.0760.0880.0780.0760.0060.0200.050.203环氧乙烷0.100.0950.1060.1110.1130.1100.1080.0920.1050.0080.0260.060.244溴甲烷0.100.0760.0710.0710.0770.0710.0850.0700.0740.0050.0170.080.325环氧丙烷0.100.1040.0880.1060.0830.0980.1050.0980.0980.0090.0280.080.326丙酮0.100.1290.1250.1120.1210.1360.1260.1140.1230.0080.0260.070.287溴乙烷0.100.0790.0710.0690.0690.0640.0710.0660.0700.0050.0150.070.288异丙醇0.100.0710.0720.0790.0740.0840.0790.0720.0760.0050.0160.050.209乙腈0.100.0930.0880.0960.0910.1080.1150.1040.0990.0100.0310.060.2410二氯甲烷0.100.0750.0800.0790.0750.0770.0910.0830.0800.0060.0170.070.2811丙烯腈0.100.0820.0720.0750.0720.0710.0920.0760.0770.0070.0230.060.2412甲基叔丁基醚0.100.0740.0680.0700.0660.0650.0770.0760.0710.0050.0150.060.2413正己烷0.100.0790.0790.0870.0900.0860.0950.0910.0870.0060.0190.080.3214乙酸乙烯酯0.100.0590.0600.0590.0550.0510.0580.0520.0560.0040.0120.050.20152-丁酮0.100.0760.0650.0600.0630.0610.0730.0590.0660.0070.0210.070.2816乙酸乙酯0.100.0640.0650.0570.0650.0640.0730.0590.0640.0050.0160.070.2817四氢呋喃0.100.0890.0820.0880.0950.0710.0800.0800.0840.0080.0250.080.3218氯仿0.100.0750.0780.0690.0710.0680.0770.0820.0740.0050.0170.090.3619环己烷0.100.0750.0740.0720.0800.0850.0870.0770.0790.0060.0180.070.2820四氯化碳0.100.0730.0780.0670.0670.0650.0760.0700.0710.0050.0150.100.4021苯0.100.0970.0960.1010.0930.0900.1130.1000.0980.0070.0230.090.36221,2-二氯乙烷0.100.0720.0720.0710.0690.0710.0850.0770.0740.0060.0170.080.3223三氯乙烯0.100.0760.0710.0740.0720.0740.0880.0750.0760.0060.0190.100.40241,2-二氯丙烷0.100.0710.0720.0700.0690.0690.0850.0750.0730.0060.0180.100.4025环氧氯丙烷0.100.0840.0900.0780.0710.0760.0760.0710.0780.0070.0210.200.80264-甲基-2-戊酮0.100.0720.0650.0710.0650.0710.0630.0750.0690.0040.0140.070.2827甲苯0.100.0510.0480.0620.0440.0530.0520.0540.0520.0050.0170.070.2828乙酸异丁酯0.100.0930.0960.0930.0930.0910.1080.1010.0970.0060.0190.100.40291-戊醇0.100.0890.0880.0980.1020.1130.1030.0840.0970.0100.0320.200.8030四氯乙烯0.100.0780.0770.0760.0750.0760.0950.0860.0800.0070.0230.200.8031乙酸正丁酯0.100.0710.0690.0770.0830.0710.0610.0790.0730.0070.0230.200.8032氯苯0.100.0850.0850.0830.0820.0800.0970.0880.0860.0060.0180.100.4033乙苯0.100.0870.0840.0830.0820.0830.1000.0900.0870.0060.0200.100.4034对+间二甲苯0.100.1770.1740.1700.1670.1690.2000.1830.1770.0110.0360.200.8035邻二甲苯0.100.0900.0880.0860.0840.0850.1030.0940.0900.0070.0210.100.4036苯乙烯0.100.0970.0960.0950.0930.0920.1130.1010.0980.0070.0230.100.4037异丙苯0.100.0880.0870.0850.0830.0830.1000.0920.0880.0060.0200.100.4038环己酮0.100.0940.0740.0780.0760.0850.0830.0810.0820.0070.0210.100.40391,3,5-三甲苯0.100.0940.0920.0900.0880.0880.1060.0950.0930.00620.0190.100.40401,2,4-三甲苯0.100.0970.0950.0940.0910.0910.1090.0990.0970.00630.0200.100.40411,2,3-三甲苯0.100.1000.0990.0970.0950.0950.1150.1030.1010.0070.0220.200.80421,2-二氯苯0.100.1040.1020.0990.0960.0970.1180.1060.1030.0080.0240.200.801.3目标化合物的精密度和准确度原始测试数据6家实验室对不含目标物的空气样品中加标量0.250μmol/mol、1.00μmol/mol、4.00μmol/mol三个不同浓度的样品在最佳实验条件下上机分析，计算目标组分的精密度和准确度。对各目标化合物的精密度、准确度原始测试数据见表1-9～表1-14。表1-9实验室1精密度、准确度测试数据表序号化合物名称空白加标量(μmol/mol)测定值(μmol/mol)平均值(μmol/mol)标准偏差Si(μmol/mol)相对标准偏差(％)回收率(％)第一次第二次第三次第四次第五次第六次1氯乙烯0.2500.2310.2340.2350.2370.2340.2370.2350.0020.993.91.001.030.980.9710.9670.9750.970.9820.0242.598.24.003.753.973.993.973.983.943.9340.0892.398.421，3-丁二烯0.250.2360.2390.2310.2360.2330.2290.2340.0041.593.61.000.9390.8650.8540.8660.8590.8480.8720.0333.887.24.004.224.564.64.584.614.584.5250.1513.31133环氧乙烷0.2500.2460.2390.2490.2510.2530.2560.2490.0062.399.51.000.9851.021.010.9280.9630.9970.9850.0353.598.54.003.783.843.943.893.943.913.8840.0651.797.14溴甲烷0.2500.2640.2660.2660.2650.2630.2650.2650.0010.41061.001.061.061.051.051.061.061.0560.0060.61064.004.084.14.064.0970.0250.61025环氧丙烷0.2500.2230.2280.2190.2310.2230.2350.2270.0062.690.61.000.9530.8990.8850.8830.890.8870.8990.027389.94.003.433.613.693.693.713.683.6370.1072.990.96丙酮0.2500.1880.1910.2010.2050.1990.2030.1980.0073.579.11.000.9840.9550.9460.940.9540.9560.9560.0151.695.64.003.83.923.943.923.963.933.910.0551.497.77溴乙烷0.2500.2580.2590.2590.2590.2580.2560.2580.0010.41031.001.051.021.011.011.021.011.0190.0131.31024.003.923.983.973.963.973.943.9570.0250.698.98异丙醇0.250.2280.2330.2240.2480.2330.2390.2340.0083.693.71.000.9980.9310.9410.9150.9230.9080.9360.0323.593.64.003.283.483.53.523.593.573.4880.1093.187.29乙腈0.2500.2250.2230.2290.2260.2300.2240.2260.0031.290.41.000.9810.9270.9450.9540.9540.8280.8610.0546.286.14.003.7073.7293.7513.6853.6853.7513.7180.0260.884.510二氯甲烷0.2500.2430.2440.2430.2440.2440.2450.2440.0010.397.51.001.061.051.041.041.061.051.0510.0070.71054.003.863.93.883.883.893.863.8770.0160.496.911丙烯腈0.2500.2420.2560.2330.2480.240.2420.2440.0083.297.51.001.020.9660.9560.9730.9370.9580.9680.0282.996.84.003.533.723.753.753.823.73.7110.0992.792.812甲基叔丁基醚0.2500.2430.2430.2410.2520.2410.2470.2450.0041.797.91.000.9850.9340.9250.9240.9250.9220.9360.0242.693.64.004.384.574.594.594.664.624.5680.0972.111413正己烷0.2500.2520.2550.2550.2570.2550.2560.2550.0020.71021.000.8790.8390.8330.8280.8290.8240.8390.0212.483.94.004.1064.2764.2844.2764.3014.2334.2460.0841.710614乙酸乙烯酯0.2500.2210.2240.2260.2170.2220.2370.2250.006389.61.000.9370.8940.8830.8740.8930.8770.8930.0232.689.34.004.194.434.474.454.54.474.4160.1152.6110152-丁酮0.2500.2550.2550.2520.2520.2530.2580.2540.00211021.000.9260.90.8920.890.8910.8870.8980.0151.689.84.003.994.084.154.1050.0661.610316乙酸乙酯0.2500.2130.2110.2140.2160.2180.2170.2150.0031.285.91.001.031.0311.020.9980.9881.0110.0181.81014.004.234.324.344.324.394.314.3170.0521.210817四氢呋喃0.2500.1930.1990.1860.20.1880.1920.1930.006377.11.000.950.910.8980.8930.90.8920.9070.0222.490.74.003.663.753.783.773.833.773.760.0581.5494.018氯仿0.2500.2740.2740.2740.2730.2750.2740.27400.21101.001.071.081.081.071.081.091.0770.0060.61084.004.023.943.923.93.913.883.9280.0491.298.219环己烷0.2500.1880.1890.1870.1850.1870.1880.1870.0010.774.91.000.8980.8730.8590.8550.8550.8580.8660.0171.986.64.004.134.2491.1510620四氯化碳0.2500.2570.2560.2560.2570.2560.2560.2560.00050.181021.001.0080.0131.11114.004.174.064.023.984.013.974.0370.0731.810121苯0.2500.2410.2440.2430.2420.2450.2460.2430.0020.897.31.001.071.071.091.081.091.091.080.0090.91084.004.330.0591.4106221,2-二氯乙烷0.2500.2450.2440.2430.2410.2460.2470.2440.0020.8497.81.0081.1620.0221.91164.004.494.284.164.2520.1222.910623三氯乙烯0.2500.2740.2760.2750.2740.2740.2770.2750.0010.41101.001.081.011.111.1020.0121.11104.004.113.983.983.943.933.923.9760.0691.799.4241,2-二氯丙烷0.2500.2750.2760.2790.2750.2780.2790.2770.0020.61111.001.071.011.11.0940.0141.31094.004.174.034.013.973.973.964.0170.079210025环氧氯丙烷0.2500.2710.2720.2710.2670.2680.2720.270.0020.81081.001.021.041.041.061.061.051.0450.0141.41054.003.723.593.63.573.593.583.6090.0541.590.2264-甲基-2-戊酮0.2500.2060.2030.2030.2050.2010.2060.2040.0020.981.51.001.061.061.081.091.081.111.0780.0181.71084.004.724.434.454.4380.1232.711327甲苯0.2500.2350.2360.2350.2340.2360.240.2360.002194.41.001.061.071.081.091.091.081.0760.0121.11084.004.684.534.514.474.474.444.5160.0871.911328乙酸异丁酯0.2500.2110.2110.2080.2110.20020.983.81.001.0441.0441.0891.081.080.991.0550.0413.51054.005.154.824.84.774.9954.9230.1483123291-戊醇0.2500.1880.2240.2110.2020.1770.1850.1980.018979.11.001.021.021.181.0950.0716.51094.004.313.863.833.8110.2055.110030四氯乙烯0.2500.2730.2760.2740.2730.2750.2780.2750.0020.61101.0011.1680.0342.91174.004.584.314.274.2860.1523.510731乙酸正丁酯0.2500.20.1960.1890.2050.1910.20.1970.006378.71.0011.1750.0494.21174.004.724.354.344.324.594.564.480.1673.711232氯苯0.2500.2380.2370.2390.2360.2370.2370.2370.0010.4951.001.021.021.021.021.021.031.0220.0050.41024.004.14.064.044.0143.984.0310.0451.110133乙苯0.2500.2170.2150.2150.2160.2160.2150.2160.0010.586.31.001111111.0020.0010.11004.004.494.444.434.374.384.344.410.061.311034对，间二甲苯0.5000.4720.4680.4680.4690.4710.4680.4690.0020.493.92.002.072.072.062.072.072.082.070.0060.31038.008.107.897.827.737.717.657.835邻二甲苯0.2500.2390.2400.2380.2360.2360.2360.2380.0020.695.01.000.9920.9880.9840.9880.9950.9970.9910.0050.599.14.004.484.384.364.34.314.274.3480.0761.810936苯乙烯0.2500.2140.2150.2160.2190.2150.2160.2160.0020.886.41.000.9470.9440.9440.9430.9370.9640.9470.009194.74.004.554.494.514.494.514.444.4970.0350.811237异丙苯0.2500.2570.2580.2590.2620.2560.2590.2580.0020.81031.001.011.021.011.011.051.031.0140.0111.11014.004.324.284.334.334.374.294.3220.0330.810838环己酮0.2500.2680.240.2580.2190.2470.240.2460.0176.898.31.000.870.810.8530.7320.7780.8260.8110.1129.281.14.004.834.314.084.794.474.284.4570.2986.7111391,3,5-三甲苯0.2500.2540.2550.2570.2590.2540.2560.2560.0020.801021.000.9450.9480.9470.9510.9420.9660.950.0090.90954.004.284.244.314.314.364.284.2970.0390.90107401,2,4-三甲苯0.2500.24540.24020.901001.000.9430.9460.9410.9450.9430.9650.9470.0090.9094.74.0074.1880.040.90105411,2,3-三甲苯0.2500.2520.2560.2550.2580.2530.2540.2550.0020.901021.000.9630.9720.9570.9620.9570.9770.9650.0080.9096.54.004.4004.3444.3844.3764.4404.3764.3870.0320.726110421,2-二氯苯0.2500.2660.2660.2660.2660.2660.2660.2690.0020.71081.001.041.061.051.051.051.071.0540.010.91054.00074.200.0240.6105表1-10实验室2精密度、准确度测试数据表序号化合物名称空白加标量(μmol/mol)测定值(μmol/mol)平均值(μmol/mol)标准偏差Si(μmol/mol)相对标准偏差(％)回收率(％)第一次第二次第三次第四次第五次第六次1氯乙烯0.2500.2380.2350.2410.2360.2360.2420.2380.0031.1895.21.000.9800.9100.9000.9000.9000.8900.9100.043.8491.44.003.7504.1604.2604.2804.3204.3104.1800.225.2410521，3-丁二烯0.250.2370.2360.2360.2390.2340.2430.2380.0031.3695.11.001.1041.0271.0141.0011.0141.0011.0270.0393.821034.004.0704.4904.5904.6404.6704.7004.5200.245.211133环氧乙烷0.2500.2340.2380.2420.2610.2470.2360.2430.000.9500.8900.9500.8900.8900.9000.9100.033.2191.24.003.8203.9103.9503.9204.0003.9703.9300.061.5698.24溴甲烷0.2500.2780.2780.2800.2790.2680.2940.2790.0083.031121.001.0501.0201.0181.0141.0221.0171.0240.0131.31024.004.1604.1804.1704.1304.1504.1804.1600.020.441045环氧丙烷0.2500.2110.2140.2320.2190.2060.2240.2180.014.3987.11.000.9100.8600.8300.8400.8400.8400.8500.033.2785.34.003.4003.6503.6603.6403.6803.6803.6200.112.9690.56丙酮0.2500.2340.2440.2440.2460.2390.2510.2000.0062.9379.91.000.8900.8600.8500.8400.8500.8400.8100.022.498