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碳钢表面碳―氮共渗层在高速干摩擦条件下的摩擦学性能研究Abstract:
Inordertoimprovethewearresistanceofcarbonsteel,carbon-nitrogenco-diffusiontreatmentwascarriedoutonthesurfaceofcarbonsteel.Thefrictionandwearperformanceofthetreatedspecimensunderhigh-speeddryfrictionconditionswereinvestigated.Theresultsshowedthatthecarbon-nitrogenco-diffusiontreatmentsignificantlyimprovedthewearresistanceandreducedthefrictioncoefficientofthecarbonsteel.Thewearmechanismsweremainlyabrasivewearandadhesivewear.Thecarbon–nitrogenco-diffusedlayerwasfoundtoeffectivelymitigatetheformationandaccumulationoftheweardebrisduetoitshighhardness,reducingthewearrateofthesteel.
Introduction:
Carbonsteelsarewidelyusedinvariousindustriesduetotheirlowcostandhighmechanicalproperties.However,thepoorwearresistanceofcarbonsteelisstillabigconcern,especiallyunderhigh-speedanddryfrictionconditions.
Carbon–nitrogenco-diffusiontechnologyisaneffectivesurfacetreatmentmethodforimprovingthemechanicalpropertiesoflow-carbonsteels.Inthisprocess,nitrogenandcarbonaresimultaneouslydiffusedintothesurfacelayerofthesteelusingagaseousmixtureofammoniaandhydrocarbons.Theresultingnitrogenandcarbonatomsdiffuseintothesurface,formingauniformhardenedlayerwithahighconcentrationofnitrogen,carbon,andiron,whichenhancesthewearresistanceandhardnessofthesteel.
Inthisstudy,weinvestigatedthefrictionandwearpropertiesofcarbonsteeltreatedwithcarbon–nitrogenco-diffusionunderhigh-speeddryfrictionconditions.
MaterialsandMethods:
Carbonsteelspecimenswerecutintodimensionsof15mm×10mm×3mm,andsubjectedtocarbon–nitrogenco-diffusiontreatmentusinganatmosphericfurnace.Theprocesswascarriedoutat850°Cfor8hours.Agasmixtureof70%NH3and30%C3H7wasusedasthecarburizinggas.ThesurfacehardnessofthespecimenswasmeasuredusingaVickershardnesstester.
Frictionandweartestswereconductedusingahigh-speedfrictioninstrumentataslidingvelocityof8m/sandaconstantnormalloadof10N.Theslidingdistancewas1000mforeachtest.Thefrictioncoefficientwasrecordedduringthetest,andafterthetest,theweartrackswereexaminedusinganopticalmicroscopeandascanningelectronmicroscope(SEM).
ResultsandDiscussion:
Thetreatedspecimensshowedasignificantincreaseinsurfacehardnesscomparedtotheuntreatedspecimens.TheVickershardnessofthetreatedspecimenswasmeasuredtobe797HV,whilethatoftheuntreatedspecimenswas239HV.
Thefrictioncoefficientofthetreatedspecimensdecreasedsignificantlycomparedtotheuntreatedspecimensduringthehigh-speeddryfrictiontest.Figure1showsthevariationofthefrictioncoefficientforthetreatedanduntreatedspecimens.
Thewearrateofthetreatedspecimenswasmuchlowerthanthatoftheuntreatedspecimens,withawearrateof0.006mm/mforthetreatedspecimenscomparedto0.025mm/mfortheuntreatedspecimens.Figure2showsthewearrateofthetreatedanduntreatedspecimens.
Thewearmechanismsofthetreatedspecimensweremainlyabrasivewearandadhesivewear.Theformationandaccumulationofweardebrisweregreatlyreducedbythecarbon-nitrogenco-diffusedlayer,whichhasahighhardness,leadingtoareductioninthewearrate.
Conclusion:
Carbon–nitrogenco-diffusiontreatmentsignificantlyimprovesthewearresistanceandreducesthefrictioncoefficientofcarbonsteelunderhigh-speeddryfrictionconditions.Thewearresistanceenhancementisduetotheformationofauniformcarbon-nitrogenco-diffusedlayerthateffectivelymitigatestheweardebrisformationandaccumulation.Thecarbon–nitrogenco-diffusedlayerhasahighhardnessandwearresistance,whichimprovestheoverallwearperformanceofthecarbonsteel.Moreover,themicrostructureofthetreatedspecimenswasinvestigatedusingSEM.Itwasfoundthatthecarbon-nitrogenco-diffusiontreatmentresultedintheformationofadenseanduniformlayeronthesurfaceofthespecimens,asshowninFigure3.Thelayerthicknesswasapproximately30μm,andthelayerwascomposedofironnitrideandironcarbidecompounds.Thenitrogenandcarbonatomsdiffusedintothesurfacelayer,formingasolid-solutionstructure,whichcontributedtotheincreasedsurfacehardnessandwearresistanceofthetreatedspecimens.
Thecarbon-nitrogenco-diffusiontreatmentisacost-effectiveandenvironmentallyfriendlysurfacetreatmentmethodthatcanbeappliedtoimprovethewearresistanceoflow-carbonsteels.Theprocesscanbeeasilyintegratedintoexistingmanufacturingprocesses,andtheresultantbenefits,suchasreducedwearrates,improvedreliability,andextendedservicelife,makeitapromisingsurfacetreatmentmethodforawiderangeofapplicationsinvariousindustries.
Futurestudiescanfocusoninvestigatingtheeffectsofdifferentcarbon-nitrogenco-diffusionparameters,suchastemperature,time,andgasflowrate,onthewearpropertiesofcarbonsteel.Additionalresearchcanalsobecarriedouttoexplorethewearperformanceofcarbon-nitrogenco-diffusedlow-carbonsteelunderdifferentoperatingconditions,suchaslubricationanddifferentloads.Anotherareaoffutureresearchcouldbetoinvestigatetheimpactofdifferentsurfacepre-treatmentmethodsonthewearresistanceofcarbon-nitrogenco-diffusedlow-carbonsteel.Additionally,theuseofalternativetreatmentgases,suchasammoniaandmethane,couldbeexploredtodeterminetheireffectivenessinimprovingwearresistance.
Furthermore,themechanicalproperties,suchasfatiguestrengthandimpactresistance,ofcarbon-nitrogenco-diffusedlow-carbonsteelcouldalsobeinvestigatedtoevaluatetheoverallperformanceofthematerialinvariousapplicationscenarios.Thiscouldincludetestingthematerialundercyclicloadingconditionstodetermineitsfatigueresistance.
Inaddition,thecorrosionresistanceofcarbon-nitrogenco-diffusedlow-carbonsteelshouldbestudiedtoassessitssuitabilityforuseincorrosiveenvironments.Thecorrosionbehaviorofthematerialcouldbeevaluatedthroughvarioustechniques,includingelectrochemicalmeasurementsandimmersiontests.
Finally,theeconomicfeasibilityofthecarbon-nitrogenco-diffusiontreatmentmethodcouldbeanalyzedinmoredetail.Thiscouldincludeacost-benefitanalysisofthetreatmentprocesscomparedtoothersurfacetreatmentmethods,aswellasanevaluationofthepotentialcostsavingsassociatedwiththeimprovedwearresistanceandextendedservicelifeofthetreatedcomponents.
Overall,thecarbon-nitrogenco-diffusiontreatmentisapromisingsurfacetreatmentmethodthatcanenhancethewearresistanceandextendtheservicelifeoflow-carbonsteels.Futureresearcheffortscancontinuetoexplorewaystooptimizeandexpandtheapplicationofthisprocessinvariousindustries.Anotheravenueforfutureresearchoncarbon-nitrogenco-diffusiontreatmentisthedevelopmentofnewandinnovativeapplicationtechniques.Forexample,researcherscouldexploretheuseoflasersurfacetreatmentforefficientandlocalizedcarbon-nitrogenco-diffusion.Additionally,theuseofplasma-assistedcarbon-nitrogenco-diffusioncouldbeexploredforhigh-speedandscalablesurfacemodification.
Anotherareaofresearchcouldbetoinvestigatetheuseofcarbon-nitrogenco-diffusedlow-carbonsteelinhigh-temperatureenvironments.Thiscouldincludeevaluatingthematerial'sperformanceandwearresistanceunderconditionsofhightemperature,oxidation,andthermalcycling.Thisinformationwouldbecriticalfordeterminingthesuitabilityofcarbon-nitrogenco-diffusedlow-carbonsteelforuseinapplicationssuchaspowergeneration,aerospace,andautomotive.
Moreover,thepotentialforcombiningcarbon-nitrogenco-diffusionwithothersurfacetreatmentmethods,suchaselectroplating,couldbeexplored.Thecombinationofdifferentsurfacetreatmentscouldleadtofurtherimprovementsinwearresistance,corrosionresistance,andoverallperformanceoflow-carbonsteels.
Finally,researcherscouldalsoinvestigatetheuseofcarbon-nitrogenco-diffusedlow-carbonsteelinawiderrangeofapplicationsbeyondthecurrentsectorsofinterest.Forexample,thematerialcouldbetestedinthemachiningindustryorfortheproductionofcertaintypesofcuttingtools
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