粉末涂料应用0805课件

粉末涂料应用推荐BASF系列颜料青岛健泰化工Contents产品目录Inorganicpigments:Sicopal/Sicotan无机颜料Hybridpigments:Paliotan钒酸铋复合有机颜料Organicpigments:Paliotol/Paliogen/Heliogen有机颜料effectpigments:Paliocrom彩色铝基材效果颜料Organicdyes:Neozapon/Thermoplast有机染料EffectPigments:Cyclo®粉末专用白色珠光颜料CoolPigment:K0095降温颜料Forpowdercoatings,BASFofferspigmentstestedforcoatingsapplications(Lgrades)aswellasplasticsapplication(Kgrades).在粉末涂料中，巴斯夫提供了像塑料应用系列颜料产品（K级）一样性能的L级颜料。Experiencehasshownthatwhenitcomestofinelydividedorganicpigments,therespectiveKgradeisoftenmorereadilydispersibleandhashighercolorstrengththantheLgradeofthesamechemicalconstitution.经验表明，在相同的化学条件下，K级产品通常比L级产品有更好的分散性和更好的着色力。BASF’shybridpigmentsaresuppliedunderthePaliotan/trademark,consistingofbismuthvanadateandahigh-qualityorganicpigment.巴斯夫钒酸铋复合有机颜料Paliotan,是用钒酸铋符合高性能的有机颜料煅烧制作.Theyprovideanidealcombinationoftheadvantagesofinorganic(highhidingpower)andorganic(chroma,highcolorstrength)pigments,whileatthesametimeofferinghighcostefficiency.这种产品集合了无机颜料(高遮盖力)和有机颜料(颜色鲜艳,着色力高)等优点,有非常高的性价比.ThemosteconomicPaliotantypesarebasedondifferentinorganiccomponents.大多数的经济型的Paliotan产品基于不同的无机成分.Hybridpigments钒酸铋复合颜料Onlyarangeoforganiccolorpigmentscanprovidethemaximumscopeofcoloristicpossibilities.

仅一个范围的有机颜料产品能够提供最大范围的颜色应用.However,noteverycoloristicallyinterestingpigmentissuitableforapplicationinpowdercoatings.但是并不是每一个产品都适合在粉末涂料中应用.Thecolorantsmustfirstsatisfyaseriesofbasictechnical/physicalrequirements.

颜料必须首先符合技术/物理的基础要求Theseincludeheatresistance,dispersibilityandgoodshadereproducibility.这包括热稳定性,分散性,和颗粒形状.Organicpigments有机颜料•resistancetoaminesandamides耐胺醛/酰胺树脂•hidingpower遮盖力•dispersibility分散性•colorstrength着色力•chromaticity色相•minimumplate-out最小起霜量，颜料的耐迁移•heatresistance热稳定性•minimumthermochromism最小热变色效应•suitabilityforovercoating适宜罩光涂层性能•fastnesstoweathering色牢度（耐候）•costefficiency经济性Examplesofdesirableproperties合适的性能无机颜料Sicopal/Sicotan

Sicopal复合无机铋颜料ShadessuchasRAL1021andRAL1028,whicharedifficulttoachievewithoutusinglead-basedpigments,areeasilyobtainedwithSicopalYellowpigments.

ThestandardpigmentisSicopalYellowL1100.

采用铋黄非常容易与RAL1021/1028黄色色相匹配，这种色相是铅颜料也难配色的黄。铋黄颜料L1100标准色。SicopalYellowL1120hasaslightlyredderwithimprovedchroma.Itismoreheat-resistantinPrimidcrosslinkedpowdercoatingsanditshidingpowerandweatherfastnessarealsooutstanding.铋黄颜料L1120有轻微红色色相改善，在Primid系列交联粉末涂料有更好的热稳定性，并且遮盖力，耐候性也出众。TomatchreddishshadeswerecommendthemuchredderalternativeSicopal?YellowL1600,whosehueoftenallowstheamountoforganicshadingpigmentsintheformulationtobereduced.

如果要配红相的颜色，推荐铋黄L1600，这个产品的色相通常可以减少有机着色颜料在配方中用量。无机颜料Sicopal/Sicotan

Sicopal复合无机铋颜料Thecolorofbismuthvanadatepigmentsisstableatnormalbakingtemperatures(180°C-210°C).铋黄颜料在180°C-210°C烘烤温度中有非常好的稳定性。However,severeoverbaking(e.g.,60minat210°C)mayresultincoloristicchangestowardsaduller,darkershadeandintheformationofvarioussurfacestructures(e.g.,craters),dependingontheresin/curingagentsystemused.Changesinfilmhardnesshavealsobeenobserved.但是在特别恶劣条件下如（60分钟210°C），可能出现色彩消色（消光，变暗），或者在不同条件（树脂，助剂）应用产生不同的表面结构。也可能出现漆膜变硬的现象。Whereespeciallygoodheatstabilityisrequired,werecommendsuitablepreliminarytestsundertheappropriateconditions.如果特别的热稳定性能需要，建议采用合适条件下初步实验方法。无机颜料Sicopal/Sicotan

Sicopal复合无机铋颜料TheSicotanYellowgradesarecomplexinorganicchromaticpigments.Ofcoloristicsignificancearethelemon-yellownickeltitanates(e.g.,SicotanYellowL1010)andtheocher-coloredchromiumtitanates,forexampleSicotanYellowL2110.

黄颜料Sicotan是复合无机铬系颜料，同时复合了镍钛成为柠檬黄，如L1010，或者钛复合土黄（赭色）色，如L2110。无机颜料Sicopal/Sicotan

钛镍黄复合颜料

Sicotan

pigments

镍/铬

钛酸盐

Sicotanyellowpigmentsareidealforuseinpowdercoatings.Sicotan钛镍黄颜料是粉末涂料非常理想的产品.Highheatstability,highhidingpowerandmaximumfastnesstoweatheringmakethemidealforcombinationwithorganicyellow,orangeandredpigments,yieldingabroadspectrumofshadesthatmeetalltherequirementswithrespecttobrillianceandhighhidingpower.非常高的耐热性/高遮盖力/最强的耐候性,最理想的复合有机黄,橙,红颜料,来满足实际对颜色的鲜艳性和高遮盖力的需求.无机颜料Sicopal/Sicotan

Sicotan

pigments

镍/铬

钛酸盐-钛镍黄复合颜料

ItisoftenpossibletouselessorganicpigmentsinformulationswithSicotanYellowpigmentsthanwithtitaniumdioxide.ThisreducesthePVC(pigmentvolumeconcentration),whichhasapositiveeffectontheflowpropertiesandalsohaseconomicbenefits.

采用Sicotan黄颜料和钛白能够用更少的有机颜料在配方中成为可能,能够减少颜料使用量(PVC),从而在流动性方面起积极作用,并且有更好的经济效果.SicotanYellowgradesarealsosuppliedaslow-dusting,freeflowingfinegranules.Suchfinegranulesofferadvantagesinlarge-scaleprocessing(weighing,automaticmetering)andatthesametimehaveasmallerphysiologicalimpactonpersonnel.

Sicotan黄系列产品同时提供了低粉尘,增加流动性的小颗粒.这种小颗粒在大规模生产(自动测量,称重)提供了优点,同时对员工的生理影响更小.无机颜料Sicopal/Sicotan

Sicotan

pigments

镍/铬

钛酸盐-钛镍黄复合颜料

有机和无机复合颜料

PaliotanHybridpigmentsWithPaliotanYellowpigments,shadesthatwerepreviouslydifficulttoformulate,suchasRAL1003,1007,1021und1028,canbeproducedlead-freewithouttechnicaldifficulties.Theymeetrequirementsforhidingpower,vividcolorandfastnesstoweatheringtoahighdegree.

采用Paliotan有机黄颜料,能够完成以前非常难的配色,比如RAL1003,1007,1021,1028黄,并且能够替代无铅产品的同时,保证非常高的遮盖力,颜色的鲜艳性,以及优秀的耐候能力.Theycanthereforebeusedinbothindustrialpolyesterandarchitecturalpowdercoatings.

它们可以用来在工业聚酯和建筑粉末涂料中应用.有机和无机复合颜料

PaliotanHybridpigmentsWherecostefficiencyisamoreimportantconsiderationthanfastnesstoweatheringinformulatingthecoatings,choiceshouldfocusonPaliotanYellowL1135,PaliotanOrangeL2935andPaliotanRedL3735.

从成本上考虑,建议选择黄L1135,橙L2935,红L3735有机和无机复合颜料

PaliotanHybridpigmentsPaliotanpigmentsaresuitableforbothindustrialpolyesterpowdercoatingsandalargenumberofsystemsforinterioruse(mixedpolyesterorhybrids).

Paliotan有机颜料适用于工业聚酯粉末和大量的室内应用的混料系统（混合聚酯或其他混合物）WithPrimidcuringagentssuppliedbyEMS-Chemie)werecommendperformingstabilitytestsfirst.Theyellowandredgradesshouldnotbeusedinpureepoxysystemsortogetherwithmattcuringagents.

采用由EMS-Chemie公司生产的Primid固化剂的时候,我们建议首先要进行稳定性的实验,黄和红的系列产品不适用于纯环氧体系或者与无光的固化剂混合使用.TheheatresistanceofPaliotan

pigmentsislimitedbecauseoftherawmaterialsused.Iftheyaretobeappliedattemperaturessignificantlyabove180°C,preliminarytestsshouldbeperformedintheintendedapplicationmedium.有机颜料

Paliotol/PaliogenPaliotolpigments喹酞酮黄，异吲哚啉黄，镍络合物黄，吡唑啉酮-喹唑啉，色酚AS红

PaliotolisBASF’strademarkfororganicpigmentsofdifferentchemicalcompositions.

Paliotol

是BASF的不同化学成分有机颜料的商标.Theproductsdescribedbelowareparticularlysuitableforuseinpowdercoatings.

这些产品非常适合在粉末涂料中使用.GradeswithhighhidingpowerandgooddispersibilityaredistinguishedbythelettersHD(hiding,dispersibility)followingthenumericalcode.

这一级别的产品有高遮盖力和良好的分散能力,在产品数字后被用HD做后缀.有机颜料Paliotol/PaliogenPaliotolpigments

PaliotolYellowandOrangegradesareidealpartnersfortheSicopalandSicotanYellowpigments,becausetheyallowtheformulationofbrilliantshadeswithgoodhidingpower.

Paliotol

有机黄和橙系列产品是理想的复合颜料Sicopal和Sicotan黄的选用成分,因为它们有鲜艳的色相和高遮盖力.Suchcombinationshaveoftenbeensuccessfullyusedas“leadsubstitutionsolutions”.

这些产品是无铅替代的成功产品.有机颜料Paliotol/PaliogenPaliotolpigments

ThePaliotolHDgradesareparticularlyrecommendedforuseinfullshades.Inmediumandstrongreductionswithtitaniumdioxidetheremaybeasubstantialdecreaseinfastnesstoweathering.

带HD系列产品是特别建议用在耐候方面真实减少钛白用量成为饱和色方案.WethereforerecommendminimizingtheamountoftitaniumdioxideintheformulationandmaximizingtheamountofSicotanYellow(nickelorchromiumtitanate)orSicopalYellow(bismuthvanadate).

因此我们推荐这些产品在镍黄Sicotan或铋黄Sicopal系列混合,或者在减少钛白用量方面使用.有机颜料Paliotol/PaliogenPaliotolpigments

PaliotolYellowL2140HDisthemostsignificantreddishyellowpigmentforpowdercoatings.Sellingpointsareitshighhidingpowerandgoodfastnesstoweathering.

Paliotol

有机黄L2140HD是应用在粉末涂料中最鲜艳的红相黄,有非常好的遮盖力和耐候性.PaliotolYellowL2146HDhasfurtherextendedthecoloristicspectrum.ItismorechromaticandslightlyredderinhuethanPaliotolL2140HD.TheapplicationpropertiesandfastnessprocomparabletothoseofPaliotolL2140HD.

Paliotol

有机黄L2146HD比L2140HD更红相,更艳,同样的应用属性.有机颜料Paliotol/PaliogenPaliotolpigments

PaliotolYellowL1820isthetransparentversionofPaliotolYellowL2140HD.Wherehighcolorstrengthisapriorityinpigmentselection,PaliotolYellowL1820istherightchoice.

Paliotol

黄L1820是L2140HD透明版的产品,当需要高色度的颜料选择时,L1820是一个正确的选择.有机颜料Paliotol/PaliogenPaliotolpigments

PaliotolOrangeL2930HDisapigmentwithaverypureorangehueandgoodfastnesstoweatheringinfullshades.

橙色L2930HD有一个很纯的橙色,在饱和色应用时有很好的耐候性.AformulationbasedonPaliotolL2930HDandSicotanYellowL1910(forexample,forRAL2004)ismuchmoreweather-resistantthanaformulationbasedontitaniumdioxide.

有一个采用L2930和SicotanL1910配色的例子如RAL2004,会有比采用钛白更好的耐候效果.PaliotolL2930HDisalsoapigmentforfullshadesandthereforenotsuitableasatintingandshadingpigmentinpowdercoatings.Atbakingtemperaturesabove180°C,itssuitabilityshouldfirstbedeterminedinpreliminarytests.

在粉末涂料中,L2930HD应该适合饱和色应用,而不是采用冲淡色使用.另外超过180度考虑做进一步实验验证.有机颜料Paliotol/PaliogenPaliotolpigments

NoneofthePaliotolgradeswerecommendisbasedondiarylpigmentchemistry.Diarylpigmentscandecomposeinpolymersprocessedattemperaturesabove200°C.

没有一个Paliotol有机系列颜料推荐在基于二芳基颜料化学成份合成的,后者的产品特性是在超过200度的条件下发生分解.Isoindolinepigmentsarenotsuitableforuseinamine-oramidecuringpowdercoatingsystems.

异吲哚啉酮系列颜料也不适合用于胺醛/氨基树脂粉末涂料.有机颜料Paliotol/PaliogenPaliogenpigments

PaliogenisBASF’strademarkfororganicpigmentsofdifferentchemicalcompositionsandahighstandardoffastness.

Paliogen是BASF的不同化学成份和高标准色牢度有机颜料的商标.Veryhighheatresistance,highhidingpowerandapurehuearetheoutstandingfeaturesofPaliogenRedL3910HD.

非常高的热稳定性,高遮盖力,和纯色是苝红L3910HD的显著特征.Itcanevenbeappliedinadirectlyheatedoven.Inreductionswithtitaniumdioxide,thefastnesstoweatheringofPaliogenL3910HDfallssignificantlysothatwedonotrecommenditforthisapplication.

它能直接用于被烤炉加热的应用.同时在减少使用钛白的条件下,耐候性能也非常优越,以致于推荐用到粉末涂料中.有机颜料Paliotol/PaliogenPaliogenpigments

PaliogenRedK4180offersoutstandingheatresistanceandextremelygoodfastnesstoweathering,bothinfullshadesandinreductionswithtitaniumdioxide.

Paliogen苝红K4180提供了优异的耐热性和杰出的耐候性能,无论是饱和色或采用钛白冲淡的情况下.PaliogenRedL4120showsthesameexceptionalfastnesspropertiesasPaliogenRedK4180butdoesnotattainitshighstandardofdispersibility.

苝红L4120像K4180一样有非常好的色牢度,但在分散性方面要差一些.有机颜料Paliotol/PaliogenPaliogenpigments

PaliogenRedVioletK5011hasdistinctlymorecolorstrengthandismoreweather-resistantthanred-violetpigmentsbasedonquinacridone.Ithasahighstandardofheatresistanceanddispersibility,butitdoesnotofferthecoloristicscopeofquinacridonepigmentswithregardtochromaticity.

紫红色K5011对比基于喹吖(二)酮成份的颜料在着色力及耐候性方面更显著,它有更高的耐热性和分散性,但它颜色鲜艳性要差一些.有机颜料Paliotol/PaliogenPaliogenpigments

PaliogenBlueL6470hasamuchredderhuethanHeliogenBlueL6700F.Oneofitsusesinpowdercoatingsistintingwhitepowders.Apurerwhiteisobtainedthanwithtitaniumdioxidealone.

就是在冲淡色的白色粉末中应用.对比单独采用钛白来说使用L6470能够得到一个更纯的白色.Paliogen阴丹酮蓝L6470对比酞氰蓝L6700F有更多的红相,在粉末涂料中其中的应用.PaliogenBlueL6470hasexcellentfastnesstoweatheringevenatlowconcentrations.However,becausethepigmentparticlesarerelativelyhard,HeliogenBlueL6700Fmayinmanycasesbethebetterchoice.L6470可以在很低用量的情况下有极其优越的耐候性,但因为颜料颗粒相当硬,采用酞氰蓝L6700F在通常的情况下是更好的选择.有机颜料Heliogen酞氰颜料-蓝/绿HeliogenisBASF’strademarkforcopperphthalocyaninepigments.Therangesforcoatingsandforplasticscomprisealargenumberofindividualproducts,eachcharacterizedbyveryspecificapplicationproperties.TheColourIndex(C.I.)providesaninitialindicationforselectionpurposes.Heliogen

是BASF酞菁系(铜酞菁)颜料的商标,这一系列产品应用在涂料和塑料中分别有不同特性的单个产品并用于不同的应用,颜色序列号(C.I.)提供了不同的型号可用来选择.有机颜料Heliogen酞氰颜料-蓝/绿Thefollowingtypesaredistinguished:酞菁蓝总览颜色索引号

P.B.15copperphthalocyanine,unstableP.B.15,α-酞菁蓝

,不稳定

P.B.15:1copperphthalocyanine,alphastableP.B.15:1,α-酞菁蓝,稳定

P.B.15:2copperphthalocyanine,alphastableandsurface-treatedP.B.15:2,

α-酞菁蓝,稳定,表面处理

P.B.15:3copperphthalocyanine,betaP.B.15:3,

β-酞菁蓝

P.B.15:4copperphthalocyanine,betaandsurface-treatedP.B.15:4,β-酞菁蓝

,表面处理

P.B.15:6copperphthalocyanine,epsilonP.B.15:6,ε-酞菁蓝

有机颜料Heliogen酞氰颜料-蓝/绿Extensivetrialswiththesepigmentsinpowdercoatingshaveshownthattheunstabilizedgradesarenotsufficientlyheatresistantandcanleadtoshadechanges.

大量的实验证明在粉末涂料中这些颜料在热稳定性方面不足能够引起色像变化Processingsurfacetreatedpigmentsofthetypedevelopedforconventionalcoatingsystemsbringsnoimprovement,thoughHeliogenBlueL6700Fisanexception.

经过表面处理的颜料在通常情况下在涂料体系中并没有改善这个情况,虽然L6700F是个特例.

有机颜料Heliogen酞氰颜料-蓝/绿BothP.B.15:1andP.B.15:3haveprovedverysatisfactory.TheColourIndexaloneisinsufficienttoassessthesuitabilityofapigmentforpowdercoatings.Verysignificantinensuringgooddispersibilityandcolorstrengthdevelopmentisthesurfacefinishofthepigment.P.B.15:1和P.B.15:3被证明有非常好的适应性.单用颜色索引号来评估在粉末涂料中应用是不够的.颜料颗粒表面光洁来保证颜料的分散性和着色力是非常有意义的.Thisisappliedinaprocessstepbythemanufacturerandtoaconsiderableextentdeterminesthespecificapplicationproperties.

这个处理过程是生产商采用并在实际应用中采取的必要过程.有机颜料Heliogen酞氰颜料-蓝/绿HeliogenBluepigments酞氰蓝颜料

HeliogenBlueK6907isanew,readilydispersible,verycostefficientP.B.15:1pigment.K6907是一个新的,非常容易分散的,非常有性价比的15:1的颜料

HeliogenBlueK6911D,becauseofitsgooddispersibility,isourspecialrecommendationforpowdercoatings.K6911D,因为其良好的分散性,特别推荐于粉末涂料有机颜料Heliogen酞氰颜料-蓝/绿HeliogenBlueL6930iscomparableincoloristicandapplicationpropertiestoHeliogenBlueK6911D.

L6930是可以在色相和应用属性中和K6911D相提并论的产品.QualitycontrolofHeliogenBlueL6930iscarriedoutinaconventionalcoatingsystem.Thespecialqualitycontrol(plasticstestmethod)usedforHeliogenBlueK6911Dismuchmorelikethepowdercoatingmanufacturingprocessthanthecoatingstestmethod.L6930的质量控制在常规涂料系统中应用,这个特殊的质量控制(塑料检测方法)对于K6911D是类似于粉末涂料生产工艺过程的涂料检测方法.有机颜料Heliogen酞氰颜料-蓝/绿HeliogenBlueL7072DandHeliogenBlueL7080offerexcellentperformanceinpowdercoatings.HeliogenBlueK7090isBASF’sbestdispersingbetabluepigment.

酞氰蓝L7072D和L7080提供了优越的粉末涂料的表现能力,另外K7090提供了蓝色颜料最佳的分散能力.有机颜料Heliogen酞氰颜料-蓝/绿Despiteexceptionalfastnessproperties,evenphthalocyaninebluepigmentshaveapplicationlimits.Forexample,strongoxidizingagentssuchas70%nitricacidandhydrogenperoxidedecolorizethecoloredcoatinganddestroythephthalocyaninebluepigment.Anitricacidtestisdescribed,forexample,inUSspecificationAAMA2604-02,item7.7.3.AAMA=AmericanArchitecturalManufacturersAssociation)

尽管酞氰蓝颜料有非常好的色牢度性能,但是还是有些受限制的条件,比如在美国建筑制造协会有关应用实验证明,在强氧化剂比如超过70%的硝酸或过氧化氢应用时会使该颜料破坏而变色.有机颜料Heliogen酞氰颜料-蓝/绿Amongthephthalocyaninegreenpigments,adistinctionismadebetweenbluish(P.G.7)andyellowish(P.G.36)greentypes.Therecommendedpigmentsfulfillthetechnicalrequirementswithrespecttoheatresistance,fastnesstoweatheringanddispersibilitytoaveryhighdegree.

在酞氰绿颜料中,有蓝相P.G.7和黄相的P.G.36两种型号.推荐的颜料要满足耐热性,耐候性及高质量的分散能力.有机颜料Heliogen酞氰颜料-蓝/绿HeliogenGreenL8730istheuniversalstandardpigmentforcoatings.Wheresuitabilityforbothpowdercoatingsandconventionalcoatingsisrequired,HeliogenL8730isthebestchoice.However,thebestpigmentforexclusiveuseinpowdercoatingsisHeliogenGreenL8731,sinceitwasdesignedforthisapplication.

酞氰绿L8730是通用的标准颜料可用于粉末或常规传统涂料,是一个最好的选择.L8731是一个专用粉末涂料设计的产品,最优秀的性能.有机颜料Heliogen酞氰颜料-蓝/绿Thehighdegreeofhalogenationofphthalocyaninegreenpigmentsmakesthemmuchmoreresistanttostrongoxidizingagentsthanphthalocyaninebluepigments.

酞氰绿的分子结构因为含有更多的溴离子,相对来说有更好的抗氧化剂能力.Variocrom™

/Paliocrom™效果颜料ColorVariablePigments™andeffectpigments™TheColorVariablePigments™Varioc