聚合物Janus微粒的合成方法及特性综述(4),高分子材料论文

聚合物Janus微粒的合成方法及特性综述(4),高分子材料论文4.5其他应用。Synytska等[108]先通过Pickering乳液修饰法制备PAA/PSJanus微粒，然后在PAA端载入Ag和Au纳米粒子，得到了具有高界面催化活性的复合型Janus微粒。复合型Janus微粒能有效降解亚甲基蓝、曙红Y和对硝基苯酚，并具有用量少、易回收、可重复使用等优点。基于蝌蚪型交联的PMMA-b-P4VP聚合物Janus纳米粒子稳定的乳液，Gao等[109]简单合成了宏蜂窝聚合物泡沫材料及载入Pd的高活性杂合泡沫催化剂。除此之外，聚合物Janus微粒还可作为吸附剂[110]和微反响器[111],并能用于制备超疏水涂层[16]等。5结论。聚合物Janus微粒具有的多功能组分、各向异性外表性质和微观形貌和多种环境响应性使其在外表活性剂和药物控释等诸多领域具有独特优势。通过合理的设计，人们已经能够可控制备具有期望尺寸、性质、形貌和组分的聚合物Janus微粒。Pickering乳液修饰法和种子聚合法合适于大量制备亚微米聚合物，是最可能实现工业应用的方式方法。可控/活性聚合法和微流体技术则能够更好地控制微粒构造；自组装法适于制备纳米级的多层级聚合物微粒。当前，聚合物Janus微粒的研究主要是合成聚合物。含有天然组分和纯天然环境友好型聚合物Janus材料的制备还较少，其制备和应用将会是将来发展的趋势之一。其次，怎样实现纳米级聚合物Janus粒子构造的精到准确控制及大量制备仍然是急需解决的问题。而聚合物构造-性质-应用的互相关系还需进一步研究。总之，通过对聚合物Janus微粒改性方式方法的创新，将有助于制备具有新型功能的聚合物Janus材料，并拓宽其应用领域。参考文献：[1]deGennesPG.Angew.Chem.Int.Ed.,1992,31:842.[2]WaltherA,MllerAHE.Chem.Rev.,2020,113:5194.[3]LattuadaM,HattonTA.NanoToday,2018,6:286.[4]Cole-HamiltonDJ.Science,2018,327:41.[5]SchickI,LorenzS,GehrigD,SchilmannAM,BauerH,PanthferM,FischerK,StrandD,LaquaiF,TremelW.J.Am.Chem.Soc.,2020,136:2473.[6]CoxLM,KillgoreJP,LiZ,ZhangZ,HurleyDC,XiaoJ,DingY.Adv.Mater.,2020,26:899.[7]LeeKJ,YoonJ,LahannJ.Curr.Opin.Colloid.In.,2018,16:195.[8]周鹏〔ZhouP〕,刘宝〔LiuB〕,梁福鑫〔LiangFX〕,王倩〔WangQ〕,屈小中〔QuXZ〕,杨振忠〔YangZZ〕.高等学校化学学报〔ChemicalJournalofChineseUniversities〕,2021,36:1431.[9]LiangF,ZhangC,YangZ.Adv.Mater.,2020,26:6944.[10]PercecV,WilsonDA,LeowanawatP,WilsonCJ,HughesAD,KaucherMS,HammerDA,LevineDH,KimAJ,BatesFS,DavisKP,LodgeTP,KleinML,DeVaneRH,AqadE,RosenBM,ArgintaruAO,SienkowskaMJ,RissanenK,NummelinS,RopponenJ.Science,2018,328:1009.[11]DupontJ,LiuG.SoftMatter,2018,6:3654.[12]WangT,ChenSR,JinF,CaiJH,CuiLY,ZhengYM,WangJX,SongYL,JiangL.Chem.Commun.,2021,51:1367.[13]GhoussoubYE,SchlenoffJB.Langmuir,2021,32:3623.[14]TangC,ZhangC,SunY,LiangF,WangQ,LiJ,QuX,YangZ.Macromolecules,2020,46:188.[15]DengR,LiuS,LiangF,WangK,ZhuJ,YangZ.Macromolecules,2020,47:3701.[16]ZhaoH,LiangF,QuX,WangQ,YangZ.Macromolecules,2021,48:700.[17]YangH,LiangF,ChenY,WangQ,QuX,YangZ.NPGAsiaMater.,2021,7:e176.[18]HuJ,ZhouS,SunY,FangX,WuL.Chem.Soc.Rev.,2020,41:4356.[19]KaewsanehaC,TangboriboonratP,PolpanichD,EissaM,ElaissariA.ACSAppl.Mater.Interfaces,2020,5:1857.[20]KaewsanehaC,TangboriboonratP,PolpanichD,EissaaM,ElaissariA.ColloidsandSurfacesA:Physicochem.Eng.Aspects,2020,439:35.[21]陈云华〔ChenYH〕,王朝阳〔WangCY〕,李煜〔LiY〕,童真〔TongZ〕.化学进展〔ProgressinChemistry〕,2018,21:615.[22]刘善芹〔LiuSQ〕,张毅军〔ZhangYJ〕,邓仁华〔DengRH〕,梅路平〔MeiLP〕.科技导报〔ScienceTechnologyReview〕,2021,34:27.[23]NisisakoT.Curr.Opin.Colloid.In.,2021,25:1.[24]杨轶〔YangY〕,叶伟〔YeW〕,陈晓〔ChenX〕.物理化学学报〔ActaPhysico-ChimicaSinica〕,2020,28:2525.[25]ChoI,LeeKWJ.Appl.Polym.Sci.,1985,30:1903.[26]YabuH,KanaharaM,ShimomuraM,AritaT,HaranoK,NakamuraE,HiguchiT,JinnaiH.ACSAppl.Mater.Interfaces,2020,5:3262.[27]UrbanM,FreisingerB,GhazyO,StaffR,LandfesterK,CrespyD,MusyanovychA.Macromolecules,2020,47:7194.[28]WeissS,HirsemannD,BiersackB,ZiadehM,MllerAHE,BreuJ.Polymer,2020,54:1388.[29]PerroA,ReculusaS,RavaineS,Bourgeat-LamicE,DuguetE.J.Mater.Chem.,2005,15:3745.[30]ZhangJT,ChaoX,AsherSA.J.Am.Chem.Soc.,2020,135:11397[31]PoggiE,BourgeoisJP,ErnouldB,GohyJF.RSCAdv.,2021,5:44218.[32]SeidelP,RavooBJ.Macromol.Chem.Phys.,2021,217:1467.[33]YamagamiT,KitayamaY,OkuboM.Langmuir,2020,30:7823.[34]LiuJ,LiuG,ZhangM,SunP,ZhaoH.Macromolecules,2020,46:5974.[35]HuangC,ShenX.Chem.Commun.,2020,50:2646.[36]SuzukiD,TsujiS,KawaguchiH.J.Am.Chem.Soc.,2007,129:8088.[37]WuH,YiW,ChenZ,WangH,DuQ.Carbon,2021,93:473.1ACSAppl.Mater.Interfaces,2021,7:9744.[39]ChoiCH,WeitzDA,LeeCS.Adv.Mater.,2020,25:2536.[40]CaoX,LiW,MaT,DongH.RSCAdv.,2021,5:79969.[41]SunX,LiuM,XuZ.Talanta,2020,121:163.[42]HuY,WangS,AbbaspourradA,ArdekaniAM.Langmuir,2021,31:1885.[43]MaedaK,OnoeH,TakinoueM,TakeuchiS.Adv.Mater.,2020,24:1340.[44]HuY,WangJ,LiC,WangQ,WangH,ZhuJ,YangY.Langmuir,2020,29:15529.[45]YoonJ,KotaA,BhaskarS,TutejaA,LahannJ.ACSAppl.Mater.Interfaces,2020,5:11281.[46]MisraAC,LukerKE,DurmazH,LukerGD,LahannJ.Biomacromolecules,2021,16:2412.[47]YoonJ,EysterTW,MisraAC,LahannJ.Adv.Mater.,2021,27:4509.[48]JinZ,FanH.SoftMatter,2020,10:9212[49]GrschelAH,MllerAHE.Nanoscale,2021,7:11841.[50]ErhardtR,BkerA,ZettlH,KayaH,Pyckhout-HintzenW,KrauschG,AbetzV,MllerAHE.Macromolecules,2001,34:1069.[51]WaltherA,MllerAHE.SoftMatter,2008,4:663.[52]GrschelAH,SchacherFH,SchmalzH,BorisovOV,ZhulinaEB,WaltherA,MllerAHE.Nat.Commun.,2020,3:710.[53]GrschelAH,WaltherA,LblingTI,SchacherFH,SchmalzH,MllerAHE.Nature,2020,503:247.[54]HiekkataipaleP,LblingTI,PoutanenM,PriimagiA,AbetzV,IkkalaO,GrschelAH.Polymer,2021,DOI:10.1016/j.polymer.2021.05.076.[55]DengRH,LiangFX,ZhouP,ZhangCL,QuXZ,WangQ,ZhuJT,YangZ.Adv.Mater.,2020,26:4469.[56]TranN,MuletX,HawleyAM,ConnCE,ZhaiJ,WaddingtonLJ,DrummondCJ.NanoLett.,2021,15:4229.[57]SkelhonTS,ChenY,BonSAF.Langmuir,2020,30:13525.[58]MockEB,ZukoskiCF.Langmuir,2018,26:13747.[59]LuC,UrbanMW.ACSMacroLett.,2020,3:346.[60]ChengZ,LuoF,ZhangZ,MaYQ.SoftMatter,2020,9:11392.[61]LiB,WangM,ChenK,ChengZ,ChenG,ZhangZ.Macromol.Rapid.Comm.,2021,36:1200.[62]LiC,WuZM,HeYF,SongPF,ZhaiWZ,WangRM.J.ColloidInterf.Sci.,2020,42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