实验室科训成果

1、1. Assemblyofthree3-DMOFsfrom2-phenyl-4,5-imidazoledicarboxylate and oxalaigands三个基于2-苯基咪唑二羧酸三维金属有机框架的自组装、*J. Coord. Chem. 2012, 65(7), 1221-1231.Three lannide-anic polymers, Ln(3-HPhIDC)(2-C2O4)0.5(H2O)2H2On (Ln= Nd (1), Sm (2) and Tb (3) have been sucsfully isolated from the reaction of2-phenyl-1H

2、-imidazole-4,5-dicarboxylic acid (H3PhIDC) with equal amount of LI)salts under solvothermal condition with the rigid coligand, oxalate. The three polymers,whichareisomorphousandisostructural,havebeenstructurallycharacterized by elementalyses, IR spectroscopy and single-crystal X-raydiffraction. Each

3、 of them exhibits a novel three-dimenal (3-D) frameworkconstructed from infinite 2-D layer motifs joined by 2-C2O4 systematically, which arecomed of 3-HPhIDC2- and trivalent lan also been investigated.nide ions. Their thermal properties have*，2009 级班本科生，学号 20092310102，在本中为第一作者。2. A series of lannide

4、-anic frameworks constructed by 2-methylimidazoledicarboxylateandoxalate:Synthesis,structuresand properties系列由2-甲基咪唑二羧酸和草酸根构筑的镧系有机框架：、结构和性能*、J. Coord. Chem. 2012, 65(10),1724-1739.Fivelannide(III)coordinationpolymerswith2-methyl-1H-imidazole-4,5-dicarboxylic acid (H3MIDC)and Ndammonium oxalate,(Ln1)

5、2(HMIDC)2(C2O4)(H2O)33H2On(Ln1=(1),Sm(2),(3),andEu2(HMIDC)2(C2O4)(H2O)30.5EtOH3H2OnCe2(HMIDC)2(C2O4)(H2O)3EtOH3H2On(4),been sucGd2(HMIDC)2(C2O4)(H2O)3MeOH4H2On (5),havesfully prepared yses reveal t them exhibits aand structurally characterized. Single crystal X-ray diffraction polymers 1 and 2 are i

6、sostructural, as are 3, 4, and 5. Each ofthree-dimenal (3-D) open framework, which is built by the regular spectacular2-D grid connected by HMIDC2- ligand and Ln() ions. The luminescence and thermal properties of these complexes have been investigated as well.*，2009 级班本科生，学号 20092310102，在本中为第二作者。3.

7、TwoUnprecedentedStrontium(II)andCadmium(II)MOFsConstructed from 2-Naphthyl Imidazole Dicarboxylaigand两个由萘基咪唑二羧酸配体构筑的无前例的Sr（II）和Cd（II）金属有机框架、*m，2012, 14 (15), 4955 4958.Solvothermal reactions of nitrate salts with the promising multifunctionalanicligand, 2-(2-naphthyl)-1H-imidazole-4,5-dicarboxylic a

8、cid(H3NIDC),lead to twonew polymers, Sr(5-HNIDC)(H2O)n (1) and Cd(3-HNIDC)(CH3CH2OH)n (2).Polymer 1 exhibits a sheet structure containing infinite distorted hexagonal rings.Polymer 2 one-dimenpresents aneresting 3D open architecturesessing infiniteal channels. The thermalyses and solid-se photolumin

9、escenceproperties of polymers 1 and 2 have been investigated as well.*，2009级班本科生，学号20092310102，在本中为第二作者。4. The construction of a 3D Pr(III) coordination polymer based on2-methyl imidazole-4,5-dicarboxylate and oxalaigands.一个基于2-甲基咪唑二羧酸的三维Pr（III）配位聚合物*、Synth. React. In. Met-. Chem., 2012, 42(7), 981-

10、986.Pr(NO3)3.6H2OSolvothermalreactionofwith2-methyl-1H-imidazole-4,5-dicarboxylicacid (H3MIDC) and ammonium oxalateaffordsametal-anicframework,Pr2(3-HMIDC)2(2-C2O4)(H2O)3EtOH3H2Oncharacterized by single-crystal X-ray diffraction.(1), which has been structurally Polymer 1 exhibits a novel 3Dstructure

11、, in which infinite 1D chains, comed of nine-coordinated Pr(III) ions andoxalates, were linked by 3-HMIDC2- to give rise to a 3D architecture. Its thermal and solid-se fluorescence properties have been investigated.*，2009级班本科生，学号20092310102，在本中为第一作者。5. Syntheses, Crystal Structures and Properties of

12、 Four Complexes Constructed from 2-Propyl-1H-Imidazole-4,5-Dicarboxylic Acid.四个由 2-丙基咪唑二羧酸构筑的配合物的、晶体结构与性质、*Synth. React. In. Met-. Chem., 2012, 42(3), 336-344.Four complexes, Cd(H2C)2(2,2-(3),andy) (1), Mn(H2Ni(H2C)2(H2O)24H2O (2),Co(H2C)2(H2O)2C)2(H2O)2by(4)havebeenofhydro(solvo)thermallysynthesize

13、dreactions2-propyl-1H-imidazole-4,5-dicarboxylic acid(H3C) with Cd(II),I), Co(II),and M) ions, respectively. Their crystalstructures have been characterized bysingle X-ray determination. The thermal properties of the four complexes have been determined as well.*，2009 级班本科生，学号 20092310102，在本中为第二作者。6.

14、 Fourcadmium(II)polymericframeworksconstructedby2-methyl or 2-ethyl imidazole dicarboxylates四个由 2-甲基或者 2-乙基咪唑二羧酸构筑的四个 Cd（II）聚合物*峰、In. Chim. Acta, 2012, 384, 352-362.Fourpolymericframeworks, (2),Cd(HMIDC)(phen)H2On(1),andCd(HMIDC)(2,2-Cd4(HMIDC)48H2Ony)n(3),Cd(HEIDC)(2,2-y)2n (4) (H3MIDC = 2-methyl-1

15、H-imidazole-4,5-dicarboxylicacid,H3EIDC=2-ethyl-1H-imidazole-4,5-dicarboxylicacid,phen=1,10-phenanthroline, 2,2-y = 2,2-yridine) have been hydro(solvo)thermallysynthesized and structurally characterized by single-crystal X-ray diffraction.Compounds 1, 3 and 4 are one-dimenal (1D) infinite chains, in

16、 which theHMIDC2- or HEIDC2- units as 2-mink the Cd(II) atoms with phen or 2,2-ychelating the central ions. Compound 2 shows a three-dimenal (3D) structureconstructed from 2D layer motifs joined by 2-HMIDC2- or 3-MIDC3- ligands. Thethermal and solid-se photoluminescence properties of complexes 1-4 h

17、ave been determined as well.*者。，2010 级应化 4 班本科生，学号 20102310413，在本中为第二作7. Metal-anicframeworksconstructedfromimidazole ition.dicarboxylates bearing aromatic substituents at the 2-基于 2 位芳香取代基咪唑二羧酸的金属有机框架、*m, 2012, 14(21), 7382-7397.Sevennovelmetal-anicframeworks,Sr(PhHIDC)(H2O)nacid)(p-OHPhH3IDC(PhH3I

18、DC= (1),= (2),(3),(4),= (5),and2-phenyl-1H-imidazole-4,5-dicarboxylicMn(p-OHPhHIDC)(H2O)2H2On2-(p-hydroxylphenyl)-1H-imidazole-4,5-dicarboxylicacid1,10-phenanthroline)Cd2(p-OHPhHIDC)2(phen)2H2On(phen(2,2-=Cd2(p-OHPhHIDC)2(2,2-Sr(p-MePhHIDC)(H2O)ny)2H2On=2,2-yyridine)(p-MePhH3IDC2-(p-methylphenyl)-1H

19、-imidazole-4,5-dicarboxylicacid) pyridine)Cd4(p-MePhHIDC)4(py)7(H2O)Co1.5(p-MePhIDC)(H2O)3H2Onhydro(solvo)thermal conditions. In(py (7)these=have(6)beensynthesizedundercomplexes, the imidazole dicarboxylateligands show strong coordination ability and various coordination modes, which areconsitentwit

20、hthetheoreticalprediction.Thethermalpropertiesandphotoluminescence properties of compounds 1-7 have been investigated as well.*者。，2010 级应化 4 班本科生，学号 20102310413，在本中为第二作8. Two Unprecedented Transition-Metal-anic Frameworks Showing1D-Hexagonal Channel Open Network and 2D Sheet Structures. 两个未见的呈现出一维六角

21、开放孔道和二维层状结构的过渡金属框架、*Cryst. Growth Des. 2012, 12(3), 1091-1094.frameworks,Co3(3-DMPhIDC)2(H2O)62H2Onnewmetal-Twoanic(1),Mn5(3-DMPhIDC)2(2-HDMPhIDC)2(Phen)52CH3OH3H2On (2), (H3DMPhIDC =2-(3,4-dimethylphenyl)-1H-imidazole-4,5-dicarboxylicacid,Phen=1,10-phenanthroline) have been hydrothermally synthesiz

22、ed and structurallycharacterized by single-crystal X-ray diffraction, elementalyses, XPRD, thermalyses and IR spectra. Polymer 1 is an enchanting 3-D network containing infinite1D-hexagonal channels and Co2(DMPhIDC)6 cages, which have two nets topology. Polymer 2 exhibits a 2-D framework, which is c

23、omenetratinged of left- andlinkages. There exists antiferromagneticMn2+righnded helipillared bycoupling betn the Co(II) ions or M) ions in 1 or 2, respectively.*，2010 级应化 4 班本科生，学号 20102310430，在本中为第三作者。9. Assemblyoffivemetal-anicframeworksbasedon2-p-methoxyphenyl-1H-imidazole-4,5-dicarboxylate.五个基于对

24、甲氧基咪唑二羧酸的金属有机框架的自组装*曹新江、In. Chim. Acta, 2012, 392, 16-24.Fivecoordinationpolymersbearing2-p-methoxyphenyl-1H-imidazole-4,5-dicarboxylic acid (H3MOPhIDC) formulatedZn2(2-HMOPhIDC)2(phen)2nas(phen=1,10-phenanthroline)(1),X(2-HMOPhIDC)(2,2-y)n (X = Ni (2) and Mn (3), 2,2-y = 2,2-yridine)and M(2-H2MOPhI

25、DC)22H2On (M = Mn (4) and Co (5) have been synthesizedunder hydrothermal conditions. Their molecular structures have been determined byIR spectra, elementalyses, thermogravimetricyses,der X-ray diffraction,and further characterized by single-crystal X-ray diffraction. Complex 1 features an infinite

26、corrugated structure. Complexes 2 and 3 display straight chains. Bothcomplexes 4 and 5 exhibit isomorphous 2D structures containing similar inanicmotifs win individual rhombus as secondary building unit. The photoluminescentbehaviors of these complexes have also been investigated.*，2010 级2 班本科生，学号 20102310412，在本中为第二作者。10.