国赛作品8.15设计ms-2010物料平衡

1、2017“东华科技陕鼓杯”第十一届大学生化工设计竞赛云南120 万 Nm3/h 催化裂化烟气脱硫项目物算一览表团队名称：兰州理工大学鸿成团队指导老师：、强、团队成员：、祥、完成时间：2017 年 8 月目录第一章 物算简介31.1 概述3物物物物算的目的3算的任务4算的基本步骤4算的方法4第二章 工艺概述4第三章 物算表53.1 二氧化硫富集工段53.1.1 吸收塔（T0101）53.1.2塔（T0102）73.1.3 闪蒸罐（V0101、V0102）83.1.4 换热器（E0101E0109）103.1.5 二氧化硫富集工段23反应工段243.2.1 反应器（R0201R0203）243.2

2、.2 闪蒸罐（V0201V0206）273.2.3 换热器（E0201E0211）333.23.2.4反应工段483.3 全装置48第一章 物算简介1.1 概述物算是确定化工生产过程中物料比例和物料转变的定量关系的过程，是化工工艺计算中最基本、最重要的内容之一。在化学工程中，设计或改造工艺流设备，了解和控制生产操作过程，核算生产的经济效益，确定主副产品的产率，确定原材料消耗，确定生产过程的损耗量，便于技术对现有的工艺过程进行分析，选择最有效的工艺路线，确定设备容量、数量及主要尺寸，对设备进行最佳设计以及确定最佳操作条件等都要进行物算。毫不夸张的说，一切化学工程的开发和放大都是以物在化工过程中，

3、物料平衡是指在算为基础的。时间内进入系统（体系）的全部物料质量必定等于离开该系统（体系）的全部物料质量再加上损失掉的与累积起来的物料质量。对物料平衡进行计算称为物算。物料平衡的理论依据是质量守恒定律，即在一个鼓励体系中不论物质发生任何变化（不包括核反应）它的质量始终不变。通常物算有两种情况，一是对已有的生产设备或过程利用实测的数据，计算出另一些不能直接测定的物料量，俗称生产查定，用此计算结果，对生产情况进行分析，做出判断，提出改进措施；二是设计一种新的设备或过程，由物料求出进出各设备的物料量、组成等，然后结合能量寸及整个工艺流程。，确定设备的工艺尺物算按操作方式则可分为间歇操作、连续操作以及半

4、连续操作等三类物算；或者将其分为稳定状态操作和不稳定状态操作两类划分，可分为单元操作过程（或者单个设备）和全流程的两类物。如按范围算。化工设计进行的物算是先做单元操作过程（或单个设备）的物算，然后将各个过程汇总得到整个流程的物算，进而完成物料流程图。1.2 物算的目的本项目拟建一套年产 万吨的硫磺装置，同时副产二氧化硫气体等产品。工艺设计中，物算是在工艺流程确定后进行的。目的是根据原料与产品之间的定量转化关系，计算原料的消耗量，各种中间产品、产品和副产品的产量，生产过程中各阶段的消耗量以及组成，进而为热量、其他工艺计算及设备计算打基础。对于已有装置，物算可以弄清原料的来龙去脉，找出生产中的薄弱

5、环节，为改进生产、完善管理提供可靠的依据和明确方向，并可作为检查原料利用率及三废处理完善程度的一种。1.3 物算的任务1、确定硫磺以及副产品的实际产量以及质量指标；2、确定工艺中的“三废”排放量等公共经济指标；3、各主要单元过程的物算，并指导工艺设备的尺寸确定；4、汇总全流程物算，数据用于完成物料流程图等后续设计任务。1.4 物算的基本步骤1、画出工艺流程示意图。2、列出化学反应方程式。3、确定计算任务书。4、收集数据资料。5、选择计算基准。6、建立物料平衡方程，展开计算。7、整理并校核计算结果。8、绘制物料流程图、填写正式物料平衡表。1.5 物算的方法物算是根据质量守恒定律，利用某进出化工过

6、程中某些已知物流的流量和组成，通过建立有关物料的平衡式和约束式，求出其他未知物流的流量和组成的过程。系统中物算一般表达式为：系统中的积累=输入-输出+生成-消耗式中生成或消耗项是由于化学反应而生成或消耗的量；积累量可以是正值，也可以是负值，当系统中积累量不为零时称为非稳定状态过程；积累量为零时，称为稳定状态过程。稳定状态过程时，可以简化为：输入=输出-生成+消耗对无化学反应的稳定过程，又可表示为：输入=输出第二章 工艺概述本项目以总厂在云南省安宁市草铺镇安宁工业园区中的催化裂化装置脱下的烟气和双脱装置的硫化氢为原料，经过烟气吸收后富集得到二氧化硫与硫化氢进行反应，产生液态硫磺，再将液态硫磺直接

7、送至下游装置，精制得到本厂产品固体硫磺。设计过程中利用 Aspen Plus 对全流程进行模拟，并在此基础上完成物能量，Aspen plus 全模拟流程如图 2.1-1 所示。算、图 2.1-1 全流程模拟流程图第三章 物算表3.1 二氧化硫富集工段3.1.1 吸收塔（T0101）表 3.1-1 吸收塔（T0101）物算一览表streamnameunitFULEGASS3CLEANGASRICH-1Temperature C555565.0108281 66.286884Prerebar1.013251.013251.013251.01325Molar Vapor1010FractionMol

8、ar0101Liquid FractionMolar Solid0000FractionMass Vapor1010FractionMass Liquid0101FractionMass Solid0000FractionMolarkcal/mol-17.777423 -102.92452 -17.274489 -102.7997EnlpyMasskcal/kg-628.91258 -3162.0928 -611.96536 -3110.199EnlpyMolarcal/mol-K 0.96580059 -39.192466 1.18688589 -38.88702EntropyMasscal

9、/gm-K0.03416717 -1.2040884 0.04204657 -1.176524EntropyMolarkmol/cum0.03718976 73.9701057 0.03608193 64.570825DensityMasskg/cum1.05124006 2407.68946 1.01851668 2134.2248DensityEnlpyGcal/hr-793.13972 -814.54282 -763.25718 -844.4252FlowAverage MW28.26692232.5494933 28.22788733.052463Mass Flowskg/hr1261

10、128.73 257596.119 1247222.86 271501.99H2Okg/hr124539.631 76611.667119212.432 79585.326SO2kg/hr8571.87024 1.57919903 153.7877950.162101O2kg/hr69287.0016 069285.2197 1.782005CO2kg/hr184255.830184109.715 146.11408N2kg/hr874474.394 0874461.703 12.691217NA2HPO4kg/hr0000NAH2PO4kg/hr0000NA2SO4kg/hr0000H3O+

11、kg/hr00.00574501 00.0091NA+kg/hr053737.6187 053737.619H3PO4kg/hr014.0008237 2.11E-1339.114329H2PO4-kg/hr029377.0008 042004.06HSO3-kg/hr0722.100211 011252.121HPO4-kg/hr082909.6549 070455.729SO3-kg/hr07.24129767 067.887739SO4-kg/hr014034.535014034.535PO4-kg/hr0180.715132 0114.83796H2Skg/hr0000S8kg/hr0

12、000S6kg/hr00003.1.2塔（T0102）表 3.1-2塔（T0102）物算一览表streamunit4RICH-2S2SI nameTemperatureC100.573315118.5110.88869169.656816Prerebar1.034213591.013251.013251.01325Molar10.0896822801Vapor FractionMolar00.9103177210Liquid FractionMolar Solid0000FractionMass Vapor10.0492989801FractionMass Liquid00.950701021

13、0FractionMass Solid0000FractionMolarkcal/mol-57.202548-101.234-95.226594-68.18255EnlpyMasskcal/kg-3175.2239-3062.8278-3171.3828-1460.977EnlpyMolarcal/mol-K-8.8349747-34.756854-36.6515511.6292521EntropyMasscal/gm-K-0.4904156-1.0515662-1.22062640.0349107EntropyMolarkmol/cum0.033527180.3473955861.49116

14、930.035819DensityMasskg/cum0.6040014511.48227941846.385321.6716398DensityEnlpyGcal/hr-114.4051-831.56384-971.60328-1.704564FlowAverage18.0152833.052462930.02683746.669135 MWMass Flowskg/hr36030.56271501.988306365.8191166.72843.1.3 闪蒸罐（V0101、V0102）表 3.1-3 闪蒸罐（V0101）物算一览表stream nameunitS2S5S6Temperatu

15、reC110.888691150150Prerebar1.013251.013251.01325Molar Vapor Fraction010Molar Liquid Fraction101Molar Solid Fraction000Mass Vapor Fraction010Mass Liquid Fraction101Mass Solid Fraction000Molar Enlpykcal/mol-95.226594-57.046699-129.40611Mass Enlpykcal/kg-3171.3828-3015.9607-2943.302Molar Entropycal/mol

16、-K-36.651551-7.306294-39.208964Mass Entropycal/gm-K-1.2206264-0.3862712-0.8917958H2Okg/hr36030.5679585.3258115727.36136.99967SO2kg/hr050.162101364.6427026869.14141O2kg/hr01.7820053.26E-251.782005CO2kg/hr0146.1140841.21E-10146.11408N2kg/hr012.6912172.86E-2512.691217NA2HPO4kg/hr0000NAH2PO4kg/hr0000NA2

17、SO4kg/hr0000H3O+kg/hr00.009100010.013146590NA+kg/hr053737.618753737.61870H3PO4kg/hr039.11432911.02E+025.26E-41H2PO4-kg/hr042004.059941027.60350HSO3-kg/hr011252.12079921.41010HPO4-kg/hr070455.728971132.10530SO3-kg/hr067.8877394277.7522530SO4-kg/hr014034.53514034.5350PO4-kg/hr0114.837964341.046310H2Sk

18、g/hr0000S8kg/hr0000S6kg/hr0000表 3.1-4 闪蒸罐（V0102）物算一览表stream nameunitS5S7S8TemperatureC1508282Prerebar1.013251.013251.01325Molar Vapor Fraction110Molar Liquid Fraction001Molar Solid Fraction000Mass Vapor Fraction110Mass Liquid Fraction001Mass Solid Fraction000Molar Enlpykcal/mol-57.046699-63.781772-6

19、7.345579Mass Enlpykcal/kg-3015.9607-1567.5523-3707.8919Molar Entropycal/mol-K-7.306294-1.167849-35.768655Molar Densitykmol/cum61.49116930.028947584.7273157Mass Densitykg/cum1846.385320.547540013725.14689Enlpy FlowGcal/hr-971.60328-335.28881-574.51588Average MW30.02683718.914934643.9663037Mass Flowsk

20、g/hr306365.819111171.48195194.339H2Okg/hr115727.36103815.19213966.1537SO2kg/hr64.64270267356.2875212.569239O2kg/hr3.26E-2500.00E+00CO2kg/hr1.21E-1000.00E+00N2kg/hr2.86E-2500.00E+00NA2HPO4kg/hr000NAH2PO4kg/hr000NA2SO4kg/hr000H3O+kg/hr0.0131465900.00135966NA+kg/hr53737.6187053737.6187H3PO4kg/hr101.731

21、8067.66E-133.88E+01H2PO4-kg/hr41027.6035029661.267HSO3-kg/hr9921.41010959.066431HPO4-kg/hr71132.1053082538.0277SO3-kg/hr277.75225300.25440431SO4-kg/hr14034.535014034.535PO4-kg/hr341.046310246.065432H2Skg/hr000S8kg/hr000S6kg/hr0003.1.4 换热器（E0101E0109）表 3.1-5 换热器（E0101）物算一览表Stream NameUnitsCOLDCOLDOUH

22、OTINHOTOUTTTemperatureC2020.05789359.15576Prerebar551.013251.01325MolarVapor0.00E+000.00E+0000FractionMass Entropycal/gm-K-0.3862712-0.028702-1.9693394Molar Densitykmol/cum0.02894750.0345868553.5221117Mass Densitykg/cum0.547540011.4072963972.109683Enlpy FlowGcal/hr-335.28881-12.664121-382.25609Avera

23、ge MW18.914934640.688767118.1627677Mass Flowskg/hr111171.488078.91446103092.565H2Okg/hr103815.1921815.78823101896.632SO2kg/hr7356.287526263.12623910.425176O2kg/hr0.00E+0000.00E+00CO2kg/hr0.00E+0000.00E+00N2kg/hr0.00E+0000.00E+00NA2HPO4kg/hr000NAH2PO4kg/hr000NA2SO4kg/hr000H3O+kg/hr0054.2596721NA+kg/h

24、r000H3PO4kg/hr7.66E-130.00E+000.00E+00H2PO4-kg/hr000HSO3-kg/hr00231.248377HPO4-kg/hr000SO3-kg/hr000.00041597SO4-kg/hr000PO4-kg/hr000H2Skg/hr000S8kg/hr000S6kg/hr000MolarLiquid111.00E+001.00E+00 FractionMolarSolid0000FractionMassVapor0.00E+000.00E+0000FractionMassLiquid111.00E+001.00E+00FractionMassSo

25、lid0000FractionMolar Enlpykcal/mol-68.405703-68.4046534.3435394.28472815653434Mass Enlpykcal/kg-3797.0935-3797.0352133.4441131.63735547851Molar Entropycal/mol-39.309028-39.305446-17.17962-17.357729K7957Mass Entropycal/gm-2.1819826-2.1817838-0.527800-0.5332720K72312Molar Densitykmol/cu41.900120141.89

26、846811.99468412.057586m999493Mass Densitykg/cum754.842397754.81265390.4208392.468243040166Enlpy FlowGcal/hr-30321.462-30320.99734.3746933.909263624569Average MW18.0152818.0152832.5494832.5494855114Mass Flowskg/hr7985439.967985439.9257596.0257596.051615775H2Okg/hr7985439.967985439.976611.66976611.669

27、16155SO2kg/hr0.00E+0001.5791801.57918011772O2kg/hr0000CO2kg/hr0000N2kg/hr0000NA2HPO4kg/hr0000NAH2PO4kg/hr0000NA2SO4kg/hr0000H3O+kg/hr0.00E+000.00E+000.0057450.00574500113NA+kg/hr0053737.6353737.638表 3.1-6 换热器（E0102）物算一览表Stream NameUnitsCOLDCOLDOUHOTINHOTOUTTTemperatureC66.373.290430150135.371Prereba

28、r1.013251.013251.013251.01325MolarVapor1.73E-085.34E-0611FractionMolarLiquid0.999999980.99999460.00E+000.00E+00Fraction362MolarSolid0000FractionMassVapor1.48E-084.45E-0611FractionMassLiquid0.999999980.99999550.00E+000.00E+00Fraction549MassSolid0000FractionMolar Enlpykcal/mol-102.79954-102.7107-57.04

29、669-57.169030605908Mass Enlpykcal/kg-3110.1942-3107.545-3015.960-3022.4288325H3PO4kg/hr0.00E+000.00E+0014.0008114.0008133443H2PO4-kg/hr0029376.9729376.9777217HSO3-kg/hr00722.0916722.091600219HPO4-kg/hr0082909.6082909.608998SO3-kg/hr0.00E+000.00E+007.24E+007.24E+00SO4-kg/hr0014034.5214034.5299993PO4-

30、kg/hr00180.7150180.715077661H2Skg/hr0000S8kg/hr0.00E+000.00E+0000S6kg/hr0.00E+000.00E+00003495718Molar Entropycal/mol-38.886521-38.63181-7.306294-7.600529K9426142Mass Entropycal/gm-1.1765095-1.1688181-0.386271-0.401826K02129Molar Densitykmol/cu64.572689663.6833500.0289470.0300046m256536Mass Densityk

31、g/cum2134.285622104.86400.5475400.567535780122Enlpy FlowGcal/hr-844.42352-843.70451-335.2888-336.0078421213Average MW33.052450333.05203118.9149318.9149349054442Mass Flowskg/hr271501.861271501.86111171.4111171.47515897H2Okg/hr79585.335079587.212103815.1103815.19939333SO2kg/hr5.02E+0156.8438127356.286

32、7356.2864434658O2kg/hr1.782005021.782005000626CO2kg/hr146.113872146.1138700424N2kg/hr12.691217612.69121700565NA2HPO4kg/hr0000NAH2PO4kg/hr0000NA2SO4kg/hr0000H3O+kg/hr9.10E-039.38E-0300NA+kg/hr53737.624753737.624007H3PO4kg/hr3.91E+014.50E+0100H2PO4-kg/hr42003.979341995.3780001HSO3-kg/hr11252.095411245

33、.39200478HPO4-kg/hr70455.699170443.27100592SO3-kg/hr6.79E+016.62E+010.00E+000.00E+00SO4-kg/hr14034.506214034.50600727表 3.1-7 换热器（E0103）物算一览表Stream NameUnitsCOLDCOLDOUHOTINHOTOUTTTemperatureC22.8125.22568299.769.6615Prerebar5511MolarVapor0.00E+000.00E+0010.0103425Fraction25MolarLiquid110.00E+009.90E-

34、01 FractionMolarSolid0000FractionMassVapor0.00E+000.00E+0010.0261931Fraction82MassLiquid110.00E+009.74E-01FractionMassSolid0000FractionMolar Enlpykcal/mol-68.351083-68.307639-57.36485-67.54260267785Mass Enlpykcal/kg-3794.0616-3791.6501-3104.670-3655.504589815Molar Entropycal/mol-39.123028-38.976664-

35、8.516036-35.975444K06161Mass Entropycal/gm-2.1716580-2.1635336-0.460900-1.9470437K62341Molar Densitykmol/cu55.391236655.3579020.0324873.2162038m340528Mass Densitykg/cum997.888636997.288110.60026159.4256619098569Enlpy FlowGcal/hr-42974.825-42947.510-153.9536-181.2683429599Average MW18.0152818.0152818

36、.4769518.476957PO4-kg/hr114.846697129.8337100688H2Skg/hr0000S8kg/hr0.00E+000.00E+0000S6kg/hr0.00E+000.00E+0000表 3.1-8 换热器（E0104）物算一览表Stream NameUnitsCOLDCOLDOUHOTINHOTOUTTTemperatureC110.9111.06082135.311516Prerebar1.013251.013251.013251.013257657Mass Flowskg/hr11326865.111326865.49587.7749587.77891

37、98326H2Okg/hr11326865.111326865.47830.1647830.1609190765SO2kg/hr0.00E+0001593.0221593.02299659O2kg/hr001.7849071.78490799111CO2kg/hr00150.1067150.106733442N2kg/hr0012.7030012.703005696NA2HPO4kg/hr0000NAH2PO4kg/hr0000NA2SO4kg/hr0000H3O+kg/hr0.00E+000.00E+0000NA+kg/hr0000H3PO4kg/hr0.00E+000.00E+0000H2

38、PO4-kg/hr0000HSO3-kg/hr0000HPO4-kg/hr0000SO3-kg/hr0.00E+000.00E+000.00E+000.00E+00SO4-kg/hr0000PO4-kg/hr0000H2Skg/hr001106.69941106.6994441S8kg/hr0.00E+000.00E+000.20762810.2076281112S6kg/hr0.00E+000.00E+000.0027530.00275311884MolarVapor6.94E-041.04E-0211FractionMolarLiquid0.999305770.98956910.00E+0

39、00.00E+00Fraction99MolarSolid0000FractionMassVapor4.19E-046.30E-0311FractionMassLiquid0.999580710.99369850.00E+000.00E+00Fraction506MassSolid0000FractionMolar Enlpykcal/mol-95.219435-95.119169-57.16903-57.3373485112Mass Enlpykcal/kg-3171.1508-3167.8982-3022.428-3031.32689521Molar Entropycal/mol-36.6

40、33313-36.377682-7.600529-8.0232027K9744Mass Entropycal/gm-1.2200215-1.2115412-0.401826-0.4241729K8319Molar Densitykmol/cu26.33060922.91761050.0300040.0315999m1666413Mass Densitykg/cum790.62328787.6040430.5675350.597710258739Enlpy FlowGcal/hr-971.53211-970.5356-336.0078-336.997084117Average MW30.0267

41、75330.02595518.9149318.9149344084656Mass Flowskg/hr306365.778306365.77111171.48111171.4799897H2Okg/hr115727.705115732.72103815.1103815.197739222SO2kg/hr6.59E+0183.7276487356.2877356.2875865216O2kg/hr0000CO2kg/hr0000N2kg/hr0000NA2HPO4kg/hr0000NAH2PO4kg/hr0000NA2SO4kg/hr0000H3O+kg/hr1.31E-021.30E-0200

42、表 3.1-9 换热器（E0105）物算一览表Stream NameUnitsCOLDCOLDOUHOTINHOTOUTTTemperatureC122.2142.5387.8219362.628456742Prerebar1.013251.013251.361.36MolarVapor3.37E-015.11E-010.9999990.9999998Fraction8878MolarLiquid0.662551590.48919061.21E-071.22E-07Fraction11MolarSolid0000FractionMassVapor2.02E-013.07E-010.999999

43、0.9999998Fraction8659MassLiquid0.797517600.69349411.40E-071.41E-07Fraction154MassSolid0000FractionMolar Enlpykcal/mol-91.777305-89.838584-43.75546-44.07751547768Mass Enlpykcal/kg-3056.8503-2992.2768-1014.878-1022.34825853Molar Entropycal/mol-27.775090-22.9721169.3666608.8699105K1555619NA+kg/hr53737.

44、644753737.64400777H3PO4kg/hr1.02E+021.02E+0200H2PO4-kg/hr41024.329240977.68700527HSO3-kg/hr9920.986099914.300600746HPO4-kg/hr71135.359671182.59600541SO3-kg/hr2.77E+022.61E+020.00E+000.00E+00SO4-kg/hr14034.528214034.52800323PO4-kg/hr340.988848340.0896500164Mass Entropycal/gm-0.9251120-0.76513820.2172

45、530.2057315K813788Molar Densitykmol/cu0.091824210.05768310.0248050.0257959m7026205Mass Densitykg/cum2.756883131.73184781.0694691.1121644247499Enlpy FlowGcal/hr-6.9287342-6.7823704-19.88582-20.0321869942Average MW30.023486530.02348643.11399443.11399485833Mass Flowskg/hr2266.625282266.625219594.281959

46、4.2886868437H2Okg/hr856.3798856.37985759.6395759.6390199SO2kg/hr0.00E+000683.7461683.746133772O2kg/hr001.7820031.78200322879CO2kg/hr002346.6102346.61033547N2kg/hr0012.69121112.691211877NA2HPO4kg/hr0000NAH2PO4kg/hr0000NA2SO4kg/hr0000H3O+kg/hr9.73E-059.73E-050.0005160.00051600106NA+kg/hr397.658426397.

47、6584200161H3PO4kg/hr7.53E-017.53E-0100H2PO4-kg/hr303.604097303.6040900979HSO3-kg/hr73.418399673.4183990.0021990.00219913631659HPO4-kg/hr526.377293526.3772900636SO3-kg/hr2.055363832.05536383.91E-093.91E-09838SO4-kg/hr103.855251103.8552500414PO4-kg/hr2.523739212.523739200表 3.1-10 换热器（E0106）物算一览表Stream

48、 NameUnitsCOLDCOLDOUTTemperatureC122.2150.6041016Prerebar1.013251.01325Molar Vapor Fraction0.337448410.540510835Molar Liquid Fraction0.662551590.459489165Molar Solid Fraction00Mass Vapor Fraction0.2024823990.324327889Mass Liquid Fraction0.7975176010.675672111Mass Solid Fraction00Molar Enlpykcal/mol-

49、91.77730547-89.449324Mass Enlpykcal/kg-3056.85035-2979.31167Molar Entropycal/mol-K-27.77509015-22.044511Mass Entropycal/gm-K-0.925112081-0.73424221Molar Densitykmol/cum0.0918242170.053459232Mass Densitykg/cum2.7568831321.605032528Enlpy FlowGcal/hr-867.0281029-845.035461Average MW30.0234865830.023486

50、58Mass Flowskg/hr283634.4614283634.4614H2Okg/hr107163.202107163.202SO2kg/hr00O2kg/hr00CO2kg/hr00N2kg/hr00NA2HPO4kg/hr00NAH2PO4kg/hr00NA2SO4kg/hr00H3O+kg/hr0.0121737570.012173757NA+kg/hr49761.0408949761.04089H3PO4kg/hr9.42E+019.42E+01H2PO4-kg/hr37991.5398237991.53982919H2Skg/hr001106.89821106.8982217

51、S8kg/hr009650.2979650.29788993S6kg/hr0032.6207432.6207444659表 3.1-11 换热器（E0107）物算一览表Stream NameUnitsCOLDCOLDOUHOTINHOTOUTTTemperatureC27.0155443115824Prerebar551.013251.01325MolarVapor0.00E+000.00E+0010.0026513Fraction57MolarLiquid1100.9973486Fraction43MolarSolid0000FractionMassVapor0.00E+000.00E+00

52、10.0051156Fraction98MassLiquid1100.9948843Fraction02MassSolid0000FractionMolar Enlpykcal/mol-68.733911-68.642101-57.06153-67.2313546675Mass Enlpykcal/kg-3815.3118-3810.2156-3141.676-3701.602968434Molar Entropycal/mol-40.464532-40.133861-8.392491-35.697400K26871Mass Entropycal/gm-2.2461228-2.2277678-

53、0.462071-1.9654163K61622Molar Densitykmol/cu42.399202542.2629520.0316369.9391927m4585597Mass Densitykg/cum763.833505761.378920.574607180.523256432503HSO3-kg/hr9187.221369187.22136HPO4-kg/hr65868.2937765868.29377SO3-kg/hr257.1982316257.1982316SO4-kg/hr12995.9409212995.94092PO4-kg/hr315.8084482315.808

54、4482H2Skg/hr00S8kg/hr00S6kg/hr00表 3.1-12 换热器（E0108）物算一览表Stream NameUnitsHOTINHOTOUTTemperatureC150125Prerebar1.013251.01325Molar Vapor Fraction00Molar Liquid Fraction11Molar Solid Fraction00Enlpy FlowGcal/hr-43215.523-43157.798-323.8834-381.607742973Average MW18.0152818.0152818.1627618.1627677774Mas

55、s Flowskg/hr11326865.111326865.103092.5103092.569196552H2Okg/hr11326865.111326865.101896.6101896.639193216SO2kg/hr0.00E+000910.4251910.425177657O2kg/hr0000CO2kg/hr0000N2kg/hr0000NA2HPO4kg/hr0000NAH2PO4kg/hr0000NA2SO4kg/hr0000H3O+kg/hr0054.2596754.2596711992NA+kg/hr0000H3PO4kg/hr0.00E+000.00E+0000H2P

56、O4-kg/hr0000HSO3-kg/hr00231.2483231.248377656HPO4-kg/hr0000SO3-kg/hr000.0004150.00041599767SO4-kg/hr0000PO4-kg/hr0000H2Skg/hr0000S8kg/hr0000S6kg/hr0000表 3.1-13 换热器（E0109）物算一览表Stream NameUnitsHOTINHOTOUTTemperatureC15055Prerebar1.013251.01325Molar Vapor Fraction00Mass Vapor Fraction00Mass Liquid Frac

57、tion11Mass Solid Fraction00Molar Enlpykcal/mol-129.4060641-129.74725Mass Enlpykcal/kg-2943.301831-2951.039Molar Entropycal/mol-K-39.20893286-40.0248171Mass Entropycal/gm-K-0.891795332-0.91034528Molar Densitykmol/cum84.7539543686.98693039Mass Densitykg/cum3726.3173824.522466Enlpy FlowGcal/hr-430.8868

58、137-432.019503Average MW43.9662907643.96663325Mass Flowskg/hr146395.7278146395.7278H2Okg/hr10474.6152810474.14801SO2kg/hr9.4268765137.765162295O2kg/hr00CO2kg/hr00N2kg/hr00NA2HPO4kg/hr00NAH2PO4kg/hr00NA2SO4kg/hr00H3O+kg/hr0.0010197440.001012846NA+kg/hr40303.2335840303.23358H3PO4kg/hr2.91E+011.67E+01H

59、2PO4-kg/hr22245.9378122197.72634HSO3-kg/hr719.2995454721.4481192HPO4-kg/hr61903.4948462037.83377SO3-kg/hr0.1907985610.145658052SO4-kg/hr10525.8961710525.89617PO4-kg/hr184.5467967110.8608544H2Skg/hr00S8kg/hr00S6kg/hr003.1.5 二氧化硫富集工段表 3.1-14 二氧化硫富集工段物算一览表见附录 1Molar Liquid Fraction11Molar Solid Fractio

60、n00Mass Vapor Fraction00Mass Liquid Fraction11Mass Solid Fraction00Molar Enlpykcal/mol-129.4060641-130.33553Mass Enlpykcal/kg-2943.301831-2964.35013Molar Entropycal/mol-K-39.20893286-41.6110249Mass Entropycal/gm-K-0.891795332-0.94640078Molar Densitykmol/cum84.7539543691.5686613Mass Densitykg/cum3726