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1、Material Safety Data SheetOil paintManufacturer: Foshan Nanhai HuaRen Chemical Co., LTDThe first part chemicals and corporate logoChemical name in Chinese: paintChemical name in English: enamelProduction enterprise name: Foshan Nanhai HuaRen Chemical Co., LTDAddress: Datong qixing area in xiqiao tow
2、n, nanhai district, foshan city, baini gang industrial zonePostcode: 528211 Fax number:nterprise emergency telephone:-mail address: huarenhuagongTechnical instruction code: HUAREN XJ-2008-06Effective date: June 13, 2014National emergency telephone:he seco
3、nd part composition/informationSingle productMixtureHarmful ingredientsConcentrationCAS No.Xylol101330-20-7Organic resinSolvent Oil8032-32-4The dimethyl benzene anhydride 85-44-9Volatile organic compounds(VOC)450g/LThe third part risk overviewRisk categories: class 3 flammable liquidsInvasive ways:
4、inhalation, eat, percutaneous absorptionHealth hazard: steam can stimulate eyes and mucosa. Inhalation of vapors can produce the symptom such as dizziness, headache, excited. Inhaling high concentrations of vapour can cause acute poisoning.Combustion hazard: flammable. Low flash point. Flame, heat o
5、r burning.The fourth part urgent rescue measuresSkin contact: remove contaminated clothing, and water to thoroughly flushed the skin with soap and water.Eye contact: mention eyelid, irrigate with flowing water or normal saline. Go to a doctor.Inhalation: quickly from the scene to fresh air. Keep res
6、piratory tract unobstructed. Such as difficulty in breathing, give oxygen. If breathing stops, artificial respiration immediately. Go to a doctor.Eating: drink enough water, vomiting. Go to a doctor.The fifth part prevention measuresDangerous characteristic: flammable. Low flash point. Flame, heat o
7、r burning.Hazardous combustion products: carbon monoxide, carbon dioxide.Fire extinguishing methods: spray cooling container, remove from the fire to empty the container if possible. Fire extinguishing agent, foam, carbon dioxide, dry powder, water mist.The sixth part leak emergency treatmentEmergen
8、cy treatment: leave quickly leak contaminated area personnel to safe areas, and in isolation, restricted access. Cut off all fire. Large leakage should establish fog water curtain explosion suppression. Recommended emergency personnel wearing self positive pressure respirator, wear protective clothi
9、ng. Cut off the leak source as possible. Prevent into the sewer, ditch having restricted space. Use explosion-proof pump to tank lorry or dedicated collector, recycling or shipped to the disposal of waste places. The pollution of the ground knife with paint.The seventh part disposal and storage oper
10、ationOperation note: airtight operation, strengthen ventilated. Operators must receive special training, strictly abide by the operation procedures. Suggest operators wear filter type gas mask (half mask), wearing chemical safety protective glasses, wear anti-static work clothes, wear protective glo
11、ves in general. Away from fire and heat source, the workplace smoking is strictly prohibited. Use explosion-proof ventilation systems and equipment. To prevent the steam leakage in the air of workplace. To avoid oxidant (including nitric acid, hydrogen peroxide, etc.).Filling time should be controll
12、ed velocity, and a grounding device, prevent electrostatic accumulation. Light light discharge when handling to prevent damage to packaging and container. Equipped with corresponding varieties and number of fire equipment and spill contingency processing equipment. Empty containers may remain inside
13、.Storage precautions: store in a cool, ventilated warehouse. Away from fire and heat source. Library temperature should not be more than 30 .Keep container sealed. Should with oxidant (such as nitric acid, hydrogen peroxide) stored separately, mixed reservoir of avoid by all means. Use explosion-pro
14、of lighting, ventilation facilities. Banning the use of easy to produce the spark of mechanical equipment and tools. Storage area should be equipped with emergency treatment equipment and suitable for material.The eighth part contact control/individual protectionThe occupational exposure limit: MAC(
15、mg/m3):300TWA(mg/m3):100STEL(mg/m3):10Methods: determination of toxic gas concentration in the air by gas chromatography.In the air with dust measurement by GB5748 measuring method of the dust in the air of workplaces.Engineering control: closed production process, to strengthen ventilated.Respirato
16、ry protection: when higher concentration in the air, wearing a filter type gas mask (half mask).Emergency rescue or evacuation, it is suggested that wear air breathing apparatus.Eye protection: wear chemical safety goggles.Body protection: wear anti-static overalls.Hand protection: wear protective g
17、loves in general.Other protection: work site no smoking, eating and drinking water. After work, shower change clothes. To maintain good health habits.The ninth part the characteristicsAppearance and properties: refer to the product informationMolecular formula: no dataMolecular weight: no dataPH: no
18、 dataMelting point () : 60Relative density (water = 1) : 1.13Boiling point () : 140Relative vapor density (air = 1):3.0-4.0Octanol/water partition coefficient: no dataLow flash point () : (closed cup)Ignition temperature ():60Explosion limit % (V/V) :6.0Lower explosive limit % (V/V) : 1.3Heat of com
19、bustion (kJ/mol) : no dataThe critical temperature () : no dataCritical pressure (MPa) : no dataSolubility: soluble in ethanol, acetone, benzene and other organic solvents.Main application: used in wood parts, wood and metal surface finishing.The tenth part the stability and reactivityStability: sta
20、bleProhibited content: antioxidant (including nitric acid, hydrogen peroxide)Avoid contact with the condition: stay away from fire and heat source, avoid direct sunlight.Aggregate hazard: no aggregationBreakdown products: no dataThe eleventh part toxicology dataAcute toxicity: LD50: no dataLC50: no
21、dataStimulus: after eye 500 pp/hour, moderate stimulus. People experience 180 pp / 8 minutes, mild stimulation.The twelfth part Ecology informationIts environmental pollution behavior mainly reflected in the water and the atmosphere, and residual accumulation is not serious, is biodegradable an
22、d chemical degradation in the environment, but the pace of the process is much lower than the speed of evaporation process, the xylene can be photolysis to evaporate into the atmosphere.The thirteenth part waste refuse disposalProperties: hazardous wasteWaste disposal method: by incinerating disposa
23、l.Note: waste disposal of the former should refer to the national and local relevant laws and regulations. And storage for disposal of waste storage see "operation". With incinerating disposal.The fourteenth part transportation informationDangerous goods number: 32198The UN number: 1139, 1
24、263, 1293Packing mark: flammable liquidPackaging categories: Packing method: iron or iron drum.Transportation note: transport vehicles should be equipped with corresponding varieties and number of fire equipment and spill contingency processing equipment. Summer best transportation sooner or later.
25、It is strictly prohibited and oxidant, such as food chemicals during conventional. Transit should prevent insolate, rain, heat. Stopover should be far away from fire, heat source and high temperature. Shipping the goods vehicle exhaust pipe must be equipped with fire device, to ban the use of sparks easy generation mechanical handling equipment and tools. Highway transportation route as prescribed, do not stay in residential areas and densely populated area.The fifteenth p
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