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1、 (persistent organic pollutants) 2001522200451750901111 “” 15, (a)/ a(b) b c the stockholm convention on persistent organic pollutants was adopted at a conference of plenipotentiaries on 22 may 2001 in stockholm, sweden. the convention entered into force on 17 may 2004, ninetieth day after the date
2、of deposit of the fiftieth instrument of ratification, acceptance, approval or accession in respect of the convention. the convention became effective in china in 11 november 11, 2004. the objective of the convention: mindful of the precautionary approach as set forth in principle 15 of the rio decl
3、aration onenvironment and development, the objective of this convention is to protect human health and theenvironment from persistent organic pollutants. measures to reduce or eliminate releases from intentional production and use: (a) parties must take measures to eliminate the production, use, imp
4、ort and export of the chemicals listed under annex a.(b) restrict its production and use of the chemicals listed in annex b in accordance with theprovisions of that annex.the convention stipulated that parties must take measures to reduce the unintentional releases of chemicals listed under annex c
5、with the goal of continuing minimization and, where feasible, ultimate elimination. 2016-03-10 a annex a (eliminatiion) a parties must take measures to eliminate the production and use of the chemicals listed under annex a. aldrin chlordane chlordecone dieldrin endrin heptachlor hexabromobiphenyl he
6、xabromocyclododecane (hbcd) hexabromodiphenyl ether and heptabromodiphenyl ether hexachlorobenzene (hcbalphabeta) hexachlorobutadiene- alpha hexachlorocyclohexane beta hexachlorocyclohexane lindane mirex pentachlorobenzene pentachlorophenol and its salts and esters polychlorinated biphenyls (pcb) po
7、lychlorinated naphthalenes technical endosulfan and its related isomers tetrabromodiphenyl ether and pentabromodiphenyl ether toxaphenenote pesticide industrial chemical unintentional production 112 29 2016-03-10 b annex b (restriction) b parties must take measures to restrict the production and use
8、 of the chemicals listed under annex b. 2,2-()-1,1,1- ddt pfosc8f17so2x perfluorooctane sulfonic acid, its salts and perfluorooctane sulfonyl fluoridenote pesticide industrial chemical unintentional production c annex c (unintentional production) c parties must take measures to reduce the unintentio
9、nal releases of chemicals listed under annex c with the goal of continuing minimization and, where feasible, ultimate elimination. pentachlorobenzeene polychlorinated biphenyls (pcb) hexachlorobenzene (hcb) polychlorinated dibenzo-p-dioxins (pcdd) polychlorinated dibenzofurans (pcdf)note pesticide i
10、ndustrial chemical unintentional production chemicals proposed for listing under the convention c-decabde decabromodiphenyl ether (commercial mixture, c-decabde) dicofol sccps short-chained chlorinated paraffins pfoa pfoa, perfluorooctanoic acid), its salts and pfoa-related compounds 2016-03-10 pops
11、 regulation (ec) no 850/2004 2004(ec) no 850/2004(eu) no 756/2010 (eu) no 757/2010 (eu) no 519/2012 (eu) no 1342/2014(eu) no 2015/2030(eu)2016/293(ec) no 850/2004 (ec) no 850/2004 i ii iii iv7 v april, 2004, european union published the regulation (ec) no 850/2004 on persistent organic pollutants in
12、 its official journal of the european union. then, the regulation was amended by (eu) no 756/2010, eu) no 757/2010, (eu) no 519/2012, (eu) no 1342/2014, (eu) 2015/2030 and (eu) 2016/293. regulation (ec) no 850/2004 includes four annexes, as shown below: annex i list of substances subject to prohibit
13、ions annex ii list of substances subject to restriction annex iii list of substances subject to release reduction provisions annex iv list of substances subject to waste management provisions set out in article 7 annex v waste management 2016-03-10 i (list of substances subject to prohibitions) a pa
14、rt a substances listed in the convention and in the protocol cas no ec no specific exemption on intermediate use or other specification tetrabromodiphenyl ether c12h6br4o 1. article 4(1)(b) 10mg/kg0,0012.(a) (b) 0.1% (b) 2002/95/ec3. 2010 8 25article 4(2) 3,41. for the purposes of this entry, articl
15、e 4(1)(b) shall apply to concentrations of tetrabromodiphenylether equal to or below 10 mg/kg (0,001 % by weight) when it occurs in substances, preparations,articles or as constituents of the flame-retarded parts of articles.2. by way of derogation, the production, placing on the market and use of t
16、he following shall beallowed:(a) without prejudice to subparagraph (b), articles and preparations containing concentrations below0,1 % of tetrabromodiphenyl ether by weight when produced partially or fully from recycled materials or materials from waste prepared for re-use; (b) electrical and electr
17、onic equipment within the scope of directive 2002/95/ec of the europeanparliament and council. 3. use of articles already in use in the union before 25 august 2010 containing tetrabromodiphenyl2016-03-10 ether as a constituent of such articles shall be allowed. article 4(2), third and fourth subpara
18、graphs shall apply in relation to such articles. pentabromodiphenyl ether c12h5br5o 1.article 4(1)(b) 10mg/kg(0,001 )2.(a)(b) 0.1% (b) 2002/95/ec3. 2010 8 25 article 4(2) 3,41. forthe purposes of this entry, article 4(1)(b) shall apply to concentrations of pentabromodiphenylether equal to or below 1
19、0 mg/kg (0,001 % by weight) when it occurs in substances, preparations,articles or as constituents of the flame-retarded parts of articles.2. by way of derogation, the production, placing on the market and use of the following shall beallowed:(a) without prejudice to subparagraph(b), articles and pr
20、eparations containing concentrations below0,1 % of pentabromodiphenyl ether by weight when produced partially or fully from recycled materials or materials from waste prepared for re-use; (b) electrical and electronic equipment within the scope of directive 2002/95/ec.3. use of articles already in u
21、se in the union before 25 august 2010 containing pentabromodiphenylether as a constituent of such articles shall be allowed. article 4(2), third and fourth subparagraphs shallapply in relation to such articles. hexabromodiphenyl ether c12h4br6o 1. article 4(1)(b) 10mg/kg0,0012.(a)(b)2016-03-10 0.1%
22、(b) 2002/95/ec3. 2010 8 25 article 4(2) 3,41. for the purposes of this entry, article 4(1)(b) shall apply to concentrations of hexabromodiphenylether equal to or below 10 mg/kg (0,001 % by weight) when it occurs in substances, preparations,articles or as constituents of the flame-retarded parts of a
23、rticles.2. by way of derogation, the production, placing on the market and use of the following shall beallowed:(a) without prejudice to subparagraph (b), articles and preparations containing concentrations below0,1 % of hexabromobiphenyl ether by weight when produced partially or fully from recycle
24、d materials or materials from waste prepared for re-use; (b) electrical and electronic equipment within the scope of directive 2002/95/ec.3. use of articles already in use in the union before 25 august 2010 containing hexabromodiphenylether as a constituent of such articles shall be allowed. article
25、 4(2), third and fourth subparagraphs shallapply in relation to such articles. heptabromodiphenyl ether c12h3br7o 1. article 4(1)(b) 10mg/kg0,0012.(a)(b) 0.1% (b) 2002/95/ec3. 2010 8 25 article 4(2) 3,41. for the purposes of this entry, article 4(1)(b) shall apply to concentrations of heptabromodiph
26、enylether equal to or below 10 mg/kg (0,001 % by weight) when it occurs in substances, preparations,2016-03-10 articles or as constituents of the flame-retarded parts of articles. 2. by way of derogation, the production, placing on the market and use of the following shall beallowed:(a) without prej
27、udice to subparagraph (b), articles and preparations containing concentrations below0,1 % of heptabromodiphenyl ether by weight when produced partially or fully from recycled materials or materials from waste prepared for re-use; (b) electrical and electronic equipment within the scope of directive
28、2002/95/ec.3. use of articles already in use in the union before 25 august 2010 containing heptabromodiphenylether as a constituent of such articles shall be allowed. article 4(2), third and fourth subparagraphs shallapply in relation to such articles.pfos perfluorooctane sulfonic acid and its deriv
29、atives (pfos) c8f17so2x(x = oh, metal salt (o-m+), halide, amide, and other derivatives including polymers) 1.pfos10mg/kg0.001%article 4(1)(b)2. article 4(1) (b)pfos0.1%pfospfos1 g/m23. 2010825pfosarticle 4(2)3,4 4. 2006122720116275.pfospfos(a)2015826(b)(c)(d)(e)(a)(e)2008/1/ec2008/1/ecarticle 17(2)
30、2pfos (b)(e)2 (i)pfos(ii) 2016-03-10 (iii) pfos 6.cen12cen1. for the purposes of this entry, article 4(1)(b) shall apply to concentrations of pfos equal to or below10 mg/kg (0,001 % by weight) when it occurs in substances or in preparations.2. for the purposes of this entry, article 4(1) (b) shall a
31、pply to concentrations of pfos in semi-finishedproducts or articles, or parts thereof, if the concentration of pfos is lower than 0,1 % by weightcalculated with reference to the mass of structurally or micro-structurally distinct parts that containcoated material.3. use of articles already in use in
32、 the union before 25 august 2010 containing pfos as a constituent ofsuch articles shall be allowed. article 4(2), third and fourth subparagraphs shall apply in relation to sucharticles.4. fire-fighting foams that were placed on the market before 27 december 2006 may be used until 27june 2011.5. if t
33、he quantity released into the environment is minimised, production and placing on the market isallowed for the following specific uses provided that member states report to the commission everyfour years on progress made to eliminate pfos:(a) until 26 august 2015, wetting agents for use in controlle
34、d electroplating systems;(b) photoresists or anti reflective coatings for photolithography processes;(c) photographic coatings applied to films, papers, or printing plates;(d) mist suppressants for non-decorative hard chromium (vi) plating in closed loop systems;(e) hydraulic fluids for aviation.whe
35、re derogations in points (a) to (e) above concern the production or use in an installation within the scope of directive 2008/1/ec of the european parliament and of the council ( 2 ), the relevant best available techniques for the prevention and minimisation of emissions of pfos described in the inf
36、ormation published by the commission pursuant to article 17(2), second subparagraph, of directive 2016-03-10 2008/1/ec shall apply. as soon as new information on details of uses and safer alternative substances or technologies for the uses in points (b) to (e) becomes available, the commission shall
37、 review the derogations in the second subparagraph so that: (i) the uses of pfos will be phased out as soon as the use of safer alternatives is technically andeconomically feasible, (ii) a derogation can only be continued for essential uses for which safer alternatives do not exist andwhere the effo
38、rts undertaken to find safer alternatives have been reported on, (iii) releases of pfos into the environment have been minimised by applying best availabletechniques. 6. once standards are adopted by the european committee for standardisation (cen) they shall be usedas the analytical test methods fo
39、r demonstrating the conformity of substances, preparations and articlesto paragraphs 1 and 2. any other analytical method for which the user can prove equivalentperformance could be used as an alternative to the cen standards.2,2-()-1,1,1- ddt (1,1,1-trichloro-2,2-bi s(4-chloro-phenyl)ethane)50-29-3
40、200-024-3 chlordane 57-74-9200-349-0 hexachlorocyclohexanes, including lindane 58-89-9200-401-2 319-84-6206-270-8319-85-7206-271-2016-03-10 3 608-73-1210-168-9 dieldrin 60-57-1200-484-5 endrin 72-20-8200-775-7 heptachlor 76-44-8200-962-3 endosulfan 115-29-7959-98-833213-65-9204-079-41.20127102023110
41、 2.2012710 3. article 4(2) 3,41,21. placing on the market and use of articles produced before or on 10 july 2012 containing endosulfanas a constituent of such articles shall be allowed until 10 january 2013.2. placing on the market and use of articles already in use before or on 10 july 2012 contain
42、ingendosulfan as a constituent of such articles shall be allowed.3. article 4(2), third and fourth subparagraphs shall apply to articles referred to in paragraphs 1 and 2. hexachlorobenzene 118-74-1200-273-9 chlordecone 143-50-0205-601-3 aldrin 309-00-2206-215-8 pentachlorobenze608-93-5210-172-5 201
43、6-03-10 ne pcb polychlorinated biphenyls (pcb) 1336-36-3 and others 215-648-1 andothers 96/59/ec without prejudice to directive 96/59/ec, articles already in use at the time of the entry into force of this regulation are allowed to be used mirex 2385-85-5 219-196-6 toxaphene 8001-35-2 232-283-3 hexa
44、bromobiphenyl 36355-01-8252-994-2 hbcdd hexabromocyclododecane “hexabromocyclododecane” means: hexabromocyclododecane, 1,2,5,6,9,10-hexabromocyclododecane and its main diastereoisomers: alpha- hexabromocyclod25637-99-43194-55-6134237-50-6134237-51-7134237-52-8247-148-4,221-695-91. article4(1)(b)100m
45、g/kg(0.01%)20193222.(ec) no 1907/2006201422120191126(ec) no 1907/20063.201632220166224. 20163226article42345.2266.2016-03-10 odecane; beta-hexabromocyclododecane; and gamma-hexabromocyclododecane 2 1.for the purposes of this entry, article 4(1)(b) shall apply to concentrations ofhexabromocyclododeca
46、ne equal to or below 100 mg/kg (0,01 % by weight) when it occurs insubstances, preparations, articles or as constituents of the flame-retarded parts of articles, subject toreview by the commission by 22 march 2019.2. the use of hexabromocyclododecane, whether on its own or in preparations, in the pr
47、oduction ofexpanded polystyrene articles, and the production and placing on the market ofhexabromocyclododecane for such use, shall be allowed provided that such use has been authorised inaccordance with title vii of regulation (ec) no 1907/2006 of the european parliament and of thecouncil(*), or is
48、 the subject of an application for authorisation submitted by 21 february 2014 where adecision on that application has yet to be taken.the placing on the market and use of hexabromocyclododecane, whether on its own or in preparations, in accordance with this paragraph shall only be allowed until 26
49、november 2019 or, if earlier, the date of expiry of the review period specified in an authorisation decision or the date of withdrawal of that authorisation pursuant to title vii of regulation (ec) no 1907/2006. the placing on the market and use in buildings of expanded polystyrene articles, that co
50、ntain hexabromocyclododecane as a constituent of such articles and are produced in accordance with the exemption in this paragraph, shall be allowed until 6 months after the date of expiry of that exemption. such articles already in use by that date may continue to be used. 3. without prejudice to t
51、he exemption in paragraph 2, the placing on the market and use in buildings ofexpanded polystyrene articles and extruded polystyrene articles that contain hexabromocyclododecaneas a constituent of such articles and are produced before or on 22 march 2016 shall be allowed until 22june 2016. paragraph
52、 6 shall apply as if such articles were produced pursuant to the exemption inparagraph 2.2016-03-10 4. articles that contain hexabromocyclododecane as a constituent of such articles and are already in usebefore or on 22 march 2016 may continue to be used and further placed on the market and paragrap
53、h 6shall not apply. article 4(2), third and fourth subparagraphs shall apply to such articles.5. the placing on the market and use in buildings of imported expanded polystyrene articles thatcontain hexabromocyclododecane as a constituent of such articles shall be allowed until the date ofexpiry of t
54、he exemption in paragraph 2 and paragraph 6 shall apply as if such articles were producedpursuant to the exemption in paragraph 2. such articles already in use by that date may continue to beused.6. without prejudice to the application of other union provisions on the classification, packaging andla
55、belling of substances and mixtures, expanded polystyrene, in which hexabromocyclododecane is usedpursuant to the exemption in paragraph 2, must be identifiable by labelling or other means throughoutits life cycle.b part b substances listed only in the protocol cas no ec no specific exemption on inte
56、rmediate use or other specification hexachlorobutadiene 87-68-3201-765-51. 2012 7 10 2013 1 102. 2012 7 103. article 4(2)34121. placing on the market and use of articles produced before or on 10 july 2012 containinghexachlorobutadiene as a constituent of such articles shall be allowed until 10 janua
57、ry 2013.2. placing on the market and use of articles already in use before or on 10 july 2012 containinghexachlorobutadiene as a constituent of such articles shall be allowed.2016-03-10 3. article 4(2), third and fourth subparagraphs shall apply to articles referred to in paragraphs 1 and 2. polychl
58、orinated naphthalenes 1. 2012 7 10 2013 1 10 2. 2012 7 103. article 4(2)34121. placing on the market and use of articles produced before or on 10 july 2012 containingpolychlorinated naphthalenes as a constituent of such articles shall be allowed until 10 january 2013.2. placing on the market and use
59、 of articles already in use before or on 10 july 2012 containingpolychlorinated naphthalenes as a constituent of such articles shall be allowed.3. article 4(2), third and fourth subparagraphs shall apply to articles referred to in paragraphs 1 and 2. alkanes c10-c13, chloro (short-chain chlorinated
60、paraffins) (sccps) 85535-84-8287-476-51. sccps 1% 0.15% 2. (a) 2015 12 4 sccps(b) 2012 7 10 sccps (a)3article 4(2)342 1. by way of derogation, the production, placing on the market and use of substances or preparationscontaining sccps in concentrations lower than 1 % by weight or articles containing
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