环境管理_高等级重交沥青项目环境空气影响评价

山东晨曦石油化工有限公司350万吨/年高等级重交沥青项目 环境空气影响评价5 环境空气影响评价5.1大气污染源调查与分析5.1.1污染源调查内容本项目环境空气评价等级确定为二级评价，按照环境影响评价技术导则 大气环境（HJ2.2-2008）中6.1.1：对于一、二级评价项目，应调查分析项目所有污染源（对于改、扩建项目应包括新、老污染源）、评价范围内与项目排放污染物有关的其他试运行项目、已经批复环境影响评价文件的未建设项目等污染源。另外，已建成但监测期间未开工企业均纳入本次污染源调查内。因此，本次大气评价污染源调查范围为山东晨曦石油化工有限公司厂内现有工程、在建运行工程及评价范围内与项目排放污染物有关的其他在建项目、已经批复环境影响评价文件的未建设项目。涉及本次污染源调查的企业或项目见表5.1-1。表5.1-1 涉及本次污染源调查的企业或项目企业名称项目（装置）名称 大气污染源编号山东晨曦石油化工有限公司5万吨/年气体分馏装置1#60万吨/年催化裂化装置2#10万吨/年气体分馏装置3#5万吨/年MTBE装置已经建成4#15万吨/年气体分馏装置在建5#120万吨/年延迟焦化装置6#80万吨/年汽柴油加氢装置7#5.1.2污染源调查结果拟建项目评价范围内污染源调查结果见表5.1-2。表5.1-2 拟建项目评价范围内大气污染源（点源）参数清单项目装置名称废气量Nm3/h名称排放浓度(mg/m3)排放速率（kg/h）年排放量（t/a）排放筒参数高度m内径m温度拟建项目预加热炉G138400SO2115.412.9335.45502.4170NOX1505.7646.08烟尘18.40.715.68加热炉G225500SO298.32.5120.10532.4170NOX1203.0624.48烟尘15.70.403.20在建MCC装置再生烟气G372000SO2420.1430.11240.856801.0170NOX20014.40115.2烟尘926.6252.99在建延迟焦化加热炉烟气G443030SO25.850.252.016801.0170NOX492.1116.88烟尘552.3718.96制氢原料预热炉烟气59700SO21.450.090.688801.0170NOX492.9123.26制氢转化炉烟气G5烟尘553.2926.32加氢加热炉烟气G66850SO25.850.040.32300.4170NOX490.342.72烟尘550.383.04厂内公共硫磺回收G717700SO24517.9863.8801.0170NOX1602.8322.648烟尘921.6613.24锅炉烟气G8SO219722.09176.7600.455NOX33537.56300.5烟尘196.722.06176.55.2 环境空气质量现状监测与评价5.2.1环境空气质量现状监测5.2.1.1监测布点本次环境空气现状监测共布8个点，查清项目厂区和周围村庄的空气环境的质量现状。监测布点情况见表5.2-1及图5.2-1：环境空气监测布点图。表5.2-1 大气现状监测布点一览表编号监测点位相对厂址方位相对厂址距离（m）设置意义1#杨家官庄NE2300主导风向上风向，敏感点2#荀家村SW1800主导风向下风向，敏感点3#后山后SE2100次主导风向上风向，敏感点4#薛家湖S1440敏感点5#大略疃W1200敏感点6#草岭NW 200次主导风向下风向、厂界近距离敏感点，了解厂址及周围环境空气质量现状7#唐水湖E400敏感点8#厂址-本底5.2.1.2 监测项目本次环评环境空气质量监测具体内容及安排见表5.2-2。表5.2-2 环境空气监测项目一览表编号监测点位小时值或一次浓度监测项目日均值监测项目1#杨家官庄SO2、NO2、CO、NH3非甲烷总烃、苯SO2、NO2、CO、TSP、PM102#荀家村3#后山后4#薛家湖5#大略疃6#草岭SO2、NO2、CO、NH3、H2S、非甲烷总烃、苯、臭气SO2、NO2、CO、TSP、PM10、苯并芘、7#唐水湖8#厂址5.2.1.3 监测时间与频率本次环境空气现状因子SO2、NO2、TSP、PM10、CO、NH3、非甲烷总烃、苯、臭气于2011年3月9日3月15日进行；H2S、苯并芘于2011年3月23日3月27日进行。1#5#监测项目为：SO2、NO2、TSP、PM10、CO、NH3、非甲烷总烃、苯。6#、7#、8#监测项目为：SO2、NO2、PM10、TSP、CO、NH3、H2S、非甲烷总烃、苯、苯并芘、臭气。监测连续7天，其中SO2、NO2、CO同时取得1小时平均浓度和日均浓度，TSP、PM10、苯并芘取得日平均浓度，非甲烷总烃、H2S、NH3、苯、臭气取得小时值。小时均值每次采样时间1小时，SO2、NO2、CO日均值保证每天至少有18小时的采样时间，TSP、PM10日均值保证每天至少有12小时的采样时间。小时浓度各点每天采样4次，采样起始时间分别为200、800、1400、2000。在空气质量监测的同时，进行气温、气压、风向、风速、总云量、低云量等气象条件观测。5.2.1.4监测方法环境空气质量现状监测分析方法见表5.2-3。表5.2-3 环境空气质量现状监测分析方法一览表监测项目分 析 方 法方 法 依 据检出下限(mg/m3)二氧化硫甲醛吸收-盐酸副玫瑰苯胺分光光度法HJ482-20090.007(小时)0.004（日均）二氧化氮Saltzman法GB/T15435-19950.015(小时)0.005（日均）TSP重量法GB/T15432-19950.001（日均）PM10重量法GB6921-19860.001（日均）CO非分散红外法GB/T9801-19880.015(小时)0.005（日均）氨纳氏试剂分光光度法0.01硫化氢亚甲基蓝分光光度法空气和废气监测分析方法第四版0.001非甲烷总烃气相色谱法0.2苯气相色谱法0.01苯并芘高效液相色谱法GB/T 15439-19951.810-4 g/m3臭气三点比较式臭袋法GB/T14675-1993-注：空气和废气监测分析方法第四版增补版5.2.1.5 监测期间气象情况监测期间气象参数见表5.2-4。表5.2-4 监测期间气象参数一览表 项目时间风向风速（m/s）气压（KP a）气温（）总云量低云量3.902:00NNW2101.32.00008:00C0101.70.22014:00NW5101.510.00020:00NE2101.64.9003.1002:00SSW2101.6-0.50008:00SSW2101.50.20014:00SW4101.414.20020:00W2101.010.0003.1102:00C0101.01.00008:00C0101.11.00014:00S5100.616.78020:00S3100.412.3803.1202:00SW2100.39.25008:00SSE2100.28.20014:00SE699.919.10020:00S2100.015.4003.1302:00S2100.210.10008:00S3100.210.20014:00S699.820.84020:00ESE2100.015.2003.1402:00N3100.39.00008:00N8101.04.910-014:00NNE7101.26.810-020:00NNE4101.04.010-03.1502:00SW2101.53.04008:00WNW3101.54.110-014:00N5101.29.60020:00W2101.46.2003.2302:00东 3.1101.81.83108:00西 0.3101.68.42014:00东南 2.1101.514.13020:00东1.4101.910.3313.2402:00南 2.5100.95.62108:00西 4.9101.110.42014:00西4.3100.914.32120:00西北0.9101.46.8103.2502:00西 2.1101.65.42108:00西南 0.9101.88.81014:00西南 7.3101.414.12120:00北 0.8101.65.5213.2602:00北 0.7101.65.01008:00西 0.8101.68.11014:00西 1.3101.417.82120:00北 2.4101.66.7103.2702:00西北 0.7101.74.34108:00西 1.2101.68.52014:00西 2.6101.417.31020:00西 1.1101.56.2105.2.1.6 监测结果本次环境空气质量现状监测结果见表5.2-5表5.2-15。 表5.2-5 二氧化硫监测结果表 单位：mg/m3测点编号测点名称采样日期二氧化硫02:0008:0014:0020:00 日均1杨家官庄3.90.0420.0630.0500.0670.0563.100.0480.0660.0580.0700.0613.110.0570.0860.0630.0750.0733.120.0440.0690.0580.0660.0563.130.0500.0760.0640.0780.0643.140.0460.0650.0540.0590.0553.150.0530.0730.0670.0880.0712荀家村3.90.0640.0830.0680.0980.0813.100.0510.0750.0680.0640.0653.110.0490.0800.0620.0710.0673.120.0500.0680.0600.0620.0583.130.0530.0670.0620.0730.0623.140.0660.0980.0860.0950.0853.150.0700.1030.0850.0950.0883后山后3.90.0530.0720.0600.0770.0653.100.0460.0660.0620.0700.0613.110.0500.0700.0610.0680.0583.120.0490.0740.0650.0630.0603.130.0510.0700.0580.0760.0673.140.0580.0840.0700.0820.0733.150.0590.0790.0720.0890.0754薛家湖3.90.0620.0890.0660.0970.0763.100.0510.0730.0630.0680.0623.110.0540.0780.0670.0890.0683.120.0600.0810.0640.0750.0713.130.0530.0740.0630.0800.0643.140.0640.0900.0710.1130.0873.150.0790.1050.0840.1090.0915大略疃3.90.0630.0890.0720.0980.0793.100.0530.0750.0640.0690.0633.110.0510.0770.0620.0720.0653.120.0530.0690.0600.0620.0613.130.0490.0720.0640.0700.0633.140.0600.0890.0920.1090.0883.150.0530.0790.0700.0720.0696草岭3.90.0560.0770.0650.0780.0703.100.0650.0980.0790.0940.0813.110.0720.1070.0930.1150.0953.120.0680.0960.0800.1050.0863.130.0780.1040.0910.1080.0983.140.0560.0840.0610.0760.0653.150.0590.0980.0720.0760.0757唐家湖3.90.0670.0980.0840.0880.0843.100.0640.0960.0800.1150.0923.110.0760.1120.0750.0900.0853.120.0780.1240.0960.1170.1033.130.0620.0940.0700.0810.0773.140.0560.0780.0620.0680.0653.150.0670.1010.0800.1200.0928厂址3.90.0760.1170.0890.1220.1093.100.0690.0900.0810.0980.0853.110.0800.1220.0930.1060.0983.120.0620.0950.0700.0940.0813.130.0690.1080.0870.1100.0903.140.0810.1140.0910.1020.0943.150.0720.1080.0860.1210.102 表5.2-6 二氧化氮监测结果表 单位：mg/m3测点编号测点名称采样日期二氧化氮02:0008:0014:0020:00 日均1杨家官庄3.90.0330.0500.0420.0550.0463.100.0400.0550.0510.0620.0523.110.0480.0810.0570.0690.0653.120.0350.0600.0490.0630.0503.130.0420.0650.0570.0700.0553.140.0380.0590.0500.0470.0463.150.0450.0710.0650.0830.0602荀家村3.90.0580.0760.0620.0920.0723.100.0400.0670.0590.0550.0563.110.0440.0710.0570.0650.0583.120.0420.0550.0630.0510.0513.130.0450.0590.0540.0650.0543.140.0570.0860.0750.0820.0703.150.0610.0900.0720.0770.0753后山后3.90.0460.0640.0520.0690.0573.100.0370.0580.0550.0630.0523.110.0410.0580.0530.0600.0493.120.0400.0670.0590.0580.0533.130.0420.0630.0500.0710.0583.140.0500.0750.0620.0780.0643.150.0530.0720.0650.0840.0674薛家湖3.90.0550.0780.0520.0880.0653.100.0430.0620.0540.0590.0513.110.0460.0670.0580.0770.0593.120.0540.0720.0530.0670.0633.130.0400.0600.0540.0660.0523.140.0570.0820.0660.0970.0733.150.0700.0890.0740.0950.0845大略疃3.90.0520.0760.0600.0850.0683.100.0440.0620.0500.0580.0513.110.0400.0640.0530.0590.0543.120.0450.0570.0510.0530.0503.130.0430.0610.0530.0570.0523.140.0520.0750.0870.0950.0783.150.0440.0680.0620.0600.0596草岭3.90.0450.0640.0510.0630.0583.100.0580.0870.0700.0750.0723.110.0660.0950.0820.1060.0863.120.0600.0830.0680.0910.0753.130.0700.0920.0800.1120.0903.140.0470.0720.0540.0610.0583.150.0510.0870.0630.0650.0667唐家湖3.90.0600.0860.0750.0690.0723.100.0560.0820.0730.1030.0813.110.0650.0940.0630.0690.0703.120.0700.1070.0850.0960.0883.130.0530.0810.0580.0660.0653.140.0480.0670.0520.0550.0533.150.0560.0880.0670.1060.0808厂址3.90.0650.1040.0710.1070.0923.100.0580.0770.0680.0850.0743.110.0710.1100.0820.0890.0863.120.0530.0820.0580.0770.0723.130.0570.0840.0740.0920.0763.140.0720.0950.0770.0860.0813.150.0650.0970.0730.1050.086表5.2-7 PM10 监测结果表 单位：mg/m3测点编号测点名称可吸入颗粒物3.93.103.113.123.133.143.151杨家官庄0.1560.1690.1380.1600.1520.2450.1742荀家村0.1210.1160.1300.1060.0980.1630.1383后山后0.1400.1290.1030.1250.1320.2060.1604薛家湖0.1540.1020.1330.1270.1400.1960.1365大略疃0.1220.1090.0860.1270.1180.1830.1246草岭0.1650.1170.1370.1130.1550.2180.1257唐家湖0.1510.1370.1260.1190.1560.2130.1338厂址0.1620.1380.1550.2010.2240.2590.183表5.2-8 TSP 监测结果表 单位：mg/m3测点编号测点名称总悬浮颗粒物3.93.103.113.123.133.143.151杨家官庄0.3270.3380.3020.3100.2970.4260.3382荀家村0.2550.2350.3050.2160.1890.3270.2953后山后0.2880.2750.1990.2470.3150.3680.3254薛家湖0.3170.2150.2670.2060.3040.3550.2835大略疃0.2570.1860.1770.2590.2030.3410.2436草岭0.3260.2490.3020.2350.3060.4040.2587唐家湖0.3240.2590.2880.2060.3350.3820.2678厂址0.3250.2870.3110.3760.4030.4180.355 表5.2-9 CO监测结果表 单位：mg/m3测点编号测点名称采样日期CO02:0008:0014:0020:00 日均1杨家官庄3.90.40.80.40.30.43.101.11.20.81.01.13.110.81.51.11.11.23.121.11.61.31.41.43.131.22.01.60.81.33.140.40.50.20.40.43.150.80.50.40.30.42荀家村3.90.50.70.40.40.43.100.60.90.81.00.93.110.71.40.80.80.93.120.91.31.21.31.23.131.11.71.20.81.33.140.50.80.50.70.63.150.50.50.30.40.43后山后3.90.70.90.50.40.63.100.70.90.70.80.83.110.71.30.80.90.93.120.81.41.21.31.23.131.31.81.50.71.33.140.30.50.20.40.43.150.40.50.40.31.64薛家湖3.90.80.90.50.40.63.100.80.90.61.00.83.110.80.50.90.91.03.120.81.21.11.01.23.131.31.81.40.61.33.140.50.60.40.40.43.150.50.60.30.40.45大略疃3.90.60.70.40.30.53.100.90.90.71.00.93.110.71.40.80.91.03.121.11.41.21.31.23.131.21.91.40.81.53.140.40.50.30.50.43.150.50.40.30.40.46草岭3.90.60.90.50.40.53.100.91.00.80.80.93.110.81.71.11.01.23.121.21.71.51.41.53.131.42.01.71.01.73.140.40.60.40.50.53.150.60.50.50.30.57唐家湖3.90.61.00.60.40.63.101.21.30.91.11.13.110.91.70.81.01.23.121.11.51.41.31.23.131.31.61.40.71.43.140.30.50.40.60.53.150.80.60.50.70.68厂址3.90.71.10.80.60.83.100.60.90.71.10.83.110.81.51.41.21.03.121.11.51.31.51.33.131.41.71.50.91.63.140.40.70.60.50.63.150.70.50.60.90.6表5.2-10 氨监测结果表 单位：mg/m3测点编号测点名称采样日期氨02:0008:0014:0020:001杨家官庄3.110.070.080.070.093.120.080.090.080.073.130.070.080.080.103.140.080.080.080.093.150.090.090.080.052荀家村3.110.080.070.090.103.120.080.090.080.083.130.060.070.060.093.140.070.070.080.083.150.080.080.080.073后山后3.110.080.070.070.063.120.070.090.070.083.130.080.090.080.093.140.080.070.080.073.150.080.090.070.084薛家湖3.110.090.070.070.063.120.080.080.060.083.130.080.070.080.083.140.060.070.080.083.150.080.090.090.075大略疃3.110.090.080.090.073.120.100.090.080.103.130.090.100.090.083.140.100.090.100.093.150.090.080.070.086草岭3.110.090.080.100.093.120.090.080.100.103.130.100.100.110.103.140.090.100.100.103.150.100.090.080.087唐家湖3.110.100.100.090.083.120.100.080.100.123.130.090.090.090.093.140.100.080.090.083.150.090.090.080.118厂址3.110.110.100.100.103.120.100.090.090.083.130.090.110.110.083.140.110.100.110.123.150.110.100.100.12表5.2-11 硫化氢监测结果表 单位：mg/m3测点编号测点名称采样日期硫化氢02:0008:0014:0020:001草岭3.230.0020.0040.0060.0053.240.0030.0050.0060.0043.250.0020.0040.0060.0063.260.0020.0060.0030.0063.270.0020.0060.0050.0062唐家湖3.230.0020.0040.0060.0053.240.0040.0060.0050.0063.250.0030.0060.0030.0053.260.0020.0050.0060.0043.270.0020.0050.0060.0043厂址3.230.0030.0050.0060.0073.240.0030.0050.0070.0063.250.0030.0060.0070.0063.260.0020.0070.0060.0043.270.0030.0070.0060.005表5.2-12 非甲烷总烃监测结果表 单位：mg/m3测点编号测点名称采样日期非甲烷总烃02:0008:0014:0020:001杨家官庄3.110.40.40.40.43.120.20.40.50.23.130.30.30.40.33.141.10.60.30.33.150.40.30.30.42荀家村3.110.30.50.31.33.120.40.40.20.33.130.20.20.30.33.140.60.40.40.53.150.40.50.50.43后山后3.110.50.60.30.53.120.40.60.40.53.130.30.30.60.73.140.30.20.50.63.150.30.50.30.54薛家湖3.110.71.00.50.93.120.30.30.20.33.130.21.40.20.43.140.51.40.50.33.150.30.40.30.55大略疃3.110.60.20.60.33.120.30.40.30.33.130.90.40.40.33.140.20.50.20.23.150.30.40.40.46草岭3.110.60.30.40.23.120.20.30.30.33.130.50.30.20.33.140.31.30.40.43.150.30.40.40.27唐家湖3.110.91.41.20.43.120.80.30.20.33.130.81.41.20.43.140.20.40.30.23.150.90.80.30.68厂址3.110.50.40.50.33.120.70.90.60.43.131.30.61.41.53.140.30.50.60.63.150.71.20.70.8表5.2-13 苯监测结果表 单位：mg/m3测点编号测点名称采样日期苯02:0008:0014:0020:001杨家官庄3.11未检出未检出未检出未检出3.12未检出未检出未检出未检出3.13未检出未检出未检出未检出3.14未检出未检出未检出未检出3.15未检出未检出未检出未检出2荀家村3.11未检出未检出未检出未检出3.12未检出未检出未检出未检出3.13未检出未检出未检出未检出3.14未检出未检出未检出未检出3.15未检出未检出未检出未检出3后山后3.11未检出未检出未检出未检出3.12未检出未检出未检出未检出3.13未检出未检出未检出未检出3.14未检出未检出未检出未检出3.15未检出未检出未检出未检出4薛家湖3.11未检出未检出未检出未检出3.12未检出未检出未检出未检出3.13未检出未检出未检出未检出3.14未检出未检出未检出未检出3.15未检出未检出未检出未检出5大略疃3.11未检出未检出未检出未检出3.12未检出未检出未检出未检出3.13未检出未检出未检出未检出3.14未检出未检出未检出未检出3.15未检出未检出未检出未检出6草岭3.11未检出未检出未检出未检出3.12未检出未检出未检出未检出3.13未检出未检出未检出未检出3.14未检出未检出未检出未检出3.15未检出未检出未检出未检出7唐家湖3.11未检出未检出未检出未检出3.12未检出未检出未检出未检出3.13未检出未检出未检出未检出3.14未检出未检出未检出未检出3.15未检出未检出未检出未检出8厂址3.11未检出未检出未检出未检出3.12未检出未检出未检出未检出3.13未检出未检出未检出未检