MSDS- TJ-YX40003,35,5-四甲基联苯二酚二缩水甘油醚

功能型环氧树脂固化系统研究开发实验室FUNCTIONALEPOXYresinsystemR&DLABORSTORIESMATERIALSAFETYDATASHEETDate:18August20161.IDENTIFICATIONOFTHESUBSTANCE/PREPARATIONANDTHECOMPANY/UNDERTAKINGProductname:4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenylProductCode:TJ-YX4000Supplier:GuangZhouTaiJiNewMaterialsCO.,ltdAddress:602-01,8JinJinStreet,WhampoaDistrict,Guangzhou,ChinaEmergencytelephone186200032222.COMPOSITION/INFORMATIONONINGREDIENTSComponentNameContent:4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenylCASNo.85954-11-6Percentage%:100%3.HAZARDIDENTIFICATIONMostimportanthazards:TheproductconsistsofasubstanceofaCategory3mutagenunderECcriteriaandaskinsensitiser.Humanhealthhazards:DustorsmallparticlesmayabradeskinandirritateeyesClassifiedasaCategory3mutagenunderECcriteriaandaskinsensitiser.Safetyhazards:Dangerofdustexplosionwhengroundtoasmallparticlesize.Electrostaticchargesmaybegeneratedduringhandling.Notclassifiedasflammablebutwillburn.Environmentalhazards:Nospecifichazards.4.FIRST-AIDMEASURESSymptomsandeffects:Notexpectedtogiverisetoanacutehazardundernormalconditionsofuse.FirstAid-Inhalation:RemovetofreshairandcallaphysicianFirstAid-Skin:Immediatelywashthoroughlywithsoapandwater.(Callaphysician)FirstAid-Eye:Flusheyewithplentyofwaterduringatleast15min.Ifpersistentirritationoccurs,obtainmedicalattention.FirstAid-Ingestion:Donotinducevomiting.Ifrapidrecoverydoesnotoccur,obtainmedicalattention.5.FIRE-FIGHTINGMEASURESSpecifichazards:Notclassifiedasflammablebutwillburn.Carbonmonoxidemaybeevolvedifincompletecombustionoccurs.Extinguishingmedia-smallfires:Drychemicalpowder,carbondioxide,foam,watersprayorfog,sandorearth.Extinguishingmedia-largefires:Foam,watersprayorfog.Unsuitableextinguishingmedia:Waterinajet.Protectiveequipment:Fullprotectiveclothingandself-containedbreathingapparatus6.ACCIDENTALRELEASEMEASURESPersonalprecautions:Avoidraisingadustcloud.Takeprecautionarymeasuresagainststaticdischarge.Nospecificmeasures.Personalprotection:Wearprotectiveclothingspecifiedfornormaloperations(seeSection8).Ifriskofinhalationofdustweargeneralpurposedustrespirator(disposable)Environmentalprecautions:Nospecificmeasures.Clean-upmethods-smallspillage:Shovelupandplaceinalabelled,sealablecontainerforsubsequentsafedisposal.Flushcontaminatedareawithplentyofwater.Clean-upmethods-largespillage:Transfertoalabelledcontainerforproductrecoveryorsafedisposal.Flushawayresidueswithwater.7.HANDLINGANDSTORAGEHandling:Uselocalexhaustextractionoverprocessingarea.Avoidgenerationoraccumulationofdusts.Electrostaticchargesmaybegeneratedduringhandling;forexample,whencrushing,grinding,andsewingoremptyingbags,particularlyinthepreparationofsolutionsinorganicsolvents.Earthallequipmentincludingfunnels,chutesanddrums.Handlingtemperatures:Ambient.Storage:Keepcontainertightlyclosedanddry.Keepawayfromheat.Keepawayfromdirectsunlight.Palletisedloadsshouldbestackedtoamaximumof3high.Maximumstoragetime12months.Storagetemperatures:Ambient.8.EXPOSURECONTROLS/PERSONALPROTECTIONOccupationalexposurestandards:NoneestablishedRespiratoryprotection:Notnormallyrequired.Ifriskofinhalationofdustweargeneralpurposedustrespirator(disposable)Handprotection:PVCgloves.Eyeprotection:Dust-tightmonogoggles.Bodyprotection:Standardissueworkclothes.Safetyboots-chemicalresistantwithoutlaceholes.9.PHYSICALANDCHEMICALPROPERTIESPhysicalstate:Whiteorpaleyellowpowder;granularsolidsrForm:GrainColour:WhiteorpaleyellowOdor:Nonirritativeodor.Meltingpoint:NotdeterminedDensity:1.149g/mlBoilingPoint/BoilingRange：473ºCFlammability：FlameretardantDecompositontemperature：NAFlashpoint:>132ºCSolubilityinwater:0.3mg/kg@25℃10.STABILITY/REACTIVITYStability:Stableundernormaluseconditions.Conditionstoavoid:Heat.Strongsunlightforprolongedperiods.Materialstoavoid:Strongacids.Strongoxidisingagents.HazardousPolymerization:NoneDecomposedmaterials:CarbonMonoxideandCarbonDioxide11.TOXICOLOGICALINFORMATIONAcutetoxicity-oral:①LD50>5,000mg/kgrat,female3,563mg/kgrat,male②LD50>1,000mg/kgratAcutetoxicity-dermal:NAEyeirritation:Notirritating.But,thedustorsmallparticlemayirritateeyes.Skinirritation:Notirritating.But,thedustorsmallparticlemayabradeskin.Respiratoryirritation:Notirritating.Skinsensitisation:ABuehlertestforsensitisationintheguineapigwasnegative,butaMagussonandKligmanmaximisationstudyintheguineapigwaspositiveandsothesubstanceisprovisionallyclassifiedasaskinsensitiser.12.ECOLOGICALINFORMATIONMobility:Thesubstanceislikelytodistributebetweentheaquaticandterrestrialenvironmentsinceitispoorlywatersolubleandno-volatile.Degradability:Thesubstanceisnotsubjecttoaerobicbiodegradation.Abioticdegradationintheenvironmentisanticipatedasthesubstancehasbeenshowntohaveashorthalf-life.Accumulation:ThesubstanceisnotlikelytobioaccumulateintheenvironmentbasedonthelogPowvalueof①2.9andaccumulationvalueincarp①<65and②<20.Ecotoxicity:Practicallynon-toxic,LC/EC50>100mg/l,toaquaticorganisms(estimated).TLm48(killfish):①3.6mg/L②>2.0mg/LSewagetreatment:Practicallynon-toxic,EC50>100mg/l,toorganismsinsewagetreatmentplants(estimated).MutagenicityPositivebothintheAmestestandChromosomalaberrationtest.ClassifiedasaCategory3mutagenunderEUcriteria.13.DISPOSALCONSIDERATIONSPrecautions:SeeSection8.RefertoSection7beforehandlingtheproductorcontainers. Wastedisposal:Recoverorrecycleifpossible.Otherwiseincineration,licensedlandfillordisposetolicenseddisposalcontractor.Productdisposal:Recoverorrecycleifpossible.Otherwiseincineration,licensedlandfillordisposetolicenseddisposalcontractor.Containerdisposal:Puncturetopreventre-use.Removeallpackagingforrecoveryorwastedisposal.Disposeasindustrialwaste.14.TRANSPORTINFORMATIONNotdangerousforconveyanceunderUN,IMO,ADR/RIDandIATA/ICAOcodes.Transportationtreatment:Preventhumidityandhightemperature.IATADGR:Notrestricted,asperspecialprovisionIMO:Notrestricted.15.REGULATORYINFORMATIONApplicableRegulations:(Notmeanttobeall-inclusive-selectedregulationsrepresented)NOTICE:Theinformationhereinispresentedingoodfaithandbelievedtobeaccurateasoftheeffectivedateshownabove.However,nowarranty,expressorimpliedisgiven.Requlatoryrequirementsaresubjecttochangeandmaydifferfromonelocationtoanother;itisthebuyer's

responsibilitytoensurethatitsactivitiescomplywithfederal,stateorprovincial,andlocallaws,Thefollowingspecificinformationismadeforthepurposeofcomplyingwithnumerousfederal,stateorprovincial,andlocallawsandrequlations.Seeothersectionsforfealthandsafetyinformation.

US.ToxicSubstancesControlAct

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