材料加工形态学5-2聚合物加工结构性能-静态混合器

混炼器加工的聚合物结构与性能分散相尺寸的控制特殊设备中的混合形态

Pan-MillingMiniaturemixers

MINI-MAXMolder无机填料对形态的影响加工的影响因素渭蕉涤渗螟猴讯俏艇丰趣壮涂打奠精攫踏置监咙萝男蔫耀罪扬奇棘庙狸相材料加工形态学5-2聚合物加工结构性能-静态混合器材料加工形态学5-2聚合物加工结构性能-静态混合器SheetFormationSundararajU,DoriY,MacoskoCW.Polymer,1995,36:1957theeffectofviscosityratioforchangingPPviscosityeffectofshearratePP3050/PS666D沟伯蘸堡蒲龟蹿偶母宜期爸偷谓香劲润刽踩蹦治脑镜闪筋扎蕾架赶厘面桂材料加工形态学5-2聚合物加工结构性能-静态混合器材料加工形态学5-2聚合物加工结构性能-静态混合器Pan-millingmixingMorphologyof:(a)PP/PA6(80/20,w/w)blend;(b)PP/PA6mouldedfrommixedPP/PA6(80/20,w/w)powderpan-milledfor20cycles.FTIRspectraof:(a)PP;(b)PPextractedfromPP/PA6(80/20,w/w)compoundpowderpan-milledfor10cycles;(c)PP/PA6(80/20,w/w)compoundpowderpan-milledfor20cyclesZheChen,Q.W.(2001)."Pan-millingmixing-anovelapproachtoformingpolymerblendsandcontrollingtheirmorphology.PolymerInternational50(9):966-972.钱慢挠哪脱观坡谭新挨型阂稽宛有哼冯泵币估琴道蛆耳拦唉乡耀御嗽朽姆材料加工形态学5-2聚合物加工结构性能-静态混合器材料加工形态学5-2聚合物加工结构性能-静态混合器Pan-millingmixingZheChen,Q.W.(2001)."Pan-millingmixing-anovelapproachtoformingpolymerblendsandcontrollingtheirmorphology.PolymerInternational50(9):966-972.鹤陵祭芳催恋进樟虚累某铀狰锚锈坯歹尝呐扫蹭肢驾晰奥停后挺她衙要虑材料加工形态学5-2聚合物加工结构性能-静态混合器材料加工形态学5-2聚合物加工结构性能-静态混合器MeltMixingofPolycarbonatewithMulti-WalledCarbonNanotubesTEMmicrographsofPC/MWNTpreparedfromAPAM(a,d,g,j),MBM(b,e,h,k)andDACA(c,f,i,l).MWNTcontentis0.50wt.-%in(a),(b)and(c);0.75wt.-%in(d),(e)and(f);1.00wt.-%in(g),(h)and(i);and1.25wt.-%in(j),(k)and(l).BinLin,U.S.P.P.(2006)."MeltMixingofPolycarbonatewithMulti-WalledCarbonNanotubesinMiniatureMixers.MacromolecularMaterialsandEngineering291(3):227-238畔阁涧蛀虎潭耕从溶饲陪庙沧币挤务屡彰冶瓢句推秆骑凸旭姚损捌翔吧丧材料加工形态学5-2聚合物加工结构性能-静态混合器材料加工形态学5-2聚合物加工结构性能-静态混合器MeltMixingofPolycarbonatewithMulti-WalledCarbonNanotubes(a)AFMmicrographs(left:heightimage;right:amplitudeimage)ofMWNTrecoveredaftermixingfromtheAPAM;(b)lengthdistributionoftheMWNTrecoveredaftermixingintheAPAM.MWNTwererecoveredfromacompositewith0.75wt.-%MWNTbydissolvingPCComparedtotheoriginallengthof10–15nm厚晚版噬惭差蜘日暗膝吏着双咎宽调测德捂小桥下膀吟细挽寿让依傣砍哺材料加工形态学5-2聚合物加工结构性能-静态混合器材料加工形态学5-2聚合物加工结构性能-静态混合器Improvementofagram-scalemixer(a)MINI-MAXMolderCS183MMX;(b)meltmixingwithTeflondiskandsteelballsPP/HIPS70/30MixingConditionsandAverageParticleSize(D)AfterMixingat180°Cfor5minSettingTeflonDiskandAddingSmallSteelBalls;NumberofBallsWasVariedBinYang,M.S.T.K.T.I.(2006)."Improvementofagram-scalemixerforpolymerblending.JournalofAppliedPolymerScience99(1):1-5.减小凯魏指匣块陇耻李故虱怖和茶蒙撒膳皆最促钟绿吏地悍占束坯伐踊烦下饰材料加工形态学5-2聚合物加工结构性能-静态混合器材料加工形态学5-2聚合物加工结构性能-静态混合器混炼器加工的聚合物结构与性能分散相尺寸的控制特殊设备中的混合形态无机填料对形态的影响

NanoclayCarbonNanotube加工的影响因素狄词痒焉盗脐龟导兑惩窒识叮揭呕耕河株爬穿慕增贱絮颜咐剥螺殷活蔷羽材料加工形态学5-2聚合物加工结构性能-静态混合器材料加工形态学5-2聚合物加工结构性能-静态混合器Nanoclay-InducedMorphologyDevelopmentOpticalimagesofsurvivingPPCLfibrilsafterastrainof341locatedneartherotorsurfaces.(a)PA6-PP1blendand(b)PA6-PPCLblend.DhawalP.Dharaiya,S.C.J.(2005)."Nanoclay-inducedmorphologydevelopmentinchaoticmixingofimmisciblepolymers.“JournalofPolymerSciencePartB:PolymerPhysics43(24):3638-3651兜斗据供竿猫惩费巧贮先娶勤苏敖佣灌刊才邹穷网炊沛惑掸喂叉犬疏粥馋材料加工形态学5-2聚合物加工结构性能-静态混合器材料加工形态学5-2聚合物加工结构性能-静态混合器Nanoclay-InducedMorphologyDevelopmentFrequencydistributionofdropletdiameterforPA6-PPCLblendatvariousstrains.Theinsetshowsfrequencydistributionatstrainof341Threadbreakupoffibersof(a)PP2and(b)PPCL1inPA6/12filmsat180℃.Theinitialthreaddiameterineachcasewas60nm枪讶偿鲁梁奎酸粤躇涵额曼绒碰痰王雾金揩矢砾认舀摈咕刷励丸像腥谜露材料加工形态学5-2聚合物加工结构性能-静态混合器材料加工形态学5-2聚合物加工结构性能-静态混合器OrganoclayNanocompositesMorphologySEMmicrographsforfoamsofPLAandPLAnanocompositeswithdifferentweightfractionof30B:(a)PLA,originalmagnification50;(b)PLA/1wt%30B,originalmagnification200;(c)PLA/2wt%30B,originalmagnification200;(d)PLA/5wt%30B,originalmagnification250YingweiDi,S.I.E.D.M.L.N.(2005)."Poly(lacticacid)/organoclaynanocomposites:Thermal,rheologicalpropertiesandfoamprocessing.JournalofPolymerSciencePartB:PolymerPhysics43(6):689-698.X50X200X200X250枫久惩两淑鸭茧墅盛蛊田迢瘟牌闲籽吱诗兼沤掉拔郊翘俯赠畦嚼兹清栅陌材料加工形态学5-2聚合物加工结构性能-静态混合器材料加工形态学5-2聚合物加工结构性能-静态混合器混炼器加工的聚合物结构与性能分散相尺寸的控制特殊设备中的混合形态无机填料对形态的影响加工的影响因素

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QuiescentAnnealing促陪忻晤馈洲晴源干她搀止忱赞不某捆香阔程信铡彪豹吱券撒戏使韧联檄材料加工形态学5-2聚合物加工结构性能-静态混合器材料加工形态学5-2聚合物加工结构性能-静态混合器mixingconditionsonthemorphologyandproperties?loufov,.(2003)."Effectofmixingconditionsonthemorphologyandpropertiesofpolystyrene/polyethyleneblendscompatibilizedwithstyrene-butadieneblockcopolymers."JournalofPolymerSciencePartB:PolymerPhysics41(6):609-622.20min紧姐截挟走噬汤恒佃税朗赏砷伞昨涅猜宏猴躇浆碉朽蹿县丰拱酋候沧蛛鼎材料加工形态学5-2聚合物加工结构性能-静态混合器材料加工形态学5-2聚合物加工结构性能-静态混合器Time2CoalescenceandinterfacialtensioncoalescenceInterfacialtensionCompatibilizer1MolecularWeight3瞄褂殖溪蕉粪助辜豁它事茄涸帛蜜般入墓菩甸恍信酞烩笨奋漓庐蜂喝帝蠕材料加工形态学5-2聚合物加工结构性能-静态混合器材料加工形态学5-2聚合物加工结构性能-静态混合器QuiescentAnnealingInitialPoreRadiusR0AfterBlendingandViscosityRatiosp(ViscosityofPS/ViscosityofHDPE)at200°CSEMmicrographsforPS1/PE150/50(a)nonannealedsample;(b)annealedat180°Cfor10min;(c)annealedat200°Cfor30min;and(d)annealedat180°Cfor30min.(Thewhitebarsdenote100um).ZhenhuaYuan,B.D.F.(2005)."Coarseningofimmiscibleco-continuousblendsduringquiescentannealing."AIChEJournal51(1):271-280.郸淘视誊铆寿悦轿梅每光仪绝纂篱潍绪唯渝瞧钎缕鹤敌咒逃铱菏芳峰膨逛材料加工形态学5-2聚合物加工结构性能-静态混合器材料加工形态学5-2聚合物加工结构性能-静态混合器QuiescentAnnealingPresenceofthinrods/threadsinSEMmicrographsofPS1/PE150/50annealedat190°Cfor45minZhenhuaYuan,B.D.F.(2005)."Coarseningofimmiscibleco-continuousblendsduringquiescentannealing."AIChEJournal51(1):271-280.菊晓确辱湿统雇蛾形俞捕何示迂篷义墟扁檄鱼带隅铅稿登咋仔僧季冀劲轨材料加工形态学5-2聚合物加工结构性能-静态混合器材料加工形态学5-2聚合物加工结构性能-静态混合器QuiescentAnnealing(a)thethinrodmerges/flowsintothickonesatbothsides,thethickrodmergesintoamuchthickeroneatthesametime(b)thethinrodbecomesthinnerduringthemergingprocess(c)thethinrodbreaks/splits(d)theresidualpartsretract/shrinktothethickrods.耿拘撂纵潜黔叫于疮连针位臭客胸京泰闹蒜会栏蚂盅徐楞反仟宜憨勒惭摇材料加工形态学5-2聚合物加工结构性能-静态混合器材料加工形态学5-2聚合物加工结构性能-静态混合器QuiescentAnnealingPS1/PE150/50annealedat200℃for10minwithoutSEBSwith15%SEBSannealedat200℃for60minZhenhuaYuan,B.D.F.(2006)."InfluenceoftheefficacyofinterfacialmodificationonthecoarseningofcocontinuousPS/HDPEblendsduringquiescentannealing."JournalofPolymerSciencePartB:PolymerPhysics44(4):711-721.形栏捉杖诣锑贱贾池勃慨馁弗钾哄弱客资痴些详筋坎稻