中国科学院-中国科学技术大学2000年有机化学（含答案）考研真题

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᳝ᴎ࣪ᄺ

ϔ,ᅠ៤ডᑨ,䇋⊼ᯢゟԧ࣪ᄺ䯂乬:(31ߚ)

COCl

NH3NaOBr

1.??

H3O

2.+C2H5MgX?

ROO

NH2

OHFeCl3

3.?

RCOO

4.(C6H5)3PCH(CH2)3COC6H5?

1.Э䝮

CH3COCH2COC2H5+(CH3)2Cd?

5.2.H

CH2OHCH2O

HOHHOHCHPh

6.?Pb(OAc)4

HOHHO?

HOHHOH

CH2OHCH2OH

ClCl

7.?

HH

OAc

8.+CH2=CHCHO?

O

LiAlH4

9.(CH3)3CCH3?

t-BuOH

CH3

NH2

10.HO+CH2=CO?

CHCl3/NaOHAg2OCH2N2

11.OH???

CH3SO2ClPhCOO

12.R-ч䝌Э䝃??

NH2

䖛䞣CHIH2O2

3?

13.CH3

OH

BrC2H5COClAlCl3Br2

14.???

৵୊

14AlCl3

15.PhCH2CH2Cl+PhOCH3?

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Br2OH

16.??

OO

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HCl

1.C2H5SCHCH2OHC2H5SCH2CHClCH3

CH3

Cl

OCHCl

2.3

COClCOOCH3

3.ᅠ៤ডᑨˈᑊᣛߎ݊ग़⿟˖

H2ˋPt

Į-⬆㛎෎㣃ϭ䝂?

95ˁЭ䝛

ClCOCH3

OH

4.CH3?



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COCHC(CH)=CHCOOH

1.33

OO

2.

CH2NCH3CH2

CH3NH2

3.

NN

CHO

CH3O

4.N

OCH3COOH

COOH

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中科院2000试题解答

一、

OHO

OH3.O

1.CONH2、NH22.R

EtEt

RCO2

OH

CH2O

4.Ph

(CH)CCHCOCHHO

*5.3222256.PhCHO、O+HCHO

C6H5

CHO

ClOAcOH

H

CHO10.

7.8.9.

ClOHNHAc

CHOCOHCOCH

11.2*23

OH、OH、OH

COCHCOCH

225225

12.HOTs13.

、PhCO2H

CHCH

3CH33

OO

OOHOHOH

OCCHOH

25BrCHCBrBrBr

BrCHCBr25

14.25、+

、+

COCHCOCH

25Br25

OMeOMe

15.

+16.

14OCOH

14CH2

CH2CH2Ph2CH2Ph

二、1.CH

3..+-HO

HCl2

C2H5SOH

C2H5SCHCH2OH2NGP

CH

+3

CHS

25Cl

C2H5SCH2CHCH3

Cl

CH3

2.

1

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3.H

NCH

CH3O3

O

HNHCH3H

HNHCH32

Pt

O

MePhHMe

PhPh

NHCH

CH33

HOH

HNHCH3

HOH

HMe

PhPh

4.

三、

O+PhOHiNaOH,HO

1.BrCH2CO2EtH3O2

+TM

COEt△

PhZn,Et2O2iiH

OO

2.CHI

3iAg2O,H2O

N(CH)+TM

32△

N(CH3)3ii

3.CH3KMnOCOOHiSOClCONH2

42NaOBrTM

iiNH

NN3N

4.

2

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CH(COEt)

5.EtONa22

2CH(COEt)BrBr

222+CH(COEt)

22

iiIiNaOEt

2

CO2Et

iNaOH,HOCOEt

22

TM+COEt

iiH△2

CO2Et

四、

1.OMeOOO

AB

ABONCH(COEt)HONC(COEt)

2..CH2(CO2Et)2.22C.22

DE.PhCHC(COEt)F.PhCHCHCO