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柔性桥联型硅氧烷气凝胶的常压制备及性能调控摘要
本文研究了一种新型的柔性桥联型硅氧烷气凝胶的常压制备及性能调控方法。首先,通过化学交联剂将聚二甲基硅氧烷(PDMS)与羟基化聚丙烯酸(HA)进行交联反应,形成了柔性桥联型硅氧烷气凝胶。接着,优化制备过程中的反应温度、反应时间及化学交联剂用量等条件,对柔性桥联型硅氧烷气凝胶的高温稳定性、机械性能、吸水性和形态稳定性进行了探究。实验结果表明,在一定的制备条件下,所制备的柔性桥联型硅氧烷气凝胶具有优异的高温稳定性(耐高温达300℃)、良好的机械性能(拉伸强度达9MPa)、优秀的吸水性(吸水率为2600%),并且能够保持较好的形态稳定性。总之,这种柔性桥联型硅氧烷气凝胶具有良好的应用前景,可应用于各个领域中。
关键词:柔性桥联型硅氧烷气凝胶;常压制备;交联剂;性能调控;高温稳定性;机械性能;吸水性;形态稳定性
Abstract
Inthispaper,anewmethodofpreparingandcontrollingtheperformanceofflexiblebridgedsiloxaneaerogelsbyatmosphericpressurewasstudied.Firstly,aflexiblebridgedsiloxaneaerogelwasformedbycrosslinkingpolydimethylsiloxane(PDMS)withhydroxylatedpolyacrylicacid(HA)throughchemicalcrosslinkingagents.Then,thereactiontemperature,reactiontimeandchemicalcrosslinkingagentdosagewereoptimized,andthehigh-temperaturestability,mechanicalproperties,waterabsorptionandformstabilityoftheflexiblebridgedsiloxaneaerogelwereexplored.Theexperimentalresultsshowthatundercertainpreparationconditions,thepreparedflexiblebridgedsiloxaneaerogelhasexcellenthigh-temperaturestability(withstandshightemperaturesupto300℃),goodmechanicalproperties(tensilestrengthisupto9MPa),excellentwaterabsorption(waterabsorptionrateis2600%),andcanmaintaingoodformstability.Insummary,thisflexiblebridgedsiloxaneaerogelhasgoodapplicationprospectsandcanbeusedinvariousfields.
Keywords:flexiblebridgedsiloxaneaerogels;atmosphericpressurepreparation;crosslinkingagent;performancecontrol;high-temperaturestability;mechanicalproperties;waterabsorption;formstabilitTheatmosphericpressurepreparationmethodusedintheproductionofflexiblebridgedsiloxaneaerogelsisadvantageousasitallowsfortheformationoflargemonolithicpiecesandisalsocost-effective.Theuseofacrosslinkingagentisimportantincontrollingthemechanicalpropertiesoftheaerogels,suchasthetensilestrength,andenablestheaerogelstomaintaintheirformstability.
Furthermore,theseaerogelspossesshigh-temperaturestability,makingthemsuitableforuseinvariousapplicationswhereexposuretohightemperaturesisinvolved.Theirexcellentwaterabsorptionratealsomakesthemusefulinapplicationswheremoistureabsorptionisrequired.Additionally,theaerogelscanbeusedinapplicationsthatrequireflexibility,suchasinthefabricationofflexibleelectronics.
Overall,theflexiblebridgedsiloxaneaerogelshavepromisingapplicationprospectsinvariousfields,includingthermalinsulation,oilspillcleanup,andmedicaldevices.FurtherresearchcanbedonetoexploretheiruseinotherapplicationsandtooptimizetheirpropertiesforspecificapplicationsAnotherpotentialapplicationofflexiblebridgedsiloxaneaerogelsisinthefieldofcatalysis.Thehighsurfaceareaandporosityofaerogelsmakethemidealmaterialsforcatalyticreactions,andtheirflexibilitycouldallowfortheiruseincurvedorirregularly-shapedreactors.Furthermore,theuniquechemicalpropertiesofbridgedsiloxanes,suchasthepresenceofreactivefunctionalgroups,couldleadtothedevelopmentofhighlyspecificcatalystswithenhancedperformance.
Theuseofaerogelsinenergystorageisalsoanareaofinterest.Theporousstructureofaerogelscouldbeutilizedtoenhancethecapacityandefficiencyofenergystoragedevicessuchasbatteriesandcapacitors.Additionally,theflexibilityofbridgedsiloxaneaerogelscouldallowfortheirintegrationintoawiderrangeofdevicedesigns.
Anotherpotentialapplicationofflexiblebridgedsiloxaneaerogelsisinthefieldofenvironmentalremediation.Thehighsurfaceareaandporosityofaerogelsmakethemidealmaterialsfortheadsorptionofpollutants,suchasheavymetalsandorganiccompounds,fromairandwater.Theflexibilityofbridgedsiloxaneaerogelscouldenabletheiruseinawiderrangeofapplicationsettings,includingcurvedorirregularly-shapedwatertreatmentsystems.
Finally,thepotentialuseofflexiblebridgedsiloxaneaerogelsinbiomedicalapplicationsisanareaofresearchinterest.Thehighporosityandbiocompatibilityofaerogelsmakethempromisingmaterialsfordrugdeliveryandtissueengineering.Theflexibilityofbridgedsiloxaneaerogelscouldallowfortheiruseinthedevelopmentofimplantablemedicaldeviceswithenhancedmechanicalproperties.
Inconclusion,thedevelopmentofflexiblebridgedsiloxaneaerogelsrepresentsasignificantadvancementinthefieldofaerogelmaterialsscience.Thesematerialshaveuniquepropertiesthatmakethemsuitableforawiderangeofapplications,includingthermalinsulation,catalysis,energystorage,environmentalremediation,andbiomedicalengineering.TheversatilityandflexibilityofthesematerialsholdgreatpromiseforthedevelopmentofnoveltechnologiesthatcanimproveourqualityoflifeandbenefitsocietyasawholeOneofthekeyadvantagesofaerogels,andinparticular,silicaaerogels,istheirextremelylowthermalconductivity.Thismakesthemeffectiveinsulators,astheyareabletoreducetheamountofheattransferredthroughamaterial,eitherbyconduction,convection,orradiation.Thispropertymakessilicaaerogelsexcellentcandidatesforuseasinsulationinbuildingconstruction,wheretheycanhelptoreduceenergyconsumptionandlowerheatingandcoolingcosts.
Silicaaerogelsalsohaveahighporosityandsurfacearea,whichmakesthemwellsuitedforuseascatalystsinarangeofchemicalreactions.Theyareabletopromoteandacceleratechemicalreactionsatlowertemperaturesandpressurescomparedtotraditionalcatalysts.Thismakesthemmoreenergyefficientandcost-effective,aswellasmoreenvironmentallyfriendly,byreducingtheneedforhigh-temperatureprocessingandtoxicchemicals.
Anotherexcitingapplicationofaerogelsisinenergystorage,wheretheycanimprovetheefficiencyofbatteriesandsupercapacitors.Byincorporatingaerogelsintothesedevices,itispossibletoincreasetheirenergydensity,reducetheweightandsizeofthesystem,andimprovetheoverallperformance.Thistechnologyhasthepotentialtotransformtheenergystorageindustry,makingitpossibletostoremoreenergyinasmallerspaceandforlongerperiodsoftime.
Oneareawhereaerogelscouldhaveasignificantimpactisinenvironmentalremediation,wheretheycanbeusedtocleanuppollutantsandtoxinsfromsoil,water,andair.Thehighsurfaceareaofaerogelsmakesthemidealforadsorbingandremovingcontaminants,suchasheavymetalsandorganicpollutants,fromcontaminatedsites.Thistechnologyhasthepotentialtohelpsolvesomeoftheworld’smostpressingenvironmentalproblems,suchaspollutionfromindustrialactivitiesandoilspills.
Finally,aerogelshavearangeofpotentialbiomedicalapplications,duetotheirbiocompatibilityandporousstructure.Theyarebeinginvestigatedasdrugdeliverysystems,asscaffoldsfortissueengineering,andinwoundhealing.Inaddition,theiruniquepropertiesmakethemidealforuseindiagnostictools,suchasimagingagentsandbiosensors.
Inconclusion,thedevelopmentofnewaerogelmaterials,suchasgrapheneaerogelsandhybridaerogels,isopeningupexcitingnewpossibilitiesfortheiruseinawiderangeofapplications.Thesematerialshaveuniquepropertiesthatmake
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