油基钻井液用有机土 编制说明

《油基钻井液用有机土》编制说明 1 4.编制原则、相关标准情况、标准检验 1本标准来源于2023年第四批推荐性国家标由TC355（全国石油天然气标准化技术委员会）归口，越来越高，对油基钻井液处理剂的质量和有效遴选着我国环保法律法规的要求日益提高，评价有机土用低于柴油中的含量，因此在白油中有机土更不易23.起草工作简要过程有限公司勘探开发研究院、中国石油集团工程技术研究院），3过程中要求样品为25kg袋装，降低了针对性送样影4.编制原则、相关标准情况、标准检验项目的确定各项检测实验操作简单可行，便于各油田实验室开的牌号为W1-110的白油。W1-110馏程、黏度区间窄，组分相对简单，有利于取得稳定的实验评价数据，同时，W1-110在中石油、中海油均有较为广泛的应用，综合上述），4Q/SY17817-2021针对油基钻井液用有机土，制订了相应的理化井液用有机土PF-MOGEL制订了相应的理化性能技针对油基钻井液用有机土，制订了基于低温（3其他民营企业的企业标准则参差不齐。总的来说，中石油和中石化产品标准相对接近，可达到同等的提切效果，浪费了大量成本；另一方面，由于低质有机土的使用和累积，1有机膨润土52油基钻井液用有机土技术规范Q/SY17817-20213油基钻井液用有机土技术要求Q/SHCG0190-2023（中石化）4钻井液用有机土PF-MOGELQ/HSYFOC027—20215油基钻井液用有机土Q/ZFH03-20216油基钻井液用增粘剂有机土PLH-OCQ/12DGPLH02-20177油基钻井液用有机土Q/0305ZLJ001-20188油基钻井液用增粘剂改性有机土HFISQ/74961404-7.66-20179油基钻井液用增粘剂改性有机土ZR-02Q/91510681777452735M.35-2018油基钻井液用增粘剂有机土TYODF-601Q/KTYC049-2018油基钻井液用提粘剂有机土LH-OCQ/LHSY0028-2017油基钻井液造浆用有机膨润土CNLQ/915108246922987249-2017油基钻井液用有机膨润土Q/SH1170053-2017油基钻井液用提粘剂改性有机土HYOTQ/WNZJ-034-2018油基钻井液用有机土ZD-JHAQ/ZDSY008-2017白油基钻井液用有机土Q/GWDC0073-2017油基钻井液用增粘剂有机土TYODF-601Q/KTYC049-2018油基钻井液用提切剂有机土BZ-OCQ/12SYBHZ1002-2016油基钻井液用有机土MOGELQ/JHK1018-2018油基钻井液用提粘剂改性有机土(HYOT)Q/WNZJ-034-2015油基钻井液用有机土活化蒙脱石JX-GELQ/KJX12-2019油基钻井液造浆用有机土（HFEL）Q/74961404-7.55-2014有机土MOGELQ/JJH26-2015钻井液用有机土改性膨润土ATOQ/KOZ-013-2018油基钻井液用增粘剂有机土TYODF-601Q/KTYC049-2016编号标准名称评价项目技术要求1Q/SHCG0190-2023（中石化）外观灰白色或浅黄色粉末水分，%≤4.0筛余量（筛孔孔径74µm），%≤4.0灼烧失量，%27.0~40.06编号标准名称评价项目技术要求），70.0/室温120℃老化16h表观黏度，mPa·s≥动切力，Pa≥2.03.0动塑比，Pa/mPa·s≥0.300.30R3读值≥2.03.0API滤失量，mL≤8.08.0*注：白油基有机土采用5号白油作为基础油进行测试2Q/SY17817-2021（中石外观灰白色或浅黄色粉末烘失量，%≤4.0筛余量0.074mm（200目），%≤4.0灼烧残渣，%58.0～70.0堆积密度，g/cm30.40～0.55≥70.0/热滚前120℃热滚后3r/min读值≥2.0≥3.0动切力，Pa≥2.0≥3.0动塑比，Pa/(mPa·s)≥0.30≥0.30滤失量，mL≤8.0≤8.0白油基有机土采用5号白油，柴油基有机土采用0号柴油3Q/HSYFOC027-2021（中海油）外观灰白或白色自由流动粉末水分，%≤5细度（100目），%≥95塑性粘度（120℃老化后），mPa·s≤13动切力（120℃老化后），Pa≥36转读数（120℃老化后）≥44Q/ZFH03-2021（浙江丰外观自由流动固体粉末水份，%≤5.0≤5.0/柴油基有机土有机土胶体率（span80），%≥95.0≥95.0表观粘度，mPa·s≥8.0≥8.0动切力，Pa≥1.5≥1.5R3读数≥1.5≥1.5序号外观水分筛余胶体率表观粘度，mPa.塑性黏度，mPa.动切力，Pa6r/min稳定性,滤失量，mL灼烧失重动切力提动塑比7ssV高率数量21614312占比70.83%87.50%75.00%66.67%54.17%54.17%62.50%25.00%4.17%%%4.17%8.33%（74μm）标准筛测试试样的筛余量，有利于有机土利用要用到大量水，为考核产品有效成分含量，拟设置烘8）；m1——烘前试样质量加称量瓶质量，单位）；9样品编号105℃烘失量，%170℃烘失量，%①②平均值平行允差①②平均值平行允差2.742.952.80.217.136.496.80.642#3.032.792.90.246.276.356.30.083#2.732.732.707.297.757.50.464#0.237.217.207.20.015#2.312.482.40.176.155.960.196#2.903.300.408.207.607.90.607#3.464.013.70.557.847.50.730.457.727.757.70.039#3.343.523.40.187.577.597.60.023.683.613.60.077.007.767.40.763.133.763.40.637.297.257.30.042.923.290.376.316.486.40.173.723.673.70.056.345.996.20.353.783.713.70.077.007.187.10.182.492.822.70.337.617.677.60.062.252.392.36.195.505.80.692.302.272.30.036.676.906.80.230.285.706.316.00.613.663.613.60.056.796.816.80.0220#4.244.274.30.03————21#4.254.284.30.03————22#4.304.314.30.01 23#2.972.922.90.05 24#5.425.555.50.13————25#4.043.874.00.17————26#0.01 ①②123456789此以此以74μm标准筛测试试样的筛余量。拟定以下实验方法：不再有试样通过时为止，将标准筛上部的试样倒出X——筛余量；）；样品编号筛余量，%①②平均值平行允差2#0.020.030.00.013#0.880.940.90.064#0.640.540.60.105#2.162.10.046#2.312.482.40.177#3.583.343.50.242.542.502.50.049#0.012.742.622.72.922.882.90.043.643.753.72.822.802.80.020.130.040.440.420.40.022.732.752.70.022.912.882.90.033.003.063.00.0620#3.984.044.00.0621#4.284.204.20.0822#5.265.185.20.0823#2.702.792.70.0924#4.644.754.725#2.882.752.80.1326#4.784.824.80.04样品编号筛余量，%①②平均值12.532.512.52样品编号筛余量，%①②平均值23.233.223.23342.522.482.5053.603.583.59672.502.462.4882.202.232.2292.542.522.534.804.754.783.152.312.482.403.583.343.462.542.502.522.742.622.682.922.882.903.643.753.702.822.802.81203））；m6——灼烧后瓷坩埚加残渣的质量，单位可知：1）700℃灼烧，75%样品灼烧残渣介于60根据试验数据得出，700℃和900℃两个温度下，灼烧残渣的结果变确定灼烧残渣的温度为700℃。对收集到的26个样品在样品编号灼烧失量，%①②平均值平行允差39.2739.3339.30.062#40.7340.740.70.033#33.9634.1344#36.1936.3936.30.25#38.3138.4138.40.16#33.0733.0933.10.027#33.7733.7533.80.0238.1337.94380.199#33.233.1733.20.0332.7732.8132.80.0433.9634.13340.1733.5333.4733.50.0629.629.6329.60.0329.4629.5129.50.0538.4638.5738.537.437.3537.40.0537.6437.6337.60.0135.5235.5735.50.0536.2736.2636.30.0120#33.1733.1833.20.0121#34.9435.9735.522#32.6332.8132.70.1823#29.6330.4300.7724#37.3337.5437.40.2125#39.7740.22400.4526#35.3735.3935.40.02编号灼烧失量，%①②平均值138.6138.6238.62231.0131.0331.04332.0332.08439.4039.3539.38531.7131.7931.75629.6229.6429.63732.1932.2432.22835.0535.0535.05930.3230.4030.3628.3228.2228.2732.6032.6532.62密度样品编号有机土在5#白油中胶体率，%有机土在0#柴油中胶体率，%50℃65℃120℃150℃50℃65℃120℃150℃175939998240699565979596953262730314303136375719598989868.4—909292—78.29 69 82827.531—929892.5—98.59.57—91.547.5—8—9492.5—232228—9077—58298—90—724359—90 71 586058—356—373256—40464545737894—20252934—253936—202428242421222730332288823232124212528289393939025314058382636353642V——90min时量筒上部析出的游离油体积，单位为毫升（m表13有机土样品胶体率初步测试（号四川0号柴油1234567895②采用北京、四川、山东不同地域市售0号柴油进行的胶体率实验数据分析，在室率同比四川高25%~64%；120℃老化后，表现出同样的胶体率规律，表明不同地域间0采用北京市售0号柴油胶体率≥85%样品有2种，占采用四川德阳市售0号柴油胶体率≥85%样品 采用山东德州市售0号柴油胶体率≥85%样品有③在中海油服实验室，取8#和11#有机土样品，采用不同地域的柴油在中海油服实%验。中石油工程院实验中，有4个样品升温至150℃后，胶体率上升，1个样品升温后降降低地域间柴油油品质量对胶体率的影响，胶体率≥70%作为胶体率指标，白油基有机土胶体率≥编号胶体率（%）120℃150℃180℃1959429290753384935426377874883346589643834209090编号胶体率%120℃150℃180℃192942949075345716556558779727086570689443224333025757970编号胶体率%120℃150℃180℃199999927578374493570756564569577777487953931285850457073性明显低于柴油，有机土在白油中胶体率较低编号胶体率（%）常温120℃150℃180℃1282823238492225235667768897597表193#白油老化后胶体率（编号胶体率（%）120℃150℃180℃1232128342123215697898788编号胶体率%120℃150℃180℃12129739994599967877888898875549在柴油中加入0.5%乙醇，测试室温下流变），中6.3方法测定基浆和试验浆在25℃±1℃下动切力、动塑比和Φ3读值。样品编号5#白油老化条件φ600φ300AVPVYP，PaYp/PV,Pa/mPa.sφ3HTHP,mL0#25.50.70.060-常温25.50.70.060全滤150℃/16h794639.5336.50.206-常温6757470.216.538150℃/16h2#664333230.437-常温样品编号5#白油老化条件φ600φ300AVPVYP，PaYp/PV,Pa/mPa.sφ3HTHP,mL412220.50.08156150℃/16h5#714235.5296.50.224.5-常温985949390.266.036150℃/16h97.55443.50.8147-常温276500.5766太稠，无滤液150℃/16h76.548.538.2280.379.0-常温90.550.045.240.54.83.062150℃/16h936741260.6323-常温>300231////52.0150℃/16h样品编号0#柴油老化条件φ600φ300AVPVYP，PaYp/PV,Pa/mPa.sφ3HTHP,mL0#65410.250-常温5.554.50.50.5全滤150℃/412620.55.50.375-常温654132.5248.50.35735150℃/2#35245.50.506-常温86.550.300.274150℃/5#362240.295-常温5635282170.33539150℃/7#83.560.541.8230.7826-常温22521097.56.2424150℃/52352690.518-常温样品编号0#柴油老化条件φ600φ300AVPVYP，PaYp/PV,Pa/mPa.sφ3HTHP,mL6144270.6024150℃/9#7454.5370.8620-常温7232.539.56436150℃/91.565.545.8260.7623-常温>300236////9820150℃/614430.50.85-常温90664524210.8832150℃/77.053.538.523.50.64-常温71.537.034.50.9371.026.0150℃/48.530.024.25.80.315.5-常温74.051.529.022.50.7826.033.6150℃/老化和滚动老化条件，分别测流变性和中压滤失量；②120℃/），加样量Φ600Φ300Φ3AVPVYPYP/PVAPIFL,mL2%0.58.570.2143%24.529.52.750.293.44%42.529821.257.750.575%532441290.413.2加样量Φ600Φ300Φ3AVPVYPYP/PVAPIFL,mL2%9187143%2320.152.34%34213.540.3135%654632.50.712.1加样量Φ600Φ300Φ3AVPVYPYP/PVAPIFL,mL2%9.5186.50.232.33%21282.50.314%35234.55.50.465%644432200.6加样量Φ600Φ300Φ3AVPVYPYP/PVmL2%9.5186.50.23223%25393.50.392104%4932824.57.50.445%7854.53923.50.66b）柴油中有机土加量测试实验化和滚动老化条件，分别测流变性和中压滤失量；②120℃/16加样量Φ600Φ300Φ3AVPVYPYP/PVAPI2%86420.54.63%203730.434.24%372687.50.684.45%624821314.1加样量Φ600Φ300Φ3AVPVYPYP/PVAPI2%75.540.385.53%2.58620.334.74%33237.56.50.654.55%564333283.8加样量Φ600Φ300Φ3AVPVYPYP/PVAPI2%6.515.2540.315.93%38530.65.24%3322.5760.575.05%503820255.2加样量Φ600Φ300Φ3AVPVYPYP/PVHTHP2%86.550.303%2247.53.50.474%5036250.795%66494224208滚后的性能测试条件为65℃±1℃。滚16h前后的65℃下的流变性和中压滤失量，实验3测试温度65℃±1℃34试温度度65℃±1℃385测试温度65℃±1℃55试温度度65℃±1℃2测试温度65℃±1℃试温度度65℃±1℃9测试温度65℃±1℃98试温度度65℃±1℃764测试温度65℃±1℃9试温度度65℃±1℃4测试温度65℃±1℃77试温度度65℃±1℃86420987动切力，Pa动切力，Pa5432100.40.30.20.10.0中压滤失量，mL中压滤失量，mL543210mm热滚前量样品编号φ600φ300φ3AVPVYPPaYp/PVPa/mPa.sFL,mL实验条件29.572.50.364.7测试温度65℃±1℃2237.53.50.475.7试温度度65℃±1℃2#2.57.254.52.750.613.5测试温度65℃±1℃24.54.57.54.750.635.6试温度度65℃±1℃5#8.7570.254.4测试温度65℃±1℃2.59.7572.750.395.8试温度度65℃±1℃7#3827880.734.4测试温度65℃±1℃4028.5208.50.743.8试温度度65℃±1℃234.574.50.644.5测试温度65℃±1℃213.56.540.625.2试温度度65℃±1℃9#422992180.625.5测试温度65℃±1℃3625.59.57.50.716.5试温度度样品编号φ600φ300φ3AVPVYPPaYp/PVPa/mPa.sFL,mL实验条件65℃±1℃42292180.624.7测试温度65℃±1℃47.53323.89.20.634.8试温度度65℃±1℃30.5216.59.55.750.614.5测试温度65℃±1℃31.5227.59.56.20.655.6试温度度65℃±1℃2.57.7552.750.553.7测试温度65℃±1℃3926.5670.567.7试温度度65℃±1℃18.256.50.277.1测试温度65℃±1℃730.53.54-0.5-全滤失试温度度65℃±1℃24#213.574.50.645.2测试温度65℃±1℃38.862.70.456.2试温度度65℃±1℃φ3读值86420图18柴油中有机土热滚前、后φ3读值动切力，Pa98765432100.70.60.50.40.30.20.10.01#2#5#7#8#9#10#12#17#24#中压滤失量，mL876543210mm热滚前1#2#5#7#8#9#10#12#17#24#量），项目技术要求白油基钻井液用有机土柴油基钻井液用有机土外观灰白色或浅黄色粉末灰白色或浅黄色粉末烘失量，%≤4.0≤4.0筛余量，%≤4.0≤4.0灼烧残渣，%58.0～70.058.0～70.0堆积密度，g/cm3≤0.55≤0.55胶体率，%≥70.0≥70.0室温Φ3读值≥2.0≥2.0动切力，Pa≥2.0≥2.0动塑比，Pa/mPa.s≥0.30≥0.30API滤失量，mL≤8.0≤8.0120℃热滚Φ3读值≥3.0≥3.0动切力，Pa≥3.0≥3.0动塑比，Pa/mPa.s≥0.30≥0.30API滤失量，mL≤8.0≤8.0注：流变性测试温度65℃±1℃。将上述配制好的柴油胶体溶液，装入高温不锈钢罐中，充氮气至1MPa，持续时间好分散及成胶能力，其他测试样品在柴油中分散性较差，编号120℃老化R600R300R6R3AVPVYPPa动塑比1老化前2255740.57老化后217.5764.50.752老化前73003.54//老化后73003.54//3老化前5005.0500.00老化后6105.0410.254老化前84004.0400.00编号120℃老化R600R300R6R3AVPVYPPa动塑比老化后95004.540.50.135老化前95004.540.50.13老化后7005.540.386老化前63003.0300.00老化后63003.0300.007老化前74003.530.50.17老化后5105.0500.008老化前84004.0400.00老化后5005.0500.009老化前84004.0400.00老化后73003.54//老化前95004.540.50.13老化后6105.550.50.10老化前95004.540.50.13老化后5005.0500.00老化前215473.50.50老化后2076730.43老化前63003300.00老化后84004400.00老化前74003.530.50.17老化后5105500.00老化前74003.530.50.17老化后95104.540.50.13老化前73003.54-0.5-0.13老化后95004.540.50.13老化前73003.54-0.5-0.13老化后84004400.00老化前84004400.00老化后6105410.25老化前73003.54-0.5-0.13老化后95004.540.50.1320老化前95004.540.50.13老化后5105500.00编号120℃老R600R300R6R3AVPVYPPa动塑比1老化前328620.33老化后559540.82老化前5005500老化后6105410.253老化前84004400编号120℃老R600R300R6R3AVPVYPPa动塑比老化后95004.540.50.134老化前95004.540.50.13老化后7005.540.385老化前74003.530.50.17老化后51055006老化前73003.54--老化后73003.54--7老化前84004400老化后840044008老化前63003300老化后630033009老化前73003.54--老化后73003.54--老化前63003300老化后63003300老化前84004400老化后5005.0500老化前327.552.50.50老化后548.562.50.42老化前63003.0300.00老化后74003.530.50.17老化前74003.530.50.17老化后85104.0310.33老化前74003.530.50.17老化后95104.540.50.13老化前73003.54-0.5-0.13老化后95004.540.50.13老化前73003.54-0.5-0.13老化后84004.0400.00老化前84004.0400.00老化后6105.0410.25老化前73003.54-0.5-0.13老化后84004.0400.0020老化前84004.0400.00老化后95104.540.50.13AV=R600（5）PV=R600−R300（6）YP=R300−AV（7）Rdp=YP（8）R600——六速旋转黏度计600r/min的读数；R300——六速旋转黏度计300r/min的读数；YP——动切力，单位为帕（Pa）；PV——塑性黏度，单位为毫帕秒（mPa•s）；测出数据。表明，采用不同炼化公司的柴油，有机土在其中的增粘提切效果有所区别，从实验数据看，在四川老化前后流变参数明）；根据实验分析，Span80作为乳化剂，抗温作用有限，Span8表36柴油基钻井液高温流变性实验（编号老化R3AVPVYPPa动塑比FLAPImL1老化前283.50.445.4120℃老化65.00.506.0150℃老化25.09.00.566.8180℃老化23.58.50.577.22老化前54.00.405.4120℃老化44.50.455.8150℃老化34.0200.707.4180℃老化动3老化前2.594.00.446.4120℃老化34.00.405.8150℃老化927.50.628.0180℃老化动4老化前395.50.616.0120℃老化34.00.40150℃老化27.59.50.53180℃老化动5老化前294.00.445.8120℃老化55.00.507.2150℃老化26.50.668.2180℃老化30.0200.507.86老化前2.54.00.366.6120℃老化55.00.427.0编号老化R3AVPVYPPa动塑比FLAPImL150℃老化2238.5260.489.2180℃老化动7老化前55.50.462.4120℃老化822.58.50.615.8150℃老化33.5249.50.408.6180℃老化46.5310.509.48老化前295.00.564.4120℃老化65.00.455.4150℃老化22.08.00.577.8180℃老化27.50.628.69老化前584.50.565.2120℃老化86.50.546.8150℃老化43.5300.457.5180℃老化动老化前273.00.437.2120℃老化34.00.406.6150℃老化21.07.00.50180℃老化动老化前394.00.445.8120℃老化55.50.557.0150℃老化520.56.50.468.4180℃老化334.0230.48表37柴钻井液高温流变性实验（编号老化温度Φ3AVPVYPPa动塑比FLAPImL1老化前34.50.454.9120℃老化76.00.466.8150℃老化25.50.707.5180℃老化无法流动2老化前44.00.364.0120℃老化25.50.707.2150℃老化25.08.02.138.3180℃老化无法流动3老化前45.00.454.0120℃老化922.58.50.616.4150℃老化935.021.00.678.6180℃老化无法流动4老化前820.55.50.37编号老化温度Φ3AVPVYPPa动塑比FLAPImL120℃老化30.50.61150℃老化28.50.68180℃老化无法流动5老化前29.57.02.50.363.2120℃老化39.03.50.394.8150℃老化923.57.50.478.0180℃老化31.021.00.487.56老化前27.03.50.504.0120℃老化55.50.506.9150℃老化3341.026.00.588.6180℃老化无法流动7老化前39.04.00.443.7120℃老化820.56.50.466.4150℃老化36.024.00.509.5180℃老化2050.535.00.448老化前58.05.50.694.9120℃老化26.521.05.50.267.0150℃老化26.00.637.6180℃老化26.00.639老化前43.50.324.0120℃老化25.00.676.6150℃老化2548.533.00.478.3180℃老化无法流动老化前55.50.466.0120℃老化722.57.50.507.4150℃老化5544.024.020.00.839.6180℃老化无法流动老化前33.50.355.2120℃老化55.00.367.0150℃老化35.024.00.468.2180℃老化无法流动老化前17.56.00.25120℃老化49.05.00.566.6150℃老化29.00.179.4180℃老化0.59.08.00.13表38柴油基钻井液高温流变性实验（中石编号老化温度Φ3AVPVYPPa动塑比FLAPImL1老化前394.50.505.4120℃老化340.366150℃老化230.924.4编号老化温度Φ3AVPVYPPa动塑比FLAPImL180℃老化无法流动2老化前43.50.327.2120℃老化280.756.8150℃老化无法流动180℃老化无法流动3老化前340.405.8120℃老化280.659.2150℃老化无法流动180℃老化无法流动4老化前550.505.4120℃老化26.50.6637150℃老化32200.6046180℃老化无法流动5老化前2.5830.387.4120℃老化77.50.686.5150℃老化26.50.778.4180℃老化32.5200.639.26老化前3760.867120℃老化280.567150℃老化2036210.71180℃老化无法流动7老化前2940.447.2120℃老化550.507.4150℃老化无法流动180℃老化无法流动8老化前44.50.456.8120℃老化270.937.2150℃老化290.718.3180℃老化32.50.919老化前560.506120℃老化290.819150℃老化无法流动180℃老化无法流动老化前29630.508.2120℃老化24.59.50.639150℃老化无法流动180℃老化无法流动老化前340.367120℃老化922.58.50.618150℃老化250.798.5180℃老化无法流动120℃、150℃、180℃的流变性和滤失量。流变性与柴油基）；），），Φ3≥3（90%），API滤失量≤8mL（7表39白油基钻井液高温流变性实验（FLAPI278358动35动582445动3动3246动FLAPI348动25动表40白油基钻井液高温流变性实验（编号老化温度Φ3AVPVYPPa动塑比FLAPImL老化前2930.336120℃老化55.50.509150℃老化290.71180℃老化434721262#老化前32.50.256120℃老化76.50.50150℃老化3335.5180℃老化无法流动-3#老化前32.50.237120℃老化860.46150℃老化2335210.67180℃老化无法流动-4#老化前660.469.2120℃老化92170.50150℃老化290.81180℃老化无法流动5#老化前292.50.287.6120℃老化393.50.399.2150℃老化2170.50180℃老化无法流动6#老化前392.50.2