烟气CEMS在线比对验收调试报告附表D.1-12计算公式(HJ-75-2017)

表D.3标准方法校准颗粒物CEMS计算公式,,,,,,,,,,

颗粒物,,,,,,,,,,

实测Y,CEMSX,,预测值yi^,,SYY,SXY,SXX,SE中间值,SY中间值,

6.0,5.89,,5.80,,1.1236,1.344786667,1.609515111,0.041437176,1.1,

5.4,6.03,,5.94,,2.7556,1.873586667,1.273888444,0.287162412,2.8,

6.5,6.36,,6.26,,0.3136,0.447253333,0.637868444,0.055437942,0.3,

6.5,7.04,,6.94,,0.3136,0.066453333,0.014081778,0.195196852,0.3,

7.4,7.63,,7.53,,0.1156,0.160253333,0.222155111,0.016753826,0.1,

6.5,6.39,,6.29,,0.3136,0.430453333,0.590848444,0.042260406,0.3,

7.4,6.93,,6.83,,0.1156,-0.077746667,0.052288444,0.322336037,0.1,

7.7,7.63,,7.53,,0.4096,0.301653333,0.222155111,0.029091884,0.4,

7.5,7.89,,7.79,,0.1936,0.321786667,0.534848444,0.083168945,0.2,

8.0,8.28,,8.18,,0.8836,1.054053333,1.257388444,0.031265598,0.9,

6.5,6.83,,6.73,,0.3136,0.184053333,0.108021778,0.0541288,0.3,

7.1,7.26,,7.16,,0.0016,0.004053333,0.010268444,0.003711922,0.0,

7.3,7.56,,7.46,,0.0576,0.09632,0.161068444,0.025509925,0.1,

7.8,7.67,,7.57,,0.5476,0.378386667,0.261461778,0.053233749,0.5,

8.3,7.99,,7.89,,1.5376,1.030853333,0.691115111,0.16975402,1.5,

7.060,7.159,,105.9,,7.8724,7.6162,7.646973333,1.410449494,8.996,

,,,,,,,SE,0.329,0.802,

f=n-1,14,,,,,,,,,

tdf,2.145,,,,,,,,,

vdf,1.4597,,,,,,,,,

n',15,,,,,,,,,

un',1.192,,,方程,Y=b0+b1X,最终结果,SE,0.329387484,,

截距,-0.069858401,,,,,,,,,

斜率,0.99597575,,,,,,,,,

CI,0.61%,,,,,,,,,

TI,1.91%,,,,,,,,,

,,,,,,,,,,,

,,,,,,,SY,0.801605532,,

,,,,,,,,,,,

,,,,,,,,,,,

,,,,,,,线性相关系数r,0.911676051,,

,mg/m3,ppm,,,,,,,,

量程SO2,500,50,,,,,,,,

量程NOX,500,150,,,,,,,,

量程O2,25,,,,,,b1斜率,0.99597575,,

量程流速,40,,,,,,,,,

量程颗粒物,300,,,,,,,,,

,,,,,,,b0截距,-0.06986,,

,,,,,,,,,,,

表D.2颗粒物CEMS零点和量程漂移检测,,,,,,,,,,

零点读数,,零点漂移绝对误差,,上标校推读数,,量程漂移绝对误差,,,,

起始(Z0),最终（Zi）,△Z=,,起始(S0),最终（Si）,△S=,,,,

0,0.36,0.36,,300,299.6,-0.4,,,,

0.36,0.25,-0.11,,301.1,300.8,-0.3,,,,

0.25,0.18,-0.07,,299.4,299.6,0.2,,,,

零点漂移绝对误差最大值,,0.36,,量程漂移绝对误差最大值,,-0.4,,,,

零点漂移,,0.12%,,量程漂移,,-0.1%,,,,

表D.4气态污染物CEMS（02）零点和量程漂移检测,,,,,,,,,,

零点读数,,零点漂移绝对误差,,上标校推读数,,量程漂移绝对误差,,,,

起始(Z0),最终（Zi）,△Z=,,起始(S0),最终（Si）,△S=,,,,

0,0.28,0.28,,21,20.67,-0.33,,,,

0.28,0.15,-0.13,,20.67,20.78,0.11,,,,

0.13,0.35,0.22,,20.78,20.95,0.17,,,,

零点漂移绝对误差最大值,,0.28,,量程漂移绝对误差最大值,,-0.33,,,,

零点漂移,,1.12%,,量程漂移,,-1.3%,漂移量=绝对误差最大值÷量程,,,

,,,,,,,注意单位一致性,,,

表D.5气态污染物CEMS（S02）零点和量程漂移检测,,,,,,,,,,

零点读数,,零点漂移绝对误差,,上标校推读数,,量程漂移绝对误差,,,,

起始(Z0),最终（Zi）,△Z=,,起始(S0),最终（Si）,△S=,,,,

0,0.31,0.31,,201.20,201.71,0.51,,,,

0.31,0.2,-0.11,,201.40,200.59,-0.81,,,,

0.2,0.05,-0.15,,200.92,201.14,0.22,,,,

零点漂移绝对误差最大值,,0.31,,量程漂移绝对误差最大值,,-0.81,,,,

零点漂移,,0.06%,,量程漂移,,-0.2%,漂移量=绝对误差最大值÷量程,,,

,,,,,,,注意单位一致性,,,

表D.5气态污染物CEMS（NOX）零点和量程漂移检测,,,,,,,,,,

零点读数,,零点漂移绝对误差,,上标校推读数,,量程漂移绝对误差,,,,

起始(Z0),最终（Zi）,△Z=,,起始(S0),最终（Si）,△S=,,,,

0,0.31,0.31,,201.20,201.71,0.51,,,,

0.31,0.2,-0.11,,201.40,200.59,-0.81,,,,

0.2,0.05,-0.15,,200.92,201.14,0.22,,,,

零点漂移绝对误差最大值,,0.31,,量程漂移绝对误差最大值,,-0.81,,,,

零点漂移,,0.06%,,量程漂移,,-0.2%,漂移量=绝对误差最大值÷量程,,,

,,,,,,,注意单位一致性,,,

表D.7气态污染物CEMS示值误差和响应时间检测,,,,,,,,,,

标准气体,CEMS显示值,CEMS显示值平均值,误差,,响应时间（S）,,,,,

SO2,327.4,328.3,-0.21%,,,,,,,

,328.6,,,,,,,,,

,328.8,,,,,,,,,

NOx,215.3,215.4,0.65%,,,,,,,

,215.9,,,,,,,,,

,215,,,,,,,,,

O2,19.96,19.98,-4.84%,,,,,,,

,20.01,,,,,,,,,

,19.98,,,,,,,,,

标气浓度SO2,329,ppm,329,mg/m3,,,,,,

标气浓度NOX,,ppm,214,mg/m3,,,,,,

标气浓度O2,,,21,%,,,,,,

表D.8标准方法评估气态污染物CEMS（气态参数）准确度,,,,,,,,,,

编号,标准方法A,CEMS方法B,数据对差=B-A,,,,,,,

1,48,48.72,0.72,,,,,,,

2,26,24.71,-1.29,,,,,,,

3,38,37.54,-0.46,,,,,,,

4,61,59.31,-1.69,,,,,,,

5,62,63.76,1.76,,,,,,,

6,58,57.76,-0.24,,,,,,,

7,82,84.51,2.51,,,,,,,

8,64,63.16,-0.84,,,,,,,

9,40,41.07,1.07,,,,,,,

参比方法平均值,53,,,,,,,,,

数据对差的平均值的绝对值,0.17,,,,,,,,,

数据对差的标准偏差,1.43,,,,,,,,,

置信系数,1.10,,,,,,,,,

相对准确度,0.024,,,,,,,,,

表D.10速度场系数检测表,,,,,,,,,,

方法,测定次数,,,,,,,,,

,1,2,3,4,5,平均值,标准偏差,相对标准偏差（%）,,

手工,7.23,7.40,7.26,7.50,7.52,7.38,1.6%,2%,,

CMS,7.49,7.65,7.67,7.72,7.60,7.63,,,,

速度场系数,1.04,1.03,1.06,1.03,1.01,1.03,,,,

手工,7.72,7.14,7.42,7.25,7.26,7.36,1.4%,1%,,

CMS,7.94,7.42,7.83,7.23,7.41,7.57,,,,

速度场系数,1.03,1.04,1.06,1.00,1.02,1.03,,,,

手工,7.54,7.36,7.81,7.52,7.39,7.52,0.1%,0%,,

CMS,7.61,7.45,7.37,7.77,7.51,7.54,,,,

速度场系数,1.01,1.01,0.94,1.03,1.02,1.00,,,,

速度场系数均值,1.02,标准偏差,1.0%,,,相对标准偏差（%）,,1.0%,,

,1.02144794,,,,,,,,,

表D.12颗粒物CEMS/流速CMS/温度CMS/湿度CMS准确度检测,,,,,,,,,,

序号,颗粒物重(mg),采气体积（NL）,浓度（mg/m3）,流速（m/s）,温度（°C）,湿度（%）,测定值（mg/m3）,流速（m/s）,温度（°C）,湿度（%）

1,5.49,1219.42,4.5,7.96,60.1,17.3,4.11,8.05,60.40,17.1

2,7.32,1306.41,5.6,7.91,59.8,17.2,5.56,7.92,59.43,17.1

3,6.18,1212.4,5.1,7.95,59.8,17.4,5.27,7.94,59.53,17.08

4,5.87,1174.26,5.0,7.88,59.6,17.3,5.32,7.92,59.41,17.07

5,6.78,1210.48,5.6,7.92,61.1,17.3,5.42,8.12,60.87,17.07

颗粒物浓度平均值（mg/m3）